BR9501859A - Copolimeros de baixa viscosidade contendo grupos hidroxila e carboxila processo para sua preparação aplicação lacas de um componente e lacas de dois componentes - Google Patents
Copolimeros de baixa viscosidade contendo grupos hidroxila e carboxila processo para sua preparação aplicação lacas de um componente e lacas de dois componentesInfo
- Publication number
- BR9501859A BR9501859A BR9501859A BR9501859A BR9501859A BR 9501859 A BR9501859 A BR 9501859A BR 9501859 A BR9501859 A BR 9501859A BR 9501859 A BR9501859 A BR 9501859A BR 9501859 A BR9501859 A BR 9501859A
- Authority
- BR
- Brazil
- Prior art keywords
- component
- hydroxyl groups
- low viscosity
- copolymers containing
- containing hydroxyl
- Prior art date
Links
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 title abstract 4
- 229920001577 copolymer Polymers 0.000 title abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 title 1
- 239000004922 lacquer Substances 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 239000011230 binding agent Substances 0.000 abstract 2
- 239000003973 paint Substances 0.000 abstract 2
- 239000004848 polyfunctional curative Substances 0.000 abstract 2
- 229920001228 polyisocyanate Polymers 0.000 abstract 2
- 239000005056 polyisocyanate Substances 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- 229920003180 amino resin Polymers 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- -1 glycidyl ester Chemical class 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
- C08G18/6258—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids the acid groups being esterified with polyhydroxy compounds or epoxy compounds during or after polymerization
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Epoxy Resins (AREA)
- Polyurethanes Or Polyureas (AREA)
- Supply Devices, Intensifiers, Converters, And Telemotors (AREA)
- Liquid Developers In Electrophotography (AREA)
- Apparatus For Radiation Diagnosis (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4415319A DE4415319A1 (de) | 1994-05-02 | 1994-05-02 | Hydroxy- und Carboxylgruppen enthaltende Copolymerisate, ihre Herstellung und ihre Verwendung in festkörperreichen Beschichtungsmitteln |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9501859A true BR9501859A (pt) | 1996-03-05 |
Family
ID=6516998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9501859A BR9501859A (pt) | 1994-05-02 | 1995-04-28 | Copolimeros de baixa viscosidade contendo grupos hidroxila e carboxila processo para sua preparação aplicação lacas de um componente e lacas de dois componentes |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5663265A (pt) |
| EP (1) | EP0680977B1 (pt) |
| JP (1) | JPH0841108A (pt) |
| KR (1) | KR950032336A (pt) |
| CN (1) | CN1112569A (pt) |
| AT (1) | ATE164600T1 (pt) |
| AU (1) | AU687520B2 (pt) |
| BR (1) | BR9501859A (pt) |
| CA (1) | CA2147723C (pt) |
| CZ (1) | CZ112895A3 (pt) |
| DE (2) | DE4415319A1 (pt) |
| DK (1) | DK0680977T3 (pt) |
| ES (1) | ES2116644T3 (pt) |
| ZA (1) | ZA953434B (pt) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4435950A1 (de) | 1994-10-07 | 1996-04-11 | Hoechst Ag | Copolymerisate mit cyclischen oder polycyclischen Monomeren mit einer speziellen Isomerenverteilung und deren Einsatz in Beschichtungsmitteln |
| DE4442769A1 (de) * | 1994-12-01 | 1996-06-05 | Hoechst Ag | Niedermolekulare funktionelle Copolymerisate, Verfahen zu ihrer Herstellung und ihre Verwendung |
| AU703551B2 (en) * | 1995-05-02 | 1999-03-25 | Hoechst Aktiengesellschaft | Hydroxyl-functional copolymers of low molar mass with substantial side-chain branching, process for their preparation, and their use |
| DE19515919A1 (de) * | 1995-05-02 | 1996-11-07 | Hoechst Ag | Neue niedermolekulare OH-funktionelle Copolymerisate mit hoher Seitenkettenverzweigung, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
| DE19628444A1 (de) * | 1996-07-15 | 1998-01-22 | Bayer Ag | Neue festkörperreiche 2 K-PUR-Bindemittelkombinationen |
| DE19704020A1 (de) * | 1997-02-04 | 1998-08-06 | Herberts Gmbh | Hydroxylgruppenhaltige Copolymerisate und Verfahren zu ihrer Herstellung |
| US6310139B1 (en) | 1999-08-31 | 2001-10-30 | Reichhold, Inc. | Burnish resistant powder coating compositions |
| DE10033512A1 (de) | 2000-07-11 | 2002-01-24 | Solutia Austria Gmbh Werndorf | Aliphatisch niedermolekulare Polyesterpolyole, deren Herstellung und Verwendung in hochwertigen Beschichtungsmitteln |
| WO2002046252A1 (en) * | 2000-12-08 | 2002-06-13 | Resolution Research Nederland B.V. | Irradiation curable, high solid coating compositions and their preparation |
| US20020156221A1 (en) * | 2001-02-20 | 2002-10-24 | Meyer Gerald Wayne | High solids acrylic resin |
| AT411762B (de) | 2001-12-13 | 2004-05-25 | Solutia Austria Gmbh | Hydroxylgruppen-haltige polymere, deren herstellung und verwendung |
| US6881786B2 (en) * | 2002-05-20 | 2005-04-19 | Ppg Industries Ohio, Inc. | One-component, waterborne film-forming composition |
| KR100518793B1 (ko) * | 2002-10-01 | 2005-10-04 | 주식회사 케이씨씨 | 하이솔리드 폴리에스테르 수지 및 이의 제조방법 |
| US20070066777A1 (en) * | 2004-09-03 | 2007-03-22 | Bzowej Eugene I | Methods for producing crosslinkable oligomers |
| MX339547B (es) * | 2012-03-02 | 2016-05-30 | Basf Coatings Gmbh | Proceso para producir un revestimiento de pintura de multicapa que imparte color y/o efecto. |
| FR3091281B1 (fr) * | 2018-12-26 | 2021-06-18 | Arkema France | Procédé de purification de l’hydroperoxyde d’alkyle par extraction à l’eau et séparation de la phase aqueuse |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE608C (de) * | 1877-08-21 | G. GÖBEL, Maschinen-Fabrikant, in Darmstadt | Tachograph zum Anzeigen der Fahrgeschwindigkeit von Lokomotiven | |
| US3330814A (en) * | 1963-05-27 | 1967-07-11 | Du Pont | Hydroxyl-containing copolymers |
| US3644255A (en) * | 1969-12-09 | 1972-02-22 | Du Pont | Stable dispersions |
| US4123401A (en) * | 1975-07-21 | 1978-10-31 | E. I. Du Pont De Nemours And Company | Finishes having improved scratch resistance prepared from compositions of fluoropolymer, mica particles or metal flake, a polymer of monoethylenically unsaturated monomers and a liquid carrier |
| DE2732693C3 (de) * | 1977-07-20 | 1980-04-17 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von in organischen Lösungsmitteln löslichen hydroxylgruppenhaltigen Copolymerisaten |
| DE2851613C2 (de) * | 1978-11-29 | 1983-04-28 | Synthopol Chemie Dr. rer. pol. Koch & Co, 2150 Buxtehude | Verfahren zur Herstellung von in organischen Lösungsmitteln löslichen hydroxylgruppentragenden Copolymerisaten |
| DE2942327A1 (de) * | 1979-10-19 | 1981-05-14 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von oh-gruppen enthaltenden copolymerisaten |
| DE3101887A1 (de) * | 1981-01-22 | 1982-09-02 | Hoechst Ag, 6000 Frankfurt | "verfahren zur herstellung von copolymerisaten und verwendung der erhaltenen produkte" |
| DE3740774A1 (de) * | 1987-12-02 | 1989-06-15 | Herberts Gmbh | Bindemittel, verfahren zu dessen herstellung und dessen verwendung in klaren oder pigmentierten ueberzugsmitteln |
| US5179157A (en) * | 1990-01-20 | 1993-01-12 | Synthopol Chemie Dr. Rer. Pol. Koch Gmbh & Co., Kg | Copolymerizate solutions based on addition products of α,β-unsaturated carboxylic acids with glycidyl esters and of α,β-unsaturated monomers which can be copolymerized with them |
| US5180773A (en) * | 1990-01-20 | 1993-01-19 | Synthopol Chemie Dr. Rer. Pol. Koch Gmbh & Co., Kg | Copolymerizate solutions based on addition products of α,β-unsaturated carboxylic acids with glycidyl esters and of α,β-unsaturated monomers which can be copolymerized with them |
| DE59105478D1 (de) * | 1990-01-20 | 1995-06-22 | Synthopol Chemie Dr Koch | Copolymerisatlösungen auf der Basis von Additionsprodukten alpha,beta-ungesättigter Carbonsäure mit Glycidylestern und damit mischpolymerisierbarer alpha,beta-ungesättigter Monomerer. |
| DE4124167A1 (de) * | 1991-07-20 | 1993-01-21 | Synthopol Chemie Dr Koch | Copolymerisatloesungen auf der basis von additionsprodukten (alpha), (beta)-ungesaettigter carbonsaeure mit glycidylestern und damit mischpolymerisierbarer (alpha), (beta)-ungesaettigter monomerer |
| DE4025347A1 (de) * | 1990-08-10 | 1992-02-13 | Bayer Ag | Verwendung von zweikomponenten-bindemittelkombinationen in autoreparaturlacken |
| DE4324801A1 (de) * | 1993-07-23 | 1995-01-26 | Hoechst Ag | Verfahren zur Herstellung von OH-Gruppen enthaltenden Copolymerisaten und deren Verwendung in festkörperreichen Beschichtungsmitteln |
-
1994
- 1994-05-02 DE DE4415319A patent/DE4415319A1/de not_active Withdrawn
-
1995
- 1995-04-19 US US08/424,081 patent/US5663265A/en not_active Expired - Lifetime
- 1995-04-24 ES ES95106087T patent/ES2116644T3/es not_active Expired - Lifetime
- 1995-04-24 CA CA002147723A patent/CA2147723C/en not_active Expired - Fee Related
- 1995-04-24 AT AT95106087T patent/ATE164600T1/de not_active IP Right Cessation
- 1995-04-24 EP EP95106087A patent/EP0680977B1/de not_active Expired - Lifetime
- 1995-04-24 DE DE59501745T patent/DE59501745D1/de not_active Expired - Lifetime
- 1995-04-24 DK DK95106087T patent/DK0680977T3/da active
- 1995-04-28 ZA ZA953434A patent/ZA953434B/xx unknown
- 1995-04-28 CN CN95105199A patent/CN1112569A/zh active Pending
- 1995-04-28 BR BR9501859A patent/BR9501859A/pt not_active IP Right Cessation
- 1995-04-28 AU AU17706/95A patent/AU687520B2/en not_active Expired - Fee Related
- 1995-05-01 JP JP7107658A patent/JPH0841108A/ja not_active Withdrawn
- 1995-05-02 KR KR1019950010703A patent/KR950032336A/ko not_active Withdrawn
- 1995-05-02 CZ CZ951128A patent/CZ112895A3/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE4415319A1 (de) | 1995-11-09 |
| AU687520B2 (en) | 1998-02-26 |
| DK0680977T3 (da) | 1998-10-19 |
| CZ112895A3 (en) | 1995-11-15 |
| AU1770695A (en) | 1995-11-09 |
| ATE164600T1 (de) | 1998-04-15 |
| KR950032336A (ko) | 1995-12-20 |
| CA2147723A1 (en) | 1995-11-03 |
| JPH0841108A (ja) | 1996-02-13 |
| DE59501745D1 (de) | 1998-05-07 |
| CA2147723C (en) | 2006-01-24 |
| ZA953434B (en) | 1996-01-29 |
| US5663265A (en) | 1997-09-02 |
| ES2116644T3 (es) | 1998-07-16 |
| EP0680977B1 (de) | 1998-04-01 |
| EP0680977A1 (de) | 1995-11-08 |
| CN1112569A (zh) | 1995-11-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB36 | Technical and formal requirements: requirement - article 36 of industrial property law | ||
| FF | Decision: intention to grant | ||
| PC | Transfer |
Owner name: SOLUTIA GERMANY GMBH & CO. KG (DE) |
|
| FG9A | Patent or certificate of addition granted | ||
| B24C | Patent annual fee: request for for restoration |
Free format text: REFERENTE 10A., 11A., 12A., 13A., 14A., 15A. E 16A. ANUIDADE(S). |
|
| B24H | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi) | ||
| B24F | Patent annual fee: publication cancelled |
Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2258 DE 15/04/2014 POR TER SIDO INDEVIDA. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE AS 10A, 11A, 12A, 13A, 14A, 15A E 16A ANUIDADES. |
|
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2607 DE 22-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |