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BE868160A - Catalyseurs superacides solides a base de graphite fluore - Google Patents

Catalyseurs superacides solides a base de graphite fluore

Info

Publication number
BE868160A
BE868160A BE188604A BE188604A BE868160A BE 868160 A BE868160 A BE 868160A BE 188604 A BE188604 A BE 188604A BE 188604 A BE188604 A BE 188604A BE 868160 A BE868160 A BE 868160A
Authority
BE
Belgium
Prior art keywords
solid superacid
catalyzers
fluorine graphite
graphite
fluorine
Prior art date
Application number
BE188604A
Other languages
English (en)
French (fr)
Inventor
G A Olah
Original Assignee
Ugine Kuhlmann
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ugine Kuhlmann filed Critical Ugine Kuhlmann
Publication of BE868160A publication Critical patent/BE868160A/xx

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • B01J27/12Fluorides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56Addition to acyclic hydrocarbons
    • C07C2/58Catalytic processes
    • C07C2/62Catalytic processes with acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66Catalytic processes
    • C07C2/68Catalytic processes with halides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/271Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with inorganic acids; with salts or anhydrides of acids
    • C07C5/2718Acids of halogen; Salts thereof; complexes thereof with organic compounds
    • C07C5/2721Metal halides; Complexes thereof with organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2727Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with hydrides or organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2778Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C5/2786Acids of halogen; Salts thereof
    • C07C5/2789Metal halides; Complexes thereof with organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18Carbon
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/03Acids of sulfur other than sulfhydric acid or sulfuric acid, e.g. halosulfonic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06Halogens; Compounds thereof
    • C07C2527/08Halides
    • C07C2527/12Fluorides
    • C07C2527/1206Hydrogen fluoride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06Halogens; Compounds thereof
    • C07C2527/133Compounds comprising a halogen and vanadium, niobium, tantalium, antimonium or bismuth
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025Sulfonic acids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BE188604A 1977-06-16 1978-06-15 Catalyseurs superacides solides a base de graphite fluore BE868160A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/807,014 US4116880A (en) 1977-06-16 1977-06-16 Solid catalysts based on fluorinated graphite

Publications (1)

Publication Number Publication Date
BE868160A true BE868160A (fr) 1978-12-15

Family

ID=25195373

Family Applications (1)

Application Number Title Priority Date Filing Date
BE188604A BE868160A (fr) 1977-06-16 1978-06-15 Catalyseurs superacides solides a base de graphite fluore

Country Status (8)

Country Link
US (1) US4116880A (de)
JP (1) JPS5417389A (de)
BE (1) BE868160A (de)
DE (1) DE2826016C3 (de)
FR (1) FR2394325A1 (de)
GB (1) GB1594050A (de)
LU (1) LU79811A1 (de)
NL (1) NL7806495A (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1129809B (it) * 1979-03-26 1986-06-11 Ugine Kuhlmann Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione
US4300008A (en) * 1980-09-25 1981-11-10 Standard Oil Company (Indiana) Preparation of 2,6-dimethyldecalin and its isomers
JPS57123125A (en) * 1981-01-20 1982-07-31 Ugine Kuhlmann Selective manufacture of beta-isopropylnaphthalene
US4433192A (en) * 1981-09-01 1984-02-21 Olah George A Condensation of natural gas or methane into gasoline range hydrocarbons
US4487970A (en) * 1983-06-03 1984-12-11 Phillips Petroleum Company Cleavage of hydroperoxides
US4463207A (en) * 1983-09-23 1984-07-31 Shell Oil Company Arene alkylation with metal oxide-tantalum halide/oxide catalysts
US4783567A (en) * 1987-11-23 1988-11-08 Uop Inc. HF alkylation process
US5288677A (en) * 1991-06-28 1994-02-22 Exxon Chemical Patents Inc. Immobilized Lewis acid catalysts
EP0700405B1 (de) * 1993-05-20 1998-04-08 Exxon Chemical Patents Inc. Lewis-säure-katalysatoren auf einem porösen polymersubstrat
WO1994028036A1 (en) * 1993-05-20 1994-12-08 Exxon Chemical Patents Inc. Heterogeneous lewis acid-type catalysts
JP2580526B2 (ja) * 1993-12-07 1997-02-12 工業技術院長 芳香族化反応用触媒及びそれを用いる芳香族化合物の製造方法
AU2131095A (en) * 1994-03-31 1995-10-23 Exxon Chemical Patents Inc. Supported lewis acid catalysts derived from superacids useful for hydrocarbon conversion reactions
US5459212A (en) * 1994-05-26 1995-10-17 E. I. Du Pont De Nemours And Company Carbon based initiators for polymerization and telomerization of vinyl monomers
US5622683A (en) * 1994-06-13 1997-04-22 Hung; Ching-Cheh Chemically modified carbonaceous materials made by the defluorination of graphite fluoride and process therefor
US6060633A (en) * 1995-10-20 2000-05-09 Chen; Frank Joung-Yei Supported Lewis acid catalysts derived from superacids useful for hydrocarbon conversion reactions
US5691431A (en) * 1996-01-18 1997-11-25 Exxon Chemical Patents Inc. Cationic polymerization catalyzed by lewis acid catalysts supported on porous polymer substrate
FR2748014B1 (fr) * 1996-04-26 1998-07-17 Centre Nat Rech Scient Nouveaux carbones fluores, leur procede de preparation et leur utilisation comme materiau d'electrode
CA2260398C (en) 1998-01-30 2008-10-14 Trysol Limited Desulfurization of petroleum products
CN1057989C (zh) 1998-04-22 2000-11-01 中国石油化工总公司 异构烷烃与烯烃的烷基化方法
RU2142931C1 (ru) * 1999-03-30 1999-12-20 Генин Геннадий Владимирович Способ переработки органического сырья и катализатор для его осуществления
US6479598B1 (en) * 1999-07-20 2002-11-12 Exxonmobil Chemical Patents Inc. Petroleum resins and their production with BF3 catalyst
CN1100028C (zh) 1999-07-22 2003-01-29 中国石油化工集团公司 一种异构烷烃与烯烃的烷基化方法
AU2002231197A1 (en) * 2000-12-07 2002-06-18 Univation Technologies Llc Support materials for use with polymerization catalysts
CN1291954C (zh) * 2004-01-19 2006-12-27 中国石油化工股份有限公司 一种固体酸催化异构烷烃与烯烃的烷基化反应方法
US8765070B2 (en) * 2009-09-22 2014-07-01 Lockheed Martin Corporation System and method for rejecting heat from equipment via endothermic isomerization
US20110091370A1 (en) * 2009-10-15 2011-04-21 U.S. Government As Represented By The Secretary Of The Army Mechanochemical Synthesis of Carbon Fluorides and an Electrochemical Cell using the Synthesized Carbon Fluorides
BR112017027823B1 (pt) 2015-06-22 2022-04-05 Exelus, Inc Alquilação catalisada melhorada, catalisadores de alquilação e métodos para fabricação de catalisadores de alquilação
US11851386B2 (en) 2021-10-15 2023-12-26 Exelus, Inc. Solid-acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3678120A (en) * 1970-01-29 1972-07-18 Universal Oil Prod Co Hydrocarbon conversion catalyst and process
US3708553A (en) * 1971-06-25 1973-01-02 Exxon Research Engineering Co Alkylation process utilizing a lewis acid halide with fluorosulfuric or trifluoromethanesulfonic acid
GB1453044A (en) * 1973-06-14 1976-10-20 British Petroleum Co Production of acid hydrocarbon conversion catalysts
US3925495A (en) * 1974-05-06 1975-12-09 Mobil Oil Corp Hydrocarbon conversion in the presence of a catalyst of a lewis acid intercalated in graphite
US3984352A (en) * 1974-05-06 1976-10-05 Mobil Oil Corporation Catalyst containing a Lewis acid intercalated in graphite
JPS5141037A (ja) * 1974-10-03 1976-04-06 Ota Toshuki Aruminiumunotosoho
GB1471587A (en) * 1974-10-09 1977-04-27 British Petroleum Co Alkylation catalyst and process
GB1460240A (en) * 1974-11-12 1976-12-31 Exxon Research Engineering Co Lewis acid-fluorine compounds of carbon
US3962133A (en) * 1974-12-12 1976-06-08 Mobil Oil Corporation Graphite intercalation
AU1439476A (en) * 1975-06-13 1977-12-01 Exxon Research Engineering Co Alkylation of light paraffins
US4041078A (en) * 1976-09-30 1977-08-09 Texaco Development Corporation Method of preparing polyaminopolyphenylmethanes

Also Published As

Publication number Publication date
US4116880A (en) 1978-09-26
JPS5417389A (en) 1979-02-08
FR2394325A1 (fr) 1979-01-12
DE2826016B2 (de) 1980-08-07
LU79811A1 (fr) 1980-01-22
GB1594050A (en) 1981-07-30
DE2826016C3 (de) 1981-06-11
NL7806495A (nl) 1978-12-19
DE2826016A1 (de) 1978-12-21
FR2394325B1 (de) 1981-10-30

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Legal Events

Date Code Title Description
RE Patent lapsed

Owner name: PRODUITS CHIMIQUES UGINE KUHLMANN

Effective date: 19870630