BR9206868A - Processo para formar uma suspensão de partículas compósitas discretas,suspensão,e,partícula multi-compósita discreta - Google Patents
Processo para formar uma suspensão de partículas compósitas discretas,suspensão,e,partícula multi-compósita discretaInfo
- Publication number
- BR9206868A BR9206868A BR9206868A BR9206868A BR9206868A BR 9206868 A BR9206868 A BR 9206868A BR 9206868 A BR9206868 A BR 9206868A BR 9206868 A BR9206868 A BR 9206868A BR 9206868 A BR9206868 A BR 9206868A
- Authority
- BR
- Brazil
- Prior art keywords
- suspension
- discrete
- forming
- composite
- composite particles
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
- C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/007—Metal oxide
- C09D17/008—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/19—Oil-absorption capacity, e.g. DBP values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
- C08L21/02—Latex
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80197591A | 1991-12-03 | 1991-12-03 | |
| US80197491A | 1991-12-03 | 1991-12-03 | |
| US07/801,992 US6080802A (en) | 1991-12-03 | 1991-12-03 | Process for preparing an aqueous dispersion of composite particles including polymeric latex adsorbed to titanium dioxide |
| PCT/US1992/009731 WO1993012184A1 (en) | 1991-12-03 | 1992-11-12 | Process for particle adsorption |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9206868A true BR9206868A (pt) | 1995-11-21 |
Family
ID=27419981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9206868A BR9206868A (pt) | 1991-12-03 | 1992-11-12 | Processo para formar uma suspensão de partículas compósitas discretas,suspensão,e,partícula multi-compósita discreta |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0615535B1 (pt) |
| JP (1) | JP3535156B2 (pt) |
| CN (1) | CN1046302C (pt) |
| AU (1) | AU670926B2 (pt) |
| BR (1) | BR9206868A (pt) |
| CA (1) | CA2124849A1 (pt) |
| DE (1) | DE69225602T2 (pt) |
| ES (1) | ES2118839T3 (pt) |
| IL (1) | IL103858A0 (pt) |
| MX (1) | MX9206987A (pt) |
| MY (1) | MY111334A (pt) |
| NZ (1) | NZ245245A (pt) |
| WO (1) | WO1993012184A1 (pt) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5385960A (en) * | 1991-12-03 | 1995-01-31 | Rohm And Haas Company | Process for controlling adsorption of polymeric latex on titanium dioxide |
| GB9127293D0 (en) * | 1991-12-23 | 1992-02-19 | Ici Plc | Coating pigment particles with polymers |
| US5454864A (en) * | 1992-02-12 | 1995-10-03 | Whalen-Shaw; Michael | Layered composite pigments and methods of making same |
| GB9500497D0 (en) * | 1995-01-11 | 1995-03-01 | Tioxide Group Services Ltd | Gloss emulsion paints |
| GB9602221D0 (en) * | 1996-02-03 | 1996-04-03 | Tioxide Group Services Ltd | Composite pigmentary material |
| GB9502982D0 (en) * | 1995-02-16 | 1995-04-05 | Tioxide Group Services Ltd | Composite pigmentary material |
| GB9504962D0 (en) * | 1995-03-11 | 1995-04-26 | Tioxide Group Services Ltd | Composite pigmentary material |
| EP0823450B1 (en) * | 1995-04-25 | 2004-11-24 | Mitsubishi Rayon Co., Ltd. | Composite and moldings produced therefrom |
| JP3364117B2 (ja) | 1997-08-06 | 2003-01-08 | 三菱重工業株式会社 | 微粒子分散液及びその製造方法 |
| FR2773167A1 (fr) * | 1997-12-30 | 1999-07-02 | Rhodia Chimie Sa | Procede de preparation de flocs mineraux mixtes a base de tio2, composition a base de tio2 et de sio2 et son utilisation a titre d'agent opacifiant notamment en industrie papetiere |
| US6214467B1 (en) | 1998-07-24 | 2001-04-10 | Rohm And Haas Company | Polymer-pigment composites |
| AU4206300A (en) * | 1999-04-07 | 2000-10-23 | Kimberly-Clark Worldwide, Inc. | Creping adhesive and products and process incorporating same |
| JP4903932B2 (ja) * | 2000-08-24 | 2012-03-28 | ケミプロ化成株式会社 | 二元金属粒子コロイド分散液の製造方法 |
| US6638998B2 (en) | 2001-04-18 | 2003-10-28 | Basf Ag | Use of surfactants for improving the compatibility of inorganic pigments in aqueous coating compositions |
| US7186770B2 (en) | 2002-02-25 | 2007-03-06 | E. I. Du Pont De Nemours And Company | Unfinished rutile titanium dioxide slurry for paints and paper coatings |
| CN100347247C (zh) * | 2002-12-26 | 2007-11-07 | 米克斯服务有限公司 | 颜料团聚体,其制备方法及其用途 |
| EP1582567B2 (en) * | 2004-04-01 | 2011-11-16 | Rohm And Haas Company | Aqueous coating composition |
| ATE462766T1 (de) | 2004-05-12 | 2010-04-15 | Alpha Calcit Fuellstoff Gmbh | Oberflächenmodifizierte anorganische füllstoffe und pigmente |
| FR2873047B1 (fr) * | 2004-07-13 | 2007-10-05 | Coatex Soc Par Actions Simplif | Procede de broyage de matieres minerales en presence de liants, suspensions aqueuses obtenues et leurs utilisations |
| FR2873046B1 (fr) * | 2004-07-13 | 2007-11-02 | Coatex Soc Par Actions Simplif | Procede de broyage de matieres minerales en presence d'epaississants, suspensions aqueuses obtenues et leurs utilisations |
| US7482054B2 (en) | 2004-08-09 | 2009-01-27 | Behr Process Corporation | Pigment spacing |
| US7947763B2 (en) | 2004-08-09 | 2011-05-24 | Behr Process Corporation | Exterior deep base paint formulation |
| US7642309B2 (en) | 2004-08-09 | 2010-01-05 | Behr Process Corporation | Exterior paint formulation |
| DE102004054048A1 (de) * | 2004-11-05 | 2006-05-11 | Basf Ag | Beschichtungsmassen |
| CN102081985A (zh) * | 2006-07-04 | 2011-06-01 | 住友化学株式会社 | 高分子电解质乳液及其用途 |
| PL2158359T3 (pl) * | 2007-06-08 | 2014-04-30 | Fpinnovations | Zawiesiny wypełniacza poddanego obróbce lateksem do stosowania w produkcji papieru |
| CN101462891B (zh) * | 2008-10-16 | 2012-09-19 | 中国科学院长春应用化学研究所 | 动态可逆调控固体材料表面润湿性的方法 |
| US9238747B2 (en) | 2008-11-17 | 2016-01-19 | Basf Se | Stain blocking compositions |
| JP5520752B2 (ja) * | 2010-09-01 | 2014-06-11 | 株式会社日立製作所 | 粘着シート,粘着シートを用いた光学部材,有機発光素子および照明装置並びにそれらの製造方法 |
| JP5580860B2 (ja) * | 2011-10-14 | 2014-08-27 | ローム アンド ハース カンパニー | 着色塗料における隠蔽効率を向上させる方法 |
| CA2818446C (en) * | 2012-07-31 | 2021-03-02 | Rohm And Haas Company | Sulfonic acid monomer based compositions |
| AU2013386771B2 (en) * | 2013-04-15 | 2018-02-22 | Dow Global Technologies Llc | Polymer particles adsorbed to sulfate-process titanium dioxide |
| CN105873960B (zh) | 2014-01-10 | 2018-07-24 | 旭化成株式会社 | 水性复合颗粒分散体 |
| CN104893399A (zh) * | 2014-03-07 | 2015-09-09 | 陶氏环球技术有限公司 | 含有三胺官能化的分散剂的涂料组合物 |
| WO2018181267A1 (ja) * | 2017-03-31 | 2018-10-04 | ナガセテクノエンジニアリング株式会社 | 粒子膜の製造方法、静電噴霧用液、及び、粒子膜 |
| WO2020076248A2 (en) * | 2018-04-02 | 2020-04-16 | Ates Erdal | Water-based liquid adhesive |
| JP7326683B2 (ja) * | 2019-09-18 | 2023-08-16 | 株式会社Screenホールディングス | 顔料組成物、化粧品組成物及びインクジェット用インク組成物 |
| CN114315207A (zh) * | 2021-12-16 | 2022-04-12 | 中国铁道科学研究院集团有限公司铁道建筑研究所 | 一种铁路混凝土用火成岩质矿物材料及其制备方法 |
| WO2025212750A1 (en) * | 2024-04-03 | 2025-10-09 | Seer, Inc. | Biomolecule preparation methods, kits, and systems |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1766592A (en) | 1928-03-13 | 1930-06-24 | Commercial Pigments Corp | Production of composite pigments containing titanium dioxide |
| US4025483A (en) * | 1975-10-06 | 1977-05-24 | Scm Corporation | Stabilizing aqueous titanium dioxide pigment slurries by blending therewith plastic particles |
| CA1226400A (en) * | 1982-12-09 | 1987-09-01 | Philip M. Smith | Opacification of paint |
| GB2220666B (en) * | 1988-07-13 | 1992-01-02 | Ecc Int Ltd | Treated inorganic filler |
| US4818783A (en) * | 1986-11-07 | 1989-04-04 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of aqueous dispersion of inorganic pigment |
| GB8808755D0 (en) * | 1988-04-13 | 1988-05-18 | Crown Decorative Prod Ltd | Aqueous surface coatings |
| GB8909730D0 (en) * | 1989-04-27 | 1989-06-14 | Ici Plc | Inorganic particles |
| DE3932816A1 (de) * | 1989-09-30 | 1991-04-11 | Hoechst Ag | Verwendung von vernetzten polymermikroteilchen in lacken als fuellstoffersatz und/oder als vernetzender fuellstoff |
| BR9206867A (pt) * | 1991-12-03 | 1995-11-21 | Rohm & Haas | Processos para preparar uma dispersão aquosa de partículas compósitas para preparar uma composição aquosa dispersão aquosa de partículas compósitas composição de revestimento suspensão de pigmento e processo para preparar uma dispersão aquosa de partículas compósitas |
-
1992
- 1992-11-12 BR BR9206868A patent/BR9206868A/pt not_active IP Right Cessation
- 1992-11-12 WO PCT/US1992/009731 patent/WO1993012184A1/en not_active Ceased
- 1992-11-12 DE DE69225602T patent/DE69225602T2/de not_active Expired - Lifetime
- 1992-11-12 ES ES92925162T patent/ES2118839T3/es not_active Expired - Lifetime
- 1992-11-12 CA CA002124849A patent/CA2124849A1/en not_active Abandoned
- 1992-11-12 EP EP92925162A patent/EP0615535B1/en not_active Expired - Lifetime
- 1992-11-12 JP JP51090493A patent/JP3535156B2/ja not_active Expired - Fee Related
- 1992-11-12 AU AU31331/93A patent/AU670926B2/en not_active Expired
- 1992-11-24 IL IL103858A patent/IL103858A0/xx unknown
- 1992-11-24 NZ NZ245245A patent/NZ245245A/en unknown
- 1992-11-25 MY MYPI92002149A patent/MY111334A/en unknown
- 1992-12-03 MX MX9206987A patent/MX9206987A/es not_active IP Right Cessation
- 1992-12-03 CN CN92113746A patent/CN1046302C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| IL103858A0 (en) | 1993-04-04 |
| NZ245245A (en) | 1995-10-26 |
| MY111334A (en) | 1999-11-30 |
| CN1046302C (zh) | 1999-11-10 |
| AU670926B2 (en) | 1996-08-08 |
| JP3535156B2 (ja) | 2004-06-07 |
| AU3133193A (en) | 1993-07-19 |
| MX9206987A (es) | 1993-08-01 |
| EP0615535A1 (en) | 1994-09-21 |
| DE69225602T2 (de) | 1998-11-26 |
| WO1993012184A1 (en) | 1993-06-24 |
| DE69225602D1 (de) | 1998-06-25 |
| ES2118839T3 (es) | 1998-10-01 |
| CN1073959A (zh) | 1993-07-07 |
| EP0615535B1 (en) | 1998-05-20 |
| CA2124849A1 (en) | 1993-06-24 |
| JPH07508047A (ja) | 1995-09-07 |
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