[go: up one dir, main page]

BR9604923A - Método para a preparação de componentes catalisadores - Google Patents

Método para a preparação de componentes catalisadores

Info

Publication number
BR9604923A
BR9604923A BR9604923-5A BR9604923A BR9604923A BR 9604923 A BR9604923 A BR 9604923A BR 9604923 A BR9604923 A BR 9604923A BR 9604923 A BR9604923 A BR 9604923A
Authority
BR
Brazil
Prior art keywords
catalyst component
catalyst components
metallocene compound
carrier
metallocene
Prior art date
Application number
BR9604923-5A
Other languages
English (en)
Inventor
Hilkka Knuuttila
Harry Hokkanen
Eija Salo
Original Assignee
Borealis As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis As filed Critical Borealis As
Publication of BR9604923A publication Critical patent/BR9604923A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

Patente de Invenção:<B>"MéTODO PARA A PREPARAçãO DE COMPONENTES CATALISADORES"<D>. Método para a preparação de um componente catalisador para a homo- ou copolimerização de olefinas, compreendendo o componente catalisador pelo menos um composto de metaloceno sobre um carreador inorgânico poroso, no qual o composto de metaloceno é misturado na forma do composto puro, na ausência de solventes, com o carreador a uma temperatura de pelo menos 50°C, porém abaixo da temperatura de vaporização do composto de metaloceno nas condições no reator, por um tempo suficiente para a obteção do componente catalisador possuindo o metaloceno uniformemente distribuído sobre as partículas do carreador.
BR9604923-5A 1995-04-12 1996-04-10 Método para a preparação de componentes catalisadores BR9604923A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI951780A FI104975B (fi) 1995-04-12 1995-04-12 Menetelmä katalyyttikomponenttien valmistamiseksi
PCT/FI1996/000190 WO1996032423A1 (en) 1995-04-12 1996-04-10 Method of preparing catalyst components

Publications (1)

Publication Number Publication Date
BR9604923A true BR9604923A (pt) 1999-11-30

Family

ID=8543241

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9604923-5A BR9604923A (pt) 1995-04-12 1996-04-10 Método para a preparação de componentes catalisadores

Country Status (11)

Country Link
EP (1) EP0820475B1 (pt)
JP (1) JPH11503480A (pt)
KR (1) KR100287799B1 (pt)
CN (1) CN1094493C (pt)
AT (1) ATE184026T1 (pt)
AU (1) AU714949B2 (pt)
BR (1) BR9604923A (pt)
CA (1) CA2218095C (pt)
DE (1) DE69604063T2 (pt)
FI (1) FI104975B (pt)
WO (1) WO1996032423A1 (pt)

Families Citing this family (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7074863B2 (en) 2001-06-22 2006-07-11 Borealis Technology Oy Metallocene catalysts containing an idenyl moiety substituted at the 4,-5,-6- or 7-position by a siloxy or germyloxy group
ES2309445T3 (es) 2004-12-17 2008-12-16 Borealis Technology Oy Proceso para la polimerizacion de olefinas en presencia de un catalizador de polimerizacion de las mismas.
EP2072587B1 (en) 2007-12-20 2020-06-03 Borealis Technology Oy Coated pipes having improved mechanical properties at elevated temperatures and a method of production thereof
EP2072588B1 (en) 2007-12-20 2012-10-10 Borealis Technology Oy Process for coating a pipe with high throughput using multimodal ethylene copolymer, and coated pipes obtained thereof
PL2072586T3 (pl) 2007-12-20 2021-05-31 Borealis Technology Oy Powlekane rury o ulepszonych właściwościach mechanicznych i sposób ich wytwarzania
EP2072589A1 (en) 2007-12-20 2009-06-24 Borealis Technology Oy Process for coating a pipe with high throughput using multimodal ethylene copolymer, and coated pipes obtained thereof
EP2130860A1 (en) 2008-06-06 2009-12-09 Borealis Technology Oy Polymer
EP2223944A1 (en) 2009-02-26 2010-09-01 Borealis AG Process for producing semicrystalline propylene polymers
EA021843B1 (ru) 2009-11-13 2015-09-30 Бореалис Аг Способ полимеризации олефина
WO2011058088A1 (en) 2009-11-13 2011-05-19 Borealis Ag Process for recovering a transition metal compound
EP2322568B1 (en) 2009-11-13 2013-05-15 Borealis AG Process for producing an olefin polymerization catalyst
EP2499168B1 (en) 2009-11-13 2017-05-10 Borealis AG Process for recovering a transition metal compound
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
PL2495037T3 (pl) 2011-03-02 2021-01-11 Borealis Ag Zespół reaktora o wysokiej przepustowości do polimeryzacji olefin
PT2495038T (pt) 2011-03-02 2020-11-06 Borealis Ag Conjunto de reator flexível para polimerização de olefinas
EP2520625A1 (en) 2011-05-06 2012-11-07 Borealis AG Coating composition
CN104582829B (zh) 2012-08-29 2016-12-28 博里利斯股份公司 用于烯烃聚合的反应器装置和方法
EP2740748B1 (en) 2012-12-07 2015-06-10 Borealis AG Method of polymerizing olefins in slurry reactors
EP2745926A1 (en) 2012-12-21 2014-06-25 Borealis AG Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor
EP2745927A1 (en) 2012-12-21 2014-06-25 Borealis AG Fluidized bed reactor with internal moving bed reaction unit
EP2913345B1 (en) 2014-02-28 2016-11-02 Borealis AG Gas phase polymerization process
EP2913346B1 (en) 2014-02-28 2016-11-02 Borealis AG Process for polymerizing olefins in a fluidized bed
ES2635519T3 (es) 2014-11-21 2017-10-04 Borealis Ag Procedimiento para producir gránulos de copolímeros blandos
KR102006091B1 (ko) 2014-11-26 2019-07-31 보레알리스 아게 필름 층
US10385194B2 (en) 2014-11-26 2019-08-20 Borealis Ag Polyethylene composition for a film layer
ES2741846T3 (es) 2015-05-20 2020-02-12 Borealis Ag Proceso de producción de una composición de polietileno
ES2673428T3 (es) 2015-06-12 2018-06-21 Borealis Ag Procedimiento y aparato para la polimerización de olefinas en fase gaseosa
EP3178853B1 (en) 2015-12-07 2018-07-25 Borealis AG Process for polymerising alpha-olefin monomers
EP3184167B8 (en) 2015-12-22 2022-03-30 Borealis AG A method for returning polymer to a fluidised bed reactor
EP3184166A1 (en) 2015-12-22 2017-06-28 Borealis AG A method for withdrawing agglomerates from a fluidised bed reactor
EP3243622B1 (en) 2016-05-13 2020-09-09 Borealis AG Process for hydraulic conveying of polyolefin pellets
CN109415545A (zh) 2016-06-17 2019-03-01 博里利斯股份公司 具有增强的流变性能的双峰或多峰聚乙烯
EP3257879A1 (en) 2016-06-17 2017-12-20 Borealis AG Bi- or multimodal polyethylene with low unsaturation level
KR20190021323A (ko) 2016-06-17 2019-03-05 보레알리스 아게 낮은 불포화 수준을 갖는 이정 또는 다정 폴리에틸렌
ES2785685T3 (es) 2016-06-17 2020-10-07 Borealis Ag Terpolímero de polietileno bimodal o multimodal con propiedades reológicas potenciadas
EP3257895A1 (en) 2016-06-17 2017-12-20 Borealis AG Bi- or multimodal polyethylene terpolymer with enhanced rheological properties
EP3475318A1 (en) 2016-06-23 2019-05-01 Borealis AG Process for catalyst deactivation
EP3418309A1 (en) 2017-06-20 2018-12-26 Borealis AG A method, an arrangement and use of an arrangement of preparing polymer
ES2786756T3 (es) 2017-06-20 2020-10-13 Borealis Ag Un método, una disposición y uso de una disposición para la polimerización de olefinas
ES2786567T3 (es) 2017-06-23 2020-10-13 Borealis Ag Procedimiento y aparato para la retirada de material polimérico de un reactor de polimerización de olefinas con gases y sólido
CN111315567B (zh) 2017-10-24 2022-02-25 博里利斯股份公司 多层聚合物膜
EP3479896A1 (en) 2017-11-03 2019-05-08 Borealis AG Polymerization reactor system comprising at least one withdrawal valve
EP3483189A1 (en) 2017-11-14 2019-05-15 Borealis AG Automated method for terminating an olefin polymerization reaction under emergency conditions
ES2806646T3 (es) 2017-11-17 2021-02-18 Borealis Ag Procedimiento para mejorar la capacidad de enfriamiento de un reactor de polimerización de olefinas de gas-sólidos
ES2795985T3 (es) 2017-11-17 2020-11-25 Borealis Ag Procedimiento de división del gas de fluidización de retorno en un reactor de polimerización de olefinas de gas sólidos
CN111801357A (zh) 2018-03-02 2020-10-20 博里利斯股份公司 方法
WO2019180166A1 (en) 2018-03-21 2019-09-26 Borealis Ag Bi- or multimodal polyethylene composition
EP3807330A1 (en) 2018-06-14 2021-04-21 Borealis AG Process for polymerizing olefin in a gas phase reactor with improved thermal homogeneity
CN112424235B (zh) 2018-08-02 2023-04-21 北欧化工公司 在多阶段聚合工艺中聚合乙烯的方法
US20210363314A1 (en) 2018-11-07 2021-11-25 Borealis Ag Polyolefin composition with improved impact and whitening resistance
SG11202102319WA (en) 2018-11-15 2021-04-29 Abu Dhabi Polymers Co Ltd Borouge Polymer composition for blow molding applications
US20220119564A1 (en) 2018-11-29 2022-04-21 Borealis Ag Process to produce a polymer and polymer
WO2020244833A1 (en) 2019-06-04 2020-12-10 Name: Borealis Ag A process and a multi-stage reactor assembly for the production of polyolefins
EP3980177A1 (en) 2019-06-04 2022-04-13 Borealis AG Process and reactor assembly for the enhancement of hydrodynamics in a gas-solids fluidized bed reactor
US12291594B2 (en) 2019-06-24 2025-05-06 Borealis Ag Process for preparing polypropylene with improved recovery
US20220282074A1 (en) 2019-07-22 2022-09-08 Abu Dhabi Polymers Co. Ltd (Borouge) L.L.C., Single site catalysed multimodal polyethylene composition
EP3868793B1 (en) 2020-02-24 2026-01-07 Borealis GmbH Process for producing alpha-olefin polymers in a multistage polymerization process
EP4126994A1 (en) 2020-03-24 2023-02-08 Borealis AG Polyethylene composition for a film layer
EP4126993A1 (en) 2020-03-24 2023-02-08 Borealis AG Polyethylene composition for a film layer
EP4185620A1 (en) 2020-07-23 2023-05-31 Borealis AG Multimodal ethylene copolymer
CA3200063A1 (en) 2020-11-27 2022-06-02 Klaus Nyfors Catalyst feed system
EP4029914B1 (en) 2021-01-14 2025-03-05 Borealis AG Heterophasic polyolefin composition
CN117561286B (zh) 2021-06-24 2025-09-09 博里利斯股份公司 在多阶段聚烯烃生产中改善催化剂性能
WO2022268951A1 (en) 2021-06-24 2022-12-29 Borealis Ag Use of a swelling agent in multi-stage polyolefin production
KR20240023652A (ko) 2021-06-24 2024-02-22 보레알리스 아게 다단계 폴리올레핀 제조에서 1-헥센의 이용
KR20240023174A (ko) 2021-06-24 2024-02-20 보레알리스 아게 올레핀 중합 촉매의 압축 특성을 결정하는 방법
EP4116091A1 (en) 2021-07-07 2023-01-11 Borealis AG Multilayer film
EP4144435A1 (en) 2021-09-01 2023-03-08 Borealis AG Gas phase polymerization process with improved gas recycling
EP4163309A1 (en) 2021-10-07 2023-04-12 Borealis AG Hdpe
EP4163334A1 (en) 2021-10-10 2023-04-12 Borealis AG Polyethylene composition for a film layer
PL4257640T3 (pl) 2022-04-04 2025-03-24 Borealis Ag Rura zawierająca kompozycję polipropylonową
EP4317216A1 (en) 2022-08-03 2024-02-07 Abu Dhabi Polymers Co. Ltd (Borouge) LLC Low density ethylene terpolymer composition
EP4389414A1 (en) 2022-12-19 2024-06-26 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer collation shrink film
EP4389418A1 (en) 2022-12-19 2024-06-26 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer collation shrink film
WO2024223777A1 (en) 2023-04-26 2024-10-31 Borealis Ag Layer element suitable as integrated backsheet for a bifacial photovoltaic module
WO2024223775A1 (en) 2023-04-26 2024-10-31 Borealis Ag Layer element suitable as integrated backsheet for a bifacial photovoltaic module
EP4455170A1 (en) 2023-04-28 2024-10-30 Borealis AG Cable compositions comprising a multimodal ethylene-butene-hexene terpolymer
EP4541583A1 (en) 2023-10-18 2025-04-23 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer film
EP4574848A1 (en) 2023-12-19 2025-06-25 Borealis AG Polypropylene copolymer composition having high molecular weight
WO2025219499A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Processes for polymerising olefins
WO2025262147A1 (en) 2024-06-19 2025-12-26 Borealis Gmbh Processes for polymerising olefins
WO2026002813A1 (en) 2024-06-24 2026-01-02 Borealis Gmbh Processes for polymerising olefins
EP4674614A1 (en) 2024-07-04 2026-01-07 Borealis GmbH A polyethylene mdo film with high stiffness, adhesion and improved barrier forming capabilities
WO2026022206A1 (en) 2024-07-25 2026-01-29 Borealis Gmbh Mixed-plastics polyethylene composition suitable for film applications
EP4685183A1 (en) 2024-07-25 2026-01-28 Borealis GmbH Mixed-plastics polyethylene composition suitable for film applications

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US5147949A (en) * 1988-03-29 1992-09-15 Exxon Chemical Patents Inc. Polymerization process using a silica gel supported metallocene-alumoxane catalyst
FI96866C (fi) * 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
FI95276C (fi) * 1993-12-03 1996-01-10 Borealis As Olefiinien polymerointikatalyytti ja menetelmä sen valmistamiseksi

Also Published As

Publication number Publication date
DE69604063T2 (de) 2000-03-30
KR19980703734A (ko) 1998-12-05
CA2218095C (en) 2005-06-14
CN1094493C (zh) 2002-11-20
ATE184026T1 (de) 1999-09-15
CN1184489A (zh) 1998-06-10
AU714949B2 (en) 2000-01-13
CA2218095A1 (en) 1996-10-17
DE69604063D1 (de) 1999-10-07
KR100287799B1 (ko) 2001-04-16
FI951780A0 (fi) 1995-04-12
FI951780L (fi) 1996-10-13
FI104975B (fi) 2000-05-15
AU5336196A (en) 1996-10-30
JPH11503480A (ja) 1999-03-26
EP0820475B1 (en) 1999-09-01
EP0820475A1 (en) 1998-01-28
WO1996032423A1 (en) 1996-10-17

Similar Documents

Publication Publication Date Title
BR9604923A (pt) Método para a preparação de componentes catalisadores
BR9807689A (pt) uras
BR9904880A (pt) Componente catalìco prepolimerizado para a polimerização de olefinas ch2=chr,processo para a sua preparação, catalisador e processo de polimeração de olefinas ch2=chr
BR9813989A (pt) Composto, processo para prepará-lo, uso do mesmo, composição farmacêutica, e, processo para o tratamento de um paciente sofrendo de uma condição
DK0665844T3 (da) Substituerede benzylaminoquinuclidinforbindelser som antagonister af substans P
NO890862L (no) Fremgangsmaate for fremstilling av monoolefiner ved katalytisk oksydativ dehydrogenering av gassformige paraffiniskehydrokarboner som har to eller flere karbonatomer.
ES2196344T3 (es) Derivados de sulfonamida y su uso en el tratamiento de trastornos de snc.
EP0742227A3 (en) Catalyst for producing hemi-isotactic polyproylene and composition containing said hemi-isotactic polypropylene
ES2179372T3 (es) Composicion de silico-aluminio-fosfato cristalino y microporoso, material catalitico que comprende dicha composicion y uso de estos para produccion de olefinas a partir de metanol.
ES2175837T3 (es) Talco, que contiene compuestos de plipropileno.
ATE37179T1 (de) Dihydropyridazinone.
BRPI0417948A (pt) derivados de quinuclidina substituìda por bicicloheterociclo fundido
MX165691B (es) Mejoras a composiciones extruibles que contienen poliolefina y metodos para su formacion en productos elastomericos
MY109434A (en) Fluoroaliphatic dimer acid derivatives and use thereof
HUP0202191A2 (hu) A koagulációs kaszkád szelektív gátlására alkalmas helyettesített policiklusos aril- és heteroaril-pirazinonok, valamint az ezeket tartalmazó gyógyszerkészítmények
BR9910031A (pt) Processo para hidrogenação de fenil acetileno em um meio contento estireno com auxìlio de um catalisador
GB9817272D0 (en) Liquid crystalline compounds
CA2010272A1 (en) Benzenesulfonamides and a process for their preparation
BR0103843A (pt) Sistema de aditivo polimérico, processo para produzir o mesmo, composição polimérica, e, processo para produzir a mesma
BR9808042A (pt) Composto, composição farmacêutica, e, processo para preparação de compostos.
KR900014389A (ko) 아데노신 수용체 선택성 약제
KR910004557A (ko) 2,4,6-치환 페놀 유도체
BR0014579A (pt) Composição refrigerante
EP0383346A3 (en) Catalyst, process for its preparation and process for polymerization of olefins using this catalyst
KR890002106A (ko) 치환된 벤즈 이미다졸, 이의 제조방법, 이를 함유하는 약제학적 제형, 및 이의 용도

Legal Events

Date Code Title Description
FB36 Technical and formal requirements: requirement - article 36 of industrial property law
FF Decision: intention to grant
FG9A Patent or certificate of addition granted
B24C Patent annual fee: request for for restoration

Free format text: REFERENTE A 15A ANUIDADE.

B24H Lapse because of non-payment of annual fees (definitively: art 78 iv lpi)
B24F Patent annual fee: publication cancelled

Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2258 DE 15/04/2014 POR TER SIDO INDEVIDA.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 15A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2607 DE 22-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.