BR0111820A - Composição de catalisador de epoxidação, e, processos para a preparação de uma composição de catalizador de epoxidação heterogêneo e de um óxido de alquileno - Google Patents
Composição de catalisador de epoxidação, e, processos para a preparação de uma composição de catalizador de epoxidação heterogêneo e de um óxido de alquilenoInfo
- Publication number
- BR0111820A BR0111820A BR0111820-0A BR0111820A BR0111820A BR 0111820 A BR0111820 A BR 0111820A BR 0111820 A BR0111820 A BR 0111820A BR 0111820 A BR0111820 A BR 0111820A
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst composition
- extrudate
- heterogeneous
- preparing
- processes
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 4
- 125000002947 alkylene group Chemical group 0.000 title abstract 2
- 238000006735 epoxidation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 8
- 239000000377 silicon dioxide Substances 0.000 abstract 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 150000002432 hydroperoxides Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0238—Impregnation, coating or precipitation via the gaseous phase-sublimation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
"COMPOSIçãO DE CATALISADOR DE EPOXIDAçãO, E, PROCESSOS PARA A PREPARAçãO DE UMA COMPOSIçãO DE CATALISADOR DE EPOXIDAçãO HETEROGêNEO E DE UM óXIDO DE ALQUILENO". Composição de catalisador compreendendo titânio ligado quimicamente a um suporte de sílica, caracterizada pelo fato de que o suporte de sílica é um extrusado conformado de pó de sílica. A composição de catalisador é muito útil na epoxidação de olefinas a óxidos de alquileno usando hidroperóxidos orgânicos. A composição pode ser preparada por meio de um processo que compreende as etapas de: (a) extrusar pó de sílica como um extrusado que possui uma forma selecionada; (b) calcinar o extrusado; (c) impregnar o extrusado com um agente de impregnação contendo titânio; e (d) secar e calcinar o extrusado impregnado.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00305252 | 2000-06-21 | ||
| PCT/EP2001/007080 WO2001097967A1 (en) | 2000-06-21 | 2001-06-21 | Catalyst composition, process for its preparation and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0111820A true BR0111820A (pt) | 2003-06-17 |
| BR0111820B1 BR0111820B1 (pt) | 2012-12-11 |
Family
ID=8173076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0111820-0A BR0111820B1 (pt) | 2000-06-21 | 2001-06-21 | processos para a preparação de um óxido de alquileno e de um catalisador heterogêneo. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7713906B2 (pt) |
| EP (1) | EP1292391B1 (pt) |
| JP (1) | JP2003535686A (pt) |
| CN (1) | CN1178929C (pt) |
| AT (1) | ATE360479T1 (pt) |
| AU (1) | AU2001267555A1 (pt) |
| BR (1) | BR0111820B1 (pt) |
| CA (1) | CA2413119A1 (pt) |
| DE (1) | DE60128085T2 (pt) |
| ES (1) | ES2282265T3 (pt) |
| MX (1) | MXPA02012591A (pt) |
| MY (1) | MY131860A (pt) |
| WO (1) | WO2001097967A1 (pt) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6844454B2 (en) * | 2002-04-12 | 2005-01-18 | Shell Oil Company | Process |
| RU2006102493A (ru) * | 2003-06-30 | 2006-06-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Получение катализатора |
| US6958405B2 (en) * | 2004-03-09 | 2005-10-25 | Arco Chemical Technology, L.P. | Polymer-encapsulated titanium zeolites for oxidation reactions |
| JP4813830B2 (ja) * | 2004-10-14 | 2011-11-09 | 三菱重工業株式会社 | 排ガス処理触媒、排ガス処理方法および排ガス処理装置 |
| JP4935604B2 (ja) * | 2006-11-27 | 2012-05-23 | 住友化学株式会社 | 担持酸化ルテニウムの製造方法 |
| CN102247895B (zh) * | 2010-05-20 | 2013-04-24 | 中国石油化工股份有限公司 | 催化剂载体的制备方法以及费托合成催化剂的制备方法 |
| US9039898B2 (en) * | 2011-11-15 | 2015-05-26 | Engineering Research Associates, Inc. | Method for separating components in natural oil |
| EP2859945A1 (en) | 2013-10-11 | 2015-04-15 | Repsol, S.A. | Process for the preparation of a heterogeneous epoxidation catalyst |
| ES3024465T3 (en) | 2014-01-22 | 2025-06-04 | Lyondell Chemical Tech Lp | Method of preparing epoxidation catalysts |
| WO2017080962A1 (en) * | 2015-11-09 | 2017-05-18 | Shell Internationale Research Maatschappij B.V. | Catalyst preparation |
| CN106378122A (zh) * | 2016-08-26 | 2017-02-08 | 天津南化催化剂有限公司 | 一种硅胶负载钛催化剂及制备方法及用途 |
| CN107224993B (zh) | 2017-05-25 | 2019-12-13 | 万华化学集团股份有限公司 | 一种烯烃环氧化催化剂的制备方法 |
| CN107715868B (zh) | 2017-10-27 | 2019-07-23 | 万华化学集团股份有限公司 | 一种丙烯环氧化催化剂的制备方法及其用途 |
| JP7803854B2 (ja) * | 2019-11-04 | 2026-01-21 | ライオンデル ケミカル テクノロジー、エル.ピー. | チタン化触媒、チタン化触媒を調製する方法、及びエポキシ化の方法 |
| SG11202109384VA (en) | 2020-01-14 | 2021-09-29 | Wanhua Chemical Group Co Ltd | Preparation method for propylene epoxidation catalyst and use thereof |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4367342A (en) * | 1969-04-02 | 1983-01-04 | Shell Oil Company | Olefin epoxidation |
| AT302983B (de) * | 1969-04-02 | 1972-11-10 | Shell Int Research | Verfahren zur Epoxydation von olefinischen Verbindungen |
| DK132544C (da) | 1970-01-22 | 1976-05-24 | Shell Int Research | Fremgangsmade til fremstilling af en siliciumdioxid-titanoxid-katalysator der egner sig til fremstilling af oxiranforbindelser ved omsetning af olefinisk umettede carbonhydrider med organiske hydroperoxider |
| US3829392A (en) * | 1970-10-01 | 1974-08-13 | Shell Oil Co | Heterogeneous catalysts for olefin epoxidation |
| US3923843A (en) * | 1972-03-13 | 1975-12-02 | Shell Oil Co | Epoxidation process with improved heterogeneous catalyst |
| IT1127311B (it) * | 1979-12-21 | 1986-05-21 | Anic Spa | Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi |
| IT1222022B (it) * | 1987-07-14 | 1990-08-31 | Montedipe Spa | Metodo per la preparazione di un catalizzatore per l' ammossimazione di composti carbonilici |
| GB8722459D0 (en) * | 1987-09-24 | 1987-10-28 | Shell Int Research | Silica extrudates |
| GB8724436D0 (en) * | 1987-10-19 | 1987-11-25 | Shell Int Research | Silica-alumina extrudates |
| GB8729555D0 (en) * | 1987-12-18 | 1988-02-03 | Shell Int Research | Alkylation process |
| DE3803895C1 (pt) | 1988-02-09 | 1989-04-13 | Degussa Ag, 6000 Frankfurt, De | |
| GB8813484D0 (en) * | 1988-06-08 | 1988-07-13 | Shell Int Research | Process for preparation of oxirane compound |
| DE3912504A1 (de) | 1989-04-17 | 1990-10-18 | Degussa | Presslinge auf basis von pyrogen hergestelltem siliciumdioxid, verfahren zu ihrer herstellung und ihre verwendung |
| US5364824A (en) * | 1992-12-08 | 1994-11-15 | Huntsman Specialty Chemicals Corporation | Catalysis for the production of maleic anhydride containing vanadium-phosphorus oxide with selected promoter elements |
| DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
| JP3658790B2 (ja) | 1995-03-30 | 2005-06-08 | 住友化学株式会社 | 触媒及びオキシラン化合物の製造方法 |
| DE19623609A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators |
| US5800136A (en) * | 1997-02-28 | 1998-09-01 | Shurflo Pump Manufacturing Co. | Pump with bypass valve |
| US6187934B1 (en) | 1997-03-26 | 2001-02-13 | Sumitomo Chemical Company Limited | Titanium-containing solid catalyst |
| JP4041575B2 (ja) * | 1997-03-26 | 2008-01-30 | 住友化学株式会社 | チタン含有固体触媒及びオキシラン化合物の製造方法 |
| BR9809020A (pt) * | 1997-05-05 | 2000-08-01 | Arco Chem Tech | Processo de epoxidação usando composição de catalisador heterogêneo aperfeiçoada |
| US6011162A (en) * | 1997-05-05 | 2000-01-04 | Arco Chemical Technology, L.P. | Epoxidation process using improved heterogeneous catalyst composition |
| JP3658973B2 (ja) | 1998-02-18 | 2005-06-15 | 住友化学株式会社 | チタン含有固体触媒及びオキシラン化合物の製造方法 |
| AU4335100A (en) * | 1999-04-08 | 2000-10-23 | Dow Chemical Company, The | Process for the hydro-oxidation of olefins to olefin oxides using oxidized gold catalyst |
| US6114552A (en) * | 1999-09-28 | 2000-09-05 | Arco Chemical Technology, L.P. | Heterogeneous epoxidation catalyst |
| RU2006102493A (ru) * | 2003-06-30 | 2006-06-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Получение катализатора |
-
2001
- 2001-06-19 MY MYPI20012875A patent/MY131860A/en unknown
- 2001-06-21 AU AU2001267555A patent/AU2001267555A1/en not_active Abandoned
- 2001-06-21 US US10/312,099 patent/US7713906B2/en not_active Expired - Fee Related
- 2001-06-21 MX MXPA02012591A patent/MXPA02012591A/es active IP Right Grant
- 2001-06-21 AT AT01945300T patent/ATE360479T1/de not_active IP Right Cessation
- 2001-06-21 CA CA002413119A patent/CA2413119A1/en not_active Abandoned
- 2001-06-21 DE DE60128085T patent/DE60128085T2/de not_active Expired - Fee Related
- 2001-06-21 JP JP2002503441A patent/JP2003535686A/ja active Pending
- 2001-06-21 CN CNB018115055A patent/CN1178929C/zh not_active Expired - Fee Related
- 2001-06-21 ES ES01945300T patent/ES2282265T3/es not_active Expired - Lifetime
- 2001-06-21 BR BRPI0111820-0A patent/BR0111820B1/pt not_active IP Right Cessation
- 2001-06-21 WO PCT/EP2001/007080 patent/WO2001097967A1/en not_active Ceased
- 2001-06-21 EP EP01945300A patent/EP1292391B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2413119A1 (en) | 2001-12-27 |
| ATE360479T1 (de) | 2007-05-15 |
| DE60128085D1 (de) | 2007-06-06 |
| US20030166951A1 (en) | 2003-09-04 |
| EP1292391B1 (en) | 2007-04-25 |
| DE60128085T2 (de) | 2007-12-27 |
| WO2001097967A1 (en) | 2001-12-27 |
| US7713906B2 (en) | 2010-05-11 |
| MXPA02012591A (es) | 2003-05-14 |
| MY131860A (en) | 2007-09-28 |
| JP2003535686A (ja) | 2003-12-02 |
| AU2001267555A1 (en) | 2002-01-02 |
| EP1292391A1 (en) | 2003-03-19 |
| ES2282265T3 (es) | 2007-10-16 |
| CN1438919A (zh) | 2003-08-27 |
| BR0111820B1 (pt) | 2012-12-11 |
| CN1178929C (zh) | 2004-12-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B09X | Republication of the decision to grant [chapter 9.1.3 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 11/12/2012, OBSERVADAS AS DEMAIS CONDICOES LEGAIS. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time | ||
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |