BR8006086A - Processo para a conversao catalitica homogenea de metanol em acetato de metila ou de metanol em etanol, acetaldeido ou suas misturas - Google Patents
Processo para a conversao catalitica homogenea de metanol em acetato de metila ou de metanol em etanol, acetaldeido ou suas misturasInfo
- Publication number
- BR8006086A BR8006086A BR8006086A BR8006086A BR8006086A BR 8006086 A BR8006086 A BR 8006086A BR 8006086 A BR8006086 A BR 8006086A BR 8006086 A BR8006086 A BR 8006086A BR 8006086 A BR8006086 A BR 8006086A
- Authority
- BR
- Brazil
- Prior art keywords
- methanol
- acetaldehyde
- ethanol
- mixtures
- methyl acetate
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title 6
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 title 2
- LFQSCWFLJHTTHZ-HQMMCQRPSA-N Ethanol-14C Chemical compound C[14CH2]O LFQSCWFLJHTTHZ-HQMMCQRPSA-N 0.000 title 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 title 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0255—Phosphorus containing compounds
- B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
- B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0211—Metal clusters, i.e. complexes comprising 3 to about 1000 metal atoms with metal-metal bonds to provide one or more all-metal (M)n rings, e.g. Rh4(CO)12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7856379A | 1979-09-24 | 1979-09-24 | |
| US7856479A | 1979-09-24 | 1979-09-24 | |
| US06/180,863 US4320230A (en) | 1979-09-24 | 1980-08-25 | Methanol homologation using iron-cobalt carbonyl cluster catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR8006086A true BR8006086A (pt) | 1981-04-07 |
Family
ID=27373307
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR8006086A BR8006086A (pt) | 1979-09-24 | 1980-09-23 | Processo para a conversao catalitica homogenea de metanol em acetato de metila ou de metanol em etanol, acetaldeido ou suas misturas |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US4320230A (pt) |
| EP (1) | EP0027000B1 (pt) |
| JP (1) | JPS56115730A (pt) |
| AU (1) | AU542341B2 (pt) |
| BR (1) | BR8006086A (pt) |
| CA (1) | CA1156258A (pt) |
| DE (1) | DE3064142D1 (pt) |
| ZA (1) | ZA805926B (pt) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3045891C2 (de) * | 1980-12-05 | 1983-03-03 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | Verfahren zur Herstellung von Acetaldehyd und Ethanol |
| US4389532A (en) * | 1982-05-10 | 1983-06-21 | Eastman Kodak Company | Process for the preparation of acetaldehyde |
| US4429165A (en) | 1982-06-24 | 1984-01-31 | Union Carbide Corporation | Hydroformylation process |
| US4476334A (en) * | 1983-05-26 | 1984-10-09 | The United States Department Of Energy | Methanol production method and system |
| US4613623A (en) * | 1985-07-23 | 1986-09-23 | The United States Of America As Represented By The United States Department Of Energy | Low temperature synthesis of methyl formate |
| US4628121A (en) * | 1985-09-27 | 1986-12-09 | The Halcon Sd Group, Inc. | Preparation of acetaldehyde |
| US4842641A (en) * | 1988-04-20 | 1989-06-27 | Gaf Corporation | Synthesis of iron-cobalt powders |
| ES2147755T3 (es) * | 1992-05-12 | 2000-10-01 | Squibb & Sons Inc | Procedimiento de moldeo de articulos de plastico y articulos asi producidos. |
| TW592819B (en) * | 2001-05-18 | 2004-06-21 | Kevin Dale Allen | One-step production of 1,3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst |
| AU2003229445A1 (en) * | 2002-05-20 | 2003-12-02 | Woodland Chemical Systems Inc. | A process for producing ethanol from organic material |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA709857A (en) | 1965-05-18 | Hohenschutz Heinz | Production of acetic acid or mixtures of the same with methyl acetate | |
| DE1250800B (de) * | 1959-06-23 | 1967-09-28 | MONTECATINI Societa Generale per rindustria Mineraria e Chimica, Mailand (Italien) | Verfahren zur Herstellung von Metallcarbonylverbindungen |
| SU437745A1 (ru) | 1972-10-06 | 1974-07-30 | Предприятие П/Я А-7531 | Способ получени уксусной кислоты и метилацетата |
| US3856856A (en) * | 1973-01-08 | 1974-12-24 | Shell Oil Co | Production of carboxylic acids and esters |
| DE2630235A1 (de) * | 1976-07-06 | 1978-01-19 | Roehm Gmbh | Verfahren zur herstellung von isobuttersaeure |
| US4126752A (en) * | 1978-03-06 | 1978-11-21 | Allied Chemical Corporation | Homologation of methanol with a carbon monoxide-water mixture |
| FR2440349A1 (fr) * | 1978-10-31 | 1980-05-30 | Rhone Poulenc Ind | Procede de preparation de l'acide acetique ou de ses melanges avec l'acetate de methyle |
| FR2441603A1 (fr) * | 1978-10-31 | 1980-06-13 | Rhone Poulenc Ind | Procede de preparation de l'acetaldehyde |
| EP0013464A1 (en) * | 1979-01-09 | 1980-07-23 | Gulf Research & Development Company | Selective formation of ethanol from methanol, hydrogen and carbon monoxide |
-
1980
- 1980-08-25 US US06/180,863 patent/US4320230A/en not_active Expired - Lifetime
- 1980-09-22 DE DE8080303311T patent/DE3064142D1/de not_active Expired
- 1980-09-22 EP EP19800303311 patent/EP0027000B1/en not_active Expired
- 1980-09-23 CA CA000360805A patent/CA1156258A/en not_active Expired
- 1980-09-23 AU AU62632/80A patent/AU542341B2/en not_active Expired - Fee Related
- 1980-09-23 BR BR8006086A patent/BR8006086A/pt unknown
- 1980-09-24 ZA ZA00805926A patent/ZA805926B/xx unknown
- 1980-09-24 JP JP13277380A patent/JPS56115730A/ja active Pending
- 1980-10-06 US US06/194,147 patent/US4408069A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0027000A1 (en) | 1981-04-15 |
| JPS56115730A (en) | 1981-09-11 |
| CA1156258A (en) | 1983-11-01 |
| AU542341B2 (en) | 1985-02-21 |
| US4408069A (en) | 1983-10-04 |
| US4320230A (en) | 1982-03-16 |
| DE3064142D1 (en) | 1983-08-18 |
| AU6263280A (en) | 1981-04-09 |
| ZA805926B (en) | 1981-09-30 |
| EP0027000B1 (en) | 1983-07-13 |
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