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AU549454B2 - Process for manufacture of epoxides - Google Patents

Process for manufacture of epoxides

Info

Publication number
AU549454B2
AU549454B2 AU85359/82A AU8535982A AU549454B2 AU 549454 B2 AU549454 B2 AU 549454B2 AU 85359/82 A AU85359/82 A AU 85359/82A AU 8535982 A AU8535982 A AU 8535982A AU 549454 B2 AU549454 B2 AU 549454B2
Authority
AU
Australia
Prior art keywords
epoxides
reaction mixture
catalyst
base
chosen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU85359/82A
Other versions
AU8535982A (en
Inventor
Claude Declerck
Andre Lecloux
Franz Legrand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Chimie SA
Original Assignee
Interox SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Interox SA filed Critical Interox SA
Publication of AU8535982A publication Critical patent/AU8535982A/en
Application granted granted Critical
Publication of AU549454B2 publication Critical patent/AU549454B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1. Process for the production of epoxides, in which hydrogen peroxide is reacted with a compound containing an ethylenic double bond in a homogeneous liquid reaction mixture containing a catalyst and a base, characterised in that the concentration of water in the reaction mixture is kept below 10% by weight, a base chosen from the organic nitrogen bases with a pKa of not more than 8 is used, and a catalyst chosen from the selenium compounds is used.
AU85359/82A 1981-06-26 1982-06-25 Process for manufacture of epoxides Ceased AU549454B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8112797A FR2508451A1 (en) 1981-06-26 1981-06-26 PROCESS FOR THE PRODUCTION OF EPOXYDES
FR8112797 1981-06-26

Publications (2)

Publication Number Publication Date
AU8535982A AU8535982A (en) 1983-01-06
AU549454B2 true AU549454B2 (en) 1986-01-30

Family

ID=9259992

Family Applications (1)

Application Number Title Priority Date Filing Date
AU85359/82A Ceased AU549454B2 (en) 1981-06-26 1982-06-25 Process for manufacture of epoxides

Country Status (8)

Country Link
US (1) US5086189A (en)
EP (1) EP0068564B1 (en)
JP (1) JPS5877872A (en)
AT (1) ATE19073T1 (en)
AU (1) AU549454B2 (en)
BR (1) BR8203729A (en)
DE (1) DE3270380D1 (en)
FR (1) FR2508451A1 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2594435B1 (en) * 1986-02-17 1988-05-20 Interox Sa PROCESS FOR THE MANUFACTURE OF HYDROXYLAMINES AND PRODUCTS THUS OBTAINED
DE4036511A1 (en) * 1990-11-16 1992-05-21 Basf Ag METHOD FOR PRODUCING EPOXIES
US6020508A (en) * 1997-05-16 2000-02-01 National Starch And Chemical Investment Holding Corporation Radiation- or thermally-initiated cationically-curable epoxide compounds and compositions made from those compounds
AU711786B2 (en) * 1997-05-16 1999-10-21 National Starch And Chemical Investment Holding Corporation Reactive radiation- or thermally-initiated cationically- curable epoxide monomers and compositions made from those monomers
EP0878472A1 (en) * 1997-05-16 1998-11-18 National Starch and Chemical Investment Holding Corporation Reactive radiation- or thermally- initiated cationically-curable epoxide monomers and compositions made from those monomers
US6043383A (en) * 1998-04-14 2000-03-28 Ube Industries, Ltd. Process for producing 1,2-epoxy-5,9-cyclododecadiene
US6037484A (en) * 1998-09-22 2000-03-14 Arco Chemical Technology, L.P. Epoxidation process
AU2003208076A1 (en) 2002-02-08 2003-09-02 Sumitomo Chemical Company, Limited Process for producing epoxide compound
GB0817528D0 (en) 2008-09-24 2008-10-29 Syntavit As Process
JP6213932B2 (en) * 2013-03-29 2017-10-18 国立大学法人 東京大学 Method for producing epoxy compound
CN106699694B (en) * 2015-11-18 2019-07-30 浙江新化化工股份有限公司 A kind of method that australene epoxidation prepares 2,3- epoxypinane

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3122569A (en) * 1964-02-25 Hydrogen peroxide epoxidation of ole-
US2833787A (en) * 1955-03-15 1958-05-06 Shell Dev Epoxidation process using hydrogen peroxide and an acid salt of a heavy metal peracid
FR1201458A (en) * 1956-12-14 1959-12-30 Columbia Southern Chem Corp Process for the preparation of epoxides, and epoxides obtained
US3293269A (en) * 1964-11-13 1966-12-20 Union Oil Co Epoxidation of olefins
FR1506459A (en) * 1966-11-02 1967-12-22 Naphtachimie Sa Process for preparing epoxides and products prepared according to this process
US3993673A (en) * 1970-02-26 1976-11-23 Union Carbide Corporation Production of olefin oxides
FR2082811A5 (en) * 1970-03-26 1971-12-10 Inst Francais Du Petrole Epoxide prepn - from hydrogen peroxide and olefins in presence of organo metallic, peroxide catalyst
BE863237A (en) * 1977-02-01 1978-07-24 Ugine Kuhlmann CATALYTIC EPOXIDATION PROCESS OF OLEFINS
FR2378773A1 (en) * 1977-02-01 1978-08-25 Ugine Kuhlmann OLEFINS EPOXIDATION PROCESS IN THE PRESENCE OF ARSENIC-BASED CATALYSTS
DE2910131A1 (en) * 1979-03-15 1980-09-25 Basf Ag PROCESS FOR THE PRODUCTION OF 2,5-DIMETHYL-4-HYDROXY-2,3-DIHYDROFURAN-3-ON
US4242285A (en) * 1979-03-16 1980-12-30 The Dow Chemical Company Novel 2,6-dinitrophenyl selenium compounds and their use as epoxidation catalysts

Also Published As

Publication number Publication date
JPH0372063B2 (en) 1991-11-15
FR2508451B1 (en) 1984-04-27
BR8203729A (en) 1983-06-21
US5086189A (en) 1992-02-04
FR2508451A1 (en) 1982-12-31
ATE19073T1 (en) 1986-04-15
EP0068564B1 (en) 1986-04-09
AU8535982A (en) 1983-01-06
DE3270380D1 (en) 1986-05-15
EP0068564A1 (en) 1983-01-05
JPS5877872A (en) 1983-05-11

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