AU699822B2 - Composition and process for forming an underpaint coating on metals - Google Patents

Composition and process for forming an underpaint coating on metals Download PDF

Info

Publication number: AU699822B2
Authority: AU; Australia
Prior art keywords: ions; document; treatment; conversion; coating
Prior art date: 1995-03-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU50291/96A

Other languages

English (en)

Other versions

AU5029196A (en

Inventor

Hitoshi Ishii

Yasuhiko Nagashima

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel Corp

Original Assignee

Henkel Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-03-07

Filing date

1996-03-05

Publication date

1998-12-17

1996-03-05 Application filed by Henkel Corp filed Critical Henkel Corp

1996-09-23 Publication of AU5029196A publication Critical patent/AU5029196A/en

1998-12-17 Application granted granted Critical

1998-12-17 Publication of AU699822B2 publication Critical patent/AU699822B2/en

2016-03-05 Anticipated expiration legal-status Critical

Status Ceased legal-status Critical Current

Links

229910052751 metal Inorganic materials 0.000 title claims description 42
239000002184 metal Substances 0.000 title claims description 42
238000000034 method Methods 0.000 title claims description 42
238000000576 coating method Methods 0.000 title claims description 34
239000011248 coating agent Substances 0.000 title claims description 28
239000000203 mixture Substances 0.000 title claims description 17
230000008569 process Effects 0.000 title claims description 12
150000002739 metals Chemical class 0.000 title description 10
238000011282 treatment Methods 0.000 claims description 119
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 23
229910000165 zinc phosphate Inorganic materials 0.000 claims description 23
-1 fluoride ions Chemical class 0.000 claims description 17
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 13
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 9
238000004140 cleaning Methods 0.000 claims description 9
238000007746 phosphate conversion coating Methods 0.000 claims description 6
238000001035 drying Methods 0.000 claims description 5
230000003750 conditioning effect Effects 0.000 claims description 4
239000008367 deionised water Substances 0.000 claims description 4
229910021641 deionized water Inorganic materials 0.000 claims description 4
239000007788 liquid Substances 0.000 claims description 4
230000002378 acidificating effect Effects 0.000 claims description 3
239000011737 fluorine Substances 0.000 claims description 3
229910052731 fluorine Inorganic materials 0.000 claims description 3
239000011777 magnesium Substances 0.000 claims description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
229910052791 calcium Inorganic materials 0.000 claims 1
239000011575 calcium Substances 0.000 claims 1
150000001768 cations Chemical class 0.000 claims 1
229910017052 cobalt Inorganic materials 0.000 claims 1
239000010941 cobalt Substances 0.000 claims 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
229910052749 magnesium Inorganic materials 0.000 claims 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
229910052759 nickel Inorganic materials 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 75
238000010422 painting Methods 0.000 description 22
239000013078 crystal Substances 0.000 description 20
238000007654 immersion Methods 0.000 description 18
229910000831 Steel Inorganic materials 0.000 description 16
238000007739 conversion coating Methods 0.000 description 16
239000010959 steel Substances 0.000 description 16
238000004381 surface treatment Methods 0.000 description 16
230000000052 comparative effect Effects 0.000 description 15
239000003973 paint Substances 0.000 description 15
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 12
238000012360 testing method Methods 0.000 description 11
239000010960 cold rolled steel Substances 0.000 description 10
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 10
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
230000015572 biosynthetic process Effects 0.000 description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
239000010953 base metal Substances 0.000 description 8
239000000084 colloidal system Substances 0.000 description 8
238000005260 corrosion Methods 0.000 description 8
230000007797 corrosion Effects 0.000 description 8
235000011007 phosphoric acid Nutrition 0.000 description 8
239000010936 titanium Substances 0.000 description 8
229910052719 titanium Inorganic materials 0.000 description 8
238000005238 degreasing Methods 0.000 description 7
150000002500 ions Chemical class 0.000 description 7
239000000243 solution Substances 0.000 description 7
238000005507 spraying Methods 0.000 description 7
239000000758 substrate Substances 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 6
238000000151 deposition Methods 0.000 description 6
230000000694 effects Effects 0.000 description 6
229910052742 iron Inorganic materials 0.000 description 6
239000000463 material Substances 0.000 description 6
239000007800 oxidant agent Substances 0.000 description 6
229910000861 Mg alloy Inorganic materials 0.000 description 5
229910000147 aluminium phosphate Inorganic materials 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 5
230000007423 decrease Effects 0.000 description 4
230000008021 deposition Effects 0.000 description 4
230000001590 oxidative effect Effects 0.000 description 4
LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
239000011701 zinc Substances 0.000 description 4
229910052725 zinc Inorganic materials 0.000 description 4
229910000838 Al alloy Inorganic materials 0.000 description 3
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Natural products CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 3
BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
238000004090 dissolution Methods 0.000 description 3
238000004070 electrodeposition Methods 0.000 description 3
238000011156 evaluation Methods 0.000 description 3
229910021645 metal ion Inorganic materials 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
239000007921 spray Substances 0.000 description 3
239000011787 zinc oxide Substances 0.000 description 3
BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 2
229920000298 Cellophane Polymers 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
229910001335 Galvanized steel Inorganic materials 0.000 description 2
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
230000008901 benefit Effects 0.000 description 2
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
229910001429 cobalt ion Inorganic materials 0.000 description 2
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000005530 etching Methods 0.000 description 2
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
239000008397 galvanized steel Substances 0.000 description 2
238000007429 general method Methods 0.000 description 2
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
229910001453 nickel ion Inorganic materials 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
239000003921 oil Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
150000003016 phosphoric acids Chemical class 0.000 description 2
238000007747 plating Methods 0.000 description 2
235000010288 sodium nitrite Nutrition 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
BLKRGXCGFRXRNQ-SNAWJCMRSA-N (z)-3-carbonoperoxoyl-4,4-dimethylpent-2-enoic acid Chemical compound OC(=O)/C=C(C(C)(C)C)\C(=O)OO BLKRGXCGFRXRNQ-SNAWJCMRSA-N 0.000 description 1
GLVYLTSKTCWWJR-UHFFFAOYSA-N 2-carbonoperoxoylbenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1C(O)=O GLVYLTSKTCWWJR-UHFFFAOYSA-N 0.000 description 1
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
HFGHRUCCKVYFKL-UHFFFAOYSA-N 4-ethoxy-2-piperazin-1-yl-7-pyridin-4-yl-5h-pyrimido[5,4-b]indole Chemical compound C1=C2NC=3C(OCC)=NC(N4CCNCC4)=NC=3C2=CC=C1C1=CC=NC=C1 HFGHRUCCKVYFKL-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical group OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
229910000676 Si alloy Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
230000001133 acceleration Effects 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 description 1
239000003788 bath preparation Substances 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
UDSAIICHUKSCKT-UHFFFAOYSA-N bromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2S(=O)(=O)O1 UDSAIICHUKSCKT-UHFFFAOYSA-N 0.000 description 1
ADKBGLXGTKOWIU-UHFFFAOYSA-N butanediperoxoic acid Chemical compound OOC(=O)CCC(=O)OO ADKBGLXGTKOWIU-UHFFFAOYSA-N 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical class OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
OBWXQDHWLMJOOD-UHFFFAOYSA-H cobalt(2+);dicarbonate;dihydroxide;hydrate Chemical compound O.[OH-].[OH-].[Co+2].[Co+2].[Co+2].[O-]C([O-])=O.[O-]C([O-])=O OBWXQDHWLMJOOD-UHFFFAOYSA-H 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
239000013527 degreasing agent Substances 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
239000000428 dust Substances 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
238000009472 formulation Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
230000001939 inductive effect Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910000398 iron phosphate Inorganic materials 0.000 description 1
WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
239000004137 magnesium phosphate Substances 0.000 description 1
229960002261 magnesium phosphate Drugs 0.000 description 1
229910000157 magnesium phosphate Inorganic materials 0.000 description 1
235000010994 magnesium phosphates Nutrition 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
229910001437 manganese ion Inorganic materials 0.000 description 1
229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
150000002828 nitro derivatives Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000011056 performance test Methods 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000002265 prevention Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000010802 sludge Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
229910000162 sodium phosphate Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
BFXAWOHHDUIALU-UHFFFAOYSA-M sodium;hydron;difluoride Chemical compound F.[F-].[Na+] BFXAWOHHDUIALU-UHFFFAOYSA-M 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/16—Orthophosphates containing zinc cations containing also peroxy-compounds

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Chemical Treatment Of Metals (AREA)
Paints Or Removers (AREA)

AU50291/96A 1995-03-07 1996-03-05 Composition and process for forming an underpaint coating on metals Ceased AU699822B2 (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
JP4760595		1995-03-07
JP7-47605		1995-03-07
PCT/US1996/002677 WO1996027692A1 (en)	1995-03-07	1996-03-05	Composition and process for forming an underpaint coating on metals

Publications (2)

Publication Number	Publication Date
AU5029196A AU5029196A (en)	1996-09-23
AU699822B2 true AU699822B2 (en)	1998-12-17

Family

ID=12779879

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU50291/96A Ceased AU699822B2 (en)	1995-03-07	1996-03-05	Composition and process for forming an underpaint coating on metals

Country Status (7)

Country	Link
EP (1)	EP0813620A4 (es)
AR (1)	AR001178A1 (es)
AU (1)	AU699822B2 (es)
BR (1)	BR9607700A (es)
CA (1)	CA2214654A1 (es)
WO (1)	WO1996027692A1 (es)
ZA (1)	ZA961841B (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU699822B2 (en) *	1995-03-07	1998-12-17	Henkel Corporation	Composition and process for forming an underpaint coating on metals
DE19540085A1 (de) *	1995-10-27	1997-04-30	Henkel Kgaa	Nitratarme, manganfreie Zinkphosphatierung
US7294211B2 (en)	2002-01-04	2007-11-13	University Of Dayton	Non-toxic corrosion-protection conversion coats based on cobalt
CN102268680A (zh) *	2011-06-24	2011-12-07	大连洁仕清洁用品有限公司	二次加工铸造件喷涂前表面综合处理剂及制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5312492A (en) *	1989-04-21	1994-05-17	Henkel Kommanditgesellschaft Auf Aktien	Process not using chlorate or nitrite for the production of nickel and manganese containing zinc phosphate films
WO1996017976A1 (en) *	1994-12-06	1996-06-13	Henkel Corporation	Zinc phosphate conversion coating composition and process
WO1996027692A1 (en) *	1995-03-07	1996-09-12	Henkel Corporation	Composition and process for forming an underpaint coating on metals

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2471908A (en) *	1948-04-08	1949-05-31	American Chem Paint Co	Method of and material for preparing surfaces of ferriferous metals for the reception of a siccative finishing coat
US3161549A (en) *	1955-04-08	1964-12-15	Lubrizol Corp	Solution for forming zinc phosphate coatings on metallic surfaces
US3676224A (en) *	1970-10-16	1972-07-11	Lubrizol Corp	Phosphating solution with scale suppressing characteristics
JPS5339945A (en) *	1976-09-25	1978-04-12	Nippon Packaging Kk	Surface treatment of zinc or zinc alloy
GB2009253B (en) *	1977-11-29	1982-06-23	Ici Ltd	Coating process
US4171231A (en) *	1978-04-27	1979-10-16	R. O. Hull & Company, Inc.	Coating solutions of trivalent chromium for coating zinc surfaces
DE3927614A1 (de) *	1989-08-22	1991-02-28	Metallgesellschaft Ag	Verfahren zur erzeugung von phosphatueberzuegen auf metallen
WO1996027693A1 (en) *	1995-03-07	1996-09-12	Henkel Corporation	Composition and process for simultaneously cleaning and conversion coating metal surfaces

1996
- 1996-03-05 AU AU50291/96A patent/AU699822B2/en not_active Ceased
- 1996-03-05 CA CA002214654A patent/CA2214654A1/en not_active Abandoned
- 1996-03-05 BR BR9607700A patent/BR9607700A/pt not_active Application Discontinuation
- 1996-03-05 EP EP96907132A patent/EP0813620A4/en not_active Withdrawn
- 1996-03-05 WO PCT/US1996/002677 patent/WO1996027692A1/en not_active Ceased
- 1996-03-06 ZA ZA961841A patent/ZA961841B/xx unknown
- 1996-03-08 AR AR33567196A patent/AR001178A1/es unknown

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5312492A (en) *	1989-04-21	1994-05-17	Henkel Kommanditgesellschaft Auf Aktien	Process not using chlorate or nitrite for the production of nickel and manganese containing zinc phosphate films
WO1996017976A1 (en) *	1994-12-06	1996-06-13	Henkel Corporation	Zinc phosphate conversion coating composition and process
WO1996027692A1 (en) *	1995-03-07	1996-09-12	Henkel Corporation	Composition and process for forming an underpaint coating on metals

Also Published As

Publication number	Publication date
MX9706315A (es)	1997-11-29
AR001178A1 (es)	1997-09-24
ZA961841B (en)	1996-09-11
WO1996027692A1 (en)	1996-09-12
EP0813620A4 (en)	1998-02-25
CA2214654A1 (en)	1996-09-12
EP0813620A1 (en)	1997-12-29
BR9607700A (pt)	1998-07-07
AU5029196A (en)	1996-09-23

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USRE35688E (en)	1997-12-16	Composition and method for treatment of phosphated metal surfaces
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Date	Code	Title	Description
2002-10-10	MK14	Patent ceased section 143(a) (annual fees not paid) or expired