AU781926B2 - Refrigerator stable raw alimentary paste - Google Patents

Description

4 WO 01/37679 PCT/AU00/01429 -1- REFRIGERATOR STABLE RAW ALIMENTARY PASTE Field of the Invention This invention generally relates to a refrigerator stable raw alimentary paste including spaghetti, macaroni, noodles, fettuccine etc. In particular, this invention relates to a raw fresh alimentary paste having extended shelf life under refrigerated conditions and a method of manufacturing same. Further aspects of the invention will become evident from the description which follows.

Background Art Traditionally, fresh or raw alimentary pastes such as pasta and noodles have been cooked and eaten within a day or two of preparation, and with a minimum of drying, before spoilage can occur due to yeast, bacteria and mould. Freshly made pasta and noodles can be purchased either uncooked (raw) or cooked. These products are usually prepared from wheat flour, with or without egg or other ingredients. They are highly perishable and must be consumed within a day or so of manufacture.

The wide popularity of pasta as a food and the necessity for shelf-stable economical distribution has resulted in the widespread production of dried pasta products having a moisture content of about 10-12%. The drying of pasta to such low moisture levels requires careful control of humidity and expensive drying equipment. Drying times can also be quite long thereby involving expensive capital equipment and increasing production costs.

Dried pasta products are preferably sufficiently thick in cross-section or have sufficiently thick cross sectional walls as are necessary to give strength for shipping to market and good mouth feel to the pasta when cooked. Such dried pasta products normally take 10 to 20 minutes to cook. With current marketing trends these cooking times are too long to be considered "convenience foods". The present day consumer is generally looking for a WO 01/37679 PCT/AU00/01429 -2product that can be prepared in five minutes or less.

The present trend in food consumption is also towards fresh products. Fresh pasta presents a conceptually desirable image to the consumer, and has a significantly shorter cooking time because it requires less rehydration on cooking.

The development of efficient refrigerated distribution methods has led to the marketing of many types of fresh pasta. Without refrigeration, pasta is very susceptible to mould and bacterial growth. At ambient temperature spoilage can develop within a few days or less.

Under efficient refrigeration the shelf-life can be extended by a week or two, and up to about a month. Even with an efficient refrigerated distribution, fresh pasta is still considered to be quite perishable.

Anything that can be done to extend the shelf-life, thereby aiding distribution and safety, would be a benefit as would any reduction in cooking time without a resulting loss of quality.

The use of fungistats such as sorbic acid and sorbates, propionates and such compounds in food products are known, and their use can extend the storage life.

The shelf-life of fresh pasta may also be extended by heat treatment with steam, microwaves or by other such methods prior to packaging. Pasteurisation however adds substantially to the cost of processing and packaging, and can cause undesirable partial cooking or gelatinisation of the pasta. Very careful control over microbiological reinfection is also necessary during packaging. The fresh pasta should be gas packed free of oxygen to deter spoilage by micro-organisms and reduce oxidative changes to colour and flavour. To remain reasonably flexible in a way similar to freshly made pasta, the moisture content should be above about 25%. Such pasta will have a water activity of 0.94-0.98. However, in the absence of oxygen at these water activities growth of anaerobic bacteria such as Clostridium botulinum can prove a considerable health hazard.

PAWPDOCS Hj.Up-0555490B P. AU.d-29104/5 -3- Lewis et al. (US 3,495,989) discloses the steeping of high moisture pasta in saturated brine to extend the shelf-life and reduce the cooking time of the pasta. Physical problems were cncountered i handling the product on an industrial scale. There were also effluent problems.

Gaebring et al. (US 4,529,609) describes the production of a semi-moist pasta with the addition of salt and partial drying to approximately 16-25% moisture together with gelatinisation to give a product with a maximum water activity of 0.85. To maintain flexibility at these salt and moisture levels, partial gelatinising in steam is required. This then necessitates cooling and drying to achieve the water activity of 0.85 or lower. Drying -can take 20-40 minutes. The salt content ranges from 3% to Salt levels in this range are generally unpalatable and the gelatinisation step is a substantial obstacle to productioill, 1 both in time, manufacturing control, capital cost and product cost.

It is a preferred object of the present invention to overcome or at least minimise or reduce substantially one or more of the above-mentioned disadvantages of the prior art, or at least to provide the public with a useful choice over existing fresh pasta products.

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Summary of the invention 20 This invention provides a raw fresh alimentary paste having a water activity (Aw) of 0.87- 0.92 comprising a raw dough formed into a shape suitable for cooking and consumption, the raw dough comprising flour, an aqueous dough-forming agent and a water activity reducing agent, wherein the water activity reducing agent is in sufficient amount to impart to the alimentary paste stability against microbial growth under refrigeration for greater then six months without gelatinisation when packaged in a container to protect the alimentary paste from oxygen.

The invention further provides a method of preparing a raw fresh alimentary paste having a water activity (Aw) of 0.87-0.92 and stability against microbial growth under refrigeration for greater than six months without gelatinisation when packaged in a container to protect the alimentary paste from oxygen, the method comprising the steps of preparing a raw P:\WPDOCSj~ spccs\735J490 Paa AU dx-29/04/05 -4dough from a mixture comprising flour, an aqueous dough-forming agent and a water activity reducing compound in an amount sufficient to impart said stability to the raw dough,; and forming the raw dough into a shape suitable for cooking and consumption.

The invention also provides a packaged, raw fresh pasta product stable against microbial growth under refrigeration for greater than six months without gelatinisation comprising an oxygen protective container enclosing an alimentary paste having a water activity (Aw) of 0.87-0.92 said alimentary paste comprising a raw dough formed into a shape suitable for cooking and consumption, the raw dough comprising flour, an aqueous dough-forming *agent and a water activity reducing compound in sufficient amount to impart said stability •-to the alimentary paste.

The invention further provides a method of making a packaged, raw fresh pasta product stable against microbial growth for greater than six months without gelatinisation and :...having a water activity of 0.87-0.92 comprising the steps of preparing a raw dough from a mixture of flour, an aqueous dough-forming agent and a water activity reducing compound in an amount sufficient to impart said stability to the raw dough; preparing an alimentary paste by forming the raw dough into a shape suitable for cooking and 20 consumption; packaging the alimentary paste in a container to protect the alimentary paste from oxygen; and storing the packaged alimentary paste under refrigeration.

Products prepared by the above methods are also provided by this invention.

The raw fresh pasta product of the present invention is not subject to significant deterioration or spoilage for at least 6 months when stored at refrigeration temperatures in the absence of oxygen.

Detailed description of the invention The term "alimentary paste" is to be taken in its broadest sense to include pasta, pasta products, noodles, egg noodles or similar products prepared by extruding, forming or PAWPDOCS".jAsp,%75554&0 P s AU.dmc29O4/O5 sheeting or otherwise shaping a farinaceous dough which has been sufficiently moistened to allow these operations.

The terms "raw" and "fresh" as used herein with reference to alimentary pastes and pasta products are taken in the broader sense to refer to alimentary pastes manufactured without having been substantially dried, canned, cooked, gelatinised or sterilised. Such raw alimentary pastes and pasta products are high in moisture content and are usually marketed in fresh or refrigerated forms.

The dough may be made from wheat semolina or flour and an aqueous dough-forming agent, optionally together with mixtures of such other meals, flours and other ingredients as may be traditionally or alternately used. The aqueous dough-forming agent is typically water, fresh or reconstituted egg products, mixtures thereof, or any other suitable watercontaining substance as known to those skilled in the art.

In preparing the dough, other additives may also be used. These include but are not limited to fresh or pasteurised whole eggs and fresh, frozen or dried egg whites and yolks, wheat gluten, protein supplements, gums, emulsifiers, salts, milk solids, soy flours and 2 isolates, flavours, colours, vegetable matter, antioxidants, preservatives and other standard agents known to those skilled in the art.

The raw pasta product of the present invention has a high moisture content and is prepared without drying, or without substantial drying. The pasta also contains a water activity reducing compound such as for example edible salt in an amount sufficient to reduce the water activity to impart stability against microbial spoilage and decomposition. Other humectants including sugars such as sucrose, lactose, xylose, glucose, fructose and maltose; and polyol alcohols such as glycerol, sorbitol and glycol may be used in place of or in addition to edible salts in alimentary pastes. These products were formulated to have a water activity low enough to inhibit microbial growth under the condition prescribed for storage but their addition levels not high enough to impart flavour changes to the products.

P \WPDOCSU"j.sp s\753480 PaSl AU doK-29/4105 Ideally the water activity of the pasta is from about 0.87-0.92, whilst the moisture content remains at about 25-35% moisture. Advantages of the higher moisture content include that the pasta product cooks more quickly, remains very flexible and has good flavour, colour and texture when cooked. The lower water activity provides a bacteriologically safe product when packaged according to the invention and kept under refrigeration for extended periods. The packaged raw pasta product is stable against microbiological spoilage for substantial periods, typical greater than one or two months and even up to six months or longer.

*o* WO 01/37679 PCT/AU00/01429 -6- In a preferred embodiment, the process of the present invention provides a raw fresh wheat or semolina dough containing from 25% moisture up to about 31% moisture, more typically about 30-31% moisture. The dough is formed by mixing salt brine or finely powdered salt with semolina flour and water as required at a rate of preferably about 1-4 wt. salt, more preferably about 2.5 wt. salt, to the weight of the dough and thoroughly mixing before extrusion or forming. If desired various additives well known in the art, such as gluten, glycerol monostearate, sodium acetate, potassium sorbate, dried vegetable, powders, egg or egg white or other common additives may optionally be added at the mixing stage.

The edible salt used is preferably sodium chloride such as common table salt or sea salt.

Other edible salts such as potassium chloride may be used or substituted for part of the common table salt if desired. The salt should be used in an amount such that the water activity of the pasta when packaged will preferably be between 0.87 and 0.92, more preferably about 0.90. At this water activity and at refrigerator temperatures most pathogenic bacteria and microbes which cause food spoilage will not grow. The resultant product made from pasta dough having about a 2.5% salt content represents a salt level in the aqueous phase in the product of about 10%, and even higher than this in the free (unbound) moisture. The resultant pasta is still quite flexible without resorting to gelatinisation. When the pasta is stored at frozen temperatures it will not freeze hard and will not become excessively brittle. When the pasta is made from flour and water, but contains no salt, it typically has a water activity of about 0.96-0.97. The addition of 2.5 wt.

salt to the pasta reduces the water activity to about 0.90. The presence of salt at this level also has a marked effect on reducing the cooking time by facilitating the absorption of water into the pasta, in addition to its microbial protection properties. As compared to a control containing no salt, the pasta containing 2.5% of salt reduces the cooking time by 20-33%. Of course the pasta at 30-31% moisture content containing no salt will spoil readily due to microbial activity, and it will be a health hazard.

After preparation, the dough is extruded, sheeted or otherwise formed as desired into shapes such as for example spaghetti, macaroni, spirals, noodles, fettuccine, lasagne, WO 01/37679 PCT/AU00/01429 -7vermicelli, penne and shells. The pasta may then if necessary be dried minimally and only sufficiently to avoid cohesion. It has been found that this may be achieved by reducing the moisture content by as little as 1% to about 29-30% moisture. This reduction in moisture will normally occur between forming and packaging operations during normal transport to the packaging area without spccialised dehydration equipment. If necessary the pasta may be dusted with flour or other meals or agents, or may be coated with about 1-2 wt. of oil to avoid sticking as is known to a person well skilled in the art.

If the moisture content of the pasta is allowed to dry to about 25% or lower, the pasta loses its flexibility to a great extent, becomes excessively brittle and can break or shatter into smaller pieces on handling. The various packaging operations that are necessary makes it desirable that the moisture content be maintained as high as practicable, preferably at a level of 27% to The pasta made in this way represents a very economical method of producing a fresh refrigerator stable pasta as it avoids the necessity of gelatinising and/or pasteurising and substantial drying, and expensive controlled reduction of reinfection during packaging.

The pasta should be packed in packaging with low oxygen and moisture permeability, preferably in an atmosphere of an oxygen free gas such as nitrogen or a mixture of nitrogen and carbon dioxide. This is important in maintaining the fresh colour of the pasta, inhibiting yeast and mould growth and avoiding storage odours that would develop if the product was packed with ready access to oxygen. Oxygen absorbers or active packaging which absorbs oxygen into the packaging film may optionally be used as well known in the art.

Pasta produced and packaged in this way, and refrigerated at about 4°C, will have a shelflife of up to and greater than six months whilst still retaining the desirable characteristics of fresh pasta.

For use, the pasta ideally should be cooked in about 10 to 15 times its weight of unsalted WO 01/37679 PCT/AU00/01429 -8boiling water until the desired consistency is obtained. This is in line with the normal recommendations for cooking pasta. With a normal 2 mm diameter extruded spaghetti the cooking time is about three to four minutes. The required cooking time may vary with the shape and thickness of the pasta.

During cooking, salt is leached out of the pasta product and into the water giving a cooked pasta with a very good taste and texture. Thus salt addition to the cook water is no longer required. The success of the invention resides in the fresh pasta product having a salt content sufficient to provide stability against microbial growth and product degradation and spoilage, yet not having a content sufficient enough to impart an undesirable salty taste after leaching of salt during cooking.

In order to facilitate an understanding of the invention, reference will be made to the following examples which describe preferred embodiments of the invention. The Examples are not to be construed as limiting the invention in any way.

Example 1 500 g of durum wheat semolina was mixed with 156 g of water and 16.9 g of salt for about five minutes to prepare a dough. The dough was extruded through a laboratory size "La Parmigiana" pasta extruder equipped with a 2 mm spaghetti die. After extrusion, the pasta was allowed to dry at ambient temperature for about ten minutes. The moisture content was 29.6% and the water activity 0.90 as determined by methods well known in the food industry. The cooking time of the pasta, when boiled in 10-15 times its weight of unsalted water, was three to four minutes. The pasta was packaged in a low oxygen transmission film in a mixture of 60% nitrogen and 40% carbon dioxide and stored under refrigeration at approximately 6°C.

After six months, the pasta had excellent colour, no off-odour and no signs of mould growth. The cooking time for the pasta product which was stored for six months was also three to four minutes, and the flavour and texture was equivalent to the cooked freshly made product above.

PAWPDOCsc.i',p\7554SO Pa AU d.-29IO4/0 -9- Example 2 400 g of wheat flour, 1 25 of water and 2.4 g of salt were mixed for ten minutes to form a dough. After the dough had rested for about 10 minutes, it was sheeted through rollers to produce a sheet 0.4 mm. This was then cut with traditional equipment into noodles 2 mm wide. The water activity of the noodles was 0.91 and the moisture content 29%. The noodles were packed in a low oxygen transmission film in a mixture of nitrogen 60% and carbon dioxide 40%, together with an oxygen absorber ("Ageless" from Mitsubishi Chemical Company, Japan).

After storage for 6 months at 4 0 C, the noodles were of excellent quality with no evidence of spoilage. The cooking time for the noodles was two minutes in unsalted boiling water, coo* and the flavour and texture was equivalent to cooked pasta that had been freshly prepared.

~Example 3 The following ingredients were mixed in a rotary blender to form a loose dough: 1.97 kg ~wheat flour (as in Example 0.49 kg water and 0.2 kg glycerol. The dough was extruded through a pasta extruder using a 2 mm spaghetti die, cut to suitable pasta lengths and packed under 100% nitrogen atmosphere with a low oxygen transmission film. The moisture content of the pasta was 28.1% and the water activity was 0.90.

The product was stored for 8 months at 4°C and showed no microbial growth, or significant colour changes. When cooked by addition to boiling water that was 10 times the weight of the pasta and simmered for 3 minutes and drained The texture and taste of the pasta was similar to that of the product from Example 1. There was no evidence of glycerol flavour after cooking and the texture was acceptable and similar to cooked fresh pasta.

Example 4 643.5 g of white rice flour, 234 g of water and 22.5 g of salt were mixed for ten minutes to form a loose dough. The dough was then passed through a pasta extruder with a 2 mm P.\WPDOCS\Hjw\pccs\7555480 Pa. AU doc.-2904/05 -9Aspaghetti die, cut to suitable lengths for noodles and packed under 60% nitrogen with carbon dioxide atmosphere with a low oxygen transmission film. The moisture content of the resultant noodles was 30% and the water activity was 0.90.

The products were stored under refrigeration at 4°C for 9 months and were stable with respect to colour, flavour and microbial growth. The noodles were cooked by addition to boiling water at 10 times the weight of the noodles, simmered for 3 minutes and drained.

The noodles had a soft and springy texture, typical rice flavour and white colour.

Those skilled in the art will appreciate that the invention described herein is susceptible to variations and modifications other than those specifically described. It is to be understood :0 that the invention includes all such variations and modifications. The invention also 0::0 includes all of the steps, features, compositions and compounds referred to or indicated in the specification, individually or collectively, and any and all combinations of any two or more of said steps of features.

S Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" or "comprising", will S be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.

o* The reference to any prior art in this specification is not, and should not be taken as, an acknowledgment or any form of suggestion that that prior art forms part of the common general knowledge in the field of endeavour.

Claims (19)

1. A raw fresh alimentary paste having a water activity (Aw) of 0.87-0.92 comprising a raw dough formed into a shape suitable for cooking and consumption, the raw dough comprising flour, an aqueous dough-forming agent and a water activity reducing agent, wherein the water activity reducing agent is in sufficient amount to impart to the alimentary paste stability against microbial growth under refrigeration for greater than six months without gelatinisation when packaged in a container to protect the alimentary paste from oxygen.

2. An alimentary paste of claim 1, wherein the alimentary paste has a moisture content of 25-31% moisture.

3. An alimentary paste of claim I or claim 2, wherein the aqueous dough-forming agent is water, egg or a mixture thereof.

4. An alimentary paste of any of claims 1-3, wherein the water activity reducing agent is an edible salt. An alimentary paste of claim 4, wherein the edible salt is sodium chloride.

6. An alimentary paste of claim 4 or claim 5, wherein the salt content of the alimentary paste is 1-4 wt.%.

7. An alimentary paste of any of claims 1-6, wherein the raw dough further comprises an additive selected from the group consisting of egg, wheat gluten, protein supplements, gums, emulsifiers, milk solids, soy flour and isolates, vegetable matter, flavours, colours, antioxidants and preservatives.

8. An alimentary paste of any of claims 1-7, wherein the shape includes spaghetti, macaroni, spirals, noodles, fettuccine, lasagne, vermicelli, penne and shells. AMEi.N.J-*.' SHE-T PCT/A U00/OT42 Received 13 March 2%62 11

9. A method of preparing a raw fresh alimentary paste having a water activity (Aw) of 0.87-0.92 and stability against microbial growth under refrigeration for greater than six months without gelatinisation when packaged in a container to protect the alimentary paste from oxygen, the method comprising the steps of: a) preparing a raw dough from a mixture comprising flour, an aqueous dough- forming agent and a water activity reducing compound in an amount sufficient to impart said stability to the raw dough; and b) forming the raw dough into a shape suitable for cooking and consumption. A method of claim 9, wherein the alimentary paste has a moisture content of 31% moisture.

11. .A method of claim 9 or claim 10, wherein the aqueous dough-forming agent is water, egg or a mixture thereof.

12. A method of any of claims 9-11, wherein the water activity reducing agent is an edible salt.

13. A method of claim 12, wherein the edible salt is sodium chloride.

14. A method of claim 12 or claim 13, wherein the salt content of the alimentary paste is 1-4 wt.%. A method of any of claims 9-14, wherein the raw dough further comprises an additive selected from the group consisting of egg, wheat gluten, protein supplements, gums, emulsifiers, milk solids, soy flour and isolates, vegetable matter, flavours, colours, antioxidants and preservatives.

16. A method of any of claims 9-15, wherein the shape includes spaghetti, macaroni, spirals, noodles, fettuccine, lasagne, vermicelli, penne and shells. AMENDE:r SHEET IPEA/AU PCT/AUOO/01429 Received 13 March 2002 -12-

17. A packaged, raw fresh pasta product stable against microbial growth under refrigeration for greater than six months without gelatinisation comprising an oxygen protective container enclosing an alimentary paste having a water activity (Aw) of 0.87-0.92 said alimentary paste comprising a raw dough formed into a shape suitable for cooking and consumption, the raw dough comprising flour, an aqueous dough-forming agent and a water activity reducing agent in sufficient amount to impart said stability to the alimentary paste.

18. A method of making a packaged, raw fresh pasta product stable against microbial growth for greater than six months without gelatinisation and having a water activity (Aw) of 0.87-0.92 comprising the steps of: a) preparing a raw dough from a mixture of flour, an aqueous dough-forming agent and a water activity reducing agent in an amount sufficient to impart said stability to the raw dough; b) preparing an alimentary paste by forming the raw dough into a shape suitable for cooking and consumption; c) packaging the alimentary paste in a container to protect the alimentary paste from oxygen; and d) storing the packaged alimentary paste under refrigeration. AMENDED. SHEF, IPEANAU PCT/AUOO/01429 Received 13 March 2002 -12A-

19. A method of providing stability to a raw fresh alimentary paste, wherein said alimentary paste has a water activity (Aw) of 0.87-0.92 and is stable against microbial growth under refrigeration for greater than six months without gelatinisation when packaged in a container to protect the alimentary paste from oxygen, said method comprising the steps of: a) preparing a raw dough from a mixture comprising flour, an aqueous dough- forming agent and a water activity reducing agent in an amount sufficient to impart said stability to the raw dough; and b) preparing the alimentary paste by forming the raw dough into a shape suitable for cooking and consumption. A method of claim 19, wherein the alimentary paste has a moisture content of 31% moisture.

21. A method of claim 19 or claim 20, wherein the water activity reducing agent is an edible salt.

22. A method of claim 21, wherein the edible salt is sodium chloride.

23. A method of claim 21 or claim 22, wherein the salt content of the alimentary paste is 1-4 wt.%. AMENDED SHEET !PEA/AU