AU737969B2 - Heat exchanger including falling-film evaporator and refrigerant distribution system - Google Patents
Heat exchanger including falling-film evaporator and refrigerant distribution system Download PDFInfo
- Publication number
- AU737969B2 AU737969B2 AU16437/00A AU1643700A AU737969B2 AU 737969 B2 AU737969 B2 AU 737969B2 AU 16437/00 A AU16437/00 A AU 16437/00A AU 1643700 A AU1643700 A AU 1643700A AU 737969 B2 AU737969 B2 AU 737969B2
- Authority
- AU
- Australia
- Prior art keywords
- heat exchanger
- refrigerant
- tubes
- exchanger according
- baffles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000003507 refrigerant Substances 0.000 title claims description 67
- 238000009826 distribution Methods 0.000 title claims description 40
- 239000011552 falling film Substances 0.000 title claims description 18
- 239000007921 spray Substances 0.000 claims description 15
- 239000011295 pitch Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 239000011306 natural pitch Substances 0.000 claims description 7
- 239000012530 fluid Substances 0.000 claims description 5
- 238000004891 communication Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- 239000010408 film Substances 0.000 description 6
- 230000005484 gravity Effects 0.000 description 3
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011176 pooling Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/008—Liquid distribution
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
- F28F9/02—Header boxes; End plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/04—Evaporators with horizontal tubes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D3/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium flows in a continuous film, or trickles freely, over the conduits
- F28D3/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium flows in a continuous film, or trickles freely, over the conduits with tubular conduits
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D3/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium flows in a continuous film, or trickles freely, over the conduits
- F28D3/04—Distributing arrangements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2339/00—Details of evaporators; Details of condensers
- F25B2339/02—Details of evaporators
- F25B2339/024—Evaporators with refrigerant in a vessel in which is situated a heat exchanger
- F25B2339/0242—Evaporators with refrigerant in a vessel in which is situated a heat exchanger having tubular elements
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Description
rIUUIU I I 2/5/91 Regulation 3.2(2)
AUSTRALIA
Patents Act 1990
ORIGINAL
COMPLETE SPECIFICATION STANDARD PATENT Application Number: Lodged: Invention Title: HEAT EXCHANGER INCLUDING FALLING-FILM EVAPORATOR AND REFRIGERANT DISTRIBUTION SYSTEM The following statement is a full description of this invention, including the best method of performing it known to us HEAT EXCHANGER INCLUDING FALLING-FILM EVAPORATOR
AND
REFRIGERANT DISTRIBUTION
SYSTEM
Technical Field This invention is directed to improving heat exchanger performance, and more particularly, to an improved Distribution System for Falling-Film Heat Exchangers.
Background Art In the horizontal shell-and-tube falling-film heat exchangers of vapor compression eee e chillers, the heat exchanging fluid is sprayed on the top of the first layer of tubes forming the tube assembly, with the use of spray nozzles. In these situations, a .staggered tube pitch is normally used. The staggered tube pitch tends to cause larger .pressure drops on the vapor side of the tube, as the vapor moves up through the stack, particularly with vapor compression chillers. To rectify this, manufactures will use liberal tube pitches in order to reduce the pressure drop. This results in a larger shell diameter leading to a higher cost for equipment. Additionally, in order to arrange tubes in an in-line pattern so as to minimize the pressure drop penalty, other manufacturers use complicated dripper distribution systems which are heavily susceptible to machine leveling and costly in design and structure. An additional :problem occurs in two phase refrigerant distribution, wherein the spray nozzles used often do not provide a uniform liquid distribution, leading to inferior heat exchanger performance. An additional weakness of staggered tube bank layout is that available fluid flow is distributed over a larger number of tubes. This leads to a relatively lower film flow rate and a lower local recirculation rate (defined as film flow rate divided by vapor production rate), increasing the potential for dry-out and significant reduction in heat transfer coefficients. An in-line tube bank arrangement allows to operate at a higher film flow rate to improve the above mentioned weakness. However, while doing so, it is possible that certain portion of distributed liquid may not reach heat transfer surface, an object of improvement for the present invention.
An example of a recent falling film evaporator design, having a refrigerant distribution system, is shown in US Patent 5,645,124, assigned to American Standard Inc. Several embodiments of refrigerant distributors are shown in this patent, the preferred one uses a mesh screen interface between a distributor and the tubes and another with a tube-in-tube arrangement for distributing the refrigerant onto the screen and heat exchange tube assembly.
As shown in FIG. 7, the refrigerant travels through and inner tube and is released through a top orifice into an outer tuber. The refrigerant drips down the sides of the inner tube through a bottom opening onto the screen and then the evaporator tube. An alternative evaporator tube design is shown whereas instead of a true cylindrical S• •structure, the tube includes a V-point on the bottom surface for directing the drips of •refrigerant onto the under-positioned evaporator tube. In another embodiment, along with the v-point, the evaporator tube includes a pooling area for collecting and then distributing the refrigerant for a more controlled distribution.
The mesh screen is placed in touch with or in close proximity to the top most evaporator tubes of the tube assembly. The mesh screen is corrugated or waved, forming peaks and valleys, such that each valley is generally parallel with and located directly above the longitudinal axis of one of the upper most evaporator tubes. In this manner, pools of liquid refrigerant grow axially along the valleys of the screen until gravity overcomes the surface attraction force which suspends the liquid refrigerant on the mesh screen surface. The refrigerant then falls and drops onto the upper most evaporator tubes. When the screen is touching the tubes, the refrigerant flows onto the tube. While the use of the screens may minimize refrigerant splashing and the amount of refrigerant sucked into the compressor, the screen acts as a substantial impediment to the flow of refrigerant to the evaporator tubes.
There exists a need therefore, for an improved refrigerant distribution system for a falling-film heat exchangers, which system allows for an in-line tube pattern, uniform distribution of the refrigerant and minimal pressure drop over the evaporator tubes.
(1, 3 Disclosure of Invention The primary object of this invention is to provide an improved distribution system for falling-film heat exchangers.
Another object of this invention is to provide an improved distribution system for fallingfilm heat exchangers, wherein an in-line heat exchanger tube system can be used with a simple distribution system, thereby decreasing pressure drop and improving refrigerant distribution efficiency.
Still another object of this invention is to provide an improved refrigerant distribution system for a falling-film heat exchanger, wherein spray nozzles are used for distribution S 10 and a mechanism is provided for accurately directing the refrigerant to the in-line stacked heat exchanger tubes for efficient distribution of the refrigerant oo•$• Still another object of this invention is to provide an improved refrigerant distribution system for a falling-film heat exchanger having increased local film flow rates by using •in-line tube banks, wherein local recirculation rate (defined as film flow rate divided by 15 vapor production rate) is increased to improve wettability and heat transfer coefficients.
According to the invention there is provided a horizontal shell-and-tube heat exchanger having a falling-film evaporator and refrigerant distribution system, including: an inline heat exchanger tube bank operating in a falling-film evaporation mode, including a plurality of unstaggered rows of heat exchanger tubes, wherein said rows are substantially vertically aligned with spaces separating the rows; a supply for providing refrigerant; at least one refrigerant distribution mechanism in fluid communication with said supply and having a refrigerant exit in proximity to said plurality of rows of heat exchanger tubes; and a plurality of baffles positioned at said refrigerant exit and horizontally spaced apart from each other, wherein each of said baffles is in substantial alignment with one of said spaces, extending over said one of said spaces to direct refrigerant from said exit of said distribution
J
7 0 mechanism away from said one of spaces and onto the substantially vertical aligned rows of heat exchanger tubes.
Other optional features are disclosed herein, including in the appended claims.
Brief Description of the Drawings FIGS. la is a frontal schematic view of the spray distribution system and heat exchanger of the present invention, using distributor baffles and an in-line tube bank in accordance with the principles of the present invention; FIG. lb is a side view taken along line lb-lb of FIG la; FIG. 2 is a schematic representation of a staggered tube bank, for a heat exchanger design 10 of the prior art; 9 9 FIG. 3a is an enlarged frontal of the baffles of the spray distribution system shown in FIG.
l;and oooo"- FIG. 3b is an enlarged side view taken along line 3b-3b of FIG 3a, of the baffles of the .99.
spray distribution system shown in FIG. 1.
o S 15 Best Mode for Carrying Out the Invention Referring to FIG. 1, a schematic representation of the preferred embodiment of the improved refrigerant distribution system of the present invention is shown, which is designated generally as 10. The system generally includes spray nozzles 12, baffles 14, and a tub bank Spray nozzles 12 are designed and function in a manner known in the art, and spray refrigerant downwardly on the heat exchanger tube system, arranged in vertically aligned, non-staggered manner. As shown in FIG. 1, each spray nozzle 12 covers an area of spray A, over which area a refrigerant is sprayed downwardly onto the heat exchanger tubes. In a typical arrangement, and with the heat exchanger tubes 16 in a non-staggered positioning, refrigerant would flow in substantial volume between the spaced apart heat exchanger tubes, thereby effecting the efficiency of the tube coverage by the available refrigerant. This is typically the reason why a staggered heat exchanger tube arrangement is used, which staggered arrangement is shown, for example, in FIG. 2. In this manner, any refrigerant falling between heat exchanger tubes is used by the next row of tubes, which are offset in a staggered manner from the previous and subsequent rows. However, as indicated in the background section, the staggered arrangements suffer from an undesirable pressure drop, among the other things described.
In accordance with the principles of the present invention, baffles 14 are provided at the edge of the spray nozzles 12, and are spaced such that they are positioned over the •spaces between heat exchanger tubes. That is, with the heat exchanger tubes arranged in the preferred un-staggered, vertically stacked manner, the baffles 14 are aligned with the spaces between the heat exchanger tubes such as, for example, baffle 14a over space 18. To facilitate directing the refrigerant toward the heat exchanger tubes between which each baffle is placed, the baffle preferably has a chevron shape, having a narrow or pointed end up toward the spray nozzles, such that the legs 22 of the baffles, and surfaces 24 thereof, are pointed substantially towards the longitudinal upper surface center 23 of the two heat exchanger tubes between which the chevron shaped baffle is positioned. In addition, the bottom edge 25 of each baffle is serrated, as shown in FIG. 3, such that the serrations face the in-line tube stacks, as shown. In the preferred embodiment, the distance between the tips 26 of the serrations 28 is a predetermined pitch P. The pitch P is selected to be less than the natural pitch of the refrigerant, measured as it drips in liquid columns from the horizontal tubes of the heat exchanger. The natural pitch of the liquid column is given by the following equation, 2 *n *sigma)/(rho where, sigma surface tension, 6 rho =liquid refrigerant density, and g acceleration due to gravity.
In one embodiment, the preferred pitch of the tips of the serrations will be in the range of sixty to eighty five percent and more particularly seventy five percent of the value determined by equation However, the type of refrigerant used and other factors, including the type of chiller and other equipment used, may effect the optimum percentage chosen. In all cases, the pitch of the serrations should be less than the value determined by Equation By having the pitch of the serrations less than the natural pitch of the liquid column, quick distribution of the liquid refrigerant is facilitated. In addition, the serrations provide passage for vapor to escape the tube bank without significant pressure drop, which would otherwise cause reduction in suction pressure and reduction in chiller efficiency.
In operation, as refrigerant is sprayed downwardly from the nozzles, the refrigerant which exits the nozzles in alignment or on a collision course with spaces 18, flows down the back edge 24 of legs 22 of baffle 14, over the edge 25 and through the serrations 28 and is directed to the top center 23 of the surrounding heat exchanger tubes. Refrigerant then flows around the heat exchanger tubes, over the outside surface of the tube until it reaches the under surface of the tube and gravity breaks the surface bond between the refrigerant and the tube to cause the remaining, non- .I vaporized refrigerant to move to the underlying heat exchanger tubes. While a chevron shaped baffle is shown, it is possible that other shapes can be used such cshaped, v-shaped and half octagonal shaped, to name a few.
The primary advantage of this invention is than an improved distribution system is provided for falling-film heat exchanger. Another advantage of this invention is that an improved distribution system is provided for falling-film heat exchanger, wherein an in-line heat exchanger tube system can be used with a simple distribution system, thereby decreasing pressure drop and improving refrigerant distribution efficiency.
Still another advantage of this invention is that an improved refrigerant distribution system is provided for falling-film heat exchanger, wherein spray nozzles are used for 7 distribution and a mechanism is provided for accurately directing the refrigerant to the inline stacked heat exchanger tubes for efficient distribution of the refrigerant. Still another advantage of this invention is that an improved distribution system is provided which uses an in-line tube bank and exhibits increased film flow rate and local recirculation rate of distributed fluid.
Although the invention has been shown and described with respect to the best mode embodiment thereof, it should be understood by those skilled in the art that the foregoing and various other changes, omissions, and additions in the form and detail thereof may be made without departing from the spirit and scope of the invention.
10 "Comprises" and "comprising" when used in this specification are to be taken to specify the presence of stated features, integers, steps or components but do not preclude the presence of one or more other features, integers, steps, components or groups thereof.
o a ao o
Claims (10)
1. A horizontal shell-and-tube heat exchanger having a falling-film evaporator and refrigerant distribution system, including: an inline heat exchanger tube bank operating in a falling-film evaporation mode, including a plurality of unstaggered rows of heat exchanger tubes, wherein said rows are substantially vertically aligned with spaces separating the rows; a supply for providing refrigerant; at least one refrigerant distribution mechanism in fluid communication with said supply and having a refrigerant exit in proximity to said plurality of rows of heat exchanger tubes; and a plurality of baffles positioned at said refrigerant exit and horizontally spaced apart from each other, wherein each of said baffles is in substantial alignment with one of said spaces, extending over said one of said spaces to direct refrigerant from said exit of said distribution mechanism away from said one of spaces and onto the substantially vertical aligned rows of heat exchanger tubes.
2. A heat exchanger according to claim 1, wherein each of said baffles has a wide ego end and a narrow end, said narrow end positioned closest to said refrigerant exit.
3. A heat exchanger according to claim 2, wherein said baffles are chevron shaped for directing the refrigerant onto the heat exchanger tubes.
4. A heat exchanger according to any one of claims 1 to 3, wherein said baffles have a serrated surface for contacting the refrigerant exiting said refrigerant distribution mechanism. A heat exchanger according to claim 4, wherein said serrated surface includes a plurality of serrations extending in the direction of refrigerant flow from said refrigerant distribution mechanism.
F_
6. A heat exchanger according to claim 5, wherein said refrigerant flows off said tubes in liquid columns spaced apart along said tubes at a natural pitch, and wherein each of said serrations has a tip and said tips are spaced apart at a predetermined pitch smaller than said natural pitch.
7. A heat exchanger according to claim 6, wherein said predetermined pitch has a size in the range of 60% to 85% of said natural pitch.
8. A heat exchanger according to claim 7, wherein said predetermined pitch is of said natural pitch. *o
9. A heat exchanger according to claim 8, wherein said refrigerant is a low surface tension refrigerant.
10. A heat exchanger according to any one of claims 1 to 9 wherein said refrigerant distribution mechanism includes a system of spray nozzles. DATED this 9th day of July 2001. CARRIER CORPORATION WATERMARK PATENT TRADEMARK ATTORNEYS 290 BURWOOD ROAD HAWTHORN VICTORIA 3122 AUSTRALIA SKP:DHS:JL P 16831AU00
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25091699A | 1999-02-16 | 1999-02-16 | |
| US09/250916 | 1999-02-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU1643700A AU1643700A (en) | 2000-08-17 |
| AU737969B2 true AU737969B2 (en) | 2001-09-06 |
Family
ID=22949695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU16437/00A Ceased AU737969B2 (en) | 1999-02-16 | 2000-02-15 | Heat exchanger including falling-film evaporator and refrigerant distribution system |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1030154B1 (en) |
| JP (1) | JP3330116B2 (en) |
| KR (1) | KR100333468B1 (en) |
| CN (1) | CN1188653C (en) |
| AU (1) | AU737969B2 (en) |
| DE (1) | DE60019181T2 (en) |
| ES (1) | ES2235772T3 (en) |
| TW (1) | TW579420B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6532763B1 (en) * | 2002-05-06 | 2003-03-18 | Carrier Corporation | Evaporator with mist eliminator |
| CN101052854B (en) | 2004-10-13 | 2010-07-21 | 约克国际公司 | Falling film evaporator |
| KR20090114367A (en) * | 2006-12-21 | 2009-11-03 | 존슨 컨트롤스 테크놀러지 컴퍼니 | Falling film evaporator |
| CN100451495C (en) * | 2007-05-10 | 2009-01-14 | 上海交通大学 | Refrigerant uniform distributor of compression refrigeration falling-film evaporator |
| CN101932893B (en) | 2008-01-11 | 2013-07-03 | 江森自控科技公司 | Heat exchanger |
| US10209013B2 (en) | 2010-09-03 | 2019-02-19 | Johnson Controls Technology Company | Vapor compression system |
| JP2014202320A (en) * | 2013-04-08 | 2014-10-27 | 株式会社神戸製鋼所 | Vaporizer of cold temperature liquid gas |
| CN103272394B (en) * | 2013-06-17 | 2014-11-26 | 四川东联新能源科技有限公司 | Horizontal pipe type falling film evaporator |
| CN105899892B (en) | 2014-01-15 | 2019-08-06 | 开利公司 | Refrigerant distributors for falling film evaporators |
| CN103900415B (en) * | 2014-03-26 | 2016-04-20 | 广州市心德实业有限公司 | A kind of Falling Film Evaporator of Horizontal Tube heat exchanger tube and heat exchange structure |
| CN106767014A (en) * | 2017-01-12 | 2017-05-31 | 中化重庆涪陵化工有限公司 | Composite fertilizer's shower type cooling device |
| CN108375247A (en) * | 2018-04-10 | 2018-08-07 | 浙江蔚庭新能源科技有限公司 | A kind of jacket type falling film evaporator |
| WO2020034937A1 (en) * | 2018-08-14 | 2020-02-20 | 约克(无锡)空调冷冻设备有限公司 | Falling film evaporator |
| CN109341147A (en) * | 2018-10-15 | 2019-02-15 | 珠海格力电器股份有限公司 | Heat exchanger and air conditioner with same |
| CN116481372A (en) * | 2023-05-31 | 2023-07-25 | 上海蓝滨石化设备有限责任公司 | A device for precise water distribution outside the tube of falling film surface evaporation tube bundle |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5645124A (en) * | 1995-05-25 | 1997-07-08 | American Standard Inc. | Falling film evaporator with refrigerant distribution system |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3332469A (en) * | 1966-09-13 | 1967-07-25 | Rosenblad Corp | Falling film type heat exchanger |
| JP2642553B2 (en) | 1991-12-20 | 1997-08-20 | 株式会社日立製作所 | Absorption chiller / heater |
| DE4431536A1 (en) * | 1994-09-03 | 1996-03-07 | Hubert De Vries | Irrigation device for evaporator elements |
-
2000
- 2000-01-25 TW TW089101185A patent/TW579420B/en not_active IP Right Cessation
- 2000-01-27 ES ES00300596T patent/ES2235772T3/en not_active Expired - Lifetime
- 2000-01-27 DE DE60019181T patent/DE60019181T2/en not_active Expired - Lifetime
- 2000-01-27 EP EP00300596A patent/EP1030154B1/en not_active Expired - Lifetime
- 2000-01-31 CN CNB001019457A patent/CN1188653C/en not_active Expired - Fee Related
- 2000-02-08 JP JP2000029921A patent/JP3330116B2/en not_active Expired - Lifetime
- 2000-02-15 AU AU16437/00A patent/AU737969B2/en not_active Ceased
- 2000-02-16 KR KR1020000007221A patent/KR100333468B1/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5645124A (en) * | 1995-05-25 | 1997-07-08 | American Standard Inc. | Falling film evaporator with refrigerant distribution system |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1264819A (en) | 2000-08-30 |
| KR20000058058A (en) | 2000-09-25 |
| EP1030154A3 (en) | 2001-01-03 |
| AU1643700A (en) | 2000-08-17 |
| DE60019181T2 (en) | 2005-09-22 |
| HK1028099A1 (en) | 2001-02-02 |
| JP3330116B2 (en) | 2002-09-30 |
| CN1188653C (en) | 2005-02-09 |
| EP1030154B1 (en) | 2005-04-06 |
| ES2235772T3 (en) | 2005-07-16 |
| TW579420B (en) | 2004-03-11 |
| KR100333468B1 (en) | 2002-04-18 |
| JP2000234878A (en) | 2000-08-29 |
| DE60019181D1 (en) | 2005-05-12 |
| EP1030154A2 (en) | 2000-08-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) |