BR0317380A - Fibras de polpa amino-funcionalizadas - Google Patents
Fibras de polpa amino-funcionalizadasInfo
- Publication number
- BR0317380A BR0317380A BR0317380-1A BR0317380A BR0317380A BR 0317380 A BR0317380 A BR 0317380A BR 0317380 A BR0317380 A BR 0317380A BR 0317380 A BR0317380 A BR 0317380A
- Authority
- BR
- Brazil
- Prior art keywords
- amino
- fibers
- pulp
- pulp fibers
- functionalized
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title abstract 7
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000013538 functional additive Substances 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 230000009257 reactivity Effects 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
- D21C9/005—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/20—Chemically or biochemically modified fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
- D21H21/20—Wet strength agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/12—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
- D21H5/1272—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of fibres which can be physically or chemically modified during or after web formation
- D21H5/1281—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of fibres which can be physically or chemically modified during or after web formation by chemical treatment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/42—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups anionic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Biochemistry (AREA)
- Paper (AREA)
Abstract
"FIBRAS DE POLPA AMINO-FUNCIONALIZADAS". A invenção descrita é voltada a fibras de polpa adequadas para a formação de produto de papel depositado no estado úmido que inclui uma funcionalidade amino que é não extraível em uma fase aquosa. As fibras de polpa podem ser preparadas aplicando-se (35a, 35b, 35c) um aditivo amino-funcional a uma trama fibrosa (33, 36) antes da operação de acabamento em uma usina de polpa. A trama fibrosa (33, 36) pode então ser novamente reduzida à polpa em uma máquina para a fabricação de papel (38) para formar uma trama de papel (64) que inclui as fibras amino-funcionalizadas da presente invenção. Uma trama de papel formada das fibras amino-funcionalizadas pode apresentar uma reatividade especifica e/ou melhorada em relação a determinados aditivos para a fabricação de papel. As tramas de papel da invenção descrita pode, por exemplo, apresentar aumentos de resistência à tração no estado seco de mais de 40% quando tratadas com um agente de resistência permanente no estado úmido tal como um agente de resistência no estado úmido de poliamina epicloridrina, ao passo que uma trama de papel que não inclui as fibras amino-funcionalizadas da presente invenção pode apresentar um aumento inferior a 20% nas propriedades de resistência quando tratada com os mesmos agentes de resistência.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/335,133 US6936136B2 (en) | 2002-12-31 | 2002-12-31 | Amino-functionalized pulp fibers |
| PCT/US2003/036406 WO2004061202A1 (en) | 2002-12-31 | 2003-11-13 | Amino-functionalized pulp fibers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0317380A true BR0317380A (pt) | 2005-11-16 |
| BR0317380B1 BR0317380B1 (pt) | 2013-12-31 |
Family
ID=32655267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0317380-1B1A BR0317380B1 (pt) | 2002-12-31 | 2003-11-13 | Fibra para a fabricação de papel, trama de papel e processo para a formação de fibra de polpa aminofuncionalizada |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6936136B2 (pt) |
| EP (1) | EP1581692B1 (pt) |
| KR (1) | KR101057947B1 (pt) |
| AR (1) | AR042796A1 (pt) |
| AU (2) | AU2003290892B2 (pt) |
| BR (1) | BR0317380B1 (pt) |
| CA (1) | CA2510599C (pt) |
| ES (1) | ES2368909T3 (pt) |
| MX (1) | MXPA05006482A (pt) |
| WO (1) | WO2004061202A1 (pt) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6749721B2 (en) | 2000-12-22 | 2004-06-15 | Kimberly-Clark Worldwide, Inc. | Process for incorporating poorly substantive paper modifying agents into a paper sheet via wet end addition |
| US7147752B2 (en) * | 2002-12-31 | 2006-12-12 | Kimberly-Clark Worldwide, Inc. | Hydrophilic fibers containing substantive polysiloxanes and tissue products made therefrom |
| US7811948B2 (en) | 2003-12-19 | 2010-10-12 | Kimberly-Clark Worldwide, Inc. | Tissue sheets containing multiple polysiloxanes and having regions of varying hydrophobicity |
| US7479578B2 (en) | 2003-12-19 | 2009-01-20 | Kimberly-Clark Worldwide, Inc. | Highly wettable—highly flexible fluff fibers and disposable absorbent products made of those |
| US7186318B2 (en) | 2003-12-19 | 2007-03-06 | Kimberly-Clark Worldwide, Inc. | Soft tissue hydrophilic tissue products containing polysiloxane and having unique absorbent properties |
| US7381299B2 (en) | 2004-06-10 | 2008-06-03 | Kimberly-Clark Worldwide, Inc. | Apertured tissue products |
| US7670459B2 (en) | 2004-12-29 | 2010-03-02 | Kimberly-Clark Worldwide, Inc. | Soft and durable tissue products containing a softening agent |
| CA2641309A1 (en) * | 2006-02-03 | 2007-08-16 | Nanopaper Llc | Functionalization of paper components with an amine-containing polymer |
| US7718036B2 (en) * | 2006-03-21 | 2010-05-18 | Georgia Pacific Consumer Products Lp | Absorbent sheet having regenerated cellulose microfiber network |
| US8187422B2 (en) | 2006-03-21 | 2012-05-29 | Georgia-Pacific Consumer Products Lp | Disposable cellulosic wiper |
| US8187421B2 (en) | 2006-03-21 | 2012-05-29 | Georgia-Pacific Consumer Products Lp | Absorbent sheet incorporating regenerated cellulose microfiber |
| US7585392B2 (en) * | 2006-10-10 | 2009-09-08 | Georgia-Pacific Consumer Products Lp | Method of producing absorbent sheet with increased wet/dry CD tensile ratio |
| US7678230B2 (en) * | 2006-12-15 | 2010-03-16 | Kimberly-Clark Worldwide, Inc. | Environmentally sustainable multiple ply paper product |
| US7951264B2 (en) | 2007-01-19 | 2011-05-31 | Georgia-Pacific Consumer Products Lp | Absorbent cellulosic products with regenerated cellulose formed in-situ |
| CA2735867C (en) | 2008-09-16 | 2017-12-05 | Dixie Consumer Products Llc | Food wrap basesheet with regenerated cellulose microfiber |
| JP5738264B2 (ja) * | 2009-03-20 | 2015-06-17 | エフピーイノベイションズ | 新規の特性を有するセルロース材料 |
| US8282777B2 (en) | 2009-03-30 | 2012-10-09 | Sellars Absorbent Materials, Inc. | Disposable wipers and towels containing 40% or more post-consumer waste |
| US9856606B2 (en) * | 2011-12-12 | 2018-01-02 | Enzymatic Deinking Technologies, L.L.C. | Enzymatic pre-treatment of market pulp to improve fiber drainage and physical properties |
| KR20150064078A (ko) | 2012-09-26 | 2015-06-10 | 케미라 오와이제이 | 흡수성 물질, 흡수성 물질을 포함하는 산물, 조성물, 및 흡수성 물질을 제조하는 방법 |
| US8916025B2 (en) | 2013-03-12 | 2014-12-23 | Sellars Absorbent Materials, Inc. | Disposable wipers and towels containing 100% recycled fibers |
| US20160032529A1 (en) * | 2013-03-14 | 2016-02-04 | Auburn University | Functionalized cellulose fibers for dewatering and energy efficiency improvements |
| US9826876B2 (en) | 2013-09-30 | 2017-11-28 | Kimberly-Clark Worldwide, Inc. | Low-moisture cloud-making cleaning article |
| KR101551970B1 (ko) * | 2014-02-07 | 2015-09-10 | 현대자동차주식회사 | 폴리프로필렌 수지 조성물 |
| CN104389233A (zh) * | 2014-10-15 | 2015-03-04 | 广西大学 | 一种提高二氧化氯漂白竹浆的纸张抗张指数的方法 |
| CN112566999A (zh) * | 2018-07-13 | 2021-03-26 | 生物吸附股份公司 | 用于回收和/或生物治理漏油和/或烃的组合物和方法 |
| KR102183584B1 (ko) * | 2019-02-13 | 2020-11-26 | (주)그린 엔바이론텍 | 펄프 몰드 성형품의 제조방법 |
| KR102836936B1 (ko) * | 2023-07-31 | 2025-07-22 | 지리산한지(유) | 고수축 폴리에스터 섬유를 포함하는 크레이프지의 제조 방법 |
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| US2233475A (en) * | 1936-12-21 | 1941-03-04 | Dreyfus Henry | Cellulose compounds containing carboxy and amine groups |
| USRE23013E (en) * | 1943-10-16 | 1948-06-29 | Method of improving the processing | |
| US2721140A (en) * | 1952-09-19 | 1955-10-18 | Hercules Powder Co Ltd | Paper of high wet strength and process therefor |
| US2961366A (en) * | 1957-02-27 | 1960-11-22 | Hercules Powder Co Ltd | Sized paper and method of making same |
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| US3128311A (en) | 1961-12-11 | 1964-04-07 | Jefferson Chem Co Inc | Preparation of primary amines |
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| US3392084A (en) | 1964-12-29 | 1968-07-09 | Procter & Gamble | Process for preparing a cohesive web from non-fibrillatable rayon fibers |
| US4014933A (en) | 1969-10-23 | 1977-03-29 | Basf Aktiengesellschaft | Production of amines from alcohols |
| US3772076A (en) | 1970-01-26 | 1973-11-13 | Hercules Inc | Reaction products of epihalohydrin and polymers of diallylamine and their use in paper |
| US3700623A (en) | 1970-04-22 | 1972-10-24 | Hercules Inc | Reaction products of epihalohydrin and polymers of diallylamine and their use in paper |
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| US4129528A (en) | 1976-05-11 | 1978-12-12 | Monsanto Company | Polyamine-epihalohydrin resinous reaction products |
| US4153581A (en) | 1977-09-01 | 1979-05-08 | The Dow Chemical Company | Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof |
| US4129722A (en) | 1977-12-15 | 1978-12-12 | National Starch And Chemical Corporation | Process for the preparation of high D. S. polysaccharides |
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| US4242408A (en) | 1979-06-25 | 1980-12-30 | The Dow Chemical Company | Easily disposable non-woven products having high wet strength at acid pH and low wet strength at base pH |
| DE2936239A1 (de) | 1979-09-07 | 1981-03-19 | Bayer Ag, 5090 Leverkusen | Polyquaternaere ammoniumverbindungen, ihre herstellung, ihre verwendung bei der papierherstellung und sie enthaltende papierbehandlungsmittel |
| ATE132556T1 (de) | 1988-06-14 | 1996-01-15 | Procter & Gamble | Sanftes tissuepapier |
| US5173521A (en) | 1990-06-19 | 1992-12-22 | Mishima Paper Co., Ltd. | Absorbent fibrous structure and producing method thereof |
| CA2100117C (en) * | 1992-07-15 | 1997-10-07 | Lloyd M. Robeson | Paper wet-strength improvement with cellulose reactive size and amine functional poly(vinyl alcohol) |
| AU5019893A (en) | 1992-08-17 | 1994-03-15 | Weyerhaeuser Company | Particle binding to fibers |
| US5300192A (en) | 1992-08-17 | 1994-04-05 | Weyerhaeuser Company | Wet laid fiber sheet manufacturing with reactivatable binders for binding particles to fibers |
| US5494554A (en) | 1993-03-02 | 1996-02-27 | Kimberly-Clark Corporation | Method for making soft layered tissues |
| US5380403A (en) * | 1993-03-22 | 1995-01-10 | Air Products And Chemicals, Inc. | Amine functional poly(vinyl alcohol) for improving properties of recycled paper |
| US5667636A (en) | 1993-03-24 | 1997-09-16 | Kimberly-Clark Worldwide, Inc. | Method for making smooth uncreped throughdried sheets |
| US5607551A (en) | 1993-06-24 | 1997-03-04 | Kimberly-Clark Corporation | Soft tissue |
| CA2134594A1 (en) | 1994-04-12 | 1995-10-13 | Kimberly-Clark Worldwide, Inc. | Method for making soft tissue products |
| WO2000040618A1 (en) | 1999-01-06 | 2000-07-13 | Pulp And Paper Research Institute Of Canada | Papermaking additive with primary amino groups and mechanical pulp treated therewith |
| US6368456B1 (en) | 1999-08-17 | 2002-04-09 | National Starch And Chemical Investment Holding Corporation | Method of making paper from aldehyde modified cellulose pulp with selected additives |
| JP2001294559A (ja) * | 2000-04-13 | 2001-10-23 | Central Glass Co Ltd | トリフルオロメチルベンジルアミンの製造方法 |
| US7749356B2 (en) | 2001-03-07 | 2010-07-06 | Kimberly-Clark Worldwide, Inc. | Method for using water insoluble chemical additives with pulp and products made by said method |
| US6582560B2 (en) | 2001-03-07 | 2003-06-24 | Kimberly-Clark Worldwide, Inc. | Method for using water insoluble chemical additives with pulp and products made by said method |
| US20040045687A1 (en) | 2002-09-11 | 2004-03-11 | Shannon Thomas Gerard | Method for using water insoluble chemical additives with pulp and products made by said method |
| US6916402B2 (en) * | 2002-12-23 | 2005-07-12 | Kimberly-Clark Worldwide, Inc. | Process for bonding chemical additives on to substrates containing cellulosic materials and products thereof |
-
2002
- 2002-12-31 US US10/335,133 patent/US6936136B2/en not_active Expired - Lifetime
-
2003
- 2003-11-13 EP EP03783477A patent/EP1581692B1/en not_active Expired - Lifetime
- 2003-11-13 AU AU2003290892A patent/AU2003290892B2/en not_active Ceased
- 2003-11-13 MX MXPA05006482A patent/MXPA05006482A/es active IP Right Grant
- 2003-11-13 WO PCT/US2003/036406 patent/WO2004061202A1/en not_active Ceased
- 2003-11-13 BR BRPI0317380-1B1A patent/BR0317380B1/pt not_active IP Right Cessation
- 2003-11-13 ES ES03783477T patent/ES2368909T3/es not_active Expired - Lifetime
- 2003-11-13 CA CA2510599A patent/CA2510599C/en not_active Expired - Fee Related
- 2003-11-13 KR KR1020057010920A patent/KR101057947B1/ko not_active Expired - Lifetime
- 2003-12-22 AR ARP030104791A patent/AR042796A1/es active IP Right Grant
-
2009
- 2009-10-16 AU AU2009227828A patent/AU2009227828A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| AU2009227828A8 (en) | 2013-01-31 |
| AR042796A1 (es) | 2005-07-06 |
| ES2368909T3 (es) | 2011-11-23 |
| AU2003290892A1 (en) | 2004-07-29 |
| KR20050086911A (ko) | 2005-08-30 |
| AU2003290892B2 (en) | 2009-07-16 |
| KR101057947B1 (ko) | 2011-08-18 |
| US6936136B2 (en) | 2005-08-30 |
| EP1581692A1 (en) | 2005-10-05 |
| CA2510599A1 (en) | 2004-07-22 |
| AU2009227828A1 (en) | 2009-11-05 |
| WO2004061202A1 (en) | 2004-07-22 |
| BR0317380B1 (pt) | 2013-12-31 |
| US20040123962A1 (en) | 2004-07-01 |
| CA2510599C (en) | 2012-10-23 |
| MXPA05006482A (es) | 2005-08-26 |
| EP1581692B1 (en) | 2011-09-21 |
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