BR0211861A - Processo para manufaturar espumas de poliuretano flexìveis e produto de poliuretano obtido - Google Patents
Processo para manufaturar espumas de poliuretano flexìveis e produto de poliuretano obtidoInfo
- Publication number
- BR0211861A BR0211861A BR0211861-0A BR0211861A BR0211861A BR 0211861 A BR0211861 A BR 0211861A BR 0211861 A BR0211861 A BR 0211861A BR 0211861 A BR0211861 A BR 0211861A
- Authority
- BR
- Brazil
- Prior art keywords
- manufacturing flexible
- polyurethane foams
- product
- foams
- flexible polyurethane
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
"PROCESSO PARA MANUFATURAR ESPUMAS DE POLIURETANO FLEXìVEIS E PRODUTO DE POLIURETANO OBTIDO". A presente invenção refere-se a um processo para a produção de espumas de poliuretano na ausência de um catalisador de amina. A reatividade do sistema formador de espuma pode ser controlado pela adição de um poliol auto-catalítico contendo uma amina terciária, sendo que a quantidade de poliol auto-catalítico compreende menos que 5 por cento em peso do poliol total.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31257601P | 2001-08-15 | 2001-08-15 | |
| PCT/US2002/026222 WO2003016372A1 (en) | 2001-08-15 | 2002-08-15 | Process to manufacture flexible polyurethane foams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0211861A true BR0211861A (pt) | 2004-09-21 |
| BRPI0211861B1 BRPI0211861B1 (pt) | 2015-09-08 |
Family
ID=23212098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0211861A BRPI0211861B1 (pt) | 2001-08-15 | 2002-08-15 | processo para produzir espuma de poliuretano flexível. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7361695B2 (pt) |
| EP (1) | EP1419189B1 (pt) |
| JP (1) | JP4220384B2 (pt) |
| KR (1) | KR100909946B1 (pt) |
| CN (1) | CN1262569C (pt) |
| AT (1) | ATE497983T1 (pt) |
| BR (1) | BRPI0211861B1 (pt) |
| CA (1) | CA2455503C (pt) |
| DE (1) | DE60239136D1 (pt) |
| ES (1) | ES2357642T3 (pt) |
| HU (1) | HU229193B1 (pt) |
| MX (1) | MXPA04001427A (pt) |
| TW (1) | TW592813B (pt) |
| WO (1) | WO2003016372A1 (pt) |
| ZA (1) | ZA200400647B (pt) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1239554C (zh) * | 2000-09-13 | 2006-02-01 | 陶氏环球技术公司 | 具有自催化特性的多元醇和从其制备的聚氨酯产物 |
| CA2528934A1 (en) * | 2003-06-13 | 2004-12-29 | Dow Global Technologies Inc. | Catalyst composition to get polyurethane product with good hydrolysis resistance |
| DE10337319A1 (de) | 2003-08-12 | 2005-03-17 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| US7078443B2 (en) * | 2003-10-22 | 2006-07-18 | Intellectual Property Holdings, Llc | Viscoelastic foam layer and composition |
| CN100473676C (zh) * | 2003-10-28 | 2009-04-01 | 三井化学聚氨酯株式会社 | 软质聚氨酯发泡体及其用途 |
| CA2549846A1 (en) * | 2003-12-23 | 2005-07-14 | Dow Global Technologies Inc. | Non-fugitive catalysts containing imine linkages and tertiary amines, and polyurethane products made therefrom |
| CN1898289B (zh) * | 2003-12-23 | 2010-05-05 | 陶氏环球技术公司 | 使用叔胺封端的聚醚多元醇自动催化产生聚氨酯产品的方法 |
| ATE380210T1 (de) * | 2004-03-31 | 2007-12-15 | Dow Global Technologies Inc | Urethanmodifizierte isocyanatzusammensetzung und polyurethanprodukt daraus |
| US20080096993A1 (en) * | 2004-11-17 | 2008-04-24 | Casati Francois M | Acid Blocked, Amine Based, Autocatalytic Polyols and Polyurethane Foams Made Therefrom |
| US20070088103A1 (en) * | 2005-10-14 | 2007-04-19 | Dow Global Technologies Inc. | Composite article and method of manufacture using an isocyanate-terminated prepolymer as binder |
| MX2009003214A (es) * | 2006-09-25 | 2009-04-06 | Dow Global Technologies Inc | Espumas de poliuretano hechas de polioles de poliester que contienen hidroximetilo y polioles que contienen amina terciaria. |
| US8552078B2 (en) | 2006-10-17 | 2013-10-08 | Air Products And Chemicals, Inc. | Crosslinkers for improving stability of polyurethane foams |
| US8367870B2 (en) | 2007-09-19 | 2013-02-05 | Air Products And Chemicals, Inc. | Autocatalytic polyols |
| EP2072556A1 (de) * | 2007-12-17 | 2009-06-24 | Sika Technology AG | Verfahren zur Herstellung von hydroxyfunktionellen Polymeren, die hieraus gewinnbaren Isocyanatgruppen-endständigen Polyadditionsprodukte sowie deren Verwendung |
| ES2408962T3 (es) * | 2008-10-24 | 2013-06-24 | Basf Se | Procedimiento para la obtención de espumas blandas de poliuretano viscoelásticas |
| AU2010221725A1 (en) * | 2009-03-05 | 2011-10-06 | Dow Global Technologies Inc. | Polyols from HPPO and polyurethane products made therefrom |
| US20130296449A1 (en) * | 2010-02-26 | 2013-11-07 | Peterson Chemical Technology, Inc. | Polyurethane Gel-Like Polymers, Methods and Use in Flexible Foams |
| US10113043B2 (en) * | 2010-02-26 | 2018-10-30 | Twin Brook Capital Partners, Llc | Polyurethane gel particles, methods and use in flexible foams |
| WO2011159424A1 (en) | 2010-06-15 | 2011-12-22 | Dow Global Technologies Llc | Method for making polyurethane foam floor covering products with postconsumer carpet fibers |
| KR20150023903A (ko) | 2010-07-09 | 2015-03-05 | 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 | 폴리우레탄 포움 성능을 개선시키기 위한 첨가제 |
| MX342085B (es) | 2010-07-09 | 2016-09-13 | Air Products And Chemicals Inc * | Proceso para producir espuma de poliuretano flexible. |
| JP5905892B2 (ja) * | 2010-10-01 | 2016-04-20 | ダウ グローバル テクノロジーズ エルエルシー | 低密度高弾性軟質ポリウレタンフォームの製造方法 |
| US9968919B2 (en) | 2011-06-29 | 2018-05-15 | Evonik Degussa Gmbh | Reducing emissions in polyurethane foam |
| US9447223B2 (en) | 2011-07-07 | 2016-09-20 | Air Products And Chemicals, Inc. | Additives for improving natural oil based polyurethane foam performance |
| US9145466B2 (en) | 2011-07-07 | 2015-09-29 | Air Products And Chemicals, Inc. | Process for producing flexible polyurethane foam using natural oil polyols |
| US10106638B2 (en) | 2011-07-29 | 2018-10-23 | Evonik Degussa Gmbh | Reduced emissions low density spray polyurethane foam |
| US9273175B2 (en) | 2011-10-03 | 2016-03-01 | Air Products And Chemicals, Inc. | Tertiary amine composition and method for making the composition |
| JP6130390B2 (ja) | 2011-11-17 | 2017-05-17 | エア プロダクツ アンド ケミカルズ インコーポレイテッドAir Products And Chemicals Incorporated | 芳香族カルボン酸のテトラアルキルグアニジン塩を有する組成物、製品及び方法 |
| BR112014015973B1 (pt) | 2011-12-29 | 2021-03-30 | Dow Global Technologies Llc | Composição, espuma de poliuretano e método para preparar uma espuma de poliuretano |
| US10144811B2 (en) | 2012-03-30 | 2018-12-04 | Evonik Degussa Gmbh | Polyurethane foam production process, pre-mix formulation, and product |
| US10023681B2 (en) | 2012-10-24 | 2018-07-17 | Evonik Degussa Gmbh | Delay action catalyst for improving the stability of polyurethane systems having halogen containing blowing agents |
| JP6191244B2 (ja) * | 2013-05-30 | 2017-09-06 | 旭硝子株式会社 | ポリマー分散ポリオール組成物の製造方法および引火点を上昇させる方法 |
| KR101850508B1 (ko) | 2013-12-19 | 2018-04-19 | 에보니크 데구사 게엠베하 | 개선된 시스템 저장 수명 안정성을 위한 비방출성 아민 조성물 |
| KR102360642B1 (ko) | 2014-04-01 | 2022-02-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리우레탄 제품을 제조하기 위한 발포-겔 균형이 우수한 폴리에테르 폴리올 |
| PL3191537T3 (pl) | 2014-09-12 | 2025-03-24 | Evonik Operations Gmbh | Niskoemisyjna pianka poliuretanowa wytwarzana za pomocą katalizatorów aminowych reaktywnych względem izocyjanianu |
| US10472459B2 (en) | 2014-10-13 | 2019-11-12 | Evonik Degussa Gmbh | Polyurethane catalysts from a sulfur based salts |
| US10081700B2 (en) | 2015-05-05 | 2018-09-25 | Evonik Degussa Gmbh | Delayed action gelling catalyst compositions and methods for making polyurethane polymers |
| KR102610948B1 (ko) | 2015-06-01 | 2023-12-06 | 에보닉 오퍼레이션스 게엠베하 | 폴리우레탄 적용물을 위한 반응성 아민 촉매 |
| JP6657267B2 (ja) | 2015-06-16 | 2020-03-04 | エボニック オペレーションズ ゲーエムベーハー | ポリウレタンフォーム用のアルデヒド捕捉剤 |
| US10696777B2 (en) | 2015-06-16 | 2020-06-30 | Evonik Operations Gmbh | Aldehyde scavengers mixtures for polyurethane foams |
| EP3310830A1 (en) | 2015-06-19 | 2018-04-25 | Dow Global Technologies LLC | Autocatalytic polyol useful for polyurethane foam manufacture |
| EP3443019B1 (en) | 2016-04-12 | 2020-08-12 | Evonik Operations GmbH | Siloxane-oxyalkylene copolymer surfactant compositions |
| CN109476807B (zh) * | 2016-06-13 | 2021-08-10 | 陶氏环球技术有限责任公司 | 自催化多元醇 |
| US11021561B2 (en) | 2016-07-11 | 2021-06-01 | Evonik Operations Gmbh | Amine composition useful for making polyurethane foam |
| US10767008B2 (en) | 2017-01-16 | 2020-09-08 | Covestro Llc | Polymer polyols comprising amine based polyether polyols and a process for preparing these polymer polyols |
| CN110167986B (zh) * | 2017-01-23 | 2022-01-18 | 陶氏环球技术有限责任公司 | 柔性聚氨酯泡沫和制得方法 |
| CN107189028B (zh) * | 2017-06-23 | 2020-02-28 | 黎明化工研究设计院有限责任公司 | 一种环保高性能快速脱模聚氨酯反应注射成型组合物及其自催化扩链剂的制备方法 |
| WO2019094158A1 (en) | 2017-11-10 | 2019-05-16 | Dow Global Technologies Llc | Polyurethane foam system |
| WO2019094157A1 (en) | 2017-11-10 | 2019-05-16 | Dow Global Technologies Llc | Polyurethane foam system |
| US10479862B2 (en) | 2017-12-07 | 2019-11-19 | Covestro Llc | Amine based polymer polyol stabilizers |
| US10526484B2 (en) | 2017-12-20 | 2020-01-07 | Covestro Llc | Dithiocarbonate containing polyols as polymer polyol stabilizers |
| EP3584726A1 (en) * | 2018-06-18 | 2019-12-25 | Covestro Deutschland AG | Method and computer system for determining polymeric product properties |
| CN109971007B (zh) * | 2019-04-01 | 2021-05-28 | 江南大学 | 一种常温固化聚氨酯类防雾薄膜及其制备方法 |
| EP3760659A1 (de) * | 2019-07-01 | 2021-01-06 | Covestro Deutschland AG | Amingestartete polyole als einbaubare katalysatoren im hr-schaum |
| US11814566B2 (en) | 2020-07-13 | 2023-11-14 | L&P Property Management Company | Thermally conductive nanomaterials in flexible foam |
| EP3954722A1 (en) | 2020-07-30 | 2022-02-16 | Evonik Operations GmbH | Process and composition for the production of flexible polyurethane foam |
| US20220235168A1 (en) * | 2021-01-22 | 2022-07-28 | Covestro Llc | Processes for making molded flexible foams and flexible foams produced thereby |
| US11738487B2 (en) * | 2021-01-22 | 2023-08-29 | Covestro Llc | Processes for making molded flexible foams and flexible foams produced thereby |
| US11597862B2 (en) | 2021-03-10 | 2023-03-07 | L&P Property Management Company | Thermally conductive nanomaterial coatings on flexible foam or fabrics |
| WO2024175628A1 (en) | 2023-02-24 | 2024-08-29 | Evonik Operations Gmbh | Inhibiting solids formation in co2 polyurethane production |
| CN121263460A (zh) | 2023-06-01 | 2026-01-02 | 赢创运营有限公司 | 用于聚氨酯应用的胺催化剂 |
| WO2025040451A1 (en) | 2023-08-18 | 2025-02-27 | Evonik Operations Gmbh | Hydrolysis resistance of polyurethane foams |
| WO2025045680A1 (en) | 2023-08-25 | 2025-03-06 | Evonik Operations Gmbh | Method to make bicyclic guanidines |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE235878C (pt) | ||||
| US3838076A (en) * | 1973-03-12 | 1974-09-24 | Jefferson Chem Co Inc | Polyurethane foams from partially aminated polyether polyols |
| US4049931A (en) * | 1975-05-29 | 1977-09-20 | Union Carbide Corporation | Catalyst systems containing dimethylamino ether mono-ols for polyurethane foam formation |
| US4383070A (en) * | 1982-05-27 | 1983-05-10 | Mobay Chemical Corporation | Storage stable polyurethane compositions |
| US4530941A (en) * | 1983-01-26 | 1985-07-23 | The Dow Chemical Company | Reaction injection molded polyurethanes employing high molecular weight polyols |
| US4517313A (en) * | 1984-04-11 | 1985-05-14 | Abbott Laboratories | Method of making polyurethane foam |
| DE3435070A1 (de) * | 1984-09-25 | 1986-04-03 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von gegebenenfalls geschaeumten polyurethanen, die mit einem anderen werkstoff verbunden oder konfektioniert worden sind |
| DD235878B5 (de) * | 1985-04-02 | 1994-04-28 | Basf Schwarzheide Gmbh | Verfahren zur Herstellung autokatalytisch wirkender Polyetheralkohole |
| GB2199504A (en) * | 1987-01-06 | 1988-07-13 | Peter Egan | Directional dice |
| US4963399A (en) * | 1987-03-31 | 1990-10-16 | Union Carbide Chemicals And Plastics Company, Inc. | Polyurethane foam with low vinyl-staining tendencies |
| US5223547A (en) | 1990-11-27 | 1993-06-29 | Kao Corporation | Polyurethane, process for producing the same, and process for producing polyurethane foam |
| DE4135588A1 (de) * | 1991-10-29 | 1993-05-06 | Basf Ag, 6700 Ludwigshafen, De | Hochreaktive, tertiaere aminogruppen gebunden enthaltende polyoxyalkylenpolyole, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyisocyanat-polyadditionsprodukten |
| GB9215488D0 (en) | 1992-07-21 | 1992-09-02 | Polyol Int Bv | Isocyanate modified amines as catalysts useful for the preparation of polyurethane materials |
| US5508340A (en) * | 1993-03-10 | 1996-04-16 | R. E. Hart Labs, Inc. | Water-based, solvent-free or low voc, two-component polyurethane coatings |
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-
2002
- 2002-08-14 TW TW091118315A patent/TW592813B/zh not_active IP Right Cessation
- 2002-08-15 WO PCT/US2002/026222 patent/WO2003016372A1/en not_active Ceased
- 2002-08-15 DE DE60239136T patent/DE60239136D1/de not_active Expired - Lifetime
- 2002-08-15 KR KR1020047002193A patent/KR100909946B1/ko not_active Expired - Fee Related
- 2002-08-15 JP JP2003521695A patent/JP4220384B2/ja not_active Expired - Fee Related
- 2002-08-15 CN CNB028158555A patent/CN1262569C/zh not_active Expired - Fee Related
- 2002-08-15 ES ES02794917T patent/ES2357642T3/es not_active Expired - Lifetime
- 2002-08-15 MX MXPA04001427A patent/MXPA04001427A/es active IP Right Grant
- 2002-08-15 HU HU0401049A patent/HU229193B1/hu not_active IP Right Cessation
- 2002-08-15 US US10/486,776 patent/US7361695B2/en not_active Expired - Lifetime
- 2002-08-15 CA CA2455503A patent/CA2455503C/en not_active Expired - Fee Related
- 2002-08-15 AT AT02794917T patent/ATE497983T1/de not_active IP Right Cessation
- 2002-08-15 BR BRPI0211861A patent/BRPI0211861B1/pt not_active IP Right Cessation
- 2002-08-15 EP EP02794917A patent/EP1419189B1/en not_active Expired - Lifetime
-
2004
- 2004-01-27 ZA ZA2004/00647A patent/ZA200400647B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200400647B (en) | 2005-03-30 |
| JP4220384B2 (ja) | 2009-02-04 |
| HU229193B1 (hu) | 2013-09-30 |
| JP2005500416A (ja) | 2005-01-06 |
| HUP0401049A3 (en) | 2008-04-28 |
| ES2357642T3 (es) | 2011-04-28 |
| CA2455503A1 (en) | 2003-02-27 |
| KR100909946B1 (ko) | 2009-07-30 |
| WO2003016372A1 (en) | 2003-02-27 |
| DE60239136D1 (de) | 2011-03-24 |
| CA2455503C (en) | 2011-03-22 |
| KR20040030084A (ko) | 2004-04-08 |
| EP1419189A1 (en) | 2004-05-19 |
| TW592813B (en) | 2004-06-21 |
| MXPA04001427A (es) | 2004-06-03 |
| US7361695B2 (en) | 2008-04-22 |
| CN1262569C (zh) | 2006-07-05 |
| HUP0401049A2 (hu) | 2004-08-30 |
| ATE497983T1 (de) | 2011-02-15 |
| EP1419189B1 (en) | 2011-02-09 |
| US20040242718A1 (en) | 2004-12-02 |
| CN1541234A (zh) | 2004-10-27 |
| BRPI0211861B1 (pt) | 2015-09-08 |
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