AU2014202401A1

AU2014202401A1 - Pesticidal mixtures

Info

Publication number: AU2014202401A1
Application number: AU2014202401A
Authority: AU
Inventors: Egon Haden; Hassan Oloumi-Sadeghi; Dirk Voeste
Original assignee: BASF SE
Current assignee: BASF SE
Priority date: 2007-02-06
Filing date: 2014-05-02
Publication date: 2014-05-22

Abstract

Abstract The present invention relates to mixtures comprising, as active components, 1) an insecticidal compound I selected from fipronil and ethiprole; and 2) a fungicidal compound IIA selected from azoles, strobilurins, carboxamides, heterocyclic compounds, carbamates, and other active compounds, and optionally 3) one or two fungicidal compounds lB selected from List B which is defined as List A plus triticonazole, orysastrobin, in synergistically effective amounts, all as further defined in the description.

Description

1 Pesticidal mixtures Description 5 The present invention relates to synergistic mixtures comprising, as active compo nents, 1) an insecticidal compound I selected from fipronil and ethiprole; 10 and 2) a fungicidal compound IIA selected from List A: a) azoles, in particular: difenoconazole, bitertanole, bromuconazole, dinicon 15 azole, enilconazole, fenbuconazole, flusilazole, fluquinconazole, flutriafol, imibenconazole, ipconazole, myclobutanil, paclobutrazol, penconazole, propiconazole, simeconazole, tetraconazole, uniconazole-P, triadimenol, triadimefon, triticonazole, cyazofamid, pefurazoate, benomyl, carbendazim, fuberidazole, thiabendazole, ethaboxam, etridiazole and hymexazole; 20 b) strobilurins, in particular: azoxystrobin, dimoxystrobin, enestroburin, fluoxa strobin, kresoxim-methyl, metominostrobin, picoxystrobin, trifloxystrobin, or methyl (2-chloro-5-[1 -(3-methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1 -(6-methylpyrid in-2-yl 25 methoxyimino)ethyl]benzyl)carbamate, methyl 2-(ortho-((2,5-d imethylphe nyloxymethylene)phenyl)-3-methoxyacrylate; c) carboxamides, in particular: carboxin, benalaxyl, boscalid, fenhexamid, flu tolanil, furametpyr, mepronil, metalaxyl, mefenoxam (metalaxyl-M), 30 ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil, N-(4'-bromobiphenyl-2-yl) 4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4'-trifluoromethylbi phenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4' chloro-3'-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5 35 carboxamide, N-(2'-fluoro-4'-chloro-5'-methyl-biphenyl-2-yl)-1 -methyl-3 trifluoro-methyl-1 H-pyrazole-4 carboxamide, N-(3',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3',4',5' trifluorobiphenyl-2-yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4 carboxamide, N-(2',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3-d ifluoromethyl 40 1 H-pyrazole-4-carboxamide, N-(3',4',5'-trifluorobiphenyl-2-yl)-3 chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(3' ,4' - 2 dichloro-4-fluorobiphenyl-2-yl)-3-difluoro-methyl-1 -methyl-pyrazole 4-carboxamide, N-(3' ,4' -dichloro-5-fluorobiphenyl-2-yl) 3-difluoromethyl-1-methylpyrazole-4-carboxamide, N-(2-(1,3 dimethylbutyl)-phenyl)-1,3-dimethyl-5-fluoro-1 H-pyrazole-4-carboxylic acid 5 amide, N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-d ifluoromethyl-1 -methyl-1 H pyrazole-4-carboxylic acid amide, N-(trans-2-bicyclopropyl-2-yl-phenyl)-3 difluoro-methyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, 3 (difluoromethyl)-1 -methyl-N-[1,2,3,4-tetrahyd ro-9-(1 -methylethyl)-1 ,4 methanonaphthalen-5-yl]-1 H-pyrazole-4carboxamide, N-(3',4'-dichloro-4 10 fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide, N (3',4'-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1 -methylpyrazole-4 carboxamide; 3,4-dichloro-N-(2-cyanophenyl)isothiazol-5-carboxamide; N (2',4'-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1 H-pyrazole- 4 carboxamide; N-(2',4'-d ichloro-biphenyl-2-yl)-1 -methyl-3-trifluoromethyl 15 1 H-pyrazole- 4-carboxamide; N-(2',4'-difluorobiphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole- 4-carboxamide; N-(2',4' dichlorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide; N-(2',5'-difluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H pyrazole- 4-carboxamide; N-(2',5'-dichlorobiphenyl-2-yl)-1 -methyl-3 20 trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2',5'-difluorobiphenyl-2-yl) 3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2',5' dichlorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide; N-(3',5'-difluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H pyrazole-4-carboxamide; N-(3',5'-dichlorobiphenyl-2-yl)-1-methyl-3 25 trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3',5'-difluorobiphenyl-2-yl) 3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(3',5' dichlorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide; N-(3'-fluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H pyrazole-4-carboxamide, N-(3'-chlorobiphenyl-2-yl)-1-methyl-3 30 trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3'-fluorobiphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide, N-(3'-chlorobiphenyl 2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2' fluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2'-chlorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4 35 carboxamide; N-(2'-fluorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H pyrazole-4-carboxamide; N-(2'-chlorbiphenyl-2-yl)-3-difluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide; N-(2'-fluoro-4'-chloro-5' methylbiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide; N-(3',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl 40 1 H-pyrazole-4-carboxamide; N-(3',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide; N-(2',4',5'-trifluorobiphenyl-2- 3 yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide; N-(3',4',5' trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide; N-[2-(1,1,2,3,3,3-hexafluoropropoxy)phenyl]-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3 5 hexafl uoropropoxy)-phenyl]-3-difluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide, N-[2-(2-chloro-1,1,2-trifluoroethoxy)phenyl]-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(2-chlor-1,1,2 trifluoroethoxy) phenyl]-3-d ifluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide; 4-carbonsaure-N-[2-(1,1,2,2-tetrafluoroethoxy)phenyl]-3 10 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,2 tetrafluoroethoxy)phenyl]-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide; N-(4'-(trifluoromethylthio)biphenyl-2-yl)-3-difluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide; N-(4'-(trifluoromethylthio)biphenyl-2 yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; 15 flumorph; flumetover, fluopicolide (picobenzamid), zoxamide; carpropamid, diclocymet, mandipropamid; N-(2-{4-[3-(4-chlorophenyl) prop-2-ynyloxy]-3-methoxyphenyl}ethyl)-2 methanesulfonylamino-3-methylbutyramide, N-(2-{4-[3-(4-chlorophenyl) 20 prop-2-ynyloxy]-3-methoxyphenyl}ethyl)-2-ethanesulfonylamino-3-methyl butyramide; d) heterocylic compounds, in particular: fluazinam, pyrifenox; bupirimate, cyprodinil, fenarimol, ferimzone, mepanipyrim, nuarimol, 25 pyrimethanil; triforine; fenpiclonil, fludioxonil; iprodione, procymidone, vinclozolin; famoxadone, fenamidone, octhilinone, probenazole; 30 amisulbrom, anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole; 2-butoxy-6-iodo-3-propylchromen-4-one; acibenzolar-S-methyl, captafol, captan, dazomet, folpet, fenoxanil, quin oxyfen; 3-[5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3-yl]pyridine; 35 e) carbamates, in particular: mancozeb, maneb, metam, metiram, ferbam, propineb,; diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb; methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methyl butyrylamino)propanoate; 40 and 4 f) other active compounds, selected from guanidines: dodine, iminoctadine, guazatine; antibiotics: kasugamycin, streptomycin, polyoxine, validamycin A; nitrophenyl derivates: binapacryl, dinocap, dinobuton; 5 sulfur-containing heterocyclyl compounds: dithianon, isoprothiolane; organometal compounds: fentin salts, such as fentin-acetate; organophosphorus compounds: edifenphos, iprobenfos, fosetyl, fosetyl aluminum, phosphorous acid and its salts, pyrazophos, tolclofos-methyl; organochlorine compounds: chlorothalonil, dichlofluanid, flusulfamide, 10 hexachlorobenzene, phthalide, pencycuron, quintozene, thiophanate methyl, tolylfluanid; inorganic active compounds: Bordeaux mixture, copper acetate, copper hy droxide, copper oxychloride, sulfur; others: cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, 15 metrafenone and spiroxamine. The present invention also comprises synergistic mixtures as defined above, which further comprise one or two fungicidal compounds llB selected from List B which is defined as List A plus triticonazole, orysastrobin, 5-chloro-7-(4-methylpiperidin-1 -yl)-6 20 (2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, 6-(3,4-dichloro-phenyl)-5-methyl [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6-(4-tert-butylphenyl)-5-methyl-[1,2,4]tri azolo[1,5-a]pyrimidine-7-ylamine, 5-methyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4]triazolo[1,5 a]pyrimidine-7-ylamine, 5-methyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6 methyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6-ethyl-5-octyl 25 [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyri midine-7-ylamine, 5-ethyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4]triazolo[1,5-a]pyrimidine-7 ylamine, 6-octyl-5-propyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-methoxymethyl 6-octyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6-octyl-5-trifluoromethyl [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine and 5-trifluoromethyl-6-(3,5,5-trimethyl 30 hexyl)-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, cyproconazole, epoxiconazole, hex aconazole, metconazole, prothioconazole, propiconazole, tebuconazole, imazalil, pro chloraz, triflumizol, dimethomorph, aldimorph, dodemorph, fenpropimorph, tridemorph; fenpropidin, mancozeb, maneb, metam, metiram, ferbam, thiram, zineb, ziram and ba sic copper sulfate; 35 in synergistically effective amounts, with the proviso that the combination of compound IIA and compounds llB is not: metalaxyl, fludioxonil and difenoconazole; metalaxyl-M, fludioxonil and difenoconazole; 5 fludioxonil, metalaxyl and azoxystrobin; fludioxonil, metalaxyl and picoxystrobin; fludio xonil, metalaxyl; trifloxystrobin; fludioxonil, metalaxyl and kresoxim-methyl; and fludio xonil and propiconazole. 5 The following subset of compounds llB is hereinafter also designated as compounds 1lC): cyproconazole, epoxiconazole, hexaconazole, metconazole, propiconazole, tebu conazole, imazalil, prochloraz, triflumizol, dimethomorph, aldimorph, dodemorph, fen propimorph, tridemorph; fenpropidin, mancozeb, maneb, metam, metiram, ferbam, thiram, zineb, ziram and basic copper sulfate. 10 The present invention also comprises fungicidal synergistic mixtures consisting of fun gicidal compound IB and lID, wherein such compounds defined above. The present invention also comprises fungicidal synergistic mixtures consisting of three 15 fungicidal compounds, wherein two compounds are selected from List B, List B is de fined above, and the third fungidical compound is fungicidal compound lID selected from List D, which is defined as List B plus pyracolostrobin. The present invention also comprises quaternary mixtures comprising, as active com 20 ponents 1) an insecticidal compound I selected from fipronil and ethiprole; and 2) a fungicidal compound IIA; 3) a fungicidal compound IIB; and 4) and a fungicide, wherein the fungicide is fungicidal compound lID 25 in synergistically effective amounts. The inventive mixtures can further contain one or more insecticidal compounds Ill. 30 In this respect, the present invention also comprises mixtures comprising, as active components (1) an insecticidal compound I selected from fipronil and ethiprole; (2) a nicotinic receptor agonists/antagonists compound IlIlA; 35 (3) and a fungicide, wherein the fungicide is fungicidal compound lID and/or com pound IIB; in synergistically effective amounts.

6 The present invention also comprises mixtures comprising, as active components (1) an insecticidal compound I selected from fipronil and ethiprole; (2) an anthraniliamide compound IllB; 5 (3) and a fungicide, wherein the fungicide is fungicidal compound lID and/or com pound IIB; in synergistically effective amounts. 10 Moreover, the invention relates to a method for controlling pests, this includes animal pests and harmful fungi, using mixtures of a compound I (optionally together with com pound Ill) with an active compound IIA and optionally compound(s) IB (or IID) and to the use of a the aforementioned compounds for preparing such mixtures, and also to compositions comprising such mixtures. 15 The invention furthermore relates to a method for controlling pests, this includes animal pests and harmful fungi, using mixtures of a compound I with an active compound IIC and optionally compound(s) IB and to the use of a compound I and the active com pound IIC and optionally compound(s) IB for preparing such mixtures. 20 The invention furthermore relates to a method for controlling pests, this includes animal pests and harmful fungi, using mixtures of a compound I with compound Ill, com pound(s) Il and to the use of the aforementioned compounds for preparing such mix tures. 25 The invention furthermore relates to a method for controlling pests, this includes animal pests and harmful fungi, using mixtures of compound I, fungicidal compound IIA, fungi cidal compound IB and compound lID and to the use of a compound I, active com pound IIA, and the active compound IB and compound lID for preparing such mixtures. 30 In one embodiment, the present invention provides methods for the control of insects, acarids or nematodes comprising contacting the insect, acarid or nematode or their food supply, habitat, breeding grounds or their locus with a pesticidally effective amount of the inventive mixtures. 35 Moreover, in another embodiment the present invention also relates to a method of protecting plants from attack or infestation by insects, acarids or nematodes comprising contacting the plant, or the soil or water in which the plant is growing, with a pesticidally effective amount of the inventive mixture. 40 7 This invention also provides a method for treating, controlling, preventing or protecting an animal against infestation or infection by parasites which comprises orally, topically or parenterally administering or applying to the animals a parasiticidally effective amount of the inventive mixture. 5 The invention also provides a process for the preparation of a composition for treating, controlling, preventing or protecting a warm-blooded animal or a fish against infestation or infection by insects, acarids or nematodes which comprises a pesticidally effective amount of the inventive mixture. 10 Moreover, the invention relates to a method for controlling harmful fungi using the in ventive mixtures and to the use of a compound I and the active compound IIA and op tionally compound(s) IlB for preparing such mixtures, and also to compositions com prising such mixtures. 15 The invention furthermore relates to a method for controlling harmful fungi, using the synergistic fungicidal mixtures as defined above. The present invention further relates to plant-protecting active ingredient mixtures hav 20 ing synergistically enhanced action of improving the health of plants and to a method of applying such inventive mixtures to the plants Fipronil, its preparation and its action against insect and acarid pests is known (EP 295117). 25 Ethiprole, its preparation and its action against insect and acarid pests is known (WO 97/22593). Mixtures, active against harmful fungi, of fipronil with benzylideneazolylmethylcycloal 30 kane fungicides have been described in a general manner in WO 95/12314 (US 5,877,194). Triticonazole and 2-(4-chlorobenzylidene)-1 -(1 H-1,2,4-triazol-1 -ylmethyl)-1 cyclohexanol have been mentioned as azole mixing partners in this document. WO 99/48366 discloses mixtures of triple oxime ether derivatives and insecticides. A 35 mixture of orysastrobin and fipronil is mentioned as an example. In WO 00/28825, at least quaternary compositions are described that comprise an in secticide selected from phenylpyrazole or neonicotinoid insecticides and at least three fungicides including metalaxyl or metalaxyl-M and their close structural derivatives, 40 fludioxonil and its close structural derivatives, and difenoconazole and its close struc- 8 tural derivatives. Explicitly preferred is a composition comprising thiamethoxam as in secticide, metalaxyl or metalaxyl-M, fludioxonil and difenoconazole. WO 02/102148 discloses mixtures of fludioxonil, metalaxyl and a strobilurine fungicide 5 such as azoxystrobin, picoxystrobin, trifloxystrobin and kresoxim-methyl which option ally may further contain an insecticide selected from fipronil or a neonicotinoid insecti cide. Mixtures containing thiamethoxam as insecticide are mentioned explicitly. WO 05/051081 discloses antimicrobial compositions of fludioxonil and at least one se 10 lected from a list of certain azole compounds which optionally may further contain an insecticide, inter alia fipronil. In WO 05/058040, combinations of fipronil and pyraclostrobin are disclosed which may contain one further fungicide or insecticide. 15 WO 03/075653 discloses mixtures of prothioconazole with several insecticides, inter alia fipronil. WO 95/00303 generically discloses mixtures of fungicides and insecticides for protec 20 tion of technical materials. Preferred insecticides were chlopyrifos, phoxim, silafluofen, cyfluthrin, cypermethrin, deltamethrin, permethrin, imidacloprid, hexaflumuron and lin dan. WO 06/066810 encompasses orysastrobin mixtures with a further fungicide, which may 25 additionally comprise an additional insecticidal mixing partner selected from the group consisting of imazethapyr, imazamox, imazapyr, imazapic, dimethenamid-p, fipronil, imidacloprid, acetamipird, nitenpyram, carbofuran, carbosulfan, benfuracarb, thiaclo prid, clothianidin, MTI 446 or CGA 293343. Specific mixtures with the additional insec ticidal mixing partner were not disclosed. 30 DE 195 48 873 discloses mixtures of fipronil with several fungicides, especially several azole fungicides for protection of technical materials, especially wood. The active compounds IIA,1IB and lID mentioned above, their preparation and their 35 action against harmful fungi are generally known (cf.: http://www.hcirss.dernon.co.uk/index.html); they are commercially available. Paticu larly, they are known from: bitertanol, p-([1,1'-biphenyl]-4-yloxy)-a-(1,1-dimethylethyl) 1H-1,2,4-triazole-1-ethanol (DE 23 24 020), bromuconazole, 1-[[4-bromo-2-(2,4-di chlorophenyl)tetrahyd ro-2-furanyl]methyl]-1 H-1,2,4-triazole (Proc. 1990 Br. Crop. Prot. 40 Conf. - Pests Dis. Vol. 1, p. 459); cyproconazole, 2-(4-chlorophenyl)-3-cyclopropyl-1 [1,2,4]triazol-1-ylbutan-2-ol (US 4 664 696); difenoconazole, 1-{2-[2-chloro-4-(4-chloro- 9 phenoxy)phenyl]-4-methyl-[1,3]dioxolan-2-ylmethyl}-1 H-[1,2,4]triazole (GB-A 2 098 607); diniconazole, (pE)-p-[(2,4-dichlorophenyl)methylene]-a-(1,1-dimethylethyl)-1 H 1,2,4-triazole-1-ethanol (Noyaku Kagaku, 1983, Vol. 8, p. 575); enilconazole (imazalil), 1 -[2-(2,4-dichlorphenyl)-2-(2-propenyloxy)ethyl]-1 H-imidazole (Fruits, 1973, Vol. 28, p. 5 545); epoxiconazole, (2RS,3SR)-1-[3-(2-chlorophenyl)-2,3-epoxy-2-(4-fluorophe nyl)propyl]-1 H-1,2,4-triazole (EP-A 196 038); fluquinconazole, 3-(2,4-dichlorophenyl)-6 fluoro-2-[1,2,4]-triazol-1-yl-3H-quinazolin-4-one (Proc. Br. Crop Prot. Conf.-Pests Dis., 5-3, 411 (1992)); fenbuconazole, a-[2-(4-chlorophenyl)ethyl]-a-phenyl-1 H-1,2,4-tri azole-1-propanenitrile (Proc. 1988 Br. Crop Prot. Conf. - Pests Dis. Vol. 1, p. 33); flusi 10 lazole, 1 -{[bis-(4-fluorophenyl)methylsilanyl]methyl}-1 H-[1,2,4]triazole (Proc. Br. Crop Prot. Conf.-Pests Dis., 1, 413 (1984)); flutriafol, a-(2-fluorophenyl)-a-(4-fluorophenyl) 1 H-1,2,4-triazole-1 -ethanol (EP 15 756); hexaconazole, 2-(2,4-dichlorophenyl)-1 [1,2,4]triazol-1-ylhexan-2-ol (CAS RN 79983-71-4); imibenconazole, (4-chlorophe nyl)methyl N-(2,4-dichlorophenyl)-1 H-1,2,4-triazole-1 -ethanimidothioate ((Proc. 1988 15 Br. Crop Prot. Conf. - Pests Dis. Vol. 2, p. 519); imidothioate ((Proc. 1988 Br. Crop Prot. Conf. - Pests Dis. Vol. 2, p. 519); ipconazole, 2-[(4-chlorophenyl)methyl]-5-(1 methylethyl)-1 -(1 H-1,2,4-triazol-1 -ylmethyl)cyclopentanol (EP 267 778); metconazole, 5-(4-chlorobenzyl)-2,2-di methyl-1-[1,2,4]triazol-1-ylmethylcyclopentanol (GB 857 383); myclobutanil, 2-(4-chlorophenyl)-2-[1,2,4]triazol-1-ylmethylpentanenitrile (CAS RN 20 88671-89-0); penconazole, 1-[2-(2,4-dichlorophenyl)pentyl]-1 H-[1,2,4]triazole (Pesti cide Manual, 12th Ed. (2000), p.

7 12); propiconazole, 1-[[2-(2,4-dichlorophenyl)-4 propyl-1,3-dioxolan-2-yl]methyl]-1 H-1,2,4-triazole (BE 835 579); prothioconazole, 2-[2 (1 -chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-2,4-dihydro-[1,2,4]triazole-3 thione (WO 96/16048); simeconazole, a-(4-fluorophenyl)-a-[(trimethylsilyl)methyl]-1 H 25 1,2,4-triazole-1-ethanol [CAS RN 149508-90-7] ; triadimefon, 1-(4-chlorophenoxy)-3,3 dimethyl-1-(1H-1,2,4-triazol-1-yl)-2-butanone; triadimenol, p-(4-chlorophenoxy)-a-(1,1 dimethylethyl)-1 H-1,2,4-triazole-1 -ethanol; tebuconazole, 1-(4-chlorophenyl)-4,4-di methyl-3-[1,2,4]triazol-1 -ylmethylpentan-3-ol (EP-A 40 345); tetraconazole, 1-[2-(2,4 dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]-1 H-1,2,4-triazole (EP 234 242); 30 triticonazole, (5E)-5-[(4-chlorophenyl)methylene]-2,2-dimethyl-1 -(1 H-1,2,4-triazol-1 ylmethyl)cyclopentanol (FR 26 41 277); prochloraz, N-{propyl-[2-(2,4,6-trichlorophen oxy)ethyl]}imidazole-1-carboxamide (US 3 991 071); pefurazoate, 4-pentenyl 2-[(2-fu ranylmethyl)(1 H-imidazol-1 -ylcarbonyl)amino]butanoate [CAS RN 101903-30-4] ; tri flumizole, (4-chloro-2-trifluoromethylphenyl)-(2-propoxy-i1-[1,2,4]triazol-1-ylethyli 35 dene)amine (JP-A 79/119 462); cyazofamid, 4-chloro-2-cyano-N,N-dimethyl-5-(4-me thylphenyl)-1 H-imidazole-1 -sulfonamide (CAS RN 120116-88-3]; benomyl, N-butyl-2 acetylaminobenzoimidazol-1-carboxamide (US 3 631 176); carbendazim, methyl (1H benzoimidazol-2-yl)-carbamate (US 3 657 443); thiabendazole, 2-(1,3-thiazol-4 yl)benzimidazole (US 3 017 415) ; fuberidazole, 2-(2-furanyl)-1 H-benzimidazole (DE 12 40 09 799); ethaboxam, N-(cyano-2-thienylmethyl)-4-ethyl-2-(ethylamino)-5-thiazolcarbox amide (EP-A 639 574); etridiazole; hymexazole, 5-methyl- 1,2-oxazol-3-ol (JP 518249, 10 JP 532202); azoxystrobin, methyl 2-{2-[6-(2-cyano-1-vinylpenta-1,3-dienyloxy)pyrimi d in-4-yloxy]phenyl}-3-methoxyacrylate (EP-A 382 375); dimoxystrobin, (E)-2-(methoxy imino)-N-methyl-2-[a-(2,5-xylyloxy)-o-tolyl]acetamide (EP-A 477 631); fluoxastrobin, (E)-{2-[6-(2-chlorophenoxy)-5-fluoropyrimidin-4-yloxy]phenyl}(5,6-dihydro-1,4,2-dioxa 5 zin-3-yl)methanone 0-methyloxime (WO 97/27189); kresoxim-methyl, methyl (E)-me thoxyim ino[a-(o-tolyloxy)-o-tolyl]acetate (EP-A 253 213); metominostrobin, (E)-2-(me thoxyimino)-N-methyl-2-(2-phenoxyphenyl)acetamide (EP-A 398 692); orysastrobin, (2E)-2-(methoxyimino)-2-{2-[(3E,5E,6E)-5-(methoxyimino)-4,6-dimethyl-2,8-dioxa-3,7 diazanona-3,6-dien-1-yl]phenyl}-N-methylacetamide (WO 97/15552); picoxystrobin, 10 methyl 3-methoxy-2-[2-(6-trifluoromethyl pyrid in-2-yloxymethyl)phenyl]acrylate (EP-A 278 595); trifloxystrobin, methyl (E)-methoxyimino-{(E)-a-[1-(a,a,a-trifluoro-m tolyl)ethylideneam inooxy]-o-tolyl}acetate (EP-A 460 575); carboxin, 5,6-dihydro-2 methyl-N-phenyl-1,4-oxathiin-3-carboxamide (US 3 249 499); benalaxyl, methyl N (phenylacetyl)-N-(2,6-xylyl)-DL-alaninate (DE 29 03 612); boscalid, 2-chloro-N-(4' 15 chlorbiphenyl-2-yl)nicotinamide (EP-A 545 099); fenhexamid, N-(2,3-dichloro-4 hydroxyphenyl)-1-methylcyclohexanecarboxamide (Proc. Br. Crop Prot. Conf. - Pests Dis., 1998, Vol. 2, p. 327); flutolanil,a,a,a-trifluoro-3'-isopropoxy-o-toluanilide (JP 1104514); furametpyr, 5-chloro-N-(1,3-dihydro-1,1,3-trimethyl-4-isobenzofuranyl)-1,3 dimethyl-1 H-pyrazole-4-carboxamide [CAS RN 123572-88-3]; mepronil, 3'-isopropoxy 20 o-toluanilide (US 3 937 840); metalaxyl, methyl N-(methoxyacetyl)-N-(2,6-xylyl)-DL alaninate (GB 15 00 581); mefenoxam (metalaxyl-M), methyl N-(2,6-dimethylphenyl)-N (methoxyacetyl)-D-alaninate; ofurace, (RS)-a-(2-chloro-N-2,6-xylylacetamido)-y butyrolactone [CAS RN 58810-48-3]; oxadixyl; N-(2,6-d imethylphenyl)-2-methoxy-N-(2 oxo-3-oxazolidinyl)acetamide (GB 20 58 059); oxycarboxin, 5,6-d ihyd ro-2-methyl-1,4 25 oxathiin-3-carboxanilide 4,4-dioxide (US 3 399 214); penthiopyrad, N-[2-(1,3 dimethylbutyl)-3-thienyl]-1 -methyl-3-(trifluoromethyl)-1 H-pyrazole-4-carboxamide (JP 10130268); thifluzamide, N-[2,6-dibromo-4-(trifluoromethoxy)phenyl]-2-methyl-4 (trifluoromethyl)-5-thiazolecarboxamide; tiadinil, 3'-chloro-4,4'-dimethyl-1,2,3 thiadiazole-5-carboxanilide [CAS RN 223580-51-6]; dimethomorph, 3-(4-chlorophenyl) 30 3-(3,4-dimethoxyphenyl)-1-morpholin-4-ylpropenone (EP-A 120 321); flumorph, 3-(4 fluorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-ylpropenone (EP-A 860 438); flumetover, 2-(3,4-dimethoxyphenyl)-N-ethyl-a,a,a-trifluoro-N-methyl-p-toluamide [AGROW No. 243, 22 (1995)]; fluopicolide (picobenzamid), 2,6-dichloro-N-(3-chloro-5 trifluoromethylpyridin-2-ylmethyl)benzamide (WO 99/42447); zoxamide, (RS)-3,5 35 d ichloro-N-(3-chloro-1 -ethyl-1 -methyl-2-oxopropyl)-p-toluam ide [CAS RN 156052-68-5]; carpropamid, 2,2-dichloro-N-[1-(4-chlorophenyl)ethyl]-1-ethyl-3-methylcyclopropane carboxamide [CAS RN 104030-54-8]; diclocymet, 2-cyano-N-[(1R)-1-(2,4 dichlorophenyl)ethyl]-3,3-dimethy butanamide; mandipropamid, (RS)-2-(4-chloro phenyl)-N-[3-methoxy-4-(prop-2-ynyloxy)phenethyl]-2-(prop-2-ynyloxy)acetamide [CAS 40 RN 374726-62-2]; fluazinam, 3-chloro-N-[3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl] 5-(trifluoromethyl)-2-pyridinamine (The Pesticide Manual, publ. The British Crop Pro- 11 tection Council, 10th ed. (1995), p. 474); pyrifenox, 1-(2,4-dichlorophenyl)-2-(3-pyridi nyl)ethanone 0-methyloxime (EP-A 49 854); bupirimate, 5-butyl-2-ethylamino-6-methyl pyrimidin-4-yldimethylsulfamate [CAS RN 41483-43-6]; cyprodinil, (4-cyclopropyl-6 methylpyrimidin-2-yl)phenylamine (EP-A 310 550); fenarimol, (4-chlorophenyl) (2 5 chlorophenyl) pyrimidin-5-ylmethanol (GB 12 18 623); ferimzone, (Z)-2'-methylaceto phenone 4,6-dimethylpyrimidin-2-ylhydrazone [CAS RN 89269-64-7]; mepanipyrim, (4 methyl-6-prop-1 -ynylpyrimidin-2-yl)phenylamine (EP-A 224 339); nuarimol, a-(2-chloro phenyl)-a-(4-fluorophenyl)-5-pyrimidinemethanol (GB 12 18 623); pyrimethanil, 4,6-di methylpyrimidin-2-ylphenylamine (DD-A 151 404); triforine, N,N-{piperazine-1,4-diyl 10 bis[(trichloromethyl)methylene]}diformamide (DE 19 01 421); fenpiclonil, 4-(2,3-di chlorophenyl)-1H-pyrrole-3-carbonitrile (Proc. 1988 Br. Crop Prot. Conf. - Pests Dis., Vol. 1, p. 65); fludioxonil, 4-(2,2-difluorobenzo[1,3]dioxol-4-yl)-1 H-pyrrole-3-carbonitrile (The Pesticide Manual, publ. The British Crop Protection Council, 10th ed. (1995), p. 482); aldimorph, 4-alkyl-2,5(or 2,6)-dimethylmorpholine, comprising 65-75% of 2,6-di 15 methylmorpholine and 25-35% of 2,5-dimethylmorpholine, comprising more than 85% of 4-dodecyl-2,5(or 2,6)-dimethylmorpholine, where "alkyl" may also include octyl, de cyl, tetradecyl or hexadecyl and where the cis/trans ratio is 1:1; dodemorph, 4-cyclo dodecyl-2,6-dimethylmorpholine (DE 1198125); fenpropimorph, (RS)-cis-4-[3-(4-tert butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine (DE 27 52 096); tridemorph, 2,6 20 dimethyl-4-tridecylmorpholine (DE 11 64 152); fenpropidin, (RS)-1-[3-(4-tert-butylphe nyl)-2-methylpropyl]piperidine (DE 27 52 096); iprodione, N-isopropyl-3-(3,5-dichloro phenyl)-2,4-dioxoimidazolidine-1-carboxamide (GB 13 12 536); procymidone, N-(3,5 dichlorophenyl)-1,2-dimethylcyclopropane-1,2-dicarboximide (US 3 903 090); vinclo zolin, 3-(3,5-dichlorophenyl)-5-methyl-5-vinyloxazolidine-2,4-dione (DE-OS 22 07 576); 25 famoxadone, (RS)-3-anilino-5-methyl-5-(4-phenoxyphenyl)-1,3-oxazolidine-2,4-dione; fenamidone, (S)-1-anilino-4-methyl-2-methylthio-4-phenylimidazolin-5-one; octhilinone; probenazole, 3-allyloxy-1,2-benzothiazole 1,1-dioxide; amisulbrom, N,N-dimethyl-3-(3 bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide (WO 03/053145); anilazine, 4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazine-2-amine (US 2 30 720 480); diclomezine, 6-(3,5-dichlorophenyl)-p-tolyl)pyridazin-3(2H)-one; pyroquilon; proquinazid, 6-iodo-2-propoxy-3-propylquinazolin-4(3H)-one (WO 97/48684); tricycla zole, 5-methyl-1,2,4-triazolo[3,4-b]benzothiazole (GB 14 19 121); acibenzolar-S-me thyl, methyl benzo[1,2,3]thiadiazole-7-carbothionate; captafol, N-(1,1,2,2-tetrachloro ethylthio)cyclohex-4-ene-1,2-dicarboximide; captan, 2-trichloromethylsulfanyl 35 3a,4,7,7a-tetrahydroisoindole-1,3-dione (US 2 553 770); dazomet, 3,5-dimethyl-1,3,5 thiadiazinane-2-thione; folpet, 2-trichloromethylsulfanylisoindole-1,3-dione (US 2 553 770); fenoxanil, N-(1-cyano-1,2-dimethylpropyl)-2-(2,4-dichlorophenoxy) propanamide; quinoxyfen, 5,7-dichloro-4-(4-fluorophenoxy)quinoline (US 5 240 940); mancozeb, manganese ethylenebis(dithiocarbanate) zinc complex (US 3 379 610); maneb, man 40 ganese ethylenebis(dithiocarbamate) (US 2 504 404); metam, methyldithiocarbaminic acid (US 2 791 605); metiram, zinc ammoniate ethylenebis(dithiocarbamate) (US 3 248 12 400); propineb, zinc propylenebis(dithiocarbamate) polymer (BE 611 960); ferbam, iron(3+) dimethyldithiocarbamate (US 1 972 961); thiram, bis(dimethylthiocarbamoyl) disulfide (DE 642 532); ziram, dimethyldithiocarbamate; zineb, zinc ethylenebis(dithio carbamate) (US 2 457 674); diethofencarb, isopropyl 3,4-diethoxycarbanilate; iprovali 5 carb, isopropyl [(1 S)-2-methyl-1 -(1 -p-tolylethylcarbamoyl)propyl]carbamate (EP-A 472 996); flubenthiavalicarb (benthiavalicarb), isopropyl {(S)-1-[(1 R)-1-(6-fluorobenzothia zol-2-yl)ethylcarbamoyl]-2-methylpropyl}carbamate (JP-A 09/323 984); propamocarb, propyl 3-(dimethylamino)propylcarbamate (DE 16 43 040); dodine, (2,4-dichlorophen oxy)acetic acid (US 2 867 562); iminoctadine, bis(8-guanidinooctyl)amine (GB 10 11 14 155); guazatine, mixture of products from the amidation of iminodi(octamethy lene)diamine, mainly iminoctadine; kasugamycin, 1 L-1,3,4/2,5,6-1 -deoxy-2,3,4,5,6 pentahydroxycyclohexyl 2-amino-2,3,4,6-tetradeoxy-4-(a-iminoglycino)-a-D-arabino hexopyranoside; streptomycin, O-2-deoxy-2-methylami no-a-L-glucopyranosyl-(1 ->2) O-5-deoxy-3-C-formyl-a-L-lyxofuranosyl-(1->4)N1,N 3 -diamidino-D-streptamine; polyox 15 ins, 5-(2-amino-5-O-carbamoyl-2-deoxy-L-xylonamido)-1-(5-carboxy-1,2,3,4-tetrahydro 2,4-dioxopyrimidin-1-yl)-1,5-dideoxy- -D-allofuranuronic acid and the salts thereof; validamycin A, binapacryl, (RS)-2-sec-butyl-4,6-dinitrophenyl 3-methylcrotonate; dino cap, the mixture of 2,6-dinitro-4-octylphenyl crotonate and 2,4-dinitro-6-octylphenyl crotonate, wherein "octyl" is a mixture of 1-methylheptyl, 1-ethylhexyl and 1-propyl 20 pentyl (US 2 526 660); dinobuton, (RS)-2-sec-butyl-4,6-dinitropheny isopropyl carbon ate; dithianon, 5,10-dioxo-5,10-dihydronaphtho[2,3-b][1,4]dithiin-2,3-dicarbonitrile (GB 857 383); isoprothiolane, indol-3-ylacetic acid; fentin acetate, triphenyltin acetate (US 3 499 086); edifenphos, O-ethyl S,S-diphenyl phosphorodithioate; iprobenfos, S benzyl O,O-diisopropyl phosphorothioate (Jpn. Pesticide Inf., No. 2, S. 11 (1970)); fo 25 setyl, fosetyl-aluminum, (aluminum) ethylphosphonate (FR 22 54 276); pyrazophos, ethyl 2-diethoxyphosphinothioyloxy-5-methylpyrazolo[1,5-a]pyrimidine-6-carboxylate (DE 15 45 790); tolclofos-methyl, O-2,6-dichloro-p-tolyl 0,0-dimethyl phosphorothioate (GB 14 67 561); chlorothalonil, 2,4,5,6-tetrachloroisophthaonitrile (US 3 290 353); di chlofluanid, N-dichlorofluoromethylthio-N,N-dimethyl-N-phenylsulfamide (DE 30 11 93 498); flusulfamide, 2',4-dichloro-a,a,a-trifluoro-4'-nitro-m-toluenesulfanilide (EP-A 199 433); hexachlorobenzene (C. R. Seances Acad. Agric. Fr., Vol. 31, p. 24 (1945)); phthalide (DE 16 43 347); pencycuron, 1-(4-chlorobenzyl)-1-cyclopentyl-3-phenylurea (DE 27 32 257); quintozene, pentachloronitrobenzene (DE 682 048); thiophanate methyl, 1,2-phenylenebis(iminocarbonothioyl)bis(dimethylcarbamate) (DE-OS 19 30 35 540); tolylfluanid, N-dichlorofluoromethylthio-N,N-dimethyl-N-p-tolylsulfamide (DE 11 93 498); Bordeaux mixture, mixture of calcium hydroxide and copper(II) sulfate; copper hydroxide, Cu(OH) 2 ; copper oxychloride, Cu 2

CI(OH)

3 ; cyflufenamid, (Z)-N-[a (cyclopropylmethoxyimino)-2,3-difluoro-6-(trifluoromethyl)benzyl]-2-phenylacetamide (WO 96/19442); cymoxanil, 1-(2-cyano-2-methoxyiminoacetyl)-3-ethylurea (US 3 957 40 847); dimethirimol, 5-butyl-2-dimethylamino-6-methylpyrimidin-4-ol (GB 11 82 584); ethirimol, 5-butyl-2-ethylamino-6-methylpyrimidin-4-ol (GB 11 82 584); furalaxyl, methyl 13 N-(2-furoyl)-N-(2,6-xylyl)-DL-alaninate (GB 14 48 810); metrafenone, 3'-bromo-2,3,4,6' tetramethoxy-2',6-dimethylbenzophenone (US 5 945 567); spiroxamine, (8-tert-butyl 1,4-dioxaspiro[4.5]dec-2-yl)diethylamine (EP-A 281 842). 5 The compounds named according to IUPAC, their preparation and their fungicidal ac tivity are likewise known: methyl (2-chloro-5-[1 -(3-methylbenzyloxyimino)ethyl]ben zyl)carbamate, methyl (2-chloro-5-[1 -(6-methylpyrid in-2-ylmethoxyimi no)ethyl]ben zyl)carbamate (EP-A 12 01 648); methyl 2-(ortho-((2,5-di methyl phenyloxymethy lene)phenyl)-3-methoxyacrylate (EP-A 226 917); 5-chloro-7-(4-methylpiperidin-1 -yl)-6 10 (2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine (WO 98/46608), 3,4-dichloro-N (2-cyanophenyl)isothiazole-5-carboxamide (WO 99/24413), N-(2-{4-[3-(4-chlorophe nyl)prop-2-ynyloxy]-3-methoxyphenyl}ethyl)-2-methanesulfonylamino-3-methylbutyr amide, N-(2-{4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl}ethyl)-2-ethane sulfonylamino-3-methylbutyramide (WO 04/049804), N-(4'-bromobipheny-2-y)-4-di 15 fluoromethyl-2-methylthiazole-5-carboxamide, N-(4'-trifluoromethylbiphenyl-2-yl)-4 difluoromethyl-2-methylthiazole-5-carboxamide, N-(4'-chloro-3'-fluorobiphenyl-2-yl)-4 difluoromethyl-2-methylthiazole-5-carboxamide, N-(3',4'-dichloro-4-fluorobiphenyl-2-yl) 3-difluoromethyl-1-methylpyrazole-4-carboxamide (WO 03/066609); N-(3',4'-dichloro-5 fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide (WO 20 03/053145); 2-butoxy-6-iodo-3-propylchromen-4-one (WO 03/14103); 3-[5-(4-chloro phenyl)-2,3-dimethylisoxazolidin-3-yl]pyridine (EP-A 10 35 122); amisulbrom, N,N dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1 -sulfonyl)-[1,2,4]triazole-1 -sulfonamide (WO 03/053145); methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methyl butyrylamino)propanoate (EP-A 1028125); pyraclostrobin (The Pesticide Manual, .13th 25 edition, p 900). 6-(3,4-dichloro-phenyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6-(4-tert butylphenyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-methyl-6-(3,5,5 trimethyl-hexyl)-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-methyl-6-octyl 30 [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6-methyl-5-octyl-[1,2,4]triazolo[1,5 a]pyrimidine-7-ylamine, 6-ethyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5 ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-ethyl-6-(3,5,5-trimethyl-hexyl) [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6-octyl-5-propyl-[1,2,4]triazolo[1,5 a]pyrimidine-7-ylamine, 5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-yl 35 amine, 6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine and 5 trifluoromethyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine are known from EP-A 71 792; EP-A 141 317; WO 03/009687; WO 05/087771; WO 05/087772; WO 05/087773; PCT/EP/05/002426; PCT/EP2006/050922; asn/or PCT/EP2006/060399. 40 14 N-(2',4'-difluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2',4'-dichlorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2',4'-difluorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2',4'-dichlorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; 5 N-(2',5'-difluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2',5'-dichlorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2',5'-difluorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2',5'-dichlorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(3',5'-difluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; 10 N-(3',5'-dichlorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3',5'-difluorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(3',5'-dichlorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(3'-fluorobiphenyl-2-yl)-i -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3'-chlorobiphenyl-2-yl)-i -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3' 15 fluorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(3'-chlorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2' fluorobiphenyl-2-yl)-i -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2' chlorobiphenyl-2-yl)-i -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2' fluorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2' 20 chlorbi phenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2'-fluoro 4'-chloro-5'-methylbiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide; N-(3',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole 4-carboxamide; N-(3',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3-difluoromethyl-1 H pyrazole-4-carboxamide; N-(2',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3-d ifluoromethyl 25 1 H-pyrazole-4-carboxamide; N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoropropoxy)phenyl]-1 methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3 hexafl uoropropoxy)-phenyl]-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide, N-[2-(2-chloro-1, 1,2-trifluoroethoxy)phenyl]-i -methyl-3-trifluoromethyl-1 H-pyrazole-4 30 carboxamide; N-[2-(2-chlor-1, 1, 2-trifluoroethoxy)phenyl]-3-difluoromethyl-1 -methyl-1 H pyrazole-4-carboxamide; 4-carbonsaure-N-[2-(1,1,2,2-tetrafluoroethoxy)phenyl]-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,2 tetrafluoroethoxy)phenyl]-i -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(4' (trifluoromethylthio)biphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4 35 carboxamide; and N-(4'-(trifluoromethylthio)biphenyl-2-yl)-1-methyl-3-trifluoromethyl 1 H-pyrazole-4-carboxamide are known from WO 2006/087343, WO 2001/42223, WO 2005/34628, WO 2005/123689, WO 2005/123690, WO 2006/120219, PCT/EP2006/064991, and/or EP application no. 06123463.9.

15 One typical problem arising in the field of pest control lies in the need to reduce the dosage rates of the active ingredient in order to reduce or avoid unfavorable environmental or toxicological effects whilst still allowing effective pest control. 5 In regard to the instant invention the term pests embrace animal pests, and harmful fungi. Another problem encountered concerns the need to have available pest control agents which are effective against a broad spectrum of pests, e.g. both animal pests and 10 harmful fungi. There also exists the need for pest control agents that combine knock-down activity with prolonged control, that is, fast action with long lasting action. 15 Another difficulty in relation to the use of pesticides is that the repeated and exclusive application of an individual pesticidal compound leads in many cases to a rapid selec tion of pests, that means animal pests, and harmful fungi, which have developed natu ral or adapted resistance against the active compound in question. Therefore there is a need for pest control agents that help prevent or overcome resistance. 20 Another problem underlying the present invention is the desire for compositions that improve plants, a process which is commonly and hereinafter referred to as "plant health". The term plant health comprises various sorts of improvements of plants that are not connected to the control of pests. For example, advantageous properties that 25 may be mentioned are improved crop characteristics including: emergence, crop yields, protein content, oil content, starch content, more developed root system (improved root growth), improved stress tolerance (e.g. against drought, heat, salt, UV, water, cold), reduced ethylene (reduced production and/or inhibition of reception), tillering increase, increase in plant height, bigger leaf blade, less dead basal leaves, stronger tillers, 30 greener leaf color, pigment content, photosynthetic activity, less input needed (such as fertilizers or water), less seeds needed, more productive tillers, earlier flowering, early grain maturity, less plant verse (lodging), increased shoot growth, enhanced plant vigor, increased plant stand and early and better germination; or any other advantages familiar to a person skilled in the art. 35 It was therefore an object of the present invention to provide pesticidal mixtures which solve the problems of reducing the dosage rate and / or enhancing the spectrum of activity and / or combining knock-down activity with prolonged control and / or to resis tance management and/or promoting the health of plants. 40 16 We have found that this object is in part or in whole achieved by the combination of active compounds defined in the outset. Especially, it has been found that a mixture of a compound of formula I and compound 5 IA as defined in the outset show markedly enhanced action against pests compared to the control rates that are possible with the individual compounds and/or is suitable for improving the health of plants when applied to plants, parts of plants, seeds, or at their locus of growth. 10 Furthermore, it has been found that a mixture of a compound of formula I, a nicotinic receptor agonists/antagonists compound IlIlA or an anthranilamide compound IllB, compound IB and/or compound lID as defined in the outset show markedly enhanced action against pests compared to the control rates that are possible with the individual compounds and/or is suitable for improving the health of plants when applied to plants, 15 parts of plants, seeds, or at their locus of growth. Furthermore, it has been found that mixtures of compound I, fungicidal compound IIA, fungicidal compound IB and compound lID as defined in the outset show markedly enhanced action against pests compared to the control rates that are possible with the 20 individual compounds and/or is suitable for improving the health of plants when applied to plants, parts of plants, seeds, or at their locus of growth. In this connection, it has been found that a mixture of a compound of formula I and compound IIC as defined in the outset can be used for plant protection, since also 25 these mixtures show markedly enhanced action against pests compared to the control rates that are possible with the individual compounds and/or is suitable for improving the health of plants when applied to plants, parts of plants, seeds, or at their locus of growth. 30 It has furthermore been found that the following mixtures can be used for plant protec tion, since these mixtures show markedly enhanced action against fungal pests com pared to the control rates that are possible with the individual compounds and/or are suitable for improving the health of plants when applied to plants, parts of plants, seeds, or at their locus of growth: 35 1) Fungicidal mixtures consisting of fungicidal compound IB and lID as defined above. 2) Fungicidal mixtures consisting of three fungicidal compounds, wherein two com pounds are selected from List B, wherein List B is defined above, and the third 40 fungidical compound is fungicidal compound lID selected from List D, which is defined as List B plus pyracolostrobin.

17 It has been found that the action of the inventive mixtures goes far beyond the fungi cidal and/or insecticidal and/or plant health improving action of the active compounds present in the mixture alone. 5 Moreover, we have found that simultaneous, that is joint or separate, application of a compound I and compound IIA (and optionally one or two compounds 1lB, or optionally compound IB and compound IID) or successive application of a compound I and the compounds IA (and IIB, lID) allows enhanced control of pests, that means animal 10 pests, and harmful fungi, compared to the control rates that are possible with the indi vidual compounds (synergistic mixtures). Moreover, we have found that simultaneous, that is joint or separate, application of a compound I, a nicotinic receptor agonists/antagonists compound IllA or an anthranila 15 mide compound IllB, compound IB and/or compound lID or successive application of a compound I, a nicotinic receptor agonists/antagonists compound IllA or an anthranila mide compound IllB and compounds lID allows enhanced control of pests, that means animal pests, and harmful fungi, compared to the control rates that are possible with the individual compounds (synergistic mixtures). 20 Moreover, we have found that simultaneous, that is joint or separate, application of a fungicidal compounds lB and lID and optionally a third fungicidal compound IB or suc cessive application of two compound IB and compound lID and optionally a third fun gicidal compound IB allows enhanced control of pests, that means harmful fungi, com 25 pared to the control rates that are possible with the individual compounds (synergistic mixtures). Preferred are the inventive secondary mixtures containing fipronil as compound I. Preferred are the inventive tertiary mixtures containing fipronil as compound I. 30 Preferred are the inventive quaternary mixtures containing fipronil as compound I. Preferred are the inventive secondary mixtures containing ethiprole as compound I. Preferred are the inventive tertiary mixtures containing ethiprole as compound I. Preferred are the inventive quaternary mixtures containing ethiprole as compound I. 35 Preferred are the inventive mixtures wherein, when compound IIA is fludioxonil, then compounds 1lB1 and 11B2 (or IID2) are not selected from bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, fenbuconazole, fluquin conazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metcona 40 zole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, tri- 18 adimenol, triadimefon, tebuconazole, tetraconazole, triticonazole, paclobutrazol, and uniconazole-P. Furthermore, inventive mixtures are preferred which do not contain fludioxonil. 5 Especially preferred are secondary mixtures containing fipronil as compound I and a fungicidal compound IIA selected from the list comprising azoles:, difenoconazole, fen buconazole, fluquinconazole, flutriafol, ipconazole, tetraconazole, triadimenol, triadime fon, triticonazole, cyazofamid, triflumizol, benomyl, carbendazim, thiabendazole, eth 10 aboxam, and hymexazole. Especially preferred are secondary mixtures containing fipronil as compound I and a fungicidal compound IIA selected from the list comprising strobilurins: azoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, picoxystrobin, and 15 trifloxystrobin; Especially preferred are secondary mixtures containing fipronil as compound I and a fungicidal compound IIA selected from the list comprising carboxamides: carboxin, benalaxyl, fenhexamid, flutolanil, furametpyr, metalaxyl, mefenoxam (metalaxyl-M), 20 ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil, fluopicolide (pico benzamid), and diclocymet. Especially preferred are secondary mixtures containing fipronil as compound I and a fungicidal compound IIA selected from the list comprising heterocylic compounds: 25 pyrimethanil, fenpiclonil, fludioxonil, iprodione, procymidone, famoxadone, fenamidone, octhilinone, probenazole, diclomezine, pyroquilon, proquinazid, tricyclazole, captafol, captan, da zomet, fenoxanil, and quinoxyfen. 30 Especially preferred are secondary mixtures containing fipronil as compound I and a fungicidal compound IIA selected from the list comprising carbamates: propineb diethofencarb, iprovalicarb, propamocarb, and methyl 3-(4-chlorophenyl)-3-(2 isopropoxycarbonylamino-3-methylbutyrylamino)propanoate. 35 Especially preferred are secondary mixtures containing fipronil as compound I and a fungicidal compound IIA selected from the carboxamides as defined at the outset, pref ereably the carboxamides, more preferably N-(2'-fluoro-4'-chloro-5'-methylhbiphenyl-2 yl)-1 -methyl-3-trifluoro'methyl-1 H-pyrazole-4 carboxamide, N-(3',4',5'-trifluorobiphenyl 2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3',4',5' 40 trifluorobiphenyl-2-yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, N (2',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, 19 N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide, N-(3' ,4' -dichloro-4-fluorobiphenyl-2-yl)-3-difluoro-methyl-1-methyl pyrazole-4-carboxamide, N-(3' ,4' -dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl 1-methylpyrazole-4-carboxamide, N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5 5 fluoro-1 H-pyrazole-4-carboxylic acid amide, N-(cis-2-bicyclopropyl-2-yl-phenyl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, N-(trans-2-bicyclopropyl 2-yl-phenyl)-3-d ifl uoro-methyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, 3 (difluoromethyl)-1 -methyl-N-[ 1,2,3,4-tetrahyd ro-9-(1 -methylethyl)-1,4 methanonaphthalen-5-yl]-1 H-pyrazole-4carboxamide. 10 Especially preferred are secondary mixtures containing fipronil as compound I and a fungicidal compound IIA selected from the list comprising: guazatine; streptomycin, validamycin A; binapacryl, dinocap, dinobuton; dithianon, isoprothiolane; fentin salts, such as fentin-acetate; edifenphos, iprobenfos, fosetyl, pyrazophos, chlorothalonil, di 15 chlofluanid, flusulfamide, phthalide, quintozene, thiophanate-methyl, tolylfluanid; cop per acetate, copper hydroxide, copper oxychloride, sulfur; cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, metrafenone and spiroxamine. Also especially preferred are secondary mixtures containing fipronil as compound I and 20 a fungicidal compound IIA selected from the list comprising prothioconazole, difeno conazole, flutriafol, triadimenol, fludioxonil, mefenoxam, metalaxyl, azoxystronbin, tri floxystrobin. Also especially preferred are tertiary mixtures containing fipronil as compound I and a 25 fungicidal compound IIA and fungicdal compound IB selected from the list comprising triticonazole, tebuconazole, cyproconazole, prochloraz or thiram. Also especially preferred are quarternary mixtures containing fipronil as compound I and a fungicidal compound IIA, fungicdal compound IB and fungicidal compound lID, 30 wherein compound lID is pyraclostrobin. In addition, with respect to their intended use, the following secondary mixtures are also especially preferred, wherein said mixtures contain fipronil as compound I and a fungicidal compound IIC selected from the group consisting of cyproconazole, epoxi 35 conazole, hexaconazole, metcona'zole, propiconazole, tebu-con-azole, imazalil, pro chloraz, dimethomorph, aldimorph, dodemorph, fenpropi-morph, tridemorph, man cozeb, maneb, metam, metiram, ferbam, thiram, zineb, ziram and basic copper sulfate. Especially preferred are tertiary mixtures containing fipronil as compound I, fungicidal 40 compound IIA, fungicidal compound IB and pyraclostrobin.

20 With respect to their intended use, the secondary, tertiary and quaternary mixtures of compound I, compound IIA (or compound IIC) and compounds 1lB1 and compound 11D2 listed in the tables below are especially preferred. If compound IIA is identical with compound IIB1 or 1ID2, the respective secondary (instead of tertiary) or tertiary mixture 5 (instead of quarternay) is disclosed. Table 1 Mixtures wherein compound I is fipronil, compound IIA is trifloxystrobin, and the combi nation of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. 10 Table 2 Mixtures wherein compound I is fipronil, compound IIA is azoxystrobin, and the combi nation of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. 15 Table 3 Mixtures wherein compound I is fipronil, compound IIA is boscalid, and the combination of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. Table 4 20 Mixtures wherein compound I is fipronil, compound IIA is metalaxyl, and the combina tion of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. Table 5 Mixtures wherein compound I is fipronil, compound IIA is metalaxyl-M, and the combi 25 nation of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. Table 6 Mixtures wherein compound I is fipronil, compound IIC is cyproconazole, and the com bination of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. 30 Table 7 Mixtures wherein compound I is fipronil, compound IIC is epoxiconazole, and the com bination of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. 35 Table 8 Mixtures wherein compound I is fipronil, compound IIA is fenbuconazole, and the com bination of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. 40 21 Table 9 Mixtures wherein compound I is fipronil, compound IIA is fluquinconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 10 Mixtures wherein compound I is fipronil, compound IIA is flutriafol, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 10 Table 11 Mixtures wherein compound I is fipronil, compound IIA is ipconazole, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 12 15 Mixtures wherein compound I is fipronil, compound IIC is metconazole, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 13 Mixtures wherein compound I is fipronil, compound IIC is propiconazole, and the com 20 bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 14 Mixtures wherein compound I is fipronil, compound IIC is tebuconazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 25 Table 15 Mixtures wherein compound I is fipronil, compound IIA is triadimenol, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. => tritconazole is not in compound IIA listing 30 Table 16 Mixtures wherein compound I is fipronil, compound IIA is imazalil, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 35 Table 17 Mixtures wherein compound I is fipronil, compound IIC is prochloraz, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 18 40 Mixtures wherein compound I is fipronil, compound IIA is carbendazim, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q.

22 Table 19 Mixtures wherein compound I is fipronil, compound IIA is thiabendazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 20 Mixtures wherein compound I is fipronil, compound IIA is ethaboxam, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 21 10 Mixtures wherein compound I is fipronil, compound IIA is hymexazole, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 22 Mixtures wherein compound I is fipronil, compound IIA is pyrimethanil, and the combi 15 nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 23 Mixtures wherein compound I is fipronil, compound IIA is fludioxonil, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 20 Table 24 Mixtures wherein compound I is fipronil, compound IIC is aldimorph, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 25 Table 25 Mixtures wherein compound I is fipronil, compound IIC is dodemorph, and the combi nation of compounds IIB1 and IID2 in each case corresponds to a row of Table Q. Table 26 30 Mixtures wherein compound I is fipronil, compound IIC is fenpropimorph, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 27 Mixtures wherein compound I is fipronil, compound IIA is iprodione, and the combina 35 tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 28 Mixtures wherein compound I is fipronil, compound IIA is captan, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 40 23 Table 29 Mixtures wherein compound I is fipronil, compound IIA is fenoxanil, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 30 Mixtures wherein compound I is fipronil, compound IIA is probenazole, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 31 10 Mixtures wherein compound I is fipronil, compound IIC is mancozeb, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 32 Mixtures wherein compound I is fipronil, compound IIC is metiram, and the combination 15 of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 33 Mixtures wherein compound I is fipronil, compound IIC is thiram, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 20 Table 34 Mixtures wherein compound I is fipronil, compound IIC is ziram, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 25 Table 35 Mixtures wherein compound I is fipronil, compound IIA is guazatin, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 36 30 Mixtures wherein compound I is fipronil, compound IIA is thiophanate-methyl, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 37 35 Mixtures wherein compound I is fipronil, compound IIA is chlorothalonil, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 38 Mixtures wherein compound I is fipronil, compound IIA is metrafenone, and the combi 40 nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q.

24 Table 39 Mixtures wherein compound I is fipronil, compound IIA is difenoconazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 40 Mixtures wherein compound I is fipronil, compound IIA is N-(2'-fluoro-4'-chloro-5' methylhbiphenyl-2-yl)-1 -methyl-3-trifluoro'methyl-1 H-pyrazole-4 carboxamide and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 10 Table 41 Mixtures wherein compound I is fipronil, compound IIA is N-(3',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 15 Table 42 Mixtures wherein compound I is fipronil, compound IIA is N-(3',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 20 Table 43 Mixtures wherein compound I is fipronil, compound IIA is N-(2',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 25 Table 44 Mixtures wherein compound I is fipronil, compound IIA is N-(3',4',5'-trifluorobiphenyl-2 yl)-3-chlorofluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 30 Table 45 Mixtures wherein compound I is fipronil, compound IIA is N-(3',4'-dichloro-4 fluorobiphenyl-2-yl)-3-difluoro-methyl-1-methyl-pyrazole-4-carboxamide, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 35 Table 46 Mixtures wherein compound I is fipronil, compound IIA is N-(3',4'-dichloro 5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 40 25 Table 47 Mixtures wherein compound I is fipronil, compound IIA is N-(2-(1,3-dimethylbutyl) phenyl)-1,3-dimethyl-5-fluoro-1 H-pyrazole-4-carboxylic acid amide, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 48 Mixtures wherein compound I is fipronil, compound IIA is N-(cis-2-bicyclopropyl-2-yl phenyl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 10 Table 49 Mixtures wherein compound I is fipronil, compound IIA is N-(trans-2-bicyclopropyl-2-yl phenyl)-3-difluoro-methyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, and the com bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 15 Table 50 Mixtures wherein compound I is fipronil, compound IIA is 3-(difluoromethyl)-1-methyl-N [1,2,3,4-tetrahydro-9-(1 -methylethyl)-1,4-methanonaphthalen-5-yl]-1 H-pyrazole-4 carboxamide, and the combination of compounds llB1 and 1ID2 in each case corre 20 sponds to a row of Table Q. Table 51 Mixtures wherein compound I is ethiprole, compound IIA is trifloxystrobin, and the combination of compounds llB1 and 1ID2 in each case corresponds to a row of Table 25 Q. Table 52 Mixtures wherein compound I is ethiprole, compound IIA is azoxystrobin, and the com bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 30 Table 53 Mixtures wherein compound I is ethiprole, compound IIA is boscalid, and the combina tion of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 35 Table 54 Mixtures wherein compound I is ethiprole, compound IIA is metalaxyl, and the combi nation of compounds IlB1 and IID2 in each case corresponds to a row of Table Q. Table 55 40 Mixtures wherein compound I is ethiprole, compound IIA is metalaxyl-M, and the com bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q.

26 Table 56 Mixtures wherein compound I is ethiprole, compound IIC is cyproconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table 5 Q. Table 57 Mixtures wherein compound I is ethiprole, compound IIC is epoxiconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table 10 Q. Table 58 Mixtures wherein compound I is ethiprole, compound IIA is fenbuconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table 15 Q. Table 59 Mixtures wherein compound I is ethiprole, compound IIA is fluquinconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table 20 Q. Table 60 Mixtures wherein compound I is ethiprole, compound IIA is flutriafol, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 25 Table 61 Mixtures wherein compound I is ethiprole, compound IIA is ipconazole, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 30 Table 62 Mixtures wherein compound I is ethiprole, compound IIC is metconazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 63 35 Mixtures wherein compound I is ethiprole, compound IIC is propiconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 40 27 Table 64 Mixtures wherein compound I is ethiprole, compound II is prothioconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 65 Mixtures wherein compound I is ethiprole, compound IIC is tebuconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 10 Table 66 Mixtures wherein compound I is ethiprole, compound IIA is triadimenol, and the combi nation of compounds IIB1 and IID2 in each case corresponds to a row of Table Q. 15 Table 67 Mixtures wherein compound I is ethiprole, compound IIC is imazalil, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 68 20 Mixtures wherein compound I is ethiprole, compound IIC is prochloraz, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 69 Mixtures wherein compound I is ethiprole, compound IIA is carbendazim, and the com 25 bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 70 Mixtures wherein compound I is ethiprole, compound IIA is thiabendazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table 30 Q. Table 71 Mixtures wherein compound I is ethiprole, compound IIA is ethaboxam, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 35 Table 72 Mixtures wherein compound I is ethiprole, compound IIA is hymexazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 40 28 Table 73 Mixtures wherein compound I is ethiprole, compound IIA is pyrimethanil, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 74 Mixtures wherein compound I is ethiprole, compound IIA is fludioxonil, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 75 10 Mixtures wherein compound I is ethiprole, compound IIC is aldimorph, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 76 Mixtures wherein compound I is ethiprole, compound IIC is dodemorph, and the com 15 bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 77 Mixtures wherein compound I is ethiprole, compound IIC is fenpropimorph, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table 20 Q. Table 78 Mixtures wherein compound I is ethiprole, compound IIA is iprodione, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 25 Table 79 Mixtures wherein compound I is ethiprole, compound IIA is captan, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 30 Table 80 Mixtures wherein compound I is ethiprole, compound IIA is fenoxanil, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 81 35 Mixtures wherein compound I is ethiprole, compound IIA is probenazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 82 Mixtures wherein compound I is ethiprole, compound IIC is mancozeb, and the combi 40 nation of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q.

29 Table 83 Mixtures wherein compound I is ethiprole, compound IIC is metiram, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 84 Mixtures wherein compound I is ethiprole, compound IIC is thiram, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 85 10 Mixtures wherein compound I is ethiprole, compound IIC is ziram, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 86 Mixtures wherein compound I is ethiprole, compound IIA is guazatin, and the combina 15 tion of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 87 Mixtures wherein compound I is ethiprole, compound IIA is thiophanate-methyl, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table 20 Q. Table 88 Mixtures wherein compound I is ethiprole, compound IIA is chlorothalonil, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table 25 Q. Table 89 Mixtures wherein compound I is ethiprole, compound IIA is metrafenone, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 30 Table 90 Mixtures wherein compound I is ethiprole, compound IIA is difenoconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 35 Table 91 Mixtures wherein compound I is fipronil, compound IIA is N-(3',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 40 30 Table 92 Mixtures wherein compound I is fipronil, compound IIA is N-(3',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. 5 Table 93 Mixtures wherein compound I is fipronil, compound IIA is N-(2',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 10 Table 94 Mixtures wherein compound I is ethiprole, compound IIA is N-(3',4',5'-trifluorobiphenyl 2-yl)-3-chlorofluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide, and the combination of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 15 Table 95 Mixtures wherein compound I is ethiprole, compound IIA is N-(3',4'-dichloro-4 fluorobiphenyl-2-yl)-3-difluoro-methyl-1-methyl-pyrazole-4-carboxamide, and the com bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 20 Table 96 Mixtures wherein compound I is ethiprole, compound IIA is N-(3',4'-dichloro 5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide, and the com bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 25 Table 97 Mixtures wherein compound I is ethiprole, compound IIA is N-(2-(1,3-dimethylbutyl) phenyl)-1,3-dimethyl-5-fluoro-1 H-pyrazole-4-carboxylic acid amide, and the combina tion of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 30 Table 98 Mixtures wherein compound I is ethiprole, compound IIA is N-(cis-2-bicyclopropyl-2-yl phenyl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, and the com bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table Q. 35 Table 99 Mixtures wherein compound I is ethiprole, compound IIA is N-(trans-2-bicyclopropyl-2 yl-phenyl)-3-d ifl uoro-methyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, and the combination of compounds llB1 and 1ID2 in each case corresponds to a row of Table 40 Q.

31 Table 100 Mixtures wherein compound I is ethiprole, compound IIA is 3-(difluoromethyl)-1-methyl N-[1,2,3,4-tetrahydro-9-(1 -methylethyl)-1,4-methanonaphthalen-5-yl]-1 H-pyrazole 4carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corre 5 sponds to a row of Table Q. Table Q Mixture No. Compound IIB1 Compound IID2 M-1 trifloxystrobin M-2 trifloxystrobin orysatrobin M-3 trifloxystrobin azoxystrobin M-4 trifloxystrobin difenoconazole M-5 trifloxystrobin boscalid M-6 trifloxystrobin metalaxyl M-7 trifloxystrobin cyproconazole M-8 trifloxystrobin epoxiconazole M-9 trifloxystrobin fenbuconazole M-1 0 trifloxystrobin fluquinconazole M-1 1 trifloxystrobin flutriafol M-12 trifloxystrobin ipconazole M-1 3 trifloxystrobin metconazole M-14 trifloxystrobin propiconazole M-1 5 trifloxystrobin prothioconazole M-1 6 trifloxystrobin tebuconazole M-17 trifloxystrobin triadimenol M-1 8 trifloxystrobin triticonazole M-19 trifloxystrobin imazalil M-20 trifloxystrobin prochloraz M-21 trifloxystrobin carbendazim M-22 trifloxystrobin thiabendazole M-23 trifloxystrobin ethaboxam M-24 trifloxystrobin hymexazole M-25 trifloxystrobin pyrimethanil M-26 trifloxystrobin fludioxonil M-27 trifloxystrobin aldimorph M-28 trifloxystrobin dodemorph M-29 trifloxystrobin fenpropimorph M-30 trifloxystrobin iprodione M-31 trifloxystrobin captan M-32 trifloxystrobin fenoxanil 32 Mixture No. Compound IIB1 Compound 1ID2 M-33 trifloxystrobin probenazol M-34 trifloxystrobin mancozeb M-35 trifloxystrobin metiram M-36 trifloxystrobin thiram M-37 trifloxystrobin ziram M-38 trifloxystrobin guazatin M-39 trifloxystrobin thiophanate-methyl M-40 trifloxystrobin chlorothalonil M-41 trifloxystrobin metrafenone M-42 trifloxystrobin pyraclostrobin M-43 orysastrobin M-44 orysastrobin azoxystrobin M-45 orysastrobin difenoconazole M-46 orysastrobin boscalid M-47 orysastrobin metalaxyl M-48 orysastrobin cyproconazole M-49 orysastrobin epoxiconazole M-50 orysastrobin fenbuconazole M-51 orysastrobin fluquinconazole M-52 orysastrobin flutriafol M-53 orysastrobin ipconazole M-54 orysastrobin metconazole M-55 orysastrobin propiconazole M-56 orysastrobin prothioconazole M-57 orysastrobin tebuconazole M-58 orysastrobin triadimenol M-59 orysastrobin triticonazole M-60 orysastrobin imazalil M-61 orysastrobin prochloraz M-62 orysastrobin carbendazim M-63 orysastrobin thiabendazole M-64 orysastrobin ethaboxam M-65 orysastrobin hymexazole M-66 orysastrobin pyrimethanil M-67 orysastrobin fludioxonil M-68 orysastrobin aldimorph M-69 orysastrobin dodemorph M-70 orysastrobin fenpropimorph 33 Mixture No. Compound IIB1 Compound 1ID2 M-71 orysastrobin iprodione M-72 orysastrobin captan M-73 orysastrobin fenoxanil M-74 orysastrobin probenazol M-75 orysastrobin mancozeb M-76 orysastrobin metiram M-77 orysastrobin thiram M-78 orysastrobin ziram M-79 orysastrobin guazatin M-80 orysastrobin thiophanate-methyl M-81 orysastrobin chlorothalonil M-82 orysastrobin metrafenone M-83 orysastrobin pyraclostrobin M-84 azoxystrobin M-85 azoxystrobin difenoconazole M-86 azoxystrobin boscalid M-87 azoxystrobin metalaxyl M-88 azoxystrobin cyproconazole M-89 azoxystrobin epoxiconazole M-90 azoxystrobin fenbuconazole M-91 azoxystrobin fluquinconazole M-92 azoxystrobin flutriafol M-93 azoxystrobin ipconazole M-94 azoxystrobin metconazole M-95 azoxystrobin propiconazole M-96 azoxystrobin prothioconazole M-97 azoxystrobin tebuconazole M-98 azoxystrobin triadimenol M-99 azoxystrobin triticonazole M-100 azoxystrobin imazalil M-101 azoxystrobin prochloraz M-102 azoxystrobin carbendazim M-103 azoxystrobin thiabendazole M-1 04 azoxystrobin ethaboxam M-1 05 azoxystrobin hymexazole M-106 azoxystrobin pyrimethanil M-107 azoxystrobin fludioxonil M-108 azoxystrobin aldimorph 34 Mixture No. Compound IIB1 Compound 1ID2 M-109 azoxystrobin dodemorph M-1 10 azoxystrobin fenpropimorph M-1 11 azoxystrobin iprodione M-1 12 azoxystrobin captan M-113 azoxystrobin fenoxanil M-1 14 azoxystrobin probenazol M-1 15 azoxystrobin mancozeb M-1 16 azoxystrobin metiram M-1 17 azoxystrobin thiram M-1 18 azoxystrobin ziram M-1 19 azoxystrobin guazatin M-120 azoxystrobin thiophanate-methyl M-121 azoxystrobin chlorothalonil M-122 azoxystrobin metrafenone M-123 azoxystrobin pyraclostrobin M-124 difenoconazole M-125 difenoconazole boscalid M-126 difenoconazole metalaxyl M-127 difenoconazole cyproconazole M-128 difenoconazole epoxiconazole M-129 difenoconazole fenbuconazole M-1 30 difenoconazole fluquinconazole M-131 difenoconazole flutriafol M-1 32 difenoconazole ipconazole M-133 difenoconazole metconazole M-1 34 difenoconazole propiconazole M-1 35 difenoconazole prothioconazole M-136 difenoconazole tebuconazole M-137 difenoconazole triadimenol M-1 38 difenoconazole triticonazole M-139 difenoconazole imazalil M-140 difenoconazole prochloraz M-141 difenoconazole carbendazim M-142 difenoconazole thiabendazole M-143 difenoconazole ethaboxam M-144 difenoconazole hymexazole M-145 difenoconazole pyrimethanil M-146 difenoconazole fludioxonil 35 Mixture No. Compound IIB1 Compound 1ID2 M-147 difenoconazole aldimorph M-148 difenoconazole dodemorph M-149 difenoconazole fenpropimorph M-150 difenoconazole iprodione M-151 difenoconazole captan M-152 difenoconazole fenoxanil M-153 difenoconazole probenazol M-154 difenoconazole mancozeb M-155 difenoconazole metiram M-156 difenoconazole thiram M-157 difenoconazole ziram M-1 58 difenoconazole guazatin M-1 59 difenoconazole thiophanate-methyl M-1 60 difenoconazole chlorothalonil M-161 difenoconazole metrafenone M-1 62 difenoconazole pyraclostrobin M-163 boscalid M-164 boscalid metalaxyl M-165 boscalid cyproconazole M-166 boscalid epoxiconazole M-167 boscalid fenbuconazole M-168 boscalid fluquinconazole M-169 boscalid flutriafol M-170 boscalid ipconazole M-171 boscalid metconazole M-172 boscalid propiconazole M-173 boscalid prothioconazole M-174 boscalid tebuconazole M-175 boscalid triadimenol M-176 boscalid triticonazole M-177 boscalid imazalil M-178 boscalid prochloraz M-179 boscalid carbendazim M-180 boscalid thiabendazole M-181 boscalid ethaboxam M-182 boscalid hymexazole M-183 boscalid pyrimethanil M-184 boscalid fludioxonil 36 Mixture No. Compound IIB1 Compound 1ID2 M-185 boscalid aldimorph M-186 boscalid dodemorph M-187 boscalid fenpropimorph M-188 boscalid iprodione M-189 boscalid captan M-190 boscalid fenoxanil M-191 boscalid probenazol M-192 boscalid mancozeb M-193 boscalid metiram M-194 boscalid thiram M-195 boscalid ziram M-196 boscalid guazatin M-197 boscalid thiophanate-methyl M-198 boscalid chlorothalonil M-199 boscalid metrafenone M-200 boscalid pyraclostrobin M-201 metalaxyl M-202 metalaxyl cyproconazole M-203 metalaxyl epoxiconazole M-204 metalaxyl fenbuconazole M-205 metalaxyl fluquinconazole M-206 metalaxyl flutriafol M-207 metalaxyl ipconazole M-208 metalaxyl metconazole M-209 metalaxyl propiconazole M-210 metalaxyl prothioconazole M-21 1 metalaxyl tebuconazole M-212 metalaxyl triadimenol M-213 metalaxyl triticonazole M-214 metalaxyl imazalil M-215 metalaxyl prochloraz M-216 metalaxyl carbendazim M-217 metalaxyl thiabendazole M-218 metalaxyl ethaboxam M-219 metalaxyl hymexazole M-220 metalaxyl pyrimethanil M-221 metalaxyl fludioxonil M-222 metalaxyl aldimorph 37 Mixture No. Compound IIB1 Compound 1ID2 M-223 metalaxyl dodemorph M-224 metalaxyl fenpropimorph M-225 metalaxyl iprodione M-226 metalaxyl captan M-227 metalaxyl fenoxanil M-228 metalaxyl probenazol M-229 metalaxyl mancozeb M-230 metalaxyl metiram M-231 metalaxyl thiram M-232 metalaxyl ziram M-233 metalaxyl guazatin M-234 metalaxyl thiophanate-methyl M-235 metalaxyl chlorothalonil M-236 metalaxyl metrafenone M-237 metalaxyl pyraclostrobin M-238 cyproconazole M-239 cyproconazole epoxiconazole M-240 cyproconazole fenbuconazole M-241 cyproconazole fluquinconazole M-242 cyproconazole flutriafol M-243 cyproconazole ipconazole M-244 cyproconazole metconazole M-245 cyproconazole propiconazole M-246 cyproconazole prothioconazole M-247 cyproconazole tebuconazole M-248 cyproconazole triadimenol M-249 cyproconazole triticonazole M-250 cyproconazole imazalil M-251 cyproconazole prochloraz M-252 cyproconazole carbendazim M-253 cyproconazole thiabendazole M-254 cyproconazole ethaboxam M-255 cyproconazole hymexazole M-256 cyproconazole pyrimethanil M-257 cyproconazole fludioxonil M-258 cyproconazole aldimorph M-259 cyproconazole dodemorph M-260 cyproconazole fenpropimorph 38 Mixture No. Compound IIB1 Compound 1ID2 M-261 cyproconazole iprodione M-262 cyproconazole captan M-263 cyproconazole fenoxanil M-264 cyproconazole probenazol M-265 cyproconazole mancozeb M-266 cyproconazole metiram M-267 cyproconazole thiram M-268 cyproconazole ziram M-269 cyproconazole guazatin M-270 cyproconazole thiophanate-methyl M-271 cyproconazole chlorothalonil M-272 cyproconazole metrafenone M-273 cyproconazole pyraclostrobin M-274 epoxiconazole M-275 epoxiconazole fenbuconazole M-276 epoxiconazole fluquinconazole M-277 epoxiconazole flutriafol M-278 epoxiconazole ipconazole M-279 epoxiconazole metconazole M-280 epoxiconazole propiconazole M-281 epoxiconazole prothioconazole M-282 epoxiconazole tebuconazole M-283 epoxiconazole triadimenol M-284 epoxiconazole triticonazole M-285 epoxiconazole imazalil M-286 epoxiconazole prochloraz M-287 epoxiconazole carbendazim M-288 epoxiconazole thiabendazole M-289 epoxiconazole ethaboxam M-290 epoxiconazole hymexazole M-291 epoxiconazole pyrimethanil M-292 epoxiconazole fludioxonil M-293 epoxiconazole aldimorph M-294 epoxiconazole dodemorph M-295 epoxiconazole fenpropimorph M-296 epoxiconazole iprodione M-297 epoxiconazole captan M-298 epoxiconazole fenoxanil 39 Mixture No. Compound IIB1 Compound 1ID2 M-299 epoxiconazole probenazol M-300 epoxiconazole mancozeb M-301 epoxiconazole metiram M-302 epoxiconazole thiram M-303 epoxiconazole ziram M-304 epoxiconazole guazatin M-305 epoxiconazole thiophanate-methyl M-306 epoxiconazole chlorothalonil M-307 epoxiconazole metrafenone M-308 epoxiconazole pyraclostrobin M-309 fenbuconazole M-31 0 fenbuconazole fluquinconazole M-31 1 fenbuconazole flutriafol M-312 fenbuconazole ipconazole M-313 fenbuconazole metconazole M-314 fenbuconazole propiconazole M-315 fenbuconazole prothioconazole M-316 fenbuconazole tebuconazole M-317 fenbuconazole triadimenol M-318 fenbuconazole triticonazole M-319 fenbuconazole imazalil M-320 fenbuconazole prochloraz M-321 fenbuconazole carbendazim M-322 fenbuconazole thiabendazole M-323 fenbuconazole ethaboxam M-324 fenbuconazole hymexazole M-325 fenbuconazole pyrimethanil M-326 fenbuconazole fludioxonil M-327 fenbuconazole aldimorph M-328 fenbuconazole dodemorph M-329 fenbuconazole fenpropimorph M-330 fenbuconazole iprodione M-331 fenbuconazole captan M-332 fenbuconazole fenoxanil M-333 fenbuconazole probenazol M-334 fenbuconazole mancozeb M-335 fenbuconazole metiram M-336 fenbuconazole thiram 40 Mixture No. Compound IIB1 Compound 1ID2 M-337 fenbuconazole ziram M-338 fenbuconazole guazatin M-339 fenbuconazole thiophanate-methyl M-340 fenbuconazole chlorothalonil M-341 fenbuconazole metrafenone M-342 fenbuconazole pyraclostrobin M-343 fluquinconazole M-344 fluquinconazole flutriafol M-345 fluquinconazole ipconazole M-346 fluquinconazole metconazole M-347 fluquinconazole propiconazole M-348 fluquinconazole prothioconazole M-349 fluquinconazole tebuconazole M-350 fluquinconazole triadimenol M-351 fluquinconazole triticonazole M-352 fluquinconazole imazalil M-353 fluquinconazole prochloraz M-354 fluquinconazole carbendazim M-355 fluquinconazole thiabendazole M-356 fluquinconazole ethaboxam M-357 fluquinconazole hymexazole M-358 fluquinconazole pyrimethanil M-359 fluquinconazole fludioxonil M-360 fluquinconazole aldimorph M-361 fluquinconazole dodemorph M-362 fluquinconazole fenpropimorph M-363 fluquinconazole iprodione M-364 fluquinconazole captan M-365 fluquinconazole fenoxanil M-366 fluquinconazole probenazol M-367 fluquinconazole mancozeb M-368 fluquinconazole metiram M-369 fluquinconazole thiram M-370 fluquinconazole ziram M-371 fluquinconazole guazatin M-372 fluquinconazole thiophanate-methyl M-373 fluquinconazole chlorothalonil M-374 fluquinconazole metrafenone 41 Mixture No. Compound IIB1 Compound 1ID2 M-375 fluquinconazole pyraclostrobin M-376 flutriafol M-377 flutriafol ipconazole M-378 flutriafol metconazole M-379 flutriafol propiconazole M-380 flutriafol prothioconazole M-381 flutriafol tebuconazole M-382 flutriafol triadimenol M-383 flutriafol triticonazole M-384 flutriafol imazalil M-385 flutriafol prochloraz M-386 flutriafol carbendazim M-387 flutriafol thiabendazole M-388 flutriafol ethaboxam M-389 flutriafol hymexazole M-390 flutriafol pyrimethanil M-391 flutriafol fludioxonil M-392 flutriafol aldimorph M-393 flutriafol dodemorph M-394 flutriafol fenpropimorph M-395 flutriafol iprodione M-396 flutriafol captan M-397 flutriafol fenoxanil M-398 flutriafol probenazol M-399 flutriafol mancozeb M-400 flutriafol metiram M-401 flutriafol thiram M-402 flutriafol ziram M-403 flutriafol guazatin M-404 flutriafol thiophanate-methyl M-405 flutriafol chlorothalonil M-406 flutriafol metrafenone M-407 flutriafol pyraclostrobin M-408 ipconazole M-409 ipconazole metconazole M-410 ipconazole propiconazole M-41 1 ipconazole prothioconazole M-412 ipconazole tebuconazole 42 Mixture No. Compound IIB1 Compound 1ID2 M-413 ipconazole triadimenol M-414 ipconazole triticonazole M-415 ipconazole imazalil M-416 ipconazole prochloraz M-417 ipconazole carbendazim M-418 ipconazole thiabendazole M-419 ipconazole ethaboxam M-420 ipconazole hymexazole M-421 ipconazole pyrimethanil M-422 ipconazole fludioxonil M-423 ipconazole aldimorph M-424 ipconazole dodemorph M-425 ipconazole fenpropimorph M-426 ipconazole iprodione M-427 ipconazole captan M-428 ipconazole fenoxanil M-429 ipconazole probenazol M-430 ipconazole mancozeb M-431 ipconazole metiram M-432 ipconazole thiram M-433 ipconazole ziram M-434 ipconazole guazatin M-435 ipconazole thiophanate-methyl M-436 ipconazole chlorothalonil M-437 ipconazole metrafenone M-438 ipconazole pyraclostrobin M-439 metconazole M-440 metconazole propiconazole M-441 metconazole prothioconazole M-442 metconazole tebuconazole M-443 metconazole triadimenol M-444 metconazole triticonazole M-445 metconazole imazalil M-446 metconazole prochloraz M-447 metconazole carbendazim M-448 metconazole thiabendazole M-449 metconazole ethaboxam M-450 metconazole hymexazole 43 Mixture No. Compound IIB1 Compound 1ID2 M-451 metconazole pyrimethanil M-452 metconazole fludioxonil M-453 metconazole aldimorph M-454 metconazole dodemorph M-455 metconazole fenpropimorph M-456 metconazole iprodione M-457 metconazole captan M-458 metconazole fenoxanil M-459 metconazole probenazol M-460 metconazole mancozeb M-461 metconazole metiram M-462 metconazole thiram M-463 metconazole ziram M-464 metconazole guazatin M-465 metconazole thiophanate-methyl M-466 metconazole chlorothalonil M-467 metconazole metrafenone M-468 metconazole pyraclostrobin M-469 propiconazole M-470 propiconazole prothioconazole M-471 propiconazole tebuconazole M-472 propiconazole triadimenol M-473 propiconazole triticonazole M-474 propiconazole imazalil M-475 propiconazole prochloraz M-476 propiconazole carbendazim M-477 propiconazole thiabendazole M-478 propiconazole ethaboxam M-479 propiconazole hymexazole M-480 propiconazole pyrimethanil M-481 propiconazole fludioxonil M-482 propiconazole aldimorph M-483 propiconazole dodemorph M-484 propiconazole fenpropimorph M-485 propiconazole iprodione M-486 propiconazole captan M-487 propiconazole fenoxanil M-488 propiconazole probenazol 44 Mixture No. Compound IIB1 Compound 1ID2 M-489 propiconazole mancozeb M-490 propiconazole metiram M-491 propiconazole thiram M-492 propiconazole ziram M-493 propiconazole guazatin M-494 propiconazole thiophanate-methyl M-495 propiconazole chlorothalonil M-496 propiconazole metrafenone M-497 propiconazole pyraclostrobin M-498 prothioconazole M-499 prothioconazole tebuconazole M-500 prothioconazole triadimenol M-501 prothioconazole triticonazole M-502 prothioconazole imazalil M-503 prothioconazole prochloraz M-504 prothioconazole carbendazim M-505 prothioconazole thiabendazole M-506 prothioconazole ethaboxam M-507 prothioconazole hymexazole M-508 prothioconazole pyrimethanil M-509 prothioconazole fludioxonil M-510 prothioconazole aldimorph M-51 1 prothioconazole dodemorph M-512 prothioconazole fenpropimorph M-513 prothioconazole iprodione M-514 prothioconazole captan M-515 prothioconazole fenoxanil M-516 prothioconazole probenazol M-517 prothioconazole mancozeb M-518 prothioconazole metiram M-519 prothioconazole thiram M-520 prothioconazole ziram M-521 prothioconazole guazatin M-522 prothioconazole thiophanate-methyl M-523 prothioconazole chlorothalonil M-524 prothioconazole metrafenone M-525 prothioconazole pyraclostrobin M-526 tebuconazole 45 Mixture No. Compound IIB1 Compound 1ID2 M-527 tebuconazole triadimenol M-528 tebuconazole triticonazole M-529 tebuconazole imazalil M-530 tebuconazole prochloraz M-531 tebuconazole carbendazim M-532 tebuconazole thiabendazole M-533 tebuconazole ethaboxam M-534 tebuconazole hymexazole M-535 tebuconazole pyrimethanil M-536 tebuconazole fludioxonil M-537 tebuconazole aldimorph M-538 tebuconazole dodemorph M-539 tebuconazole fenpropimorph M-540 tebuconazole iprodione M-541 tebuconazole captan M-542 tebuconazole fenoxanil M-543 tebuconazole probenazol M-544 tebuconazole mancozeb M-545 tebuconazole metiram M-546 tebuconazole thiram M-547 tebuconazole ziram M-548 tebuconazole guazatin M-549 tebuconazole thiophanate-methyl M-550 tebuconazole chlorothalonil M-551 tebuconazole metrafenone M-552 tebuconazole pyraclostrobin M-553 triadimenol M-554 triadimenol triticonazole M-555 triadimenol imazalil M-556 triadimenol prochloraz M-557 triadimenol carbendazim M-558 triadimenol thiabendazole M-559 triadimenol ethaboxam M-560 triadimenol hymexazole M-561 triadimenol pyrimethanil M-562 triadimenol fludioxonil M-563 triadimenol aldimorph M-564 triadimenol dodemorph 46 Mixture No. Compound IIB1 Compound 1ID2 M-565 triadimenol fenpropimorph M-566 triadimenol iprodione M-567 triadimenol captan M-568 triadimenol fenoxanil M-569 triadimenol probenazol M-570 triadimenol mancozeb M-571 triadimenol metiram M-572 triadimenol thiram M-573 triadimenol ziram M-574 triadimenol guazatin M-575 triadimenol thiophanate-methyl M-576 triadimenol chlorothalonil M-577 triadimenol metrafenone M-578 triadimenol pyraclostrobin M-579 triticonazole M-580 triticonazole imazalil M-581 triticonazole prochloraz M-582 triticonazole carbendazim M-583 triticonazole thiabendazole M-584 triticonazole ethaboxam M-585 triticonazole hymexazole M-586 triticonazole pyrimethanil M-587 triticonazole fludioxonil M-588 triticonazole aldimorph M-589 triticonazole dodemorph M-590 triticonazole fenpropimorph M-591 triticonazole iprodione M-592 triticonazole captan M-593 triticonazole fenoxanil M-594 triticonazole probenazol M-595 triticonazole mancozeb M-596 triticonazole metiram M-597 triticonazole thiram M-598 triticonazole ziram M-599 triticonazole guazatin M-600 triticonazole thiophanate-methyl M-601 triticonazole chlorothalonil M-602 triticonazole metrafenone 47 Mixture No. Compound IIB1 Compound 1ID2 M-603 triticonazole pyraclostrobin M-604 imazalil M-605 imazalil prochloraz M-606 imazalil carbendazim M-607 imazalil thiabendazole M-608 imazalil ethaboxam M-609 imazalil hymexazole M-610 imazalil pyrimethanil M-611 imazalil fludioxonil M-612 imazalil aldimorph M-613 imazalil dodemorph M-614 imazalil fenpropimorph M-615 imazalil iprodione M-616 imazalil captan M-617 imazalil fenoxanil M-618 imazalil probenazol M-619 imazalil mancozeb M-620 imazalil metiram M-621 imazalil thiram M-622 imazalil ziram M-623 imazalil guazatin M-624 imazalil thiophanate-methyl M-625 imazalil chlorothalonil M-626 imazalil metrafenone M-627 imazalil pyraclostrobin M-628 prochloraz M-629 prochloraz carbendazim M-630 prochloraz thiabendazole M-631 prochloraz ethaboxam M-632 prochloraz hymexazole M-633 prochloraz pyrimethanil M-634 prochloraz fludioxonil M-635 prochloraz aldimorph M-636 prochloraz dodemorph M-637 prochloraz fenpropimorph M-638 prochloraz iprodione M-639 prochloraz captan M-640 prochloraz fenoxanil 48 Mixture No. Compound IIB1 Compound 1ID2 M-641 prochloraz probenazol M-642 prochloraz mancozeb M-643 prochloraz metiram M-644 prochloraz thiram M-645 prochloraz ziram M-646 prochloraz guazatin M-647 prochloraz thiophanate-methyl M-648 prochloraz chlorothalonil M-649 prochloraz metrafenone M-650 prochloraz pyraclostrobin M-651 carbendazim M-652 carbendazim thiabendazole M-653 carbendazim ethaboxam M-654 carbendazim hymexazole M-655 carbendazim pyrimethanil M-656 carbendazim fludioxonil M-657 carbendazim aldimorph M-658 carbendazim dodemorph M-659 carbendazim fenpropimorph M-660 carbendazim iprodione M-661 carbendazim captan M-662 carbendazim fenoxanil M-663 carbendazim probenazol M-664 carbendazim mancozeb M-665 carbendazim metiram M-666 carbendazim thiram M-667 carbendazim ziram M-668 carbendazim guazatin M-669 carbendazim thiophanate-methyl M-670 carbendazim chlorothalonil M-671 carbendazim metrafenone M-672 carbendazim pyraclostrobin M-673 thiabendazole M-674 thiabendazole ethaboxam M-675 thiabendazole hymexazole M-676 thiabendazole pyrimethanil M-677 thiabendazole fludioxonil M-678 thiabendazole aldimorph 49 Mixture No. Compound IIB1 Compound 1ID2 M-679 thiabendazole dodemorph M-680 thiabendazole fenpropimorph M-681 thiabendazole iprodione M-682 thiabendazole captan M-683 thiabendazole fenoxanil M-684 thiabendazole probenazol M-685 thiabendazole mancozeb M-686 thiabendazole metiram M-687 thiabendazole thiram M-688 thiabendazole ziram M-689 thiabendazole guazatin M-690 thiabendazole thiophanate-methyl M-691 thiabendazole chlorothalonil M-692 thiabendazole metrafenone M-693 thiabendazole pyraclostrobin M-694 ethaboxam M-695 ethaboxam hymexazole M-696 ethaboxam pyrimethanil M-697 ethaboxam fludioxonil M-698 ethaboxam aldimorph M-699 ethaboxam dodemorph M-700 ethaboxam fenpropimorph M-701 ethaboxam iprodione M-702 ethaboxam captan M-703 ethaboxam fenoxanil M-704 ethaboxam probenazol M-705 ethaboxam mancozeb M-706 ethaboxam metiram M-707 ethaboxam thiram M-708 ethaboxam ziram M-709 ethaboxam guazatin M-710 ethaboxam thiophanate-methyl M-71 1 ethaboxam chlorothalonil M-712 ethaboxam metrafenone M-713 ethaboxam pyraclostrobin M-714 hymexazole M-715 hymexazole pyrimethanil M-716 hymexazole fludioxonil 50 Mixture No. Compound IIB1 Compound 1ID2 M-717 hymexazole aldimorph M-718 hymexazole dodemorph M-719 hymexazole fenpropimorph M-720 hymexazole iprodione M-721 hymexazole captan M-722 hymexazole fenoxanil M-723 hymexazole probenazol M-724 hymexazole mancozeb M-725 hymexazole metiram M-726 hymexazole thiram M-727 hymexazole ziram M-728 hymexazole guazatin M-729 hymexazole thiophanate-methyl M-730 hymexazole chlorothalonil M-731 hymexazole metrafenone M-732 hymexazole pyraclostrobin M-733 pyrimethanil M-734 pyrimethanil fludioxonil M-735 pyrimethanil aldimorph M-736 pyrimethanil dodemorph M-737 pyrimethanil fenpropimorph M-738 pyrimethanil iprodione M-739 pyrimethanil captan M-740 pyrimethanil fenoxanil M-741 pyrimethanil probenazol M-742 pyrimethanil mancozeb M-743 pyrimethanil metiram M-744 pyrimethanil thiram M-745 pyrimethanil ziram M-746 pyrimethanil guazatin M-747 pyrimethanil thiophanate-methyl M-748 pyrimethanil chlorothalonil M-749 pyrimethanil metrafenone M-750 pyrimethanil pyraclostrobin M-751 fludioxonil M-752 fludioxonil aldimorph M-753 fludioxonil dodemorph M-754 fludioxonil fenpropimorph 51 Mixture No. Compound IIB1 Compound 1ID2 M-755 fludioxonil iprodione M-756 fludioxonil captan M-757 fludioxonil fenoxanil M-758 fludioxonil probenazol M-759 fludioxonil mancozeb M-760 fludioxonil metiram M-761 fludioxonil thiram M-762 fludioxonil ziram M-763 fludioxonil guazatin M-764 fludioxonil thiophanate-methyl M-765 fludioxonil chlorothalonil M-766 fludioxonil metrafenone M-767 fludioxonil pyraclostrobin M-768 aldimorph M-769 aldimorph dodemorph M-770 aldimorph fenpropimorph M-771 aldimorph iprodione M-772 aldimorph captan M-773 aldimorph fenoxanil M-774 aldimorph probenazol M-775 aldimorph mancozeb M-776 aldimorph metiram M-777 aldimorph thiram M-778 aldimorph ziram M-779 aldimorph guazatin M-780 aldimorph thiophanate-methyl M-781 aldimorph chlorothalonil M-782 aldimorph metrafenone M-783 aldimorph pyraclostrobin M-784 dodemorph M-785 dodemorph fenpropimorph M-786 dodemorph iprodione M-787 dodemorph captan M-788 dodemorph fenoxanil M-789 dodemorph probenazol M-790 dodemorph mancozeb M-791 dodemorph metiram M-792 dodemorph thiram 52 Mixture No. Compound IIB1 Compound 1ID2 M-793 dodemorph ziram M-794 dodemorph guazatin M-795 dodemorph thiophanate-methyl M-796 dodemorph chlorothalonil M-797 dodemorph metrafenone M-798 dodemorph pyraclostrobin M-799 fenpropimorph M-800 fenpropimorph iprodione M-801 fenpropimorph captan M-802 fenpropimorph fenoxanil M-803 fenpropimorph probenazol M-804 fenpropimorph mancozeb M-805 fenpropimorph metiram M-806 fenpropimorph thiram M-807 fenpropimorph ziram M-808 fenpropimorph guazatin M-809 fenpropimorph thiophanate-methyl M-81 0 fenpropimorph chlorothalonil M-8 11 fenpropimorph metrafenone M-812 fenpropimorph pyraclostrobin M-813 iprodione M-814 iprodione captan M-815 iprodione fenoxanil M-816 iprodione probenazol M-817 iprodione mancozeb M-818 iprodione metiram M-819 iprodione thiram M-820 iprodione ziram M-821 iprodione guazatin M-822 iprodione thiophanate-methyl M-823 iprodione chlorothalonil M-824 iprodione metrafenone M-825 iprodione pyraclostrobin M-826 captan M-827 captan fenoxanil M-828 captan probenazol M-829 captan mancozeb M-830 captan metiram 53 Mixture No. Compound IIB1 Compound 1ID2 M-831 captan thiram M-832 captan ziram M-833 captan guazatin M-834 captan thiophanate-methyl M-835 captan chlorothalonil M-836 captan metrafenone M-837 captan pyraclostrobin M-838 fenoxanil M-839 fenoxanil probenazol M-840 fenoxanil mancozeb M-841 fenoxanil metiram M-842 fenoxanil thiram M-843 fenoxanil ziram M-844 fenoxanil guazatin M-845 fenoxanil thiophanate-methyl M-846 fenoxanil chlorothalonil M-847 fenoxanil metrafenone M-848 fenoxanil pyraclostrobin M-849 probenazol M-850 probenazol mancozeb M-851 probenazol metiram M-852 probenazol thiram M-853 probenazol ziram M-854 probenazol guazatin M-855 probenazol thiophanate-methyl M-856 probenazol chlorothalonil M-857 probenazol metrafenone M-858 probenazol pyraclostrobin M-859 mancozeb M-860 mancozeb metiram M-861 mancozeb thiram M-862 mancozeb ziram M-863 mancozeb guazatin M-864 mancozeb thiophanate-methyl M-865 mancozeb chlorothalonil M-866 mancozeb metrafenone M-867 mancozeb pyraclostrobin M-868 metiram 54 Mixture No. Compound IIB1 Compound IID2 M-869 metiram thiram M-870 metiram ziram M-871 metiram guazatin M-872 metiram thiophanate-methyl M-873 metiram chlorothalonil M-874 metiram metrafenone M-875 metiram pyraclostrobin M-876 thiram M-877 thiram ziram M-878 thiram guazatin M-879 thiram thiophanate-methyl M-880 thiram chlorothalonil M-881 thiram metrafenone M-882 thiram pyraclostrobin M-883 ziram M-884 ziram guazatin M-885 ziram thiophanate-methyl M-886 ziram chlorothalonil M-887 ziram metrafenone M-888 ziram pyraclostrobin M-889 guazatin M-890 guazatin thiophanate-methyl M-891 guazatin chlorothalonil M-892 guazatin metrafenone M-893 guazatin pyraclostrobin M-894 thiophanate-methyl M-895 thiophanate-methyl chlorothalonil M-896 thiophanate-methyl metrafenone M-897 thiophanate-methyl pyraclostrobin M-898 chlorothalonil M-899 chlorothalonil metrafenone M-900 chlorothalonil pyraclostrobin M-901 metrafenone M-902 metrafenone pyraclostrobin In a particular preferred embodiment, the present invention comprises the following tertiary and quaternay mixtures: 55 Table 1' Mixtures wherein compound I is fipronil, compound IIA is trifloxystrobin, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Table S. 5 Table 2' Mixtures wherein compound I is fipronil, compound IIA is azoxystrobin, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Table S. 10 Table 3' Mixtures wherein compound I is fipronil, compound IIA is metalaxyl, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Ta ble S. 15 Table 4' Mixtures wherein compound I is fipronil, compound IIA is metalaxyl-M, and the combi nation of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Table S. 20 Table 5' Mixtures wherein compound I is fipronil, compound IIC is cyproconazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Table S. 25 Table 6' Mixtures wherein compound I is fipronil, compound IIA is flutriafol, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Table S. 30 Table 7' Mixtures wherein compound I is fipronil, compound IIC is tebuconazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Table S. 35 Table 8' Mixtures wherein compound I is fipronil, compound IIA is triadimenol, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Ta ble S. 40 56 Table 9' Mixtures wherein compound I is fipronil, compound IIC is prochloraz, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Ta ble S. 5 Table 10' Mixtures wherein compound I is fipronil, compound IIA is fludioxonil, and the combina tion of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Ta ble S. 10 Table 11' Mixtures wherein compound I is fipronil, compound IIC is thiram, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Table S. 15 Table 12' Mixtures wherein compound I is fipronil, compound IIA is difenoconazole, and the com bination of compounds 1lB1 and 1ID2 in each case corresponds to a mixture set forth in Table S. 20 Table S Mixture Mixture Mixture Mixture No No S-1. M-1 as disclosed in Table Q S-53. M-247 as disclosed in Table Q S-2. M-3 as disclosed in Table Q S-54. M-248 as disclosed in Table Q S-3. M-4 as disclosed in Table Q S-55. M-249 as disclosed in Table Q S-4. M-6 as disclosed in Table Q S-56. M-251 as disclosed in Table Q S-5. M-7 as disclosed in Table Q S-57. M-257 as disclosed in Table Q S-6. M-1 1 as disclosed in Table Q S-58. M-267 as disclosed in Table Q S-7. M-15 as disclosed in Table Q S-59. M-273 as disclosed in Table Q S-8. M-16 as disclosed in Table Q S-60. M-376 as disclosed in Table Q S-9. M-1 7 as disclosed in Table Q S-61. M-380 as disclosed in Table Q S-10. M-18 as disclosed in Table Q S-62. M-381 as disclosed in Table Q S-11. M-20 as disclosed in Table Q S-63. M-382 as disclosed in Table Q S-12. M-26 as disclosed in Table Q S-64. M-383 as disclosed in Table Q S-13. M-36 as disclosed in Table Q S-65. M-385 as disclosed in Table Q S-14. M-42 as disclosed in Table Q S-66. M-391 as disclosed in Table Q S-15. M-84 as disclosed in Table Q S-67. M-401 as disclosed in Table Q S-16. M-85 as disclosed in Table Q S-68. M-407 as disclosed in Table Q S-17. M-87 as disclosed in Table Q S-69. M-498 as disclosed in Table Q S-18. M-88 as disclosed in Table Q S-70. M-499 as disclosed in Table Q 57 Mixture Mixture Mixture Mixture No No S-19. M-92 as disclosed in Table Q S-71. M-500 as disclosed in Table Q S-20. M-96 as disclosed in Table Q S-72. M-501 as disclosed in Table Q S-21. M-97 as disclosed in Table Q S-73. M-503 as disclosed in Table Q S-22. M-98 as disclosed in Table Q S-74. M-509 as disclosed in Table Q S-23. M-99 as disclosed in Table Q S-75. M-519 as disclosed in Table Q S-24. M-101 as disclosed in Table Q S-76. M-525 as disclosed in Table Q S-25. M-107 as disclosed in Table Q S-77. M-526 as disclosed in Table Q S-26. M-1 17 as disclosed in Table Q S-78. M-527 as disclosed in Table Q S-27. M-123 as disclosed in Table Q S-79. M-528 as disclosed in Table Q S-28. M-126 as disclosed in Table Q S-80. M-530 as disclosed in Table Q S-29. M-127 as disclosed in Table Q S-81. M-536 as disclosed in Table Q S-30. M-131 as disclosed in Table Q S-82. M-546 as disclosed in Table Q S-31. M-135 as disclosed in Table Q S-83. M-552 as disclosed in Table Q S-32. M-136 as disclosed in Table Q S-84. M-553 as disclosed in Table Q S-33. M-137 as disclosed in Table Q S-85. M-554 as disclosed in Table Q S-34. M-138 as disclosed in Table Q S-86. M-556 as disclosed in Table Q S-35. M-140 as disclosed in Table Q S-87. M-562 as disclosed in Table Q S-36. M-146 as disclosed in Table Q S-88. M-572 as disclosed in Table Q S-37. M-156 as disclosed in Table Q S-89. M-578 as disclosed in Table Q S-38. M-162 as disclosed in Table Q S-90. M-579 as disclosed in Table Q S-39. M-201 as disclosed in Table Q S-91. M-581 as disclosed in Table Q S-40. M-202 as disclosed in Table Q S-92. M-587 as disclosed in Table Q S-41. M-206 as disclosed in Table Q S-93. M-597 as disclosed in Table Q S-42. M-210 as disclosed in Table Q S-94. M-603 as disclosed in Table Q S-43. M-211 as disclosed in Table Q S-95. M-628 as disclosed in Table Q S-44. M-212 as disclosed in Table Q S-96. M-634 as disclosed in Table Q S-45. M-213 as disclosed in Table Q S-97. M-644 as disclosed in Table Q S-46. M-215 as disclosed in Table Q S-98. M-650 as disclosed in Table Q S-47. M-221 as disclosed in Table Q S-99. M-751 as disclosed in Table Q S-48. M-231 as disclosed in Table Q S-100. M-876 as disclosed in Table Q S-49. M-237 as disclosed in Table Q S-101. M-761 as disclosed in Table Q S-50. M-238 as disclosed in Table Q S-102. M-767 as disclosed in Table Q S-51. M-242 as disclosed in Table Q S-103. M-882 as disclosed in Table Q S-52. M-246 as disclosed in Table Q The inventive mixtures can further contain one or more insecticidal compound Ill. The following list of insecticides together with which the inventive mixtures according to the 58 invention can be used, is intended to illustrate the possible combinations, but not to impose any limitation: A.1. Organo(thio)phosphates: acephate, azamethiphos, azinphos-ethyl, azinphos 5 methyl, chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos, chlorpyrifos methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos/ DDVP, dicro tophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, famphur, fenamiphos, fenitrothion, fenthion, flupyrazophos, fosthiazate, heptenophos, isoxathion, malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, 10 naled, omethoate, oxydemeton-methyl, parathion, parathion-methyl, phenthoate, phor ate, phosalone, phosmet, phosphamidon, phoxim, pirimiphos-methyl, profenofos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirim fos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon, vamido thion; 15 A.2. Carbamates: aldicarb, alanycarb, bendiocarb, benfuracarb, butocarboxim, butoxy carboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, pro poxur, thiodicarb, thiofanox, trimethacarb, XMC, xylylcarb, triazamate; 20 A.3. Pyrethroids: acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-, yfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, 25 deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flu cythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, permethrin, phenothrin, prallethrin, resmethrin, RU 15525, silafluofen, tefluthrin, tetramethrin, tralomethrin, transfluthrin, ZXI 8901; 30 A.4. Juvenile hormone mimics: hydroprene, kinoprene, methoprene, fenoxycarb, pyriproxyfen; A.5. Nicotinic receptor agonists/antagonists compounds: acetamiprid, bensultap, cartap hydrochloride, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, nico 35 tine, spinosad (allosteric agonist), thiacloprid, thiocyclam, thiosultap-sodium, and AKD 1022. A.6. GABA gated chloride channel antagonist compounds: chlordane, endosulfan, gamma-HCH (lindane); acetoprole, pyrafluprole, pyriprole, vaniliprole, the phenylpyra 40 zole compound of formula F 1 59 0 S CF-- NH 2 2 N () Cl Cl

CF

3 A.7. Chloride channel activators: abamectin, emamectin benzoate, milbemectin, le pimectin; 5 A.8. METI I compounds: fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufen pyrad, tolfenpyrad, flufenerim, rotenone; A.9. METI || and Ill compounds: acequinocyl, fluacyprim, hydramethylnon; 10 A.10. Uncouplers of oxidative phosphorylation: chlorfenapyr, DNOC; A.1 1. Inhibitors of oxidative phosphorylation: azocyclotin, cyhexatin, diafenthiuron, fen butatin oxide, propargite, tetradifon; 15 A.12. Moulting disruptors: cyromazine, chromafenozide, halofenozide, methoxy fenozide, tebufenozide; A.13. Synergists: piperonyl butoxide, tribufos; 20 A.14. Sodium channel blocker compounds: indoxacarb, metaflumizone; A.15. Fumigants: methyl bromide, chloropicrin sulfuryl fluoride; A.16. Selective feeding blockers: crylotie, pymetrozine, flonicamid; 25 A.17. Mite growth inhibitors: clofentezine, hexythiazox, etoxazole; A.18. Chitin synthesis inhibitors: buprofezin, bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, te 30 flubenzuron, triflumuron; A.19. Lipid biosynthesis inhibitors: spirodiclofen, spiromesifen, spirotetramat; 60 A.20. octapaminergic agonsits: amitraz; A.21. ryanodine receptor modulators: flubendiamide; 5 A.22. Various: aluminium phosphide, amidoflumet, benclothiaz, benzoximate, bifenazate, borax, bromopropylate, cyanide, cyenopyrafen, cyflumetofen, chinomethionate, dicofol, fluoroacetate, phosphine, pyridalyl, pyrifluquinazon, sulfur, tartar emetic; 10 A.23. N-R'-2,2-dihalo-1 -R"cyclo-propanecarboxamide-2-(2,6-dichloro- a,a,a -tri-fluoro p-tolyl)hydrazone or N-R'-2,2-di(R"')propionamide-2-(2,6-dichloro- a,a,a -trifluoro-p tolyl)-hydrazone, wherein R' is methyl or ethyl, halo is chloro or bromo, R" is hydrogen or methyl and R"' is methyl or ethyl; 15 A.24. Anthranilamides: chloranthraniliprole, the compound of formula F2

CH

3 O Br NC N N N H Cl

H

3 C-N H A.25. Malononitrile compounds: CF 3

(CH

2

)

2

C(CN)

2

CH

2

(CF

2

)

3

CF

2 H,

CF

3

(CH

2

)

2

C(CN)

2

CH

2

(CF

2

)

5

CF

2 H, CF 3

(CH

2

)

2

C(CN)

2

(CH

2

)

2 C(CF3) 2 F,

CF

3

(CH

2

)

2

C(CN)

2

(CH

2

)

2

(CF

2

)

3

CF

3 , CF 2

H(CF

2

)

3

CH

2

C(CN)

2

CH

2

(CF

2

)

3

CF

2 H, 20 CF 3

(CH

2

)

2

C(CN)

2

CH

2

(CF

2

)

3

CF

3 , CF 3

(CF

2

)

2

CH

2

C(CN)

2

CH

2

(CF

2

)

3

CF

2 H,

CF

3

CF

2

CH

2

C(CN)

2

CH

2

(CF

2

)

3

CF

2 H, 2-(2,2,3,3,4,4,5,5-octafluoropentyl)-2-(3,3,4,4,4 pentafluorobutyl)-malonodinitrile, and CF 2

HCF

2

CF

2

CF

2

CH

2 C(CN) 2

CH

2

CH

2

CF

2

CF

3 ; A.26. Microbial disruptors: Bacillus thuringiensis subsp. Israelensi, Bacillus sphaericus, 25 Bacillus thuringiensis subsp. Aizawai, Bacillus thuringiensis subsp. Kurstaki, Bacillus thuringiensis subsp. Tenebrionis; The commercially available compounds of the list above may be found in The Pesticide Manual, 13th Edition, British Crop Protection Council (2003) among other publications. 30 Thioamides of formula F1 and their preparation have been described in WO 98/28279. Lepimectin is known from Agro Project, PJB Publications Ltd, November 2004. Ben clothiaz and its preparation have been described in EP-Al 454621. Methidathion and Paraoxon and their preparation have been described in Farm Chemicals Handbook, 35 Volume 88, Meister Publishing Company, 2001. Acetoprole and its preparation have 61 been described in WO 98/28277. Metaflumizone and its preparation have been de scribed in EP-Al 462 456. Flupyrazofos has been described in Pesticide Science 54, 1988, p.237-243 and in US 4822779. Pyrafluprole and its preparation have been de scribed in JP 2002193709 and in WO 01/00614. Pyriprole and its preparation have 5 been described in WO 98/45274 and in US 6335357. Amidoflumet and its preparation have been described in US 6221890 and in JP 21010907. Flufenerim and its prepara tion have been described in WO 03/007717 and in WO 03/007718. AKD 1022 and its preparation have been described in US 6300348. Chloranthraniliprole has been de scribed in WO 01/70671, WO 03/015519 and WO 05/118552. Anthranilamide deriva 10 tives of formula F 2 have been described in WO 01/70671, WO 04/067528 and WO 05/118552. Cyflumetofen and its preparation have been described in WO 04/080180. The aminoquinazolinone compound pyrifluquinazon has been described in EP A 109 7932. The malononitrile compounds CF 3

(CH

2

)

2

C(CN)

2

CH

2

(CF

2

)

3

CF

2 H,

CF

3

(CH

2

)

2

C(CN)

2

CH

2

(CF

2

)

5

CF

2 H, CF 3

(CH

2

)

2

C(CN)

2

(CH

2

)

2 C(CF3) 2 F, 15 CF 3

(CH

2

)

2

C(CN)

2

(CH

2

)

2

(CF

2

)

3

CF

3 , CF 2

H(CF

2

)

3

CH

2

C(CN)

2

CH

2

(CF

2

)

3

CF

2 H,

CF

3

(CH

2

)

2

C(CN)

2

CH

2

(CF

2

)

3

CF

3 , CF 3

(CF

2

)

2

CH

2

C(CN)

2

CH

2

(CF

2

)

3

CF

2 H,

CF

3

CF

2

CH

2

C(CN)

2

CH

2

(CF

2

)

3

CF

HCF

2

CF

2

CF

2

CH

2 C(CN) 2

CH

2

CH

2

CF

2

CF

3 have been described in WO 05/63694. 20 Preferred mixing partners are pyrethroids, especially alpha-cypermethrin, anthranila mides, especially chloranthraniliprole, the compound of formula G 2

CH

3 O Br NC N N N H Cl (G 2 )

H

3 C-N H nicotinic receptor agonists/antagonists compounds, especially acetamiprid, clothianidin, 25 dinotefuran, imidacloprid, thiamethoxam, nitenpyram, thiacloprid. Most preferred part ners are clothianidin and imidacloprid. As mentioned above, the present invention also comprises mixtures comprising, as active components 30 (1) an insecticidal compound I selected from fipronil and ethiprole; (2) a nicotinic receptor agonists/antagonists compound IlIlA; (3) and compound IlB and/or compound lID selected from List D, which is defined as List B plus pyracolostrobin. 35 62 In a preferred embodiment, the nicotinic receptor agonists/antagonists compound Ill is acetamiprid, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram or thia cloprid. In a more preferred embodiment, the nicotinic receptor agonists/antagonists compound Ill is clothianidin, thiamethoxam or imidacloprid, wherein chlothianidin is 5 most preferred. Preferred are also quarternary mixtures containing fipronil as compound I, clothianidin as compound IlIlA and compounds lID and compound IlB. 10 Preferred are also quarternary mixtures containing fipronil as compound I, imidacloprid as compound IlIlA and compounds lID and compound IlB. Preferred are also quarternary mixtures containing fipronil as compound I, thiameth oxam as compound IlIlA and and compounds lID and compound IlB. 15 Especially preferred are also tertiary mixtures containing fipronil as compound I, clothianidin and triticonazole. Especially preferred are also tertiary mixtures containing fipronil as compound I, 20 clothianidin and pyraclostrobin. Especially preferred are also mixtures containing fipronil, clothianidin, pyraclostrobin and prochloraz. 25 Especially preferred are also mixtures containing fipronil, clothianidin, pyraclostrobin and triticonazole. Especially preferred are also mixtures containing fipronil, clothianidin, pyraclostrobin and thiophanate-methyl. 30 Especially preferred are also mixtures containing fipronil, clothianidin, pyraclostrobin and thiophanate-methyl. Preferred are also mixtures wherein compound I is fipronil, compound IllA is 35 clothianidin, and the combination of compounds 1lB1 and IID2 in each case corre sponds to a row of Table Q. More preferred are also mixtures, wherein compound I is fipronil, compound IlIlA is clothianidin, and the combination of compounds 1lB1 and IID2 in each case corre 40 sponds to a row of Table S.

63 Preferred are also mixtures wherein compound I is fipronil, compound IlIlA is imidaclo prid, and the combination of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. 5 More preferred are also mixtures, wherein compound I is fipronil, compound IlIlA is imi dacloprid, and the combination of compounds 1lB1 and IID2 in each case corresponds to a row of Table S. Preferred are also mixtures wherein compound I is fipronil, compound IlIlA is thiameth 10 oxam, and the combination of compounds 1lB1 and IID2 in each case corresponds to a row of Table Q. More preferred are also mixtures, wherein compound I is fipronil, compound IlIlA is thiamethoxam, and the combination of compounds 1lB1 and IID2 in each case corre 15 sponds to a row of Table S. As mentioned above, the present invention also comprises mixtures comprising, as active components 20 (1) an insecticidal compound I selected from fipronil and ethiprole; (2) an anthranilamide compound IllB; (3) and compound IB and/or compound lID selected from List D, which is defined as List B plus pyracolostrobin. 25 In a preferred embodiment, compound IllB is chloranthraniliprole. In a further preferred embodiment, compound IllB is the compound of formula G2. Preferred are also quarternary mixtures containing fipronil as compound I, compound 30 IllB and compounds lID and compound IlB. Especially preferred are also tertiary mixtures containing fipronil as compound I, chlor anthraniliprole and compounds lID and compound IlB. 35 Preferred are also mixtures wherein compound I is fipronil, compound IllB is chloran thraniliprole, and the combination of compounds 1lB1 and IID2 in each case corre sponds to a row of Table Q. More preferred are also mixtures, wherein compound I is fipronil, compound IllB is 40 chloranthraniliprole, and the combination of compounds 1lB1 and IID2 in each case corresponds to a row of Table S.

64 Preferred are also mixtures wherein compound I is fipronil, compound IllB is is the compound of formula G2., and the combination of compounds IIB1 and IID2 in each case corresponds to a row of Table Q. 5 More preferred are also mixtures, wherein compound I is fipronil, compound IllB is the compound of formula G2, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table S. 10 As mentioned above, the present invention also comprises fungicidal synergistic mix tures consisting of compound IB and compound IID. Preferred are the combinations of compound IIB1 and IID2 as set forth in Table R. Table R corresponds to table Q, however excluding the mixture numbers M-1, M-43, 15 M-84, M-124, M-163, M-201, M-238, M-274, M-309, M-343, M-376, M-408, M-439, M 469, M-498, M-526, M-553, M-579, M-604, M-628, M-651, M-673, M-694, M-714, M 733, M-751, M-768, M-784, M-799, M-813, M-826, M-838, M-849, M-859, M-868, M 876, M-883, M-889, M-894, M-898 and M-901, which just represent single compound IIB1 and no compound 1ID2. 20 The present invention also comprises mixtures of three fungicidal compounds, wherein two compounds are selected from List B, as defined above, and the third fungidical compound is fungicidal compound lID in synergistically effective amounts. 25 With respect to their intended use, the following tertiary fungicidal mixtures are espe cially preferred: Table 1" Mixtures wherein compound IB is trifloxystrobin, and the combination of compounds 30 IIB1 and 1ID2 in each case corresponds to a row of Table R. Table 2" Mixtures wherein compound IB is azoxystrobin, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 35 Table 3" Mixtures wherein compound IB is boscalid, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. 40 65 Table 4" Mixtures wherein compound IB is metalaxyl, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. 5 Table 5" Mixtures wherein compound IB is metalaxyl-M, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 6" 10 Mixtures wherein compound IIB is cyproconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 7" Mixtures wherein compound IB is epoxiconazole, and the combination of compounds 15 IIB1 and 1ID2 in each case corresponds to a row of Table R. Table 8" Mixtures wherein compound IB is fenbuconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 20 Table 9" Mixtures wherein compound IB is fluquinconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 25 Table 10" Mixtures wherein compound IB is flutriafol, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 11" 30 Mixtures wherein compound IB is ipconazole, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. Table 12" Mixtures wherein compound IIB is metconazole, and the combination of compounds 35 IIB1 and 1ID2 in each case corresponds to a row of Table R. Table 13" Mixtures wherein compound IIB is propiconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 40 66 Table 14" Mixtures wherein compound I is ethiprole, compound II is prothioconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 5 Table 15" Mixtures wherein compound IB is tebuconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 10 Table 16" Mixtures wherein compound IB is triadimenol, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. Table 17" 15 Mixtures wherein compound IB is imazalil, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. Table 18" Mixtures wherein compound IIB is prochloraz, and the combination of compounds IIB1 20 and 11D2 in each case corresponds to a row of Table R. Table 19" Mixtures wherein compound IB is carbendazim, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 25 Table 20" Mixtures wherein compound IB is thiabendazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 30 Table 21" Mixtures wherein compound IB is ethaboxam, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. Table 22" 35 Mixtures wherein compound IB is hymexazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 23" Mixtures wherein compound IB is pyrimethanil, and the combination of compounds 40 IIB1 and 1ID2 in each case corresponds to a row of Table R.

67 Table 24" Mixtures wherein compound IB is fludioxonil, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. 5 Table 25" Mixtures wherein compound IB is aldimorph, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. Table 26" 10 Mixtures wherein compound IB is dodemorph, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. Table 27" Mixtures wherein compound IIB is fenpropimorph, and the combination of compounds 15 IIB1 and 1ID2 in each case corresponds to a row of Table R. Table 28" Mixtures wherein compound IB is iprodione, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 20 Table 29" Mixtures wherein compound IB is captan, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 25 Table 30" Mixtures wherein compound IB is fenoxanil, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. Table 31" 30 Mixtures wherein compound IB is probenazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 32" Mixtures wherein compound IIB is mancozeb, and the combination of compounds IIB1 35 and 11D2 in each case corresponds to a row of Table R. Table 33" Mixtures wherein compound IB is metiram, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. 40 68 Table 34" Mixtures wherein compound IIB is thiram, and the combination of compounds IIB1 and 1ID2 in each case corresponds to a row of Table R. 5 Table 35" Mixtures wherein compound IB is ziram, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 36" 10 Mixtures wherein compound IB is guazatin, and the combination of compounds 1lB1 and 11D2 in each case corresponds to a row of Table R. Table 37" Mixtures wherein compound IB is thiophanate-methyl, and the combination of com 15 pounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 38" Mixtures wherein compound IB is chlorothalonil, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 20 Table 39" Mixtures wherein compound IB is metrafenone, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. 25 Table 40" Mixtures wherein compound IB is difenoconazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 41" 30 Mixtures wherein compound IB is triticonazole, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R. Table 42" Mixtures wherein compound I is fipronil, compound IIA is N-(3',4',5'-trifluorobiphenyl-2 35 yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table Q. Table 43" Mixtures wherein compound I is fipronil, compound IIA is N-(3',4',5'-trifluorobiphenyl-2 40 yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of compounds 1lB1 and 1ID2 in each case corresponds to a row of Table R.

69 Table 44" Mixtures wherein compound I is fipronil, compound IIA is N-(2',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, and the combination of 5 compounds llB1 and 1ID2 in each case corresponds to a row of Table R. Table 45" Mixtures wherein compound I is ethiprole, compound IIA is N-(3',4',5'-trifluorobiphenyl 2-yl)-3-chlorofluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide, and the combination 10 of compounds llB1 and 1ID2 in each case corresponds to a row of Table R. Table 46" Mixtures wherein compound I is ethiprole, compound IIA is N-(3',4'-dichloro-4 fluorobiphenyl-2-yl)-3-difluoro-methyl-1-methyl-pyrazole-4-carboxamide, and the com 15 bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table R. Table 47" Mixtures wherein compound I is ethiprole, compound IIA is N-(3',4'-dichloro 5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide, and the com 20 bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table R. Table 48" Mixtures wherein compound I is ethiprole, compound IIA is N-(2-(1,3-dimethylbutyl) phenyl)-1,3-dimethyl-5-fluoro-1 H-pyrazole-4-carboxylic acid amide, and the combina 25 tion of compounds llB1 and 1ID2 in each case corresponds to a row of Table R. Table 49" Mixtures wherein compound I is ethiprole, compound IIA is N-(cis-2-bicyclopropyl-2-yl phenyl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, and the com 30 bination of compounds llB1 and 1ID2 in each case corresponds to a row of Table R. Table 50" Mixtures wherein compound I is ethiprole, compound IIA is N-(trans-2-bicyclopropyl-2 yl-phenyl)-3-d ifl uoro-methyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, and the 35 combination of compounds llB1 and 1ID2 in each case corresponds to a row of Table R. Table 51" Mixtures wherein compound I is ethiprole, compound IIA is 3-(difluoromethyl)-1-methyl 40 N-[1,2,3,4-tetrahydro-9-(1 -methylethyl)-1,4-methanonaphthalen-5-yl]-1 H-pyrazole- 70 4carboxamide, and the combination of compounds 1lB1 and IID2 in each case corre sponds to a row of Table R. Herein, the following mixtures are especially preferred: 5 (1) the mixture consisting of prochloraz, triticonazole and pyraclostrobin; (2) the mixture consisting of thiophanatemethyl, triticonazole and pyraclostrobin; and (3) the mixture consisting of boscalid, metalxyl and pyraclostrobin. For use according to the present invention, the mixtures according to the invention, or 10 the compound I and the active compounds IlA (or IIC) and optionally llB or IlB and IID (alternatively the fungicidal mixtures as defined above or the mixtures of compound I, compound Ill (e.g. IlIlA or IllB) and one or more compounds llB or compound IlB and compound IID), can be converted into the customary formulations, for example solu tions, emulsions, suspensions, dusts, powders, pastes and granules. The use form 15 depends on the particular intended purpose; in each case, it should ensure a fine and even distribution of the compound according to the invention. The formulations are prepared in a known manner, for example by extending the active compound with solvents and/or carriers, if desired using emulsifiers and dispersants. 20 Solvents/auxiliaries which are suitable are essentially: - water, aromatic solvents (for example Solvesso products, xylene), paraffins (for example mineral oil fractions), alcohols (for example methanol, butanol, pentanol, benzyl alcohol), ketones (for example cyclohexanone, gamma-butyrolactone), pyrrolidones (NMP, NOP), acetates (glycol diacetate), glycols, fatty acid dimethyl 25 amides, fatty acids and fatty acid esters. In principle, solvent mixtures may also be used, - carriers such as ground natural minerals (for example kaolins, clays, talc, chalk) and ground synthetic minerals (for example highly disperse silica, silicates); emulsifiers such as nonionic and anionic emulsifiers (for example polyoxyethyl 30 ene fatty alcohol ethers, alkylsulfonates and arylsulfonates) and dispersants such as lignosulfite waste liquors and methylcellulose. Suitable surfactants are alkali metal, alkaline earth metal and ammonium salts of ligno sulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic 35 acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naph thalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octyl phenol ethers, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol poly 40 glycol ethers, tributylphenyl polyglycol ethers, tristearylphenyl polyglycol ethers, alkyl aryl polyether alcohols, alcohol and fatty alcohol ethylene oxide condensates, ethoxy- 71 lated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors and methyl cellulose. 5 Suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene, paraffin, tetrahydro naphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, 10 butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone and water. Also anti-freezing agents such as glycerin, ethylene glycol, propylene glycol and bacte ricides such as can be added to the formulation. 15 Suitable antifoaming agents are for example antifoaming agents based on silicon or magnesium stearate. Seed treatment formulations may additionally comprise binders and optionally color 20 ants. Binders can be added to improve the adhesion of the active materials on the seeds after treatment. Suitable binders are block copolymers EO/PO surfactants but also polyvinyl alcoholsl, polyvinylpyrrolidones, polyacrylates, polymethacrylates, polybutenes, polyiso 25 utylenes, polystyrene, polyethyleneamines, polyethyleneamides, polyethyleneimines (Lupasol@, Polymin@), polyethers, polyurethans, polyvinylacetate, tylose and copolymers derived from these polymers. Optionally, also colorants can be included in the formulation. Suitable colorants or dyes 30 for seed treatment formulations are Rhodamin B, C.I. Pigment Red 112, C.I. Solvent Red 1, pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1, pigment blue 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48:1, pigment red 57:1, pigment red 53:1, pigment orange 43, pig ment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 35 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108. Examples of a gelling agent is carrageen (Satiagel*). 40 Powders, materials for spreading and dustable products can be prepared by mixing or concomitantly grinding the active substances with a solid carrier.

72 Granules, for example coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active compounds to solid carriers. Examples of solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay, 5 limestone, lime, chalk, bole, less, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, for example, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers. 10 In general, the formulations comprise from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight, of the active compound. The active compounds are employed in a purity of from 90% to 100%, preferably 95% to 100% (according to NMR spectrum). 15 For seed treatment purposes, respective formulations can be diluted 2-10 fold leading to concentrations in the ready to use preparations of 0,01 to 60% by weight active compound by weight, preferably 0,1 to 40% by weight. The following are examples of formulations: 1. Products for dilution with water 20 For seed treatment purposes, such products may be applied to the seed diluted or undiluted. A Water-soluble concentrates (SL, LS) 10 parts by weight of the active compounds are dissolved with 90 parts by weight of 25 water or a water-soluble solvent. As an alternative, wetters or other auxiliaries are added. The active compound dissolves upon dilution with water. A formulation having an active compound content of 10% by weight is obtained in this manner. B Dispersible concentrates (DC) 30 20 parts by weight of the active compounds are dissolved in 70 parts by weight of cyclohexanone with addition of 10 parts by weight of a dispersant, for example polyvinylpyrrolidone. Dilution with water gives a dispersion. The active compound content is 20% by weight. 35 C Emulsifiable concentrates (EC) 15 parts by weight of the active compounds are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The formulation has an active compound content of 15% by weight. 40 73 D Emulsions (EW, EO, ES) 25 parts by weight of the active compounds are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This mixture is added into 30 parts by weight of water by 5 means of an emulsifying machine (e.g. Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion. The formulation has an active compound content of 25% by weight. E Suspensions (SC, OD, FS) 10 In an agitated ball mill, 20 parts by weight of the active compounds are comminuted with addition of 10 parts by weight of dispersants and wetters and 70 parts by weight of water or an organic solvent to give a fine active compound suspension. Dilution with water gives a stable suspension of the active compound. The active compound content in the formulation is 20% by weight. 15 F Water-dispersible granules and water-soluble granules (WG, SG) 50 parts by weight of the active compounds are ground finely with addition of 50 parts by weight of dispersants and wetters and made into water-dispersible or water-soluble granules by means of technical appliances (for example extrusion, spray tower, 20 fluidized bed). Dilution with water gives a stable dispersion or solution of the active compound. The formulation has an active compound content of 50% by weight. G Water-dispersible powders and water-soluble powders (WP, SP, SS, WS) 75 parts by weight of the active compounds are ground in a rotor- stator mill with 25 addition of 25 parts by weight of dispersants and wetters as well as silica gel. Dilution with water gives a stable dispersion or solution of the active compound. The active compound content of the formulation is 75% by weight. H Gel formulations (GF) 30 In a ball mill, 20 parts by weight of the active compounds, 10 parts by weight of dispersant, 1 part by weight of gelling agent and 70 parts by weight of water or an organic solvent are ground to give a fine suspension. On dilution with water, a stable suspension having an active compound content of 20% by weight is obtained. 35 2. Products to be applied undiluted I Dustable powders (DP, DS) 5 parts by weight of the active compounds are ground finely and mixed intimately with 95 parts by weight of finely divided kaolin. This gives a dustable product having an 40 active compound content of 5% by weight.

74 J Granules (GR, FG, GG, MG) 0.5 part by weight of the active compounds is ground finely and associated with 99.5 parts by weight of carriers. Current methods are extrusion, spray-drying or the fluidized bed. This gives granules to be applied undiluted having an active compound content of 5 0.5% by weight. K ULV solutions (UL) 10 parts by weight of the active compounds are dissolved in 90 parts by weight of an organic solvent, for example xylene. This gives a product to be applied undiluted 10 having an active compound content of 10% by weight. For seed treatment, use is usually made of water-soluble concentrates (LS), suspensions (FS), dustable powders (DS), water-dispersible and water-soluble powders (WS, SS), emulsions (ES), emulsifiable concentrates (EC) and gel 15 formulations (GF). These formulations can be applied to the seed in undiluted form or, preferably, diluted. Application can be carried out prior to sowing. In a preferred embodiment a FS formulation is used for seed treatment. Typcially, a FS formulation may comprise 1-800 g/I of active ingredient, 1-200 g/I Surfactant, 0 to 200 20 g/I antifreezing agent, 0 to 400 g/I of binder, 0 to 200 g/I of a pigment and up to 1 liter of a solvent, preferably water. The inventive mixtures can be used as such, in the form of their formulations or the use forms prepared therefrom, for example in the form of directly sprayable solutions, 25 powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading or pouring. The use forms depend entirely on the intended purposes; the intention is to ensure in each case the finest possible distribution of the active compounds according to the invention. 30 Aqueous use forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water. To prepare emulsions, pastes or oil dispersions, the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetter, tackifier, dispersant or emulsifier. 35 Alternatively, it is possible to prepare concentrates composed of active substance, wetter, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil, and such concentrates are suitable for dilution with water. The active compound concentrations in the ready-to-use preparations can be varied 40 within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.01 to 1%.

75 The active compounds may also be used successfully in the ultra-low-volume process (ULV), by which it is possible to apply formulations comprising over 95% by weight of active compound, or even to apply the active compounds without additives. 5 Various types of oils, wetters, adjuvants, herbicides, fungicides, other pesticides, or bactericides may be added to the active compounds, if appropriate not until immediately prior to use (tank mix). These agents can be admixed with the agents according to the invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1. 10 Compositions of this invention may also contain fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators and safeners. These may be used sequentially or in combination with the above-described compositions, if appropriate also added only immediately prior to use (tank mix). For example, the plant(s) may be sprayed with a composition of this invention either before 15 or after being treated with the fertilizers. The compounds contained in the mixtures as defined above can be applied simultane ously, that is jointly or separately, or in succession, the sequence, in the case of sepa rate application, generally not having any effect on the result of the control measures. 20 Advantageously, they are suitable for controlling the following plant diseases: e Alternaria species on vegetables, oilseed rape, sugar beet and fruit and rice, such as, for example, A. solani or A. alternata on potatoes and tomatoes; 25 e Aphanomyces species on sugar beet and vegetables; e Ascochyta species on cereals and vegetables; e Bipolaris and Drechslera species on corn, cereals, rice and lawns, such as, for example, D. maydis on corn; * Blumeria graminis (powdery mildew) on cereals; 30 e Botrytis cinerea (gray mold) on strawberries, vegetables, flowers and grapevines; e Bremia lactucae on lettuce; e Cercospora species on corn, soybeans, rice and sugar beet; e Cochliobolus species on corn, cereals, rice, such as, for example, Cochliobolus sativus on cereals, Cochliobolus miyabeanus on rice; 35 e Colletotricum species on soybeans and cotton; e Drechslera species, Pyrenophora species on corn, cereals, rice and lawns, such as, for example, D. teres on barley or D. tritici-repentis on wheat; e Esca on grapevines, caused by Phaeoacremonium chlamydosporium, Ph. Aleophilum and Formitipora punctata (syn. Phellinus punctatus); 40 e Exserohilum species on corn; 76 e Erysiphe cichoracearum and Sphaerotheca fuliginea on cucumbers; * Fusarium and Verticillium species on various plants, such as, for example, F. graminearum or F. culmorum on cereals or F. oxysporum on a multitude of plants, such as, for example, tomatoes; 5 e Gaeumanomyces graminis on cereals; e Gibberella species on cereals and rice (for example Gibberella fujikuroi on rice); e Grainstaining complex on rice; e Helminthosporium species on corn and rice; e Michrodochium nivale on cereals; 10 e Mycosphaerella species on cereals, bananas and groundnuts, such as, for example, M. graminicola on wheat or M.fijiensis on bananas; e Peronospora species on cabbage and bulbous plants, such as, for example, P. brassicae on cabbage or P. destructor on onions; e Phakopsara pachyrhizi and Phakopsara meibomiae on soybeans; 15 e Phomopsis species on soybeans and sunflowers; * Phytophthora infestans on potatoes and tomatoes; e Phytophthora species on various plants, such as, for example, P. capsici on bell pepper; e Plasmopara viticola on grapevines; 20 e Podosphaera leucotricha on apples; e Pseudocercosporella herpotrichoides on cereals; e Pseudoperonospora on various plants, such as, for example, P. cubensis on cu cumber or P. humili on hops; e Puccinia species on various plants, such as, for example, P. triticina, P. striformins, 25 P. hordei or P.graminis on cereals or P. asparagi on asparagus; e Pyricularia oryzae, Corticium sasakii, Sarocladium oryzae, S.attenuatum, Entyloma oryzae on rice; e Pyricularia grisea on lawns and cereals; e Pythium spp. on lawns, rice, corn, cotton, oilseed rape, sunflowers, sugar beet, 30 vegetables and other plants, such as, for example, P. ultiumum on various plants, P. aphanidermatum on lawns; e Rhizoctonia species on cotton, rice, potatoes, lawns, corn, oilseed rape, potatoes, sugar beet, vegetables and on various plants, such as, for example, R. solani on beet and various plants; 35 e Rhynchosporium secalis on barley, rye and triticale; e Sclerotinia species on oilseed rape and sunflowers; e Septoria tritici and Stagonospora nodorum on wheat; e Erysiphe (syn. Uncinula) necator on grapevines; e Setospaeria species on corn and lawns; 40 e Sphacelotheca reilinia on corn; e Thievaliopsis species on soybeans and cotton; 77 e Tilletia species on cereals; e Ustilago species on cereals, corn and sugar cane, such as, for example, U. maydis on corn; e Venturia species (scab) on apples and pears, such as, for example, V. inaequalis 5 on apples. The inventive mixtures are furthermore suitable for controlling harmful fungi in the protection of materials (for example wood, paper, paint dispersions, fibers or fabrics) and in the protection of stored products. In the protection of wood, particular attention is 10 paid to the following harmful fungi: Ascomycetes, such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp., Trichurus spp.; Basidiomycetes, such as Coniophora spp., Coriolus spp., Gloeophyllum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp. and Tyromyces spp., Deuteromycetes, such as Aspergillus spp., 15 Cladosporium spp., Penicillium spp., Trichoderma spp., Alternaria spp., Paecilomyces spp. and Zygomycetes, such as Mucor spp., additionally in the protection of materials the following yeasts: Candida spp. and Saccharomyces cerevisae. They are particularly important for controlling a multitude of fungi on various cultivated 20 plants, such as bananas, cotton, vegetable species (for example cucumbers, beans and cucurbits), barley, grass, oats, coffee, potatoes, corn, fruit species, rice, rye, soya, tomatoes, grapevines, wheat, ornamental plants, sugar cane and also on a large num ber of seeds. 25 The inventive mixtures (except the mixtures comprising fungicides only) exhibit also outstanding action against pests from the following orders: insects from the order of the lepidopterans (Lepidoptera), for example Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, 30 Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheima tobia brumata, Choristoneura fumiferana, Choristoneura occidentalis, Cirphis unipuncta, Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, Diatraea grandi osella, Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bou liana, Feltia subterranea, Galleria mellonella, Grapholitha funebrana, Grapholitha mo 35 lesta, Heliothis armigera, Heliothis virescens, Heliothis zea, Hellula undalis, Hibernia defoliaria, Hyphantria cunea, Hyponomeuta malinellus, Keiferia lycopersicella, Lamb dina fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera scitella, Lithocol letis blancardella, Lobesia botrana, Loxostege sticticalis, Lymantria dispar, Lymantria monacha, Lyonetia clerkella, Malacosoma neustria, Mamestra brassicae, Orgyia pseu 40 dotsugata, Ostrinia nubilalis, Panolis flammea, Pectinophora gossypiella, Peridroma saucia, Phalera bucephala, Phthorimaea operculella, Phyllocnistis citrella, Pieris bras- 78 sicae, Plathypena scabra, Plutella xylostella, Pseudoplusia includens, Rhyacionia frus trana, Scrobipalpula absoluta, Sitotroga cerealella, Sparganothis pilleriana, Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Thaumatopoea pityocampa, Tortrix viridana, Trichoplusia ni and Zeiraphera canadensis, 5 beetles (Coleoptera), for example Agrilus sinuatus, Agriotes lineatus, Agriotes obscu rus, Amphimallus solstitialis, Anisandrus dispar, Anthonomus grandis, Anthonomus pomorum, Aphthona euphoridae, Athous haemorrhoidalis, Atomaria linearis, Blasto phagus piniperda, Blitophaga undata, Bruchus rufimanus, Bruchus pisorum, Bruchus 10 lentis, Byctiscus betulae, Cassida nebulosa, Cerotoma trifurcata, Cetonia aurata, Ceuthorrhynchus assimilis, Ceuthorrhynchus napi, Chaetocnema tibialis, Conoderus vespertinus, Crioceris asparagi, Ctenicera ssp., Diabrotica longicornis, Diabrotica semipunctata, Diabrotica 12-punctata Diabrotica speciosa, Diabrotica virgifera, Epila chna varivestis, Epitrix hirtipennis, Eutinobothrus brasiliensis, Hylobius abietis, Hypera 15 brunneipennis, Hypera postica, Ips typographus, Lema bilineata, Lema melanopus, Leptinotarsa decemlineata, Limonius californicus, Lissorhoptrus oryzophilus, Melanotus communis, Meligethes aeneus, Melolontha hippocastani, Melolontha melolontha, Oulema oryzae, Ortiorrhynchus sulcatus, Otiorrhynchus ovatus, Phaedon cochleariae, Phyllobius pyri, Phyllotreta chrysocephala, Phyllophaga sp., Phyllopertha horticola, 20 Phyllotreta nemorum, Phyllotreta striolata, Popillia japonica, Sitona lineatus and Sito philus granaria, flies, mosquitoes (Diptera), e.g. Aedes aegypti, Aedes albopictus, Aedes vexans, An astrepha ludens, Anopheles maculipennis, Anopheles crucians, Anopheles albimanus, 25 Anopheles gambiae, Anopheles freeborni, Anopheles leucosphyrus, Anopheles mini mus, Anopheles quadrimaculatus, Calliphora vicina, Ceratitis capitata, Chrysomya bezziana, Chrysomya hominivorax, Chrysomya macellaria, Chrysops discalis, Chrysops silacea, Chrysops atlanticus, Cochliomyia hominivorax, Contarinia sorghicola Cordylobia anthropophaga, Culicoides furens, Culex pipiens, Culex nigripalpus, Culex 30 quinquefasciatus, Culex tarsalis, Culiseta inornata, Culiseta melanura, Dacus cucurbi tae, Dacus oleae, Dasineura brassicae, Delia antique, Delia coarctata, Delia platura, Delia radicum, Dermatobia hominis, Fannia canicularis, Geomyza Tripunctata, Gaster ophilus intestinalis, Glossina morsitans, Glossina palpalis, Glossina fuscipes, Glossina tachinoides, Haematobia irritans, Haplodiplosis equestris, Hippelates spp., Hylemyia 35 platura, Hypoderma lineata, Leptoconops torrens, Liriomyza sativae, Liriomyza trifolii, Lucilia caprina, Lucilia cuprina, Lucilia sericata, Lycoria pectoralis, Mansonia titillanus, Mayetiola destructor, Musca domestica, Muscina stabulans, Oestrus ovis, Opomyza florum, Oscinella frit, Pegomya hysocyami, Phorbia antiqua, Phorbia brassicae, Phor bia coarctata, Phlebotomus argentipes, Psorophora columbiae, Psila rosae, Psoro 40 phora discolor, Prosimulium mixtum, Rhagoletis cerasi, Rhagoletis pomonella, Sar cophaga haemorrhoidalis, Sarcophaga sp., Simulium vittatum, Stomoxys calcitrans, 79 Tabanus bovinus, Tabanus atratus, Tabanus lineola, and Tabanus similis, Tipula ol eracea, and Tipula paludosa thrips (Thysanoptera), e.g. Dichromothrips corbetti, Dichromothrips ssp , Frankliniella 5 fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips palmi and Thrips tabaci, termites (Isoptera), e.g. Calotermes flavicollis, Leucotermes flavipes, Heterotermes aureus, Reticulitermes flavipes, Reticulitermes virginicus, Reticulitermes lucifugus, 10 Termes natalensis, and Coptotermes formosanus, cockroaches (Blattaria - Blattodea), e.g. Blattella germanica, Blattella asahinae, Peri planeta americana, Periplaneta japonica, Periplaneta brunnea, Periplaneta fuligginosa, Periplaneta australasiae, and Blatta orientalis, 15 true bugs (Hemiptera), e.g. Acrosternum hilare, Blissus leucopterus, Cyrtopeltis nota tus, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integriceps, Euschistus impictiventris, Leptoglossus phyllopus, Lygus lineolaris, Lygus pratensis, Nezara viridu la, Piesma quadrata, Solubea insularis , Thyanta perditor, Acyrthosiphon onobrychis, 20 Adelges laricis, Aphidula nasturtii, Aphis fabae, Aphis forbesi, Aphis pomi, Aphis gos sypii, Aphis grossulariae, Aphis schneideri, Aphis spiraecola, Aphis sambuci, Acyrtho siphon pisum, Aulacorthum solani, Bemisia argentifolii, Brachycaudus cardui, Brachy caudus helichrysi, Brachycaudus persicae, Brachycaudus prunicola, Brevicoryne bras sicae, Capitophorus horni, Cerosipha gossypii, Chaetosiphon fragaefolii, Cryptomyzus 25 ribis, Dreyfusia nordmannianae, Dreyfusia piceae, Dysaphis radicola, Dysaulacorthum pseudosolani, Dysaphis plantaginea, Dysaphis pyri, Empoasca fabae, Hyalopterus pruni, Hyperomyzus lactucae, Macrosiphum avenae, Macrosiphum euphorbiae, Ma crosiphon rosae, Megoura viciae, Melanaphis pyrarius, Metopolophium dirhodum, My zus persicae, Myzus ascalonicus, Myzus cerasi, Myzus varians, Nasonovia ribis-nigri, 30 Nilaparvata lugens, Pemphigus bursarius, Perkinsiella saccharicida, Phorodon humuli, Psylla mali, Psylla piri, Rhopalomyzus ascalonicus, Rhopalosiphum maidis, Rhopalosi phum padi, Rhopalosiphum insertum, Sappaphis mala, Sappaphis mali, Schizaphis graminum, Schizoneura lanuginosa, Sitobion avenae, Trialeurodes vaporariorum, Toxoptera aurantiiand, Viteus vitifolii, Cimex lectularius, Cimex hemipterus, Reduvius 35 senilis, Triatoma spp., and Arilus critatus. ants, bees, wasps, sawflies (Hymenoptera), e.g. Athalia rosae, Atta cephalotes, Atta capiguara, Atta cephalotes, Atta laevigata, Atta robusta, Atta sexdens, Atta texana, Crematogaster spp., Hoplocampa minuta, Hoplocampa testudinea, Monomorium pha 40 raonis, Solenopsis geminata, Solenopsis invicta, Solenopsis richteri, Solenopsis xyloni, Pogonomyrmex barbatus, Pogonomyrmex californicus, Pheidole megacephala, Dasy- 80 mutilla occidentalis, Bombus spp. Vespula squamosa, Paravespula vulgaris, Paraves pula pennsylvanica, Paravespula germanica, Dolichovespula maculata, Vespa crabro, Polistes rubiginosa, Camponotus floridanus, and Linepithema humile, 5 crickets, grasshoppers, locusts (Orthoptera), e.g. Acheta domestica, Gryllotalpa gryllo talpa, Locusta migratoria, Melanoplus bivittatus, Melanoplus femurrubrum, Melanoplus mexicanus, Melanoplus sanguinipes, Melanoplus spretus, Nomadacris septemfasciata, Schistocerca americana, Schistocerca gregaria, Dociostaurus maroccanus, Tachycines asynamorus, Oedaleus senegalensis, Zonozerus variegatus, Hieroglyphus daganensis, 10 Kraussaria angulifera, Calliptamus italicus, Chortoicetes terminifera, and Locustana pardalina, Arachnoidea, such as arachnids (Acarina), e.g. of the families Argasidae, lxodidae and Sarcoptidae, such as Amblyomma americanum, Amblyomma variegatum, Ambryomma 15 maculatum, Argas persicus, Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, Dermacentor silvarum, Dermacentor andersoni, Dermacentor variabilis, Hyalomma truncatum, Ixodes ricinus, Ixodes rubicundus, Ixodes scapularis, Ixodes holocyclus, Ixodes pacificus, Ornithodorus moubata, Ornithodorus hermsi, Ornithodo rus turicata, Ornithonyssus bacoti, Otobius megnini, Dermanyssus gallinae, Psoroptes 20 ovis, Rhipicephalus sanguineus, Rhipicephalus appendiculatus, Rhipicephalus evertsi, Sarcoptes scabiei, and Eriophyidae spp. such as Aculus schlechtendali, Phyllocoptrata oleivora and Eriophyes sheldoni; Tarsonemidae spp. such as Phytonemus pallidus and Polyphagotarsonemus latus; Tenuipalpidae spp. such as Brevipalpus phoenicis; Tetra nychidae spp. such as Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus 25 pacificus, Tetranychus telarius and Tetranychus urticae, Panonychus ulmi, Panony chus citri, and Oligonychus pratensis; Araneida, e.g. Latrodectus mactans, and Loxos celes reclusa, fleas (Siphonaptera), e.g. Ctenocephalides felis, Ctenocephalides canis, Xenopsylla 30 cheopis, Pulex irritans, Tunga penetrans, and Nosopsyllus fasciatus, silverfish, firebrat (Thysanura), e.g. Lepisma saccharina and Thermobia domestica, centipedes (Chilopoda), e.g. Scutigera coleoptrata, 35 millipedes (Diplopoda), e.g. Narceus spp., Earwigs (Dermaptera), e.g. forficula auricularia, 81 lice (Phthiraptera), e.g. Pediculus humanus capitis, Pediculus humanus corporis, Pthi rus pubis, Haematopinus eurysternus, Haematopinus suis, Linognathus vituli, Bovicola bovis, Menopon gallinae, Menacanthus stramineus and Solenopotes capillatus, 5 plant parasitic nematodes such as root-knot nematodes, Meloidogyne arenaria, Meloi dogyne chitwoodi, Meloidogyne exigua, Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica and other Meloidogyne species; cyst nematodes, Globodera rostochiensis, Globodera pallida, Globodera tabacum and other Globodera species, Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii, and 10 other Heterodera species; seed gall nematodes, Anguina funesta, Anguina tritici and other Anguina species; stem and foliar nematodes, Aphelenchoides besseyi, Aphelen choides fragariae, Aphelenchoides ritzemabosi and other Aphelenchoides species; sting nematodes, Belonolaimus longicaudatus and other Belonolaimus species; pine nematodes, Bursaphelenchus xylophilus and other Bursaphelenchus species; ring ne 15 matodes, Criconema species, Criconemella species, Criconemoides species, and Me socriconema species; stem and bulb nematodes, Ditylenchus destructor, Ditylenchus dipsaci, Ditylenchus myceliophagus and other Ditylenchus species; awl nematodes, Dolichodorus species; spiral nematodes, Helicotylenchus dihystera, Helicotylenchus multicinctus and other Helicotylenchus species, Rotylenchus robustus and other Roty 20 lenchus species; sheath nematodes, Hemicycliophora species and Hemicriconemoides species; Hirshmanniella species; lance nematodes, Hoplolaimus columbus, Hoplolai mus galeatus and other Hoplolaimus species; false root-knot nematodes, Nacobbus aberrans and other Nacobbus species; needle nematodes, Longidorus elongates and other Longidorus species; pin nematodes, Paratylenchus species; lesion nematodes, 25 Pratylenchus brachyurus, Pratylenchus coffeae, Pratylenchus curvitatus, Pratylenchus goodeyi, Pratylencus neglectus, Pratylenchus penetrans, Pratylenchus scribneri, Praty lenchus vulnus, Pratylenchus zeae and other Pratylenchus species; Radinaphelenchus cocophilus and other Radinaphelenchus species; burrowing nematodes, Radopholus similis and other Radopholus species; reniform nematodes, Rotylenchulus reniformis 30 and other Rotylenchulus species; Scutellonema species; stubby root nematodes, Tri chodorus primitivus and other Trichodorus species; Paratrichodorus minor and other Paratrichodorus species; stunt nematodes, Tylenchorhynchus claytoni, Tylenchorhyn chus dubius and other Tylenchorhynchus species and Merlinius species; citrus nema todes, Tylenchulus semipenetrans and other Tylenchulus species; dagger nematodes, 35 Xiphinema americanum, Xiphinema index, Xiphinema diversicaudatum and other Xi phinema species; and other plant parasitic nematode species. Moreover, the inventive mixtures are especially useful for the control of Lepidoptera, Coleoptera, Diptera, Thysanoptera and Hymenoptera. 40 82 Moreover, the inventive mixtures are especially useful for the control of non-crop pests (household, turf, ornamental). The mixtures according to the invention can be applied to any and all developmental 5 stages of pests, such as egg, larva, pupa, and adult. The pests may be controlled by contacting the target pest, its food supply, habitat, breeding ground or its locus with a pesticidally effective amount of the inventive mixtures or of compositions comprising the mixtures. 10 "Locus" means a plant, seed, soil, area, material or environment in which a pest is growing or may grow. In general, "pesticidally effective amount" means the amount of the inventive mixtures or of compositions comprising the mixtures needed to achieve an observable effect on 15 growth, including the effects of necrosis, death, retardation, prevention, and removal, destruction, or otherwise diminishing the occurrence and activity of the target organism. The pesticidally effective amount can vary for the various mixtures / compositions used in the invention. A pesticidally effective amount of the mixtures / compositions will also vary according to the prevailing conditions such as desired pesticidal effect and dura 20 tion, weather, target species, locus, mode of application, and the like. The compound I and the compound IIA (or compound IIC) are usually applied in a weight ratio of from 500:1 to 1:100, preferabglyl:40 to 100:1, more preferably from 1:20 to 100:1, most preferably from 1:2 to 100:1, in particular from 10:1 to 1:10. 25 The compound I, the compound IIA and the compound IB (or compound IIC) are usu ally applied in a weight ratio of from 1:50:500 to 50:1:1, preferably 1:40:40 to 100:1:1, more preferably from 1:20:20 to 100:1:1, in particularfrom 1:2:2 to 100:1:1. The compound I, the compound IIA, the compound IB and the compound IB (or IID) are usually applied in a weight ratio of of from 1:40:40:40 to 100:1:1:1, more preferably 30 from 1:20:20:20 to 100:1:1:1, in particular from 1:2:2:2 to 100:1:1:1. The two fungicidal compound IIB and fungicidal compound IID are usually applied in a weight ratio of of from 1:200 to 200:1, more preferably from 1:100 to 100:1, in particular from 1:20 to 20:1. 35 The two fungicidal compounds selected from list B and the third fungicidal compound lID are usually applied in a weight ratio of of from 1.200:200 to 200:1:1, more prefera bly from 1:100:100 to 100:1:1, in particular froml0:20:20 to 20:1:1.

83 The compound I, compound IlIlA or other neonicotinid and the compound IB or com pound lID are usually applied in a weight ratio of of from 1:100:40 to 100:5:1 more preferably from 1:50:20 to 100:5:1, in particular from 1:10:2 to 100:10:1. 5 The compound I, compound IlIlA or other neonicotinoid and the compound IB and compound lID are usually applied in a weight ratio of of from 1:100:40 :40 to 100:5:1:1, more preferably from 1:50:20:20 to 100:5:1:1, in particular from 1:10:2:2 to 100:10:1:1. The compound I, compound IllB and the compound IB or compound lID are usually 10 applied in a weight ratio of from 1:20:40 to 100:1:1, more preferably from1:35:20 to 100:1:1, in particular from from1:5:20 to 100:1:1 . The compound I, compound IllB and the compound IB and compound lID are usually applied in a weight ratio of of from 1:20:40:40 to 100:1:1:1, more preferably from 15 1:35:20:20 to 100:5:1:1, in particular from1:5:2:2 to 100:1:1:1. When preparing the mixtures, it is preferred to employ the pure active compounds I and IIA (or IIC) and optionally one or more lB (and optionally Ill (e.g. IllB or IlIlA) and optionally lID), to which further active compounds against pests, such as insects, 20 arachnids or nematodes, or else herbicidal or growth-regulating active compounds or fertilizers can be added as further active components according to need. The inventive mixtures are employed by treating the fungi or the plants, seeds, materials or soil to be protected from fungal attack with a pesticidally effective amount 25 of the active compounds. The application can be carried out both before and after the infection of the materials, plants or seeds by the pests. In the method of combating harmful fungi depending on the type of compound and the desired effect, the application rates of the mixtures according to the invention are from 30 5 g/ha to 2000 g/ha, preferably from 50 to 900 g/ha, in particular from 50 to 750 g/ha. The inventive mixtures or compositions of these mixtures can also be employed for protecting plants from attack or infestation by insects, acarids or nematodes comprising contacting a plant, or soil or water in which the plant is growing. 35 In the context of the present invention, the term plant refers to an entire plant, a part of the plant or the propagation material of the plant, that is, the seed or the seedling. The treatment can be made into the seedbox before planting into the field. 40 84 Plants which can be treated with the inventive mixtures include all genetically modified plants or transgenic plants, e.g. crops which tolerate the action of herbicides or fungi cides or insecticides owing to breeding, including genetic engineering methods, or plants which have modified characteristics in comparison with existing plants, which 5 can be generated for example by traditional breeding methods and/or the generation of mutants, or by recombinant procedures. For example, mixtures according to the present invention can be applied to transgenic crops (as seed treatment, spray treatment, in furrow or by any other means) which are 10 resistant to herbicides from the group consisting of the sulfonylureas (EP-A-0257993, U.S. Pat. No. 5,013,659), imidazolinones (see for example US 6222100, W00182685, W00026390, W09741218, W09802526, W09802527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073), glufosinate-type (see for example EP-A-0242236, EP-A-242246) or glyphosate-type (see for example WO 15 92/00377) or in plants resistant towards herbicides selected from the group of cyclo hexadienone/Aryloxyphenoxypropionic acid herbicides (US 5,162,602 , US 5,290,696 , US 5,498,544, US 5,428,001 , US 6,069,298, US 6,268,550, US 6,146,867 , US 6,222,099 , US 6,414,222) or in transgenic crop plants, for example cotton, with the capability of producing Bacillus thuringiensis toxins (Bt toxins) which make the plants 20 resistant to certain pests (EP-A-0142924, EP-A-0193259). Furthermore, can be applied to transgenic crops (as seed treatment, spray treatment, in furrow or by any other means), which have modified characteristics in comparison with existing plants consist, which can be generated for example by traditional breeding 25 methods and/or the generation of mutants, or by recombinant procedures). For exam ple, a number of cases have been described of recombinant modifications of crop plants for the purpose of modifying the starch synthesized in the plants (e.g. WO 92/11376, WO 92/14827, WO 91/19806) or of transgenic crop plants having a modified fatty acid composition (WO 91/13972). 30 The inventive mixtures can therefore be used for the protection of the plant shoot against foliar pests as well as for the treatment of the seed and roots against soil pests, especially those mixtures having systemic action. The term seed treatment comprises all suitable seed treatment techniques known in the art, such as seed dressing, seed 35 coating, seed dusting, seed soaking and seed pelleting. The compounds I (optionally together with compound Ill, e.g. IlIlA or IIIB) and the one or more compound(s) II (selected from compound IIB, IC and lID depending on the mix ture employed) are usually applied in a weight ratio of from 100:1 to 1:100. 40 85 Depending on the desired effect, the application rates of the mixtures according to the invention are from 0,3 g/ha to 2000 g/ha.. The inventive mixtures are also suitable for the protection of the seed and the seed 5 lings' roots and shoots, preferably the seeds, against soil pests. Compositions, which are especially useful for seed treatment are e.g.: A Soluble concentrates (SL, LS) 10 D Emulsions (EW, EO, ES) E Suspensions (SC, OD, FS) F Water-dispersible granules and water-soluble granules (WG, SG) G Water-dispersible powders and water-soluble powders (WP, SP, WS) H Gel-Formulations (GF) 15 I Dustable powders (DP, DS) In the treatment of seed, the application rates of the inventive mixture are generally for the formulated product (which usually comprises from1O to 750 g/I of the active(s)) 0,00 1 Ito 1 1 per 100 kg of seed, dependent from the desired effect and the kind of 20 seed. Application rates are preferably from 0,011 to 1 1/100 kg of seed, more preferably from 0,1 to 0,75 1/100 kg. In a particular preferred embodiment, each insecticidal compound of the mixtures as defined above (compound I, the nicotinic receptor agonists/antagonists compound, the 25 anthranilamide compound) is generally applied from 1 to 500 g of active ingredient/100 kg seed. In a further particular preferred embodiment, each of the the fungicidal compound II (compound IID, IC, 1lB, IlA, depending on the mixture used) is generally applied from 1 30 g to 200 g of active ingredient/100 kg seed. The separate or joint application of the compounds I (and optionally the a nicotinic re ceptor agonists/antagonists compound or optionally the anthranilamide compound) and II or of the mixtures of the compounds I (and optionally the a nicotinic receptor ago 35 nists/antagonists compound or optionally the anthranilamide compound) and II is car ried out by spraying or dusting the seeds, the seedlings, the plants or the soils before or after sowing of the plants or before or after emergence of the plants. The invention also relates to the propagation products of plants, and especially the 40 seed comprising, that is, coated with and/or containing, a mixture as defined above or a composition containing the mixture of two or more active ingredients or a mixture of two 86 or more compositions each providing one of the active ingredients. The seed com prises the inventive mixtures in an amount of from 0.1 g to 10 kg per 100 kg of seed. The inventive mixtures are effective through both contact (via soil, glass, wall, bed net, 5 carpet, plant parts or animal parts), and ingestion (bait, or plant part) and through trophallaxis and transfer. Preferred application methods are into water bodies, via soil, cracks and crevices, pastures, manure piles, sewers, into water, on floor, wall, or by perimeter spray 10 application and bait. According to another preferred embodiment of the invention, for use against non crop pests such as ants, termites, wasps, flies, mosquitoes, crickets, locusts, or cock roaches the inventive mixtures are prepared into a bait preparation. 15 The bait can be a liquid, a solid or a semisolid preparation (e.g. a gel). The bait em ployed in the composition is a product which is sufficiently attractive to incite insects such as ants, termites, wasps, flies, mosquitoes, crickets etc. or cockroaches to eat it. This attractant may be chosen from feeding stimulants or para and / or sex phero 20 mones readily known in the art. Methods to control infectious diseases transmitted by insects (e.g. malaria, dengue and yellow fever, lymphatic filariasis, and leishmaniasis) with the inventive mixtures and their respective compositions also comprise treating surfaces of huts and houses, air 25 spraying and impregnation of curtains, tents, clothing items, bed nets, tsetse-fly trap or the like. Insecticidal compositions for application to fibers, fabric, knitgoods, non wovens, netting material or foils and tarpaulins preferably comprise a composition in cluding the inventive mixtures, optionally a repellent and at least one binder. 30 The inventive mixtures and the compositions comprising them can be used for protect ing wooden materials such as trees, board fences, sleepers, etc. and buildings such as houses, outhouses, factories, but also construction materials, furniture, leathers, fibers, vinyl articles, electric wires and cables etc. from ants and/or termites, and for control ling ants and termites from doing harm to crops or human being (e.g. when the pests 35 invade into houses and public facilities). In the case of soil treatment or of application to the pests dwelling place or nest, the quantity of active ingredient ranges from 0.0001 to 500 g per 100 M 2 , preferably from 0.001 to 20 g per 100 M 2 . 40 87 Customary application rates in the protection of materials are, for example, from 0.01 g to 1000 g of active compound per m 2 treated material, desirably from 0.1 g to 50 g per m 2 . 5 Insecticidal compositions for use in the impregnation of materials typically contain from 0.001 to 95 weight %, preferably from 0.1 to 45 weight %, and more preferably from 1 to 25 weight % of at least one repellent and / or insecticide. For use in bait compositions, the typical content of active ingredient is from 0.0001 10 weight % to 15 weight %, desirably from 0.001 weight % to 5% weight % of active compound. The composition used may also comprise other additives such as a solvent of the active material, a flavoring agent, a preserving agent, a dye or a bitter agent. Its attractiveness may also be enhanced by a special color, shape or texture. 15 For use in spray compositions, the content of the mixture of the active ingredients is from 0.00 1 to 80 weights %, preferably from 0.01 to 50 weight % and most preferably from 0.01 to 15 weight %. For use in treating crop plants, the rate of application of the mixture of the active ingre 20 dients of this invention may be in the range of 0.1 g to 4000 g per hectare, desirably from 25 g to 600 g per hectare, more desirably from 50 g to 500 g per hectare. It was also an object of the present invention to provide mixtures suitable for treating, controlling, preventing and protecting warm-blooded animals, including humans, and 25 fish against infestation and infection by pests. Problems that may be encountered with pest control on or in animals and/or humans are similar to those described at the out set, namely the need for reduced dosage rates, and / or enhanced spectrum of activity and / or combination of knock-down activity with prolonged control and / or resistance management. 30 This invention also provides a method for treating, controlling, preventing and protect ing warm-blooded animals, including humans, and fish against infestation and infection by pests of the orders Siphonaptera, Hymenoptera, Hemiptera, Orthoptera, Acarina, Phthiraptera, and Diptera, which comprises orally, topically or parenterally administer 35 ing or applying to said animals a pesticidally effective amount of mixtures according to the invention. The invention also provides a process for the preparation of a composition for treating, controlling, preventing or protecting a warm-blooded animal or a fish against infestation 40 or infection by pests of the Siphonaptera, Hymenoptera, Hemiptera, Orthoptera, 88 Acarina, Phthiraptera, and Diptera orders which comprises a pesticidally effective amount of a mixture according to the invention. The above method is particularly useful for controlling and preventing infestations and 5 infections in warm-blooded animals such as cattle, sheep, swine, camels, deer, horses, poultry, goats, dogs and cats as well as humans. Infestations in warm-blooded animals and fish including, but not limited to, lice, biting lice, ticks, nasal bots, keds, biting flies, muscoid flies, flies, myiasitic fly larvae, chig 10 gers, gnats, mosquitoes and fleas may be controlled, prevented or eliminated by the mixtures according to the invention. For oral administration to warm-blooded animals, the mixtures according to the inven tion may be formulated as animal feeds, animal feed premixes, animal feed concen 15 trates, pills, solutions, pastes, suspensions, drenches, gels, tablets, boluses and cap sules. In addition, the mixtures according to the invention may be administered to the animals in their drinking water. For oral administration, the dosage form chosen should provide the animal with 0.01 mg/kg to 100 mg/kg of animal body weight per day of the mixture. 20 Alternatively, the mixtures according to the invention may be administered to animals parenterally, for example, by intraruminal, intramuscular, intravenous or subcutaneous injection. The mixtures according to the invention may be dispersed or dissolved in a physiologically acceptable carrier for subcutaneous injection. Alternatively, the mixtures 25 according to the invention may be formulated into an implant for subcutaneous admini stration. In addition the mixtures according to the invention may be transdermally ad ministered to animals. For parenteral administration, the dosage form chosen should provide the animal with 0.01 mg/kg to 100 mg/kg of animal body weight per day of the mixture. 30 The mixtures according to the invention may also be applied topically to the animals in the form of dips, dusts, powders, collars, medallions, sprays, spot-on and pour-on for mulations. For topical application, dips and sprays usually contain 0,5 ppm to 5,000 ppm and preferably 1 ppm to 3000 ppm of the inventive compounds. In addition, the 35 mixtures according to the invention may be formulated as ear tags for animals, particu larly quadrupeds such as cattle and sheep. 40 89 Biological Examples 1) Fungicidal action 5 The fungicidal effect of the compound and the mixtures could be demonstrated by the following tests: The active compounds, separately or jointly, were prepared as a stock solution comprising 0.25% by weight of active compound in acetone or DMSO. 1 % by weight of 10 the emulsifier Uniperol@ EL (wetting agent having emulsifying and dispersant action based on ethoxylated alkylphenols) was added to this solution, and the mixture was diluted with water to the desired concentration. The visually determined percentages of infected leaf areas were converted into 15 efficacies in % of the untreated control: The efficacy (E) is calculated as follows using Abbot's formula: E = (1 - up ) 100 20 a corresponds to the fungicidal infection of the treated plants in % and P corresponds to the fungicidal infection of the untreated (control) plants in % An efficacy of 0 means that the infection level of the treated plants corresponds to that 25 of the untreated control plants; an efficacy of 100 means that the treated plants were not infected. The expected efficacies of mixtures of active compounds were determined using Colby's formula (Colby, S.R. "Calculating synergistic and antagonistic responses of 30 herbicide Combinations", Weeds, 15, 20-22, 1967) and compared with the observed efficacies. Colby's formula: E = x + y - x-y/100 35 E expected efficacy, expressed in % of the untreated control, when using the mixture of the active compounds A and B at the concentrations a and b x efficacy, expressed in % of the untreated control, when using the active compound A at the concentration a 40 y efficacy, expressed in % of the untreated control, when using the active compound B at the concentration b 90 Use example 1 - Fungicidal control of brown spot caused by Cochliobolus miyabeanus (protective) Leaves of pot-grown rice seedlings were sprayed to run-off with an aqueous suspension, 5 containing the concentration of active ingredient as described below prepared from the stock solution. The plants were allowed to air-dry. At the following day the plants were inoculated with an aqueous spore suspension of Cochliobolus miyabeanus. Then the trial plants were immediately transferred to a humid chamber. After 6 days at 22-240C and a relative humidity close to 100 % the extent of fungal attack on the leaves was visually 10 assessed as % diseased leaf area. The test results show that, by virtue of strong synergism, the activity of the mixtures according to the invention is considerably higher than had been predicted using Colby's formula. 15 2) Action against animal pests The following tests demonstrate the control efficacy of compounds, mixtures or compo sitions of this invention on specific pests. However, the pest control protection afforded 20 by the compounds, mixtures or compositions is not limited to these species. In certain instances, combinations of a compound of this invention with other invertebrate pest control compounds or agents are found to exhibit synergistic effects against certain important invertebrate pests. 25 The analysis of synergism or antagonism between the mixtures or compositions is de termined using Colby's equation. Use example 2 For evaluating control of vetch aphid (Megoura viciae) through contact or systemic 30 means the test unit consists of 24-well-microtiter plates containing broad bean leaf disks. The compounds or mixtures are formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures are 35 sprayed onto the leaf disks at 2.5pl, using a custom built micro atomizer, at two replica tions. For experimental mixtures in these tests identical volumes of both mixing partners at the desired concentrations respectively, are mixed together. 40 After application, the leaf disks are air-dried and 5 - 8 adult aphids placed on the leaf disks inside the microtiter plate wells. The aphids are then allowed to suck on the 91 treated leaf disks and incubated at 23 ±1 C, 50 ± 5 % RH (room humidity) for 5 days. Aphid mortality and fecundity is visually assessed. Use example 3 5 For evaluating control of boll weevil (Anthonomus grandis) the test unit consists of 24 well-microtiter plates containing an insect diet and 20-30 A. grandis eggs. The compounds or mixtures are formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures are 10 sprayed onto the insect diet at 20pl, using a custom built micro atomizer, at two replica tions. For experimental mixtures in these tests identical volumes of both mixing partners at the desired concentrations respectively, are mixed together. 15 After application, microtiter plates are incubated at 23 ±1 C, 50 ± 5 % RH for 5 days. Egg and larval mortality is visually assessed. Use example 4 For evaluating control of Mediterranean fruitfly (Ceratitis capitata) the test unit consists 20 of 96-well-microtiter plates containing an insect diet and 50-80 C. capitata eggs. The compounds or mixtures are formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures are sprayed onto the insect diet at 5pl, using a custom built micro atomizer, at two replica 25 tions. For experimental mixtures in these tests identical volumes of both mixing partners at the desired concentrations respectively, are mixed together. After application, microtiter plates are incubated at 28 ±1 C, 80 ± 5 % RH for 5 days. 30 Egg and larval mortality is visually assessed. Use example 5 For evaluating control of tobacco budworm (Heliothis virescens) the test unit consists of 96-well-microtiter plates containing an insect diet and 15-25 H. virescens eggs. 35 The compounds or mixtures are formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures are sprayed onto the insect diet at 1 Opl, using a custom built micro atomizer, at two replica tions. 40 For experimental mixtures in these tests identical volumes of both mixing partners at the desired concentrations respectively, are mixed together.

92 After application, microtiter plates are incubated at 28 ±1 C, 80 ± 5 % RH for 5 days. Egg and larval mortality is visually assessed. In the following examples 6 and 7, the active ingredients were formulated separately as 5 stock solutions at a concentration of 10 000 ppm in DMSO. The active ingredient pyra clostrobin was employed as a commercially available formulation. Use example No. 6 - Activity against the causative agent of gray mold Botrytis cinerea in the microtiter test (Botrci) 10 The stock solution was pipetted into a microtiter plate (MTP) and diluted to the stated active ingredient concentration with an aqueous malt-based medium for fungi. An aqueous spore suspension of Botrytis cinerea was subsequently added. The plates were placed into a water-vapor-saturated chamber at temperatures of 18'C. On day 7 post-inoculation, the MTPs were measured at 405 nm using an absorption photometer. 15 The parameters measured were related to the growth of the control variant, which was free from active ingredients, and the blank, which was free from fungi and active ingre dients, in order to determine the relative growth % of the pathogens in the individual active ingredients. 20 The visually determined data for the affected leaf area in % was first averaged and then converted into efficacies as % of the untreated control. An efficacy of 0 is the same disease level as in the untreated control, an efficacy of 100 is 0% disease level. The expected efficacies for active ingredient combinations were determined using 25 Colby' s formula (Colby, S. R. (Calculating synergistic and antagonistic responses of herbicide Combinations", Weeds, 15, pp. 20-22, 1967) and compared with the observed efficacies. Active ingredient/a.i. Concentration Ratio Observed Activity cal- Synergistic combination (ppm) activity culated us- effect in (%) (%) ing Colby' s formula (%) pyraclostrobin 0.016 4 triticonazole + thi ophanate-methyl 0.063+0.25 12 pyraclostrobin 0.016+0.063+0.25 1:4:16 35 15 20 triticonazole + thi ophanate-methyl 93 Use example No. 7 - Activity against the causative agent of rice blast disease Pyricu laria oryzae in the microtiter test (Pyrior) 5 The stock solution was pipetted into a microtiter plate (MTP) and diluted to the stated active ingredient concentration with an aqueous malt-based medium for fungi. An aqueous spore suspension of Pyricularia oryzae was subsequently added. The plates were placed into a water-vapor-saturated chamber at temperatures of 18'C. On day 7 post-inoculation, the MTPs were measured at 405 nm using an absorption photometer. 10 The parameters measured were related to the growth of the control variant, which was free from active ingredients, and the blank, which was free from fungi and active ingre dients, in order to determine the relative growth % of the pathogens in the individual active ingredients. 15 The visually determined data for the affected leaf area in % was first averaged and then converted into efficacies as % of the untreated control. An efficacy of 0 is the same disease level as in the untreated control, an efficacy of 100 is 0% disease level. The expected efficacies for active ingredient combinations were determined using 20 Colby' s formula (Colby, S. R. (Calculating synergistic and antagonistic responses of herbicide Combinations", Weeds, 15, pp. 20-22, 1967) and compared with the observed efficacies. Active ingredient/a.i. Concentration Ratio Observed Activity cal- Synergistic combination (ppm) activity culated effect in (%) (%) using Colby' s formula (%) pyraclostrobin 0.001 31 triticonazole + thi ophanate-methyl 0.004+0.016 5 pyraclostrobin 0.001+0.004+0.016 1:4:16 60 35 25 triticonazole + thi ophanate-methyl 25 Use example No. 8 - Activity against the causative agent of rice blast disease Pyricu laria oryzae in the microtiter test (Pyrior) The active ingredients were formulated separately as stock solutions at a concentration of 10 000 ppm in DMSO.

94 The stock solution was pipetted into a microtiter plate (MTP) and diluted to the stated active ingredient concentration with an aqueous malt-based medium for fungi. An aqueous spore suspension of Pyricularia oryzae was subsequently added. The plates were placed into a water-vapor-saturated chamber at temperatures of 180C. On day 7 5 post-inoculation, the MTPs were measured at 405 nm using an absorption photometer. The parameters measured were related to the growth of the control variant, which was free from active ingredients, and the blank, which was free from fungi and active ingredients, in order to determine the relative growth % of the pathogens in the individual 10 active ingredients. The visually determined data for the affected leaf area in % was first averaged and then converted into efficacies as % of the untreated control. An efficacy of 0 is the same disease level as in the untreated control; an efficacy of 100 is 0% disease level. The 15 expected efficacies for active ingredient combinations were determined using Colby's formula (Colby, S. R. (Calculating synergistic and antagonistic responses of herbicide Combinations", Weeds, 15, pp. 20-22, 1967) and compared with the observed efficacies. Active ingredient/a.i. Concentration Ratio Observed Activity Synergistic combination (ppm) activity calculated effect in (%) using (%) Colby's formula (%) triticonazole + 2+2 22 clothianidin fipronil 2 5 triticonazole + 222 111 6 63 cloth ianidin + fipronil 2+2+2 1:1:1 61 26 35 20 Comparative Example No. 1 Synergistic activity of claimed mixtures against harmful fungi The active compounds were formulated separately as a stock solution having a 25 concentration of 10000 ppm in dimethyl sulfoxide.

95 1. Activity against snow mould caused by Microdochium nivale (Micniv) The stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations. A spore suspension of Microdochium nivale in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added. The plates were placed in a water vapor-saturated chamber at a temperature of 180C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation. The measured parameters were compared to the growth of the active compound-free control variant (100%) and the fungus-free and active compound-free blank value to determine the relative growth in % of the pathogens in the respective active compounds. These percentages were converted into efficacies. The expected efficacies of active compound mixtures were determined using Colby's formula [R.S. Colby, "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, 20-22 (1967)] and compared with the observed efficacies. As a general rule the comparison of the expected degree of action ("E" according to the Colby formula) with the degree of action found shows whether the effect is synergistic or not, the correlation being as follows: degree of action found > "E" -> synergism degree of action found < "E" -> no synergism The test results are listed in the following tables: Observed Compound Concentration [ppm] efficacy [%] 0.016 0 Fipronil llA carboxamide N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoro- 0.25 15 methyl-1-methyl-1 H-pyrazole-4-carboxylic acid amide 96 Mixture according to the I Calculated efficacy invention Observed efficacy [%] [%] (Colby) Concentration [ppm] I + IIA 0.016 + 0.25 ppm 45 15 ratio 1 : 16 2. Activity against rice blast Pyricularia oryzae in the microtiterplate test (Pyrior) The stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations. A spore suspension of Pyricularia oryzae in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added. The plates were placed in a water vapor-saturated chamber at a temperature of 180C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation. The assessment and calculation was made as discussed above. The test results are listed in the following tables: Compound Concentration [ppm] Observed efficacy [%] 0.063 0 Fipronil IIA carboxamide N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5- 0.063 0 fluoro-1 H-pyrazole-4-carboxylic acid amide 11B strobilurin 0.063 24 Trifloxystrobin Mixture according to the I Calculated efficacy invention Observed efficacy [%] [%] (Colby) Concentration [ppm] I + IIA + 11B 0.063 + 0.063 + 0.063 ppm 48 24 ratio 1 : 1 : 1 97 3. Activity against leaf blotch on wheat caused by Septoria tritici (Septtr) The stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations. A spore suspension of Septoria tritici in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added. The plates were placed in a water vapor-saturated chamber at a temperature of 180C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation. The assessment and calculation was made as discussed above. The test results are listed in the following tables: Observed Compound Concentration [ppm] efficacy 0.25 0 0.063 2 Fipronil 0.004 llA 0.063 55 Penthiopyrad IIA 0.063 28 Prochloraz llA IA4 17 Thiabendazole llA 0.063 53 Picoxystrobin IIA 0.016 55 Trifloxystrobin 0.004 26 IIB 0.016 22 Prothioconazole llB 0.016 4 Penflufen insecticidal compound 16 0 Chloranthraniliprole (p. 63, 1. 25) 98 Mixture according to the invention Observed ffi Calculated efficacy Concentration [ppm] [%] (Colby) I + IIA Picoxystrobin 0.063 + 0.063 76 53 1:1 1 1 + IIA Trifloxystrobin 0.004 + 0.004 52 26 1 : 1 1 + IIA Prochloraz 0.063 + 0.063 49 29 I + IIA Thiabendazole 0.25+4 34 17 1 : 16 1 + IIA Trifloxystrobin + 11B Penflufen 0.063 + 0.016 + 0.016 79 58 4 :1:1 1 + IIA Penthiopyrad + insecticidal compound Chloranthraniliprole 79 55 0.063 + 0.063 + 16 1 : 1 : 250 4. Activity against anthracnose disease caused by Colletotrichum truncatum (Colldu) The stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations. A spore suspension of Colletotrichum truncatum in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added. The plates were placed in a water vapor-saturated chamber at a temperature of 180C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation. The assessment and calculation was made as discussed above.

99 The test results are listed in the following tables: Compound Concentration [ppm] Observed efficacy [%] 0.25 4 Fipronil llA 0.063 37 Prochloraz Mixture according to the I Calculated efficacy invention Observed efficacy [%] [%] (Colby) Concentration [ppm] I + lIIA 0.25 + 0.063 ppm 73 39 ratio 4 : 1 Comparative Example No. 2 Synergistic activity of claimed mixtures against harmful fungi The active compounds were formulated separately as a stock solution having a concentration of 10000 ppm in dimethyl sulfoxide. 1. Activity against snow mould caused by Microdochium nivale (Micniv) The stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations. A spore suspension of Microdochium nivale in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added. The plates were placed in a water vapor-saturated chamber at a temperature of 180C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation. The measured parameters were compared to the growth of the active compound-free control variant (100%) and the fungus-free and active compound-free blank value to determine the relative growth in % of the pathogens in the respective active compounds. These percentages were converted into efficacies. The expected efficacies of active compound mixtures were determined using Colby's formula [R.S. Colby, "Calculating synergistic and antagonistic responses of herbicide 100 combinations", Weeds 15, 20-22 (1967)] and compared with the observed efficacies. Again, as a general rule the comparison of the expected degree of action ("E" according to the Colby formula) with the degree of action found shows whether the effect is synergistic or not, the correlation being as follows: degree of action found > "E" -> synergism degree of action found < "E" => no synergism The test results are listed in the following tables: Observed Compound Concentration [ppm] efic[ efficacy [%] 0.016 0 Fipronil llA strobilurin 0.063 75 Trifloxystrobin llB azoles 0.063 2 Prothioconazole Mixture according to the I Calculated efficacy invention Observed efficacy [%] [%] (Colby) Concentration [ppm] I + IIA + llB 0.016 + 0.063 + 0.063 ppm 99 77 ratio 4 : 1 : 1 2. Activity against rice blast Pyricularia oryzae in the microtiterplate test (Pyrior) The stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations. A spore suspension of Pyricularia oryzae in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added. The plates were placed in a water vapor-saturated chamber at a temperature of 180C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation. The assessment and calculation was made as discussed above.

101 The test results are listed in the following tables: Observed Compound Concentration [ppm] efic[ efficacy [%] 1 0 Fipronil 0.063 1 IIA.1 strobilurin 0.063 75 Trifloxystrobin IIA.2 carboxamide N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoro 0.25 5 methyl-1-methyl-1 H-pyrazole-4-carboxylic acid amide (Sedaxane) IIB.1 azole 0.063 2 Prothioconazole llB.2 carboxamide 0.063 0 Penthiopyrad IIB.3 heterocyclic compound 0.063 10 Fludioxonil Mixture according to the Calculated efficacy invention Observed efficacy [%] [%] (Colby) Concentration [ppm] I + IIA.1 + llB.1 0.016 + 0.063 + 0.063 ppm 70 25 ratio 4 : 1 : 1 1 + IIA.2 + llB.2 1 + 0.25 + 0.063 ppm 28 5 ratio 16 : 4: 1 1 + IIA.2 + llB.3 1 + 0.25 + 0.063 ppm 43 14 ratio 16 : 4: 1 1 + IIA.2 + llB.3 0.063 + 0.25 + 0.063 ppm 55 15 ratio 1 : 4 : 1 102 3. Activity against early blight caused by Alternaria solani (Alteso) The stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations. A spore suspension of Alternaria solani in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added. The plates were placed in a water vapor-saturated chamber at a temperature of 180C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation. The assessment and calculation was made as discussed above. The test results are listed in the following tables: Observed Compound Concentration [ppm] efficacy 1 0 0.25 0 Fipronil 0.016 5 IIA.1 carboxamide N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoro- 0.063 6 methyl-1-methyl-1 H-pyrazole-4-carboxylic acid amide (Sedaxane) IIA.2 heterocyclic compound 0.016 6 Fludioxonil llB 0.016 26 Penthiopyrad Mixture according to the invention Observed efficacy [ Calculated efficacy Concentration [ppm] [%] (Colby) I + 11A.1 + 11B 0.25 + 0.063 + 0.016 60 31 16 : 4 :1 I + IIA.2 1 +0.016 24 6 63 : 1 103 4. Activity against net blotch Pyrenophora teres on barley in the microtiter test (Pyrnte) The stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations. A spore suspension of Pyrenophora teres in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added. The plates were placed in a water vapor-saturated chamber at a temperature of 180C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation. The assessment and calculation was made as discussed above. The test results are listed in the following tables: Compound Concentration [ppm] Observed efficacy [%] 1 3 0.063 0 Fipronil 0.016 0 11A.1 carboxamide 0.063 3 Sedaxane IIA.2 heterocyclic compound 0.016 28 Fludioxonil 11B carboxamide 0.016 24 Penthiopyrad Mixture according to the Observed efficacy [%] Calculated efficacy invention [%] (Colby) Concentration [ppm] I + 11A.1 1 + 0.063 ppm 27 7 ratio 16 : 1 1 + IIA.2 1 + 0.016 ppm 53 30 ratio 63 : 1 1 + 11A.1 + 11B 0.063 + 0.063 + 0.016 ppm 46 26 ratio 4 : 4 : 1 104 Mixture according to the Calculated efficacy Observed efficacy [%][%(Cly invention [%] (Colby) Concentration [ppm] I + IIA.1 + 11B 0.016 + 0.063 + 0.016 ppm 45 26 ratio 1 : 4 : 1 Comprises/comprising and grammatical variations thereof when used in this specification are to be taken to specify the presence of stated features, integers, steps or components or groups thereof, but do not preclude the presence or addition of one or more other features, integers, steps, components or groups thereof.

Claims

1. Mixtures comprising, as active components, 5 1) an insecticidal compound I selected from fipronil and ethiprole; and 2) a fungicidal compound IIA selected from List A: 10 a) azoles, in particular: difenoconazole, bitertanole, bromuconazole, dinicon azole, enilconazole, fenbuconazole, flusilazole, fluquinconazole, flutriafol, imibenconazole, ipconazole, myclobutanil, paclobutrazol, penconazole, simeconazole, tetraconazole, uniconazole-P, triadimenol, triadimefon, triti 15 conazole, cyazofamid, pefurazoate, benomyl, carbendazim, fuberidazole, thiabendazole, ethaboxam, etridiazole and hymexazole; b) strobilurins, in particular: azoxystrobin, dimoxystrobin, enestroburin, fluoxa strobin, kresoxim-methyl, metominostrobin, picoxystrobin, trifloxystrobin, or 20 methyl (2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1 -(6-methylpyrid in-2-yl methoxyimino)ethyl]benzyl)carbamate, methyl 2-(ortho-((2,5-d imethylphe nyloxymethylene)phenyl)-3-methoxyacrylate; 25 c) carboxamides, in particular: carboxin, benalaxyl, boscalid, fenhexamid, flu tolanil, furametpyr, mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil, N-(4'-bromobiphenyl-2-yl)

4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4'-trifluoromethylbi phenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4'-chloro 30 3'-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N (3',4'-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1 -methylpyrazole-4 carboxamide, N-(2'-fluoro-4'-chloro-5'-methyl-biphenyl-2-yl)-1 -methyl-3 trifluoro-methyl-1 H-pyrazole-4-carboxamide, N-(3',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3',4',5' 35 trifluorobiphenyl-2-yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4 carboxamide, N-(2',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3-d ifluoromethyl 1 H-pyrazole-4-carboxamide, N-(3',4',5'-trifluorobiphenyl-2-yl)-3 chlorofluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide, N-(3',4'-dichloro 4-fluorobiphenyl-2-yl)-3-d ifl uoro-methyl-1 -methyl-pyrazole-4-carboxamide, 40 N-(3',4'-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1 -methylpyrazole 4-carboxamide, N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5-fluoro-1 H pyrazole-4-carboxylic acid amide, N-(cis-2-bicyclopropyl-2-yl-phenyl)-3- 106 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxylic acid amide, N-(trans-2 bicyclopropyl-2-yl-phenyl)-3-d ifl uoro-methyl-1 -methyl-1 H-pyrazole-4 carboxylic acid amide, 3-(difluoromethyl)-1-methyl-N-[1,2,3,4-tetrahydro-9 (1 -methylethyl)-1,4-methanonaphthalen-5-yl]-1 H-pyrazole-4carboxamide, 5 N-(3',4'-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1 -methylpyrazole-4 carboxamide; 3,4-dichloro-N-(2-cyanophenyl)isothiazol-5-carboxamide; N (2',4'-difluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide; N-(2',4'-dichloro-biphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H pyrazole-4-carboxamide; N-(2',4'-difluorobiphenyl-2-yl)-3-difluoromethyl-1 10 methyl-1 H-pyrazole-4-carboxamide; N-(2',4'-dichlorobiphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2',5' difluorobiphenyl-2-yl)-i -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide; N-(2',5'-dichlorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H pyrazole-4-carboxamide; N-(2',5'-difluorobiphenyl-2-yl)-3-difluoromethyl-1 15 methyl-1 H-pyrazole-4-carboxamide; N-(2',5'-dichlorobiphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(3',5' difluorobiphenyl-2-yl)-i -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide; N-(3',5'-dichlorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H pyrazole-4-carboxamide, N-(3',5'-difluorobiphenyl-2-yl)-3-difluoromethyl-1 20 methyl-1 H-pyrazole-4-carboxamide; N-(3',5'-dichlorobiphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole- 4-carboxamide; N-(3'-fluorobiphenyl 2-yl)-i -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3' chlorobiphenyl-2-yl)-i -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3'-fluorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4 25 carboxamide, N-(3'-chlorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H pyrazole-4-carboxamide; N-(2'-fluorobiphenyl-2-yl)-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2'-chlorobiphenyl-2-yl)-i methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2'-fluorobiphenyl 2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2' 30 chlorbi phenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide; N-(2'-fluoro-4'-chloro-5'-methylbiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H pyrazole-4-carboxamide; N-(3',4',5'-trifluorobiphenyl-2-yl)-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3',4',5'-trifluorobiphenyl-2 yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide; N-(2',4',5' 35 trifluorobiphenyl-2-yl)-i -methyl-3-difluoromethyl-1 H-pyrazole-4 carboxamide; N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3 hexafluoropropoxy)phenyl]-i -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide; N-[2-(1,1,2,3,3,3-hexafluoropropoxy)-phenyl]-3 40 difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-[2-(2-chloro-1,1,2 trifluoroethoxy)phenyl]-i -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide; N-[2-(2-chlor-1,1,2-trifluoroethoxy)phenyl]- 3-difluoromethyl- 107 1-methyl-1 H-pyrazole-4-carboxamide; 4-carbonsaure-N-[2-(1,1,2,2 tetrafl uoroethoxy)phenyl]-3-difluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide; N-[2-(1,1,2,2-tetrafluoroethoxy)phenyl]-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(4' 5 (trifluoromethylthio)biphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4 carboxamide; N-(4'-(trifluoromethylthio)biphenyl-2-yl)-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide; flumorph; flumetover, fluopicolide (picobenzamid), zoxamide; 10 carpropamid, diclocymet, mandipropamid; N-(2-{4-[3-(4-chlorophenyl) prop-2-ynyloxy]-3-methoxyphenyl}ethyl)-2 methanesulfonylamino-3-methylbutyramide, N-(2-{4-[3-(4-chlorophenyl) prop-2-ynyloxy]-3-methoxyphenyl}ethyl)-2-ethanesulfonylamino-3-methyl butyramide; 15 d) heterocylic compounds, in particular: fluazinam, pyrifenox; bupirimate, cyprodinil, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil; triforine; 20 fenpiclonil, fludioxonil;, iprodione, procymidone, vinclozolin; famoxadone, fenamidone, octhilinone, probenazole; amisulbrom, anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole; 2-butoxy-6-iodo-3-propylchromen-4-one; 25 acibenzolar-S-methyl, captafol, captan, dazomet, folpet, fenoxanil, quin oxyfen; 3-[5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3-yl]pyridine; e) carbamates, in particular: propineb; diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb; 30 methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methyl butyrylamino)propanoate; and f) other active compounds, selected from 35 guanidines: dodine, iminoctadine, guazatine; antibiotics: kasugamycin, streptomycin, polyoxine, validamycin A; nitrophenyl derivates: binapacryl, dinocap, dinobuton; sulfur-containing heterocyclyl compounds: dithianon, isoprothiolane; organometal compounds: fentin salts, such as fentin-acetate; 40 organophosphorus compounds: edifenphos, iprobenfos, fosetyl, fosetyl aluminum, phosphorous acid and its salts, pyrazophos, tolclofos-methyl; organochlorine compounds: chlorothalonil, dichlofluanid, flusulfamide, 108 hexachlorobenzene, phthalide, pencycuron, quintozene, thiophanate methyl, tolylfluanid; inorganic active compounds: Bordeaux mixture, copper acetate, copper hy droxide, copper oxychloride, sulfur; 5 others: cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, metrafenone and spiroxamine; 2. Mixtures according to claim 1 additionally comprising as active components one or two fungicidal compounds lB selected from List B which is defined as List 10 A plus triticonazole, orysastrobin, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6 trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, 6-(3,4-d ichloro-phenyl)-5-methyl [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6-(4-tert-butylphenyl)-5-methyl [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-methyl-6-(3,5,5-trimethyl-hexyl) [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-methyl-6-octyl-[1,2,4]triazolo[1,5 15 a]pyrimidine-7-ylamine, 6-methyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-yl amine, 6-ethyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-ethyl-6-octyl [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5-ethyl-6-(3,5,5-trimethyl-hexyl) [1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 6-octyl-5-propyl-[1,2,4]triazolo[1,5 a]pyrimidine-7-ylamine, 5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidine 20 7-ylamine, 6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-ylamine, 5 trifluoromethyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4]triazolo[1,5-a]pyrimidine-7 ylamine,cyproconazole, epoxiconazole, hexaconazole, metconazole, propicona zole, tebuconazole, imazalil, prochloraz, triflumizol, dimethomorph, aldimorph, dodemorph, fenpropimorph, tridemorph; fenpropidin, mancozeb, maneb, metam, 25 metiram, ferbam, thiram, zineb, ziram and basic copper sulfate; in synergistically effective amounts. with the proviso that the combination of compound IIA and compounds lB is not: 30 metalaxyl, fludioxonil and difenoconazole; metalaxyl-M, fludioxonil and difeno conazole; fludioxonil, metalaxyl and azoxystrobin; fludioxonil, metalaxyl and pi coxystrobin; fludioxonil, metalaxyl; trifloxystrobin; fludioxonil, metalaxyl and kresoxim-methyl; and fludioxonil and propiconazole. 35 3. The mixture according to claim 1, comprising as insecticidal compound I fipronil. 4. The mixture according to any of claims 1, 2 or 3, comprising as compound IIA an active compound selected from azoxystrobin, trifloxystrobin, dimoxystrobin, enestroburin, and metominostrobin. 40

5. The mixture according to any of claims 1, 2 or 3, comprising as compound IIA prochloraz. 109

6. The mixture according to any of claims 1, 2 or 3, comprising as compound IIA metalaxyl. 5 7. The mixture according to any of claims 1, 2 or 3, comprising as compound IIA thiram.

8. The mixture according to any of claims 1, 2 or 3, comprising as compound IIA thiophanate-methyl. 10

9. The mixture according to any of claims 1, 2 or 3, comprising as compound IIA boscalid.

10. The mixture according to any of claims 1 to 8, comprising as compound IIA 15 prothioconazole, difenoconazole, flutriafol, triadimenol, fludioxonil or mefenoxam.

11. The mixture according to any of claims 1 to 10, comprising as compound IB triti conazole. 20

12. The mixture according to any of claims 1 to 10, comprising as compound IB ory sastrobin.

13. The mixture according to any of claims 1 to 10, comprising as compound IB tebu 25 conazole, cyproconazole, prochloraz or thiram.

14. A quaternary mixture according to any of claims 1 to 13, comprising compound I, compound IA, two active compounds llB. 30 15. A quaternary mixture according to any of claims 1 to 13, comprising compound I, compound IIA, compound IIB, and active compound lID selected from List D, which is defined as List B plus pyracolostrobin.

16. A mixture according to any of claims 1 to 15, further comprising an insecticidal 35 compound.

17. A mixture according to claim 16, wherein the insecticidal compound is selected from the pyrethroids, especially alpha-cypermethrin and nicotinic receptor ago nists/antagonists compounds. 40

18. A mixture comprising, as active components 110 (1) an insecticidal compound I selected from fipronil and ethiprole; (2) a nicotinic receptor agonists/antagonists compound IlIlA or an anthranilia mide compound IllB; (3) and compound IB and/or compound lID selected from List D, which is de 5 fined as List B plus pyracolostrobin. in synergistically effective amounts.

19. Fungicidal Mixture comprising fungicidal compound IB as defined in claim 1 and 10 fungicidal compound lID selected from List D, which is defined as List B plus pyracolostrobin in synergistically effective amounts.

20. Fungicidal synergistic mixtures according to claim 19 additionally comprising a third fungicidal compound IB selected from List B, as defined in claim 1. 15

21. Fungicidal mixture according to claim 20, consisting of clothianidin prochloraz, triticonazole and pyracolostrobin.

22. Fungicidal mixture according to claim 20, consisting of clothianidin, thiophanate 20 methyl, triticonazole and pyracolostrobin.

23. Fungicidal mixture according to claim 20 consisting of clothianidin, boscalid, metalxyl and pyracolostrobin. 25 24. A pesticidal composition, comprising a liquid or solid carrier and a mixture as de fined in any of claims 1 to 23.

25. A method for controlling phytopathogenic harmful fungi, wherein the fungi, their habitat or the plants to be protected against fungal attack, the soil or seed are 30 treated with an effective amount of a mixture as defined in any of claims 1 to 23.

26. A method for controlling insects, arachnids or nematodes comprising contacting an insect, acarid or nematode or their food supply, habitat, breeding grounds or their locus with a mixture as defined in any of claims 1 to 18 in pesticidally effec 35 tive amounts.

27. A method for protecting plants from attack or infestation by insects, acarids or nematodes comprising contacting the plant, or the soil or water in which the plant is growing, with a mixture as defined in any of claims 1 to 18 in pesticidally effec 40 tive amounts. 111

28. A method as claimed in claims 26 or 27, wherein the mixture as defined in any of claims 1 to 20 is applied in an amount of from 5 g/ha to 2000 g/ha.

29. A method for protection of seed comprising contacting the seeds with a mixture as 5 defined in any of claims 1 to 23 in pesticidally effective amounts.

30. A method as claimed in claim 29 wherein the mixture as defined in any of claims 1 to 23 is applied in an amount of from 0.01 g to 10 kg per 100 kg of seeds. 10 31. Seed, comprising the mixture as defined in any of claims 1 to 23 in an amount of from 0.1 g to 10 kg per 100 kg of seeds.

32. A method as claimed in claims 25 to 30 wherein a) the compounds I and compounds IA and compounds llB; 15 b) or compound I, compounds IlA, llB and IID; or c) one or two compound(s) IIB and compound IID; or d) compound I, compound IlIlA or compound IllB and compound IlB and/or com pound IID; as defined in any of claims 1 to 13 are applied simultaneously, that is jointly or 20 separately, or in succession.

33. The mixture according to any of claims 1 to 17, comprising the compound I and the compound IIA in a weight ratio of from 100:1 to 1:100. 25 34. The mixture according to any of claims 1 to 17, comprising the compound I, the compound IIA and the compound IlB in a weight ratio of from 1:50:500 to 50:1:1.

35. Method for controlling pests or increasing the health of plants using mixtures of a compound I as defined in claim 1or 2 with an active compound IIC, wherein com 30 pounds IC are selected from List C: cyproconazole, epoxiconazole, hexacona zole, metconazole, propiconazole, tebuconazole, imazalil, prochloraz, triflumizol, dimethomorph, aldimorph, dodemorph, fenpropimorph, tridemorph; fenpropidin, mancozeb, maneb, metam, metiram, ferbam, thiram, zineb, ziram and basic cop per sulfate.