BR0315734A - Composição de tinta de látex, artigo, e, método para conferir resistência à mancha e sujeira a um revestimento de tinta de látex - Google Patents
Composição de tinta de látex, artigo, e, método para conferir resistência à mancha e sujeira a um revestimento de tinta de látexInfo
- Publication number
- BR0315734A BR0315734A BR0315734-2A BR0315734A BR0315734A BR 0315734 A BR0315734 A BR 0315734A BR 0315734 A BR0315734 A BR 0315734A BR 0315734 A BR0315734 A BR 0315734A
- Authority
- BR
- Brazil
- Prior art keywords
- latex paint
- article
- paint composition
- latex
- composition
- Prior art date
Links
- 239000004816 latex Substances 0.000 title abstract 6
- 229920000126 latex Polymers 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000003973 paint Substances 0.000 title abstract 4
- 239000011248 coating agent Substances 0.000 title abstract 2
- 238000000576 coating method Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000049 pigment Substances 0.000 abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
"COMPOSIçãO DE TINTA DE LáTEX, ARTIGO, E, MéTODO PARA CONFERIR RESISTêNCIA A MANCHA E SUJEIRA A UM REVESTIMENTO DE TINTA DE LáTEX". Uma composição de tinta de látex compreendendo (a) um polímero tendo unidades interpolimerizadas, que compreendem unidades derivadas de estireno, metil estireno, vinila ou suas combinações e unidades derivadas de um ou mais acrilatos, metacrilatos, acrilonitrila ou suas combinações; (b) pigmento de escondimento; c) espessante não-celulósico; e (d) um aditivo de polifluorouretano, que é o produto de reação de (i) pelo menos um reagente isocianato, (ii) pelo menos um composto fluoroquímico, contendo pelo menos um hidrogênio de Zerewitinoff em uma quantidade suficiente para reagir com cerca de 5% a cerca de 80% dos grupos isocianato e (iii) pelo menos um composto não-fluorado; em que dita composição de tinta de látex tem uma concentração de volume de pigmento de pelo menos 20% e menos do que sua concentração crítica de volume de pigmento.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/288,887 US6881782B2 (en) | 2002-11-06 | 2002-11-06 | Latex paint compositions and coatings |
| PCT/US2003/031475 WO2004044064A1 (en) | 2002-11-06 | 2003-10-06 | Latex paint compositions and coatings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0315734A true BR0315734A (pt) | 2005-09-06 |
Family
ID=32175990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0315734-2A BR0315734A (pt) | 2002-11-06 | 2003-10-06 | Composição de tinta de látex, artigo, e, método para conferir resistência à mancha e sujeira a um revestimento de tinta de látex |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6881782B2 (pt) |
| EP (1) | EP1558685B1 (pt) |
| JP (1) | JP2006505669A (pt) |
| CN (1) | CN1331954C (pt) |
| AT (1) | ATE348864T1 (pt) |
| AU (1) | AU2003277281A1 (pt) |
| BR (1) | BR0315734A (pt) |
| CA (1) | CA2503005C (pt) |
| DE (1) | DE60310601T2 (pt) |
| MX (1) | MXPA05004408A (pt) |
| WO (1) | WO2004044064A1 (pt) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7399807B2 (en) * | 2004-07-09 | 2008-07-15 | Unitex Chemical Corporation | Hydrophobic, oleophobic and alcohol-resistant fluorochemical additive |
| US7763359B2 (en) | 2004-08-30 | 2010-07-27 | Bunge Fertilizantes S.A. | Aluminum phosphate, polyphosphate and metaphosphate particles and their use as pigments in paints and method of making same |
| BRPI0403713B1 (pt) | 2004-08-30 | 2021-01-12 | Universidade Estadual De Campinas - Unicamp | processo de fabricação de um pigmento branco baseado na síntese de partículas ocas de ortofosfato ou polifosfato de alumínio |
| CA2620201A1 (en) * | 2005-09-07 | 2007-03-15 | Elementis Specialities, Inc. | Improved paint compositions containing an additive to reduce the effect of viscosity loss caused by the addition of colorants |
| US7498377B2 (en) * | 2005-10-24 | 2009-03-03 | Unimin Corporation | Fluoride based composite material and method for making the same |
| US7582157B2 (en) * | 2005-10-24 | 2009-09-01 | The Unimin Corporation | Pigment composition for paint |
| US7731106B2 (en) * | 2006-01-04 | 2010-06-08 | Nano Mist International, Llc | Air driven delivery system for sprayable media |
| US20070212560A1 (en) * | 2006-03-08 | 2007-09-13 | Yen Jessica C | Fluorochemical and lecithin additive for coatings |
| US20070212491A1 (en) * | 2006-03-08 | 2007-09-13 | Yen Jessica C | Fluorochemical and lecithin additive for coatings |
| HUE032934T2 (en) | 2006-08-11 | 2017-11-28 | Bunge Amorphic Solutions Llc | Preparation of aluminum phosphate or polyphosphate particles |
| EP2263990B1 (en) * | 2006-11-03 | 2012-12-26 | E. I. du Pont de Nemours and Company | Liquid-repellent and stain-resistant cementitious product |
| US7470745B2 (en) * | 2006-11-13 | 2008-12-30 | E. I. Du Pont De Nemours And Company | Perfluoroether based polymers |
| US7723414B2 (en) | 2006-12-22 | 2010-05-25 | E. I. Du Pont De Nemours And Company | Antistatic system for polymers |
| US20080153963A1 (en) * | 2006-12-22 | 2008-06-26 | 3M Innovative Properties Company | Method for making a dispersion |
| CN101838434B (zh) * | 2007-05-06 | 2011-11-23 | 石磊 | 改性普通泥土的弹性体产品及其生产方法 |
| US20090088516A1 (en) * | 2007-10-01 | 2009-04-02 | Chunzhao Li | Method to improve the color acceptance of viscosity stabilized latex paints |
| WO2009079578A1 (en) * | 2007-12-17 | 2009-06-25 | Elements Specialties, Inc. | Low voc waterbased coatings with efflorescence resistance |
| US9023145B2 (en) * | 2008-02-12 | 2015-05-05 | Bunge Amorphic Solutions Llc | Aluminum phosphate or polyphosphate compositions |
| PL2285754T3 (pl) * | 2008-06-13 | 2018-12-31 | Benjamin Moore & Co. | Wodne kompozycje powłokowe z minimalną emisją związków lotnych |
| CN102076909A (zh) * | 2008-06-26 | 2011-05-25 | 纳幕尔杜邦公司 | 具有改进的易清洁性和耐磨性的纸层压体 |
| JP5654204B2 (ja) * | 2009-02-16 | 2015-01-14 | 菊水化学工業株式会社 | 芝用塗料組成物の塗装方法 |
| WO2011059938A1 (en) | 2009-11-10 | 2011-05-19 | E. I. Du Pont De Nemours And Company | Process for in-situ formation of chlorides of silicon and aluminum in the preparation of titanium dioxide |
| AU2010346502B2 (en) | 2010-02-22 | 2015-01-22 | The Chemours Company Fc,Llc | Process for in-situ formation of chlorides of silicon, aluminum and titanium in the preparation of titanium dioxide |
| CA2796377C (en) * | 2010-04-19 | 2018-03-06 | Benjamin Moore & Co. | Paints with improved water staining and color rub-off qualities |
| CN102695763A (zh) | 2010-09-21 | 2012-09-26 | 纳幕尔杜邦公司 | 包含钨处理过的具有改善的光稳定性的二氧化钛的涂料组合物 |
| US8734756B2 (en) | 2010-09-21 | 2014-05-27 | E I Du Pont De Nemours And Company | Process for in-situ formation of chlorides in the preparation of titanium dioxide |
| US9371454B2 (en) | 2010-10-15 | 2016-06-21 | Bunge Amorphic Solutions Llc | Coating compositions with anticorrosion properties |
| US9005355B2 (en) | 2010-10-15 | 2015-04-14 | Bunge Amorphic Solutions Llc | Coating compositions with anticorrosion properties |
| CN102604539B (zh) * | 2012-03-14 | 2014-01-08 | 吴尚泉 | 一种释放远红外和负离子的内墙涂料及其制备方法 |
| US9078445B2 (en) | 2012-04-16 | 2015-07-14 | Bunge Amorphic Solutions Llc | Antimicrobial chemical compositions |
| US9611147B2 (en) | 2012-04-16 | 2017-04-04 | Bunge Amorphic Solutions Llc | Aluminum phosphates, compositions comprising aluminum phosphate, and methods for making the same |
| US9155311B2 (en) | 2013-03-15 | 2015-10-13 | Bunge Amorphic Solutions Llc | Antimicrobial chemical compositions |
| CA2867904C (en) | 2012-04-20 | 2020-04-14 | Valspar Sourcing, Inc. | Method for making titanium dioxide pigment grind dispersion and paint |
| CN106978014B (zh) | 2012-04-20 | 2021-02-09 | 宣伟投资管理有限公司 | 二氧化钛颜料研磨分散体和油漆 |
| CN104497753A (zh) * | 2014-11-21 | 2015-04-08 | 广东巴德士化工有限公司 | 一种含天然芦荟净味全效内墙乳胶漆 |
| CN105111877B (zh) * | 2015-08-05 | 2018-02-16 | 浙江康德新材料有限公司 | 一种喷雾型表面防污处理组合物 |
| CN105219199B (zh) * | 2015-11-13 | 2018-10-09 | 河北晨阳工贸集团有限公司 | 一种耐污渍的白色乳胶漆及其制备方法 |
| CN105505183B (zh) * | 2015-12-26 | 2017-08-25 | 杭州福斯特应用材料股份有限公司 | 一种高性能氟碳涂料的制备方法 |
| US11608388B2 (en) | 2019-11-06 | 2023-03-21 | Nutrition & Biosciences USA 4, Inc. | Highly crystalline alpha-1,3-glucan |
| US20230051343A1 (en) | 2020-02-04 | 2023-02-16 | Nutrition & Bioscience Usa 4 Inc. | Aqueous dispersions of insoluble alpha-glucan comprising alpha-1,3 glycosidic linkages |
| MX2022015379A (es) | 2020-06-04 | 2023-01-16 | Nutrition & Biosciences Usa 4 Inc | Copolimeros de injerto de dextrano-alfa-glucano y derivados de estos. |
| EP4334363A1 (en) | 2021-05-04 | 2024-03-13 | Nutrition & Biosciences USA 4, Inc. | Compositions comprising insoluble alpha-glucan |
| US20240239921A1 (en) | 2021-05-04 | 2024-07-18 | Nutrition & Biosciences USA 4, Inc. | Compositions comprising oxidized insoluble alpha-glucan |
| EP4370560A1 (en) | 2021-07-13 | 2024-05-22 | Nutrition & Biosciences USA 4, Inc. | Cationic glucan ester derivatives |
| WO2024015769A1 (en) | 2022-07-11 | 2024-01-18 | Nutrition & Biosciences USA 4, Inc. | Amphiphilic glucan ester derivatives |
| WO2026024663A1 (en) | 2024-07-24 | 2026-01-29 | Nutrition & Biosciences USA 4, Inc. | Compositions comprising alpha-glucan with alpha-1,3 glycosidic linkages |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2803615A (en) | 1956-01-23 | 1957-08-20 | Minnesota Mining & Mfg | Fluorocarbon acrylate and methacrylate esters and polymers |
| US2975554A (en) * | 1957-03-20 | 1961-03-21 | Owens Illinois Glass Co | Press mold and method of operation |
| US2915554A (en) | 1957-07-23 | 1959-12-01 | Minnesota Mining & Mfg | Non-ionic surfactant derivatives of perfluoro alkane-sulfonamides |
| US3124605A (en) | 1963-12-05 | 1964-03-10 | Biuret polyisocyanates | |
| US3822228A (en) | 1969-11-10 | 1974-07-02 | Air Prod & Chem | Fluorochemical surfactants for latex paints |
| US3787351A (en) | 1972-02-28 | 1974-01-22 | Minnesota Mining & Mfg | Use of soluble fluoroaliphatic oligomers in resin composite articles |
| US3891591A (en) | 1973-08-13 | 1975-06-24 | Du Pont | Coating compositions |
| US4208496A (en) | 1977-02-02 | 1980-06-17 | N L Industries, Inc. | Dust repellent paint |
| US4600441A (en) | 1985-03-21 | 1986-07-15 | Westinghouse Electric Corp. | Oil and dirt repellent alkyd paint |
| US5006624A (en) | 1987-05-14 | 1991-04-09 | The Dow Chemical Company | Fluorocarbon containing, reactive polymeric surfactants and coating compositions therefrom |
| US4929666A (en) | 1987-05-14 | 1990-05-29 | The Dow Chemical Company | Fluorocarbon containing, reactive polymeric surfactants and coating compositions therefrom |
| US5082895A (en) | 1988-12-30 | 1992-01-21 | Doris Wolff | High solids, large particle size latex compositions |
| AT392478B (de) | 1989-09-01 | 1991-04-10 | Vianova Kunstharz Ag | Verwendung von acrylatcopolymerisaten als additive fuer waessrige kationische lacksysteme |
| JP3033105B2 (ja) * | 1989-11-27 | 2000-04-17 | 三井化学株式会社 | 含フッ素共重合体組成物、フッ素系塗料用組成物およびその塗膜 |
| CA2114706A1 (en) | 1993-03-08 | 1994-09-09 | Edward R. Hauser | Stain-resistant latex paint |
| DE19522476A1 (de) | 1995-06-21 | 1997-01-02 | Bayer Ag | Fluor enthaltende Dispergierhilfsmittel für wäßrige Lacke |
| US5688884A (en) | 1995-08-31 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Polymerization process |
| US5827919A (en) | 1995-10-06 | 1998-10-27 | E. I. Du Pont De Nemours And Company | Fluorourethane additives for water-dispersed coating compositions |
| US5789513A (en) * | 1997-02-26 | 1998-08-04 | E. I. Du Pont De Nemours And Company | Polyfluorourethane additives for curable coating compositions |
| EP1246856B1 (en) | 1999-10-27 | 2009-07-15 | 3M Innovative Properties Company | Fluorochemical sulfonamide surfactants |
| AU2001294391A1 (en) | 2000-09-07 | 2002-03-22 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappijk Onderzoek Tno | Coating compositions containing perfluoropolyether surfactants |
| US7041727B2 (en) * | 2002-06-25 | 2006-05-09 | 3M Innovative Properties Company | Latex paint compositions and coatings |
-
2002
- 2002-11-06 US US10/288,887 patent/US6881782B2/en not_active Expired - Lifetime
-
2003
- 2003-10-06 MX MXPA05004408A patent/MXPA05004408A/es active IP Right Grant
- 2003-10-06 AU AU2003277281A patent/AU2003277281A1/en not_active Abandoned
- 2003-10-06 DE DE60310601T patent/DE60310601T2/de not_active Expired - Lifetime
- 2003-10-06 WO PCT/US2003/031475 patent/WO2004044064A1/en not_active Ceased
- 2003-10-06 CN CNB2003801029187A patent/CN1331954C/zh not_active Expired - Fee Related
- 2003-10-06 EP EP03811226A patent/EP1558685B1/en not_active Expired - Lifetime
- 2003-10-06 AT AT03811226T patent/ATE348864T1/de not_active IP Right Cessation
- 2003-10-06 JP JP2004551497A patent/JP2006505669A/ja active Pending
- 2003-10-06 CA CA2503005A patent/CA2503005C/en not_active Expired - Fee Related
- 2003-10-06 BR BR0315734-2A patent/BR0315734A/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1711327A (zh) | 2005-12-21 |
| EP1558685B1 (en) | 2006-12-20 |
| US6881782B2 (en) | 2005-04-19 |
| US20040087709A1 (en) | 2004-05-06 |
| DE60310601D1 (de) | 2007-02-01 |
| CA2503005A1 (en) | 2004-05-27 |
| DE60310601T2 (de) | 2007-09-27 |
| WO2004044064A1 (en) | 2004-05-27 |
| CN1331954C (zh) | 2007-08-15 |
| CA2503005C (en) | 2011-10-04 |
| ATE348864T1 (de) | 2007-01-15 |
| MXPA05004408A (es) | 2005-07-26 |
| JP2006505669A (ja) | 2006-02-16 |
| EP1558685A1 (en) | 2005-08-03 |
| AU2003277281A1 (en) | 2004-06-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE AS 7A E 8A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2160 DE 29/05/2012. |