AU4016401A - Method for removing make-up from skin - Google Patents

Description

AUSTRALIA

Patents Act COMPLETE SPECIFICATION

(ORIGINAL)

Class Int. Class Application Number: Lodged: Complete Specification Lodged: Accepted: Published: Priority Related Art: Name of Applicant: The Procter Gamble Company Doc Doct Actual Inventor(s): P Australia 7 uments received on 0 r" Addres David Michael McAtee, Robert Bao Kim Ha, Lourdes Dessus Albacar& 1 MAY 2001 s for Service: Batch No: PHILLIPS ORMONDE FITZPATRICK Patent and Trade Mark Attorneys 367 Collins Street Melbourne 3000 AUSTRALIA -n s cr, Invention Title: METHOD FOR REMOVING MAKE-UP FROM SKIN Our Ref 642423 POF Code: 103357/44135 The following statement is a full description of this invention, including the best method of performing it known to applicant(s): -1- METHOD FOR REMOVING MAKE-UP FROM SKIN The present application is a divisional application from Australian patent application number 60334/98, the entire disclosure of which is incorporated herein by reference.

TECHNICAL FIELD The present invention relates to methods for cleansing the face and for removing make-up from the face using personal cleansing using surfactant solutions which have low pH and low interfacial tension. These solutions provide properties better matched for removing silicone based make-ups.

BACKGROUND OF THE INVENTION Personal cleansing products have traditionally been marketed in a variety of forms such as bar soaps, creams, lotions, and gels. These cleansing formulations have attempted to satisfy a number of criteria to be acceptable to consumers. In order to be acceptable to consumers, a product must exhibit good cleansing properties, must exhibit good lathering characteristics, must be mild to the skin and preferably should provide a moisturizing benefit to the skin. Ideal personal cleansers should gently .cleanse the skin or hair, cause little or no irritation, and not leave the skin or hair overly dry after frequent use.

These traditional forms of personal cleansing products have included two types of formulations, oil free cleansers and oil and water emulsions. The oil free cleansers utilize water based surfactants, fatty acid soaps, synthetic isethionates and the like to remove dirt and oil from the skin. However, many of these surfactants, especially fatty acid soaps, have been found to be irritating to the skin.

Milder components and water based humectants are used in order to minimize the skin drying and.

irritation negatives The oil and water emulsions utilize insoluble skin conditioning oils along with the water based cleansing systems. The products are formulated to balance the cleansing benefits of *the water phase and the conditioning benefits of the oils. which are deposited on the skin. However, it is known that the emulsification of oils in water cleaners negatively impacts the lathering and cleansing properties of the products.

Recently, cosmetics manufacturers have introduced silicone based make-ups, especially lipsticks, which resist smear and rub-off. However, as products are designed to resist removal, they by their nature are more difficult to wash off. The traditional oil free cleansers and oil and water emulsion cleansers have difficulty removing these new products, without being irritating to the skin.

A need clearly exists to develop a method for cleansing the face and specifically a method for removing make-up from the skin.

It has been surprisingly found in the present invention that personal cleansing products can be formulated with properties designed to soften and remove the silicone in these new make-up products.

It has been found that solutions of lathering surfactant and water having a pH of less than 8.3 and having an interfacial tension of less than 3.5 provide improved ability to remove silicone based compounds from the skin without increasing skin irritation. The methods of the present invention are highly efficacious for cleansing the skin of the face, especially for removing silicone based compounds from the face. Without being limited by theory, it is believed that the lower than typical interfacial tension better softens and breaks up the lipid and silicone base of the make-up compound. The lower than typical pH reduces irritation over soap-based products. This combination provides the improved make-up removal benefit of the methods of the present invention.

The present invention relates to methods of cleaning lipid and silicone based compounds from a solid substrate.

The present invention also relates to methods of cleaning the skin of the face and methods for removing make-up from the face using compositions in which the pH and interfacial tension have been adjusted to remove silicone based compounds from the skin. The methods provide improved cleansing and make-up removal over traditional cleansing methods of cleaning the face.

This and other aspects of this invention 'will become apparent in light of the following disclosure.

SUMMARY OF THE INVENTION The present invention relates to a method for removing lipid and silicone based compounds from solid substrates comprising: application of an effective amount of a cleansing composition comprising: a) from about 5% to about 74.5% of a lathering surfactant; and b) from about 25% to about 94.9% water.

wherein the pH of the composition is less than about 8.3 and wherein the interfacial tension of the composition with mineral oil is less than to about In another embodiment, the present invention relates to a method for removing lipid and siliconc based compounds from human skin comprising: applying a safe and effective amount of a cleansing composition comprising: a) from about 7.5% to about 50% of a lathering surfactant; and b) from about 50% to about 92.5% water, wherein the pH of the composition is less than about 8.3 and wherein the interfacial tension of the composition with mineral oil is less than about All percentages and ratios used herein, unless otherwise indicated, are by weight anA all measurements made are at 25 0 C, unless otherwise designated. The invention hereof can comprise.

consist of, or consist essentially of, the essential as well as optional ingredients and components described therein.

DETAILED DESCRIPTION OF THE INVENTION I. THE CLEANSING COMPOSITIONS The term "cleansing composition" as used herein means a composition suitable for application to a solid substrate for the purpose of removing dirt, make-up, oil and the like. The cleansing compositions of the present invention comprise the following essential components.

A. LATHERING SURFACTANT The cleansing compositions of the present invention comprise from about 5% to about 74.5%, preferably from about 7.5% to about 50%, and more preferably from about 10% to about 25%, based on the weight of the cleansing composition, of a lathering surfactant By a "lathering surfactant" it is meant a surfactant, which when combined with water and mechanically agitated generates a foam or lather. Preferably, these surfactants should be mild, which means that these surfactants provide sufficient cleansing or detersive benefits but do not overly dry the skin or hair, and yet meet the lathering criteria described above. A lathering surfactant is further defined herein as a synthetic surfactant or mixture of surfactants which has an equilibrium surface tension of between 15 and 50 dynes/centimeter, more preferably between 20 and 45 dynes/centimeter as measured at the critical miscelle concentration at 25C. Some surfactant mixtures can have a surface tension lower than any of its components.

The term "mild" as used herein in reference to the lathering surfactants and products of the present invention means that the products of the present invention demonstrate skin mildness S. comparable to a mild alkyl glyceryl ether sulfonate (AGS) surfactant based synthetic bar, i.e. synbar.

Methods for measuring mildness, or inversely the irritancy, of surfactant containing products, are based on a skin barrier destruction test. In this test, the milder the surfactant. the lesser the skin barrier is destroyed. Skin barrier destruction is measured by the relative amount of radio-labeled (tritium labeled) water (3H-H 2 0) which passes from the test solution through the skin epidermis into the physiological-buffer contained in the diffusate chamber. This test is described by T.J. Franz in the JInveas Dermatol.., 1975, 64, pp. 190-195; and in U.S. Patent No. 4,673,525, to Small et al., issued June 16, 1987, which are both incorporated by reference herein in their entirety. Other testing methodologies for determining surfactant mildness well known to one skilled in the art can also be used.

A wide variety of lathering surfactants are useful herein and include those selected from the group consisting of anionic lathering surfactants. nonionic lather surfactants, amphoteric lathering surfactants, and mixtures thereof. Cationic surfactants can also be used as optional components.

provided they do not negatively impact the overall lathering characteristics of the required, lathering surfactants.

Anionic Lathering Surfactants Nonlimiting examples of anionic lathering surfactants useful in the compositions of the present invention are disclosed in McCutcheon's, Detergents and Emulsifiers, North American ediuon (1986), published by allured Publishing Corporation: McCutcheon's, Functional Materials, North American Edition (1992); and U.S. Patent No. 3,929,678, to Laughlin et al., issued December 1975.

A wide variety of anionic lathering surfactants are useful herein. Nonlimiting examples of anionic lathering surfactants include those selected from the group consisting of sarcosinates, sulfates, isethionates. taurates, phosphates, carboxylates, and mixtures thereof Amongst the isethionates, the alkoyi isethionates are preferred, and amongst the sulfates, the alkyl and alkyl ether sulfates are preferred. The alkoyl isethionates typically have the formula RCO-OCH 2

CH

2 SO M wherein R is alkyl or alkenyl of from about 10 to about 30 carbon atoms, and M is a water-soluble cation such as ammonium, sodium, potassium and triethanolamine. Nonlimiting examples of these isethionates include those alkoyl isethionates selected from the group consisting of ammonium cocoyl isethionate, sodium cocoyl isethionate, sodium lauroyl isethionate, and mixtures thereof.

The alkyl and alkyl ether sulfates typically have the respective formulae ROSO M and RO(C2H40)xSO M, wherein R is alkyl or alkenyl of from about 10 to about 30 carbon atoms, x is from about I to about 10, and M is a water-soluble cation such as ammonium, sodium, potassium and triethanolamine. Another suitable class of anionic surfactants are the water-soluble salts of the organic, sulfuric acid reaction products of the general formula: R -SO -M 1 3 wherein RI is chosen from the group consisting of a straight or branched chain, saturated aliphatic hydrocarbon radical having from about 8 to about 24, preferably about 10 to about 16, carbon atoms; and M is a cation. Still other anionic synthetic surfactants include the class designated as succinamates, olefin sulfonates having about 12 to about 24 carbon atoms, and b-alkyloxy alkane sulfonates. Examples of these materials are sodium lauryl sulfate and ammonium lauryl sulfate.

Other anionic materials include the sarcosinates, nonlimiting examples of which include sodium lauroyl sarcosinate, sodium cocoyl sarcosinate, and ammonium lauroyl sarcosinate.

Other anionic materials useful herein are soaps alkali metal salts, sodium or potasium salts) of fatty acids, typically having from about 8 to about 24 carbon atoms, preferably from about 10 to about 20 carbon atoms. The fatty acids used in making the soaps can be obtained from natural sources such as, for instance, plant or animal-derived glycerides palm oil, coconut oil, soybean oil castor oil, tallow, lard, etc.) The fatty acids can also be synthetically prepared.

Soaps are described in more detail in U.S. Patent No. 4.557,853, cited above.

Other anionic materials include phosphates such as monoalkyl, dialkyl, and trialkylphosphate salts.

Other anionic materials include alkanoyl sarcosinates corresponding to the formula

RCON(CH

3

)CH

2 CH CO2M wherein R is alkyi or alkenyl of about 10 to about 20 carbon atoms, and M is a water-soluble cation such as ammonium, sodium, potassium and trialkanolamine (e.g.

triethanolamine), a preferred example of which is sodium lauroyl sarcosinate.

Other anionic materials include the carboxylaies, nonlimiuing examples of which include sodium laureth carboxylate, sodium lauroyl carboxylaie, sodium cocoyl carboxylate, and ammnonium lauroyl carboxylate.

Also useful are taurates which are based on taurine, which is also known as 2.

aminoethanesulfonic acid. Examples of taurates include N-alkyltaurines such as the one prepared by reacting dodecylainine with sodium isethionate according to the leaching of U.S. Patent 2,658,072 which is incorporated herein by reference in its entirety.

Nonlimiting examples of preferred anionic lathering surfactants useful herein include those selected from the group consisting of sodium lauryl sulfate, ammonium lauryl sulfate, ammonium laureth sulfate, sodium laureth sulfate, sodium trideceth sulfate, amnmonium cetyl sulfate, sodium cetyl sulfate, ammnonium cocoyl isethionate, sodium lauroyl isethionate, sodium lauroyl sarcosinate, sodium laureth carboxylate, and mixtures thereof.

Especially preferred for use herein is sodium laureth sulfate and sodium laureth carboxylate.

Nonionic Lathering Surfactants Nonlimiting examples of nonionic lathering surfactants for use in te compositions of the present invention are disclosed in McCutcheon's, Detergents and Emulsifiers, North American edition (1986), published by allured Publishing Corporation; and McCutcheon's, Functional Materials North American Edition (1992); both of which are incorporated by reference herein in their entirely.

Nonionic lathering surfactants useful herein include those selected from the group consisting of alkyl glucosides. alkyl polygiucosides, polyhydroxy fatty acid amides alkoxylated fatty acid esters, sucrose esters, amine oxides, and mixures thereof.

Alkyl glucosides and alkyl polygiucosides are useful herein and can be broadly defined. as condensation products of long chain alcohols. e.g. C 8 3 alcohols, with sugars or starches or sugar or starch polymers glycouides or polyglycosides. These compounds can be represented by the formula (S) 5 -O-R wherein S is a sugar moiety such as glucose, fructose, mannose, and galactose; n is an zqrof from about I to about 1000, and R is a C 0 alkyl group. Examples of long chain alool from whuch the alkyl group can be derived include decyl alcohol, cetyl alcohol steazyl alcohol, lauryl alcohol myristyl alcohol, oleyl alcohol, and the like. Preferred examples of these surfactants include those wherein S is a glucose moiety, R is a C 8 20 alkyl group, and n is an integer of from about I to about 9. Commercially available examples of these sufactants include decyl polyglucoside (available as APG 325 CS from Henkel) and lauzyl polyglucoside (available as APG 600CS and 625 CS from Henkel). Also useful are sucrose ester surfactants such as sucrose cocoate and sucrose laurate.

Other useful nonionic surfactants include polyhydroxy fatty acid amide surfactants, more specific examples of which include glucosamides. corresponding to the structuWa formula: 0 RI II I 2-C -Nwherein: R is H. C-C 4 alkyl, 2-hydroxyethyl, 2-hydroxy- propyl, preferably C -C 4 alkyl, more preferably methyl or ethyl, most preferably methyl; R 2 is C-C 3 1 alkyl or alkenyl, preferably C -C9 alkyl or alkenyl, more preferably C 9

-C

17 alkyl or alkenyl, most preferably C 11

C

15 alkyl or alkenyl; and Z is a polhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with a least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof. Z preferably is a sugar moiety selected from the group consisting of glucose, fructose, maltose, lactose, galactose, mannose, xylose. and mixtures thereof. An especially preferred surfactant corresponding to the above structure is coconut alkyl N-methyl glucoside amide wherein the R CO- moiety is derived from coconut oil fatty acids). Processes for making compositions containing polyhydroxy fatty acid amides are disclosed, for example, in U.S. Patent No. 2,965,576, to E.R.

Wilson, issued December 20, 1960; U.S. Patent No. 2,703,798, to A.M. Schwartz, issued March 8, 1955; and U.S. Patent No. 1,985,424, to Piggott, issued December 25, 1934; which are incorporated herein by reference in their entirety.

Other examples of nonionic surfactants include amine oxides. Amine oxides correspond to the general formula RR 2

R

3 NO, wherein R, contains an alkyl, alkenyl or monohydroxy alkyl radical of from about 8 to about 18 carbon atoms, from 0 to about 10 ethylene oxide moieties, and from 0 to about 1 glyceryl moiety, and R 2 and R3 contain from about 1 to about 3 carbon atoms and from 0 to about I hydroxy group, methyl, ethyl, propyl, hydroxyethyl, or hydroxypropyl radicals. The arrow in the formula is a conventional representation of a semipolar bond. Examples of amine oxides suitable for use in this invention include dimethyl-dodecylamine oxide, oleyldi(2-hydroxyethyl) amine oxide, dimethyloctylamine oxide, dimethyl-decylamine oxide, dimethyl-tetradecylamine oxide, 3,6,9trioxaheptadecyldiethylaminc oxide, di(2-lydroxyethyl)-tetradecylamine oxide, 2dodecoxyethyldimethylamine oxide, 3 -dodecoxvy-2-hydroxypropyldi(3-hydroxypropyl)amine oxide, dimetylhexadecylamine oxide.

Nonlimiting examples of preferred nonionic surfactants for use herein are those selected form the group consisting of C-C 14 glucose amides. C 8

-C

14 alkyl polyglucosides, sucrose cocoate, sucrose laurate, lauramine oxide, cocoamine oxide. and mixtures thereof.

Amphoteric Lathering Surfactants The term "amphoteric lathering surfactant." as used herein, is also intended to encompass zwitterionic surfactants, which are well known to formulators skilled in the art as a subset of amphoteric surfactants.

A wide variety of amphoteric lathering surfactants can be used in the compositions of the present invention. Particularly useful are those hich are broadly described as derivatives of aliphatic secondary and tertiary amines, preferably wherein the nitrogen is in a cationic state, in which the aliphatic radicals can be straight or branchecd chain and wherein one of the radicals contains an ionizable water solubilizing group, carbox-y, sulfonate, sulfate, phosphate, or phosphonate.

Nonlimiting examples of ainphotenic surfactants useful in the compositions of the present invention are disclosed in McCutcheon's, Detergents and Emulsifiers, North American edition (1986), published by allured Publishing Corporation, and McCutcheon's, Functional Materials, North American Edition (1992); both of which are incorporated by reference herein in their entirety.

Nonlimiting examples of amphoteric or zwitterionic surfactants are those selected from the group consisting of betaines, sultaines, hydroxysultaines, alkyliminoacetates, iminodialkanoates, aminoalkanoates. and mixtures thereof.

Examples of betaines include the higher alkyl betaines. such as coco dimethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alpha-carboxyethyl betaine, cetyl dimethyl carboxymethyl betaine, cetyl dimethyl betaine (available as Lonzaine 16SP from Lonza Corp.), lauryl bis-{2-hydroxyethyl) carboxyrnethyl betaine, oleyl dimethyl gamrna-carboxypropyl betaine, lauryl bis-(2-hydrox-ypropyl)aipha..carboxyethyl bet aine, coca, dimnethyl sulfopropyl betaine, lauryl dirnethyl sulfoethyl betaine, lauryl bis-(2-hydroxyethyl) sulfopropyl betaine, arnidobetaines and amidosulfobetaines (wherein the RCON1-(CI-1 2 3 radical is attached to the nitrogen atom of the betaine), oleyl betaine (available as amphoteric Velvetex OLB-50 from Henkel), and cocamnidopropyl betaine (available as Velvetex BK-35 and BA-35 from Henkel).

Examples of sultaines and hydroxysultaines include materials such as cocamidopropyl hydroxysuitaine (available as Mrataine CBS from Rhone-Poulenc).

Preferred for use herein ame amphoteric surfactants having the following structure: 0 R2 R 44 -NR4-X R3 wherein RI is unsubstituted, saturated or unsaturated, straight or branched chain alkyl having from about 9 to about 22 carbon atoms. Preferred R I has from about I1I to about 18 carbon atoms, more preferably from about 12 to about 1S carbon atoms; more preferably still from about 14 to about 18 carbonatoms mi n integerfrom to about3. morepreferably fomabout 2to about 3, and morc preferab ly about 3; n is either 0 or 1, preferably 1; R 2 and R 3 are independently selected from the group consisting of alkyl having from I to about 3 carbon atoms, unsubstituted or mono-substituted with hydroxy, preferred R 2 and R 3 are CH 3 X is selected from the group consisting Of CO 2 S0 3 and S04; R4 is selected from the group consisting of saturated or unsaturated, straight or branched chain alkyl, unsubstituted or monosubstituted with hydroxy. having from I to about 5 carbon atomns When X is C0 2 R4 preferably has I or 3 carbon atoms, more preferably 1 carbon atom. When X is S0 3 or S0 4

R

4 preferably has from about 2 to about 4 carbon atoms, more preferably 3 carbon atoms.

Examples of amphoteric surfactants of the present invention include the following compounds: Cetyl dimethyl betaine (this material also has the CiTA designation cetyl betaine)

C

6

H

33

-N--CH

2 C0 2 &H3 Cocamidopropylbetaine R-C-Nf-(CH2) 3

-N-CH

2 -Coj wherein R has from about 9 to about 13 carbon atoms 9.Cocamidopropyl hydroxy suhtaine

?H

3 wherein R has from about 9 to about 13 carbon atoms.

Examples of other useful aniphoteric surfactants are alkylinnoacetates, and iminodialkanoates aminoalkanoates of the formulas RNICH 2 mCO 2 MN and RN(H2)mC wherein m is from I to 4, R is a CB-C 22 alkyl or alkenyl, and M is K al~ai metal allmline earth metal ammon, or alkanolammonium. Also included are imidazolinium and ammnoniumn derivatives.

Specific examples of suitable amphoteric surfactants include sodium 3-dodecyl-aminopropionate, sodium 3-dodecyLaminopropane sulfonate, N-higher alkyl aspartic acids such as those produced according to the teaching of U.S. Patent 2.438,091 which is incorporated herein by reference in its entirety; and the products sold under the trade name "Mfiranol* and described in U.S. Patent 2,523,378, which is incorporated herein by reference in its entirety. Other examples of useful amphoterics include amphoteric phosphates, such as coamnidopropyl POG-dimonium chloride phosphate (commercially available as Monaquat FTC, from Mona Corp.). Also useful are amphoacetates such as disodiumn lauroamphodiacetate, sodium lauroaniphoacetate, and mixtures thereof.

Preferred lathering surfactants for use herein are the follow~ing, wherein the anionic lathering surfactant is selected from the group consisting of amnmonium lauroyl sarcosinate, sodium trideceth sulfate, sodium lauroyl sarcosinate, amnmonium laureth sulfate, sodium laureth sulfate, ammoniunm lawryl sulflate, sodium lauryl sulflate, ammonium COCoYl isethionate, sodium cocoyl isethionate.

sodium lauroyl isethionate, sodium cetyl sulfate. sodium laureth carboxylate and mixtures thereof-, wherein the nonionic lathering surfactant is selected from the group consisting of lauramine oxide, cocoamine oxide, decyl polyglucose, lauryl polyglucose, sucrose cocoate, C12.14 glucosamides, sucrose laurate, and mixtures thereof; and wherein the amphoteric lathering surfactant is selected from the group consisting of disodium lauroamphodiacetate, sodium lauroamphoacetate, cetyl dimethyl betaine, cocoamidopropyl betaine, cocoamidopropyl hydroxy sultaine, and mixtures thereof.

B. WATER The compositions of the present invention comprise from about 25% to about 94.9%, preferably from about 35% to about 90%, more preferably from about 40% to about 70% water. The level of water within these ranges which should be employed depends upon the form and rheology of the product desired.

C. pH The cleansing compositions of the present invention comprise a pH of less than about 8.3, preferably from about 4.0 to about 8.0, and more preferably from about 5.0 to about 7.5. The pH of the composition is measured using standard calibrated pH measuring method ASTM Designation: E 70-90, "Standard Test Method for pH of Aqueous Solutions With the Glass Electrode", hereby incorporated by reference in its entirety.

D. INTERFACIAL TENSION The compositions of the present invention comprise an interfacial tension of less than preferably from about 0.5 to about 3.0, and more preferably from about 1.0 to 2.5. The interfacial tension is measured using ASTM Designation: D 971-91, "Standard Test Method for Interfacial Tension of Oil Against Water by the Ring Method", hereby incorporated by reference in its entirety.

E. OPTIONAL INGREDIENTS .:The compositions of the present invention can comprise a wide range of optional ingredients.

The CTFA Cosmetic Ingedient Handbook, Second Edition, 1992, which is incorporated by reference herein in its entirety, describes a wide variety of nonlimiting cosmetic and pharmaceutical ingredients commonly used in the skin care industry, which are suitable for use in the compositions of the present invention. Nonlimiting examples of functional classes of ingredients are described at page 537 of this refernce. Examples of these functional classes include: abrasives, anti-acne agents, anticaking agents, antimicrobial agents, antioxidants, binders, biological additives, buffering agents, bulking agents, chelating agents, chemical additives, colorants, cosmetic astringents, cosmetic biocides, denaturants, drug astringents, external analgesics, film formers, fragrance components, humectants, insoluble skin conditioning oils, insoluble skin conditioning solids, opacifying agents, pH adjusters, plasticizers, preservatives, propellants, reducing agents, skin bleaching agents, skin-conditioning agents (emollient, humectants, miscellaneous. and occlusive), skin protectants, solvents, foam boosters, hydrotropes, solubilizing agents, and suspending agents), suspending agents (nonsurfactant).

sunscreen agents, ultraviolet light absorbers. and viscosity increasing agents (aqueous and nonaqueous). Examples of other functional classes of materials useful herein that are well known to one of ordinary skill in the an include solubilizing agents, sequestrants, and keratolytics, and the like.

Nonlimiting examples of these additional components cited in the CTFA Cosmetic Ingredient Handbook, as well as other materials useful herein, include the following: vitamins and derivatives thereof le.g., vitamin C, Vitamin A retinoic acid), retinol, retinoids, panthenol, niacinamide and the like]; sunscreening agents; other silicone materials such as dimethiconol, dimethicone copolyol.

and amodimethicone, and the like); anti-oxidants; anti-microbial agents; preservatives; emulsifiers; polyethyleneglycols and polypropyleneglyocls; polymers for aiding the film-forming properties and substantivity of the composition (such as a copolymer of eicosene and vinyl pyrrolidone, an example of which is available from GAF Chemical Corporation as Ganex® V-220); preservatives for maintaining the antimicrobial integrity of the compositions; anti-acne medicaments resorcinol, sulfur, salicylic acid, erythromycin, zinc, and the like); skin bleaching (or lightening) agents including but not limited to hydroquinone, kojic acid; antioxidants; chelators and sequestrants; thickening agents such as carbomers (homopolymers of acrylic acid crosslinked with an allyl ether of pentaerythritol or an allyl ether of sucrose), crosslinked and noncrosslinked nonionic and cationic o ~polyacrylamides Salcare® SC92 which has the CTFA designation polyquatemium 32 (and) mineral oil, and Salcare@ SC 95 which has the CTFA designation polyquaternium 37 (and) mineral oil (and) PPG-I trideceth-6, and the nonionic Seppi-Gel polyacrylamides available from Seppic Corp.]; aesthetic components such as fragrances, pigments, colorings, essential oils, skin senates, astingents, skin soothing agents, skin healing agents and the like, Inonlimiting examples of these aesthetic components include clove oil, menthol, camphor, eucalyptus oil, eugenol, menthyl lactate, witch hazel distillate, bisabolol, dipotassium glycyrrhizinate and the likel; and skin conditioning agents such as urea and glycerol, and also the propoxylated glycerols described in U.S. Patent No.

4,976,953, to Orr et al., issued December 11, 1990, which is incorporated by reference herein in its Sentirety.

i. METHODS OF CLEANSING The compositions of the present invention are useful for cleansing lipid and silicone based compounds from solid substrates. The compositions are useful for cleaning such compounds from a wide variety of solid substrates, including but not limited to textile fabrics, human skin and human hair. The compositions of the present invention are especially useful for cleansing of the face and neck areas.

The method for removing lipid and silicone based compounds from solid substrates of the present invention comprises applying a safe and effective amount of the cleansing composition.

described hereabove, to the area to be cleansed. "A safe and effective amount" of the cleansing composition will depend upon the needs and usage habits of the individual using the composition Typical amounts of the present compositions useful for cleansing range from about 0.5 mg/cm 2 to about 25 mg/cm 2 of skin area to be cleansed.

11 A suitable amount of the cleansing composition can be applied either directly to the solid surface or via intermediate application to a washcloth, sponge, pad. cotton ball or other application device. If desired, the area to be cleansed can be premoistened with water. It has been found that the compositions of the present invention can be combined with water during the cleansing process and nnsed-off from the skin. Alternatively, the product can be used alone and wiped-off from the skin using a pad, cotton ball, tissue, or other like device. The cleansing process is typically a two-step process involving application of the product followed either by rinsing of the product with water or wiping without the use of water.

Throughout the description and claims of this specification the word "comprise", and variations of the word such as "comprising" and "comprises", is not intended to exclude other additives or components or integers or steps.

III. EXAMPLES OF THE CLEANSING PRODUCTS The following examples further describe and demonstrate the cleansing compositions of the embodiments within the scope of the present invention. In the following examples, all ingredients are listed at an active level. The examples are given solely for the purpose of illustration and are not to be construed as limitations of the present invention, as many variations thereof are possible without departing from the spirit and scope of the invention.

Ingredients are identified by chemical or CTFA name.

Examples 1-4 Bodvwash Products

S

Ex. I Ex. 2 Ex. 3 Ex.4 Phas A Water Disodium EDTA Phase B Glycerine Polyquaternium 10 Phase C Sodium/Magnesium Laureth-3-3.6 Sulphate Cocunide MEA Sodium Lauoaphoacetate Myristic Acid Magnesium Sulphate Hepta Hydrate Trihydroxystearin PEG-6 Caprylic/Capric Triglycerides Phase D Sucrose Polyesters of Cottonate Fatty Acid Sucrose Polyesters of Bhenate Fatty Acid Petrolatum 65.72 0.20 3.00 0.40 12.00 2.80 6.00 1.60 0.30 0.50 3.00 3.00 62.72 0.20 59.72 0.20 63.72 0.20 3.00 3.00 3.00 0.40 0.40 0.40 12.00 2.80 6.00 1.60 0.30 0.50 3.00 2.00 4.00 12.00 2.80 6.00 1.60 0.30 0.50 12.00 2.80 6.00 1.60 0.30 0.50 4.00 8.00 2.00 Documenl 14 Mineral Oil Phase E 6.00 .Yj~ M J oJlUII 0.08 0.08 0.08 0.08 Citric Acid 1.40 1.40 1.40 1.40 100.00, 100.00 100.00 100.00 All of these compositions have a pH of 8.3 or less and an interfacial tension of 3.5 or less.

Method of manufacture: I In a stainless steel vessel combine ingredients in phase A.

2. In a separate vessel combine ingredients in phase B until a homogeneous mixture is formed.

3. Add Phase B to phase A.

4. Add phase C ingredients to phase A vessel while heating to Cool to 45 Oc. Add ingredients in phase D and mill for 20 minutes.

6. Continue cooling. When temperature reaches 30*c. add ingredients in phase E.

Examples 5-8 Facewash Product Ex. 5 Ex6 Ex. 7 Ex. 8 Water Disodiumn EDTA Citric Acid Sodium Laureth-3 Sulfate Sodium Lawreth-4 Carboxilate Lauretb-12 Poyquatrnium 10 Polyqiutrnium 25 Sodium Lauroamphoacetate Lauric Acid Myristic Acid Magnesium Sulphate Hepta Hydrate Triethanol Amine Sucrose Polyesters of Behenate Fatty Acid Sucrose Polyesters of Cottonate Fatty Acid Trihydroxystearin 61.52 0.10 3.00 3.00 1.00 0.30 3.00 6.00 6.00 2.30 4.00 2.00 3.00 0.50 61.17 0.10 3.50 3.50 1.20 0.30 3.00 6.00 6.00 2.00 4.00 2.00 2.00 0.50 64.97 0.20 1.40 67.22 0.20 1.40 0.40 0.40 3.00 3.00 3.00 3.00 2.00 4.00 4.00 0.50 3.00 3.00 2.00 4.00 2.00 0.50 Phase D Cocamridopropyl Betaine 2.00 3.00 L-80 1.80 Lauryl; dirnethyl amine oxide 1.00 1.20 1.20 1.20 PEG-6 Caprylic/Capric Triglycerides 2.00 Petrolatumi- 4.00 Mineral Oil 2.00 Dcx Panthenol 1.00 0.25 0.25 DMDM Hydantoin 0.08 0.08 0.08 0.08 Fragrance 0 20 0.20 0.20 0.20 100.00 100.00 100.00 100.00 All of these compositions have a pH of 8.3 or less and an interfacial tension of 3.5 or less.

Method of manufacture: 1. In a stainless steel vessel combine ingredients in phase A.

In a separate vessel combine ingredients in phase B until a homogeneous mixture is formed.

3. Add Phase Bto phase A.

4. Add phase C ingredients to phase A vessel while beating to Cool to 45 Add ingredients in phase D and mill for 20 minutes.

6. Continue cooling. When temperature reaches 30TC, add ingredients in phase E.

Example 9 Facewash a...Water 68.05 Disodium EDTA 0.10 3.00 Polyqternium 10 0.50 Pas Sodium Lauroyl Sarcossinate 5.00 Sodium Lauro Amphoacetate 5.00 Citric Acid 0.24 DMDM Hydantoin 0.08 Fragrance 0.10 This composition have a pH of 8.3 or less and an interfacial tension of 3.5 or less.

Method of manufacture: 1. In a stainless steel vessel combine ingredients in phase A.

2. In a separate vessel combine ingredients in phase B until a homogeneous mixture is formed.

3. Add Phase Bto phase A.

4. A phase C ingredients to phase A vessel.

4. Heat to 75 0

C.

Cool to 30 0

C.

6. Add ingredients in phase D.

ENamGIRes 10 Facewash Product Ex. e.

a a a a a C. a Water Disodium EDTA Phase B Polyquaternitum 24 Glyceine Phase C Sodium Cocoyl Isethionate Sodium Lauroyll Glutamate Myristic Acid Magnesium Sulphate Hepta Hydrate Thiethanol Amine Launic Acid Trihydroxystearn Cocaidapopy Beauine Lauz)1 dimethyl amine o~dde Decyl Polygiucose Pbenoxyetanol Panthenol DMDM Hydantoin Fragrance Tis composition have a pH of(8.3 or Method of manufacture: 1. In a stainless steel vessel combine 67.52 0.10 0.35 3.00 5.00 5.00 3.00 2.40 3.80 0.50 0.50 1.80 1.20 1.8 0.50 1.00 0.08 0.30 100.00 less and an intcrfacial tension of 3.5 or less.

ingredients in phase A.

2. In a separate vessel combine ingredients in phase B until a homogeneous mixture is formed.

3. Add Phase Bto phase A.

4. Add phase C ingredients to phase A vessel while heating to 75 0

C.

Cool to 45*C. Add ingredients in phase D.

6. Continue cooling. When temperature reaches 30'c, add ingredients in phase E.

Examvle I I Mild Facewash Ex. I11 PhasA Water 68.05 Disodiumn EDTA 0.10 Phase B Sodium Laureth 3 Sulfate 5.00 Sodium Laureth 4 Carboxylate 6.00 Laureth 12 1.00 *Lauric Acid 3.00 Triethanoiamine 3.50 Magnesium Sul~fate 2.00 *Phas Cocainidopropyl Betaine 3.00 *.*.Lauraine Oxide 1.00 *Decyl Polyglucs 1.00 ~:DMDM Hydantoin 0.08 *Fragrance 0.20 This composition havw a pH of 8.3 or less and an interfacial tension of 3.5 or less.

1. in a stainless steel vessel combine ingredients in phase Begin mixing.

2. Add ingredients in phase B while heating to 3. Hem to750C.

4. Cool to 456C.

Add phase C ingredients topas A vessel.

6. Cool to309C 7. Add ingredients in phase D.

Example 12 Mild Cleanser Ex. 12 PhanA Water 65.72 Disodiun EDTA Phase B Glycerine Polyquaternium 10 Phase C Sodium Laureth Sulfate Sodium Laureth Carboxylate Lauric Acid Triethanolamine Magnesium Sulphate Trihydroxystearin Phase D Cocamidopropyl Betaine Lauramine Oxide Decyl Polyglucose PhaseE 1.00 3.00 0.20 5.00 5.00 3.00 4.00 2.50 1.00 1.50 2.00 1.20 0 0*0* 0* 0 0 0000 DMDM Hydantoin 0.08 Fragrance 0.20 100.00 This composition have a pH of 8.3 or less and an interfacial tension of 3.5 or less Method of manufacture: 1. In a stainless steel vessel combine ingredients in phase A.

2. In a separate vessel combine ingredients in phase B until a homogeneous mixture is formed.

3. Add Phase B to phase A.

4. Add phase C. ingredients to phase A vessel while heating to 5. Cool to 45 Add ingredients in phase D.

6. Continu cooling. When temperature reaches 300C. add ingredients in phas;6 E.

S S .000 000* 0 900550 0 0005

S

5000

Claims (8)

1. A method for removing lipid and silicone based compounds from solid substrates, wherein the method comprises application of an effective amount of a cleansing composition comprising: a) from 5% to 74.5% of a lathering surfactant; and b) from 25% to 94.9% water; wherein the pH of the composition is less than 8.3 and wherein the interfacial tension of the composition with mineral oil is less than

2. A method for removing lipid and silicone based compounds according to claim 1, wherein said compound is make-up.

3. A method according to claim 1 or 2, wherein the solid substrate is textile fabric.

4. A method according to claim 1 or 2, wherein the solid substrate is human skin. 0

5. A method according to claim 4, wherein the human skin is human facial skin. gees

6. A method for removing lipid and silicone based compounds from human skin, wherein the method comprises the application of a safe and effective amount of a cleansing composition comprising: a) from 7.5% to 50% of a lathering surfactant; and b) from 50% to 92.5% water; wherein the pH of the composition is less than 8.3 and wherein the interfacial tension of the composition with mineral oil is less than

7. A method for cleansing the skin of the face of a human wherein the method comprises the application of a safe and effective amount of cleansing composition comprising: MINNIE JCEabeth\PJC\ WORKYj590535P.DOC a) b) wherein the wherein the 18 from 5% to 74.5% of a lathering surfactant; and from 25% to 94.9 water; pH of the composition is less than 8.3 and interfacial tension of the composition with mineral oil is less than

8. A method for removing lipid and silicone based compounds according to claim 1 substantially as hereinbefore described with reference to any one of the examples. DATED: 30 April 2001 PHILLIPS ORMONDE FITZPATRICK Atorneys for: THE PROCTER GAMBLE COMPANY 0 0 S00% 55550 0* S 0000 Oseo see W~INNIEWJC~EhSbethMPJCXWORXKiS90535P.DOC