AU2014100870A4 - Transparent, heat-insulting, UV-blocking coatings - Google Patents
Transparent, heat-insulting, UV-blocking coatings Download PDFInfo
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- AU2014100870A4 AU2014100870A4 AU2014100870A AU2014100870A AU2014100870A4 AU 2014100870 A4 AU2014100870 A4 AU 2014100870A4 AU 2014100870 A AU2014100870 A AU 2014100870A AU 2014100870 A AU2014100870 A AU 2014100870A AU 2014100870 A4 AU2014100870 A4 AU 2014100870A4
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- 238000000576 coating method Methods 0.000 title claims abstract description 41
- 239000011248 coating agent Substances 0.000 claims abstract description 34
- 230000000903 blocking effect Effects 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000011521 glass Substances 0.000 claims abstract description 14
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 4
- 239000006185 dispersion Substances 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000008096 xylene Substances 0.000 claims description 7
- 229920002050 silicone resin Polymers 0.000 claims description 6
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920003180 amino resin Polymers 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 4
- 229920000180 alkyd Polymers 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- -1 deformer Substances 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 239000011858 nanopowder Substances 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 10
- 230000005855 radiation Effects 0.000 abstract description 10
- 239000000758 substrate Substances 0.000 abstract description 9
- 230000005540 biological transmission Effects 0.000 abstract description 4
- 239000012780 transparent material Substances 0.000 abstract description 4
- 241000282414 Homo sapiens Species 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000001816 cooling Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000010348 incorporation Methods 0.000 abstract description 2
- 230000008833 sun damage Effects 0.000 abstract description 2
- 239000011147 inorganic material Substances 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 229920006254 polymer film Polymers 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 description 14
- 238000002834 transmittance Methods 0.000 description 9
- 238000009736 wetting Methods 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000004576 sand Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000002105 nanoparticle Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 239000012963 UV stabilizer Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000007766 curtain coating Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003009 polyurethane dispersion Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
Abstract Disclosed herein is a method of obtaining transparent, heat-insulating, UV-blocking coating through the incorporation of various nanopowders into coating formulaion, wchi are able to shield UV light and infrared light in sun radiation to provide heat insulting and UV blocking performance. As-produced coatings are capable of reducing the transmission of solar energy and UV radiation from outside, which can decrease energy consumption for cooling/heating and protect human beings/decoration materials insides from sun damage. The transparent, heat-insulting, UV-blocking coating disclosed in this invention can be manufactured by a process comprising the steps of: (1) Preparing nanodispersions from one or a mixture of nanopowders, which are capable of shielding UV light and infrared light; (2) Blending the nanodispersions with film formation materials and other necessary additives to obtain transparent, heat-insulting, UV-blocking coating; (3) Applying above obtained coating on the surface of various transparent materials to form a transparent layer that endows the substrates with heat-insulting and UV-blocking properties. As disclosed coatings can be applied on various transparent substrates from organic materials, like glass, to inorganic materials, like polymer films.
Description
EDITORIAL NOTE Application No. 2014100870 There is 8 pages of description Field The present invention relates to a transparent, heat-insulting, UV-blocking coating, which can be applied on inorganic and organic glass for energy saving purpose. Background In order to prevent sun radiation, various approaches have been developed to modify the light transmission property of transparent materials such as glass. For example, adhesive films containing thin metal layers have been used widely for car windows to shield sun radiation, which in turn reduces the damages of harmful UV radiation to human beings and decrease the energy consumption of air conditioner. Besides adhesive window films, thin metal layers have also been directly deposited on the surface of glass during glass production process, such as Low-E glass. Recently, many metal oxides have been found to possess excellent optical properties. For example, antinomy tin oxide (ATO) is known to be able to block the near infrared light in the wavelength range of 1400 nm to 2500 nm, indium tin oxide (ITO) has the capability to block infrared light from 1100 nm to 2500 nm, while specially processed ITO can block a much wide range of infrared light from 900 nm to 2500 nm. (Patent US5518810, EP1008564, US6620872, US691154) Ultrafine nanopowders like titanium dioxide, zinc oxide, iron oxide possess outstanding UV light blocking property, which can prevent UV radiation initiated degradation of the decoration materials inside. Among the commonly used ultrafine nanopowders, nano titanium dioxide, especially iron or manganese doped nano titanium dioxide has the capability of shielding UV light with the wavelength below 390 nm. Besides, compared to organic UV stabilizers, inorganic UV stabilizers, such as nano titanium dioxide, do not degrade along using, which ensures long term UV shielding performance. Although these nanoparticles have very attractive properties, it is still difficult to directly use them in transparent coatings. Attributing to their high surface energy and specific surface area, nanoparticles usually are not thermal dynamically stable, which means there is a strong tendency for them to aggregate and form large agglomerates that are difficult to disperse. Therefore, a dispersion of nanoparticles is commonly prepared forehand and then blended with other coating components. However, nanodispersions prepared by current technique have a series of drawbacks, including low solid content, large average particle size, short storage time, and so on. The solid content of the dispersion described in Chinese patents CN 101054455A and CN 1563231A is around 2 wt% ~ 15 wt%. One consequence of such low solid content is the requirement to proceed two coating cycles (cast and dry), which usually brings negative effects on coatings' optical properties. Chinese patent CN101230234A has provided a method to produce nanodispersion with the solid content of 40 wt% based on co-precipitation and surface modification method. However, the production process is very complicated and is unable to obtain high-solid-content dispersions with long term stability. This invention has utilized the synergetic effect between two types of dispersant: one is wetting agent, which is able to disperse nanopowders quickly during grinding, while the other one is hyperdispersant, which can endow the dispersed nanopowders long term stability by avoiding secondary coagulation. The nanodispersion produced through this method can maintain stability after storing for more than half year. Description A detailed disclosure for the purpose of illustrating representative embodiments of the present invention are given below, but the present invention should not be construed as being limited by these embodiments. The present invention discloses a method to obtain transparent, heat insulting, UV blocking coatings through the incorporation of various nanopowders into coating formulation, which are able to shield UV light and infrared light in sun radiation to provide heat insulting and UV blocking performance. As-produced coatings are capable of reducing the transmission of solar energy and UV radiation from outside, which can decrease energy consumption for cooling/heating and protect human beings/decoration materials insides from sun damage. The major advantages of the transparent, heat-insulting, UV-blocking coating disclosed in the present invention include: 1. This invention discloses a method to produce nanodispersions with high solid content and high colloidal stability, which simplifies the further coating production process and ensures the high optical performance of the coating; 2. This invention discloses a transparent, heat-insulating, UV-blocking coating that can be applied directly on various transparent substrates, such as glass, polycarbonate, organic glass, polyester, etc. This coating has excellent adhesion to the substrates, which can be applied by blade coating, curtain coating or spray coating process to endow the substrates with UV and infrared light blocking properties. The transparent, heat-insulting, UV-blocking coating disclosed in this invention can be manufactured by a process comprising the steps of: (1) Preparing nanodispersions from one or a mixture of nanopowders, which are capable of shielding UV light and infrared light; (2) Blending the nanodispersions with film formation materials and other necessary additives to obtain transparent, heat-insulting, UV-blocking coating; (3) Applying above obtained coating on the surface of various transparent materials to form a transparent layer that endows the substrates with heat-insulting and UV-blocking properties. In this invention, heat-insulting property is derived from the shielding effect of infrared light in sun radiation, because most of the heat brought by sun is generated by the infrared part in sunlight. Therefore, heat-insulting and infrared light shielding properties can be seen as identical in this invention. In the present invention, nanodispersions which have UV blocking and infrared light shielding properties were generated by grinding corresponding nanopowders in special milling equipment. The nanopowders used herein denote as the materials that possessing low transmission rate of infrared light and UV light in sun radiation, which are selected from antimony tin oxide (ATO), indium tin oxide (ITO), lanthanum hexaboride (LaB 6 ), doped vanadium dioxide (V0 2 ), titanium dioxide, zinc oxide, iron oxide. UV blocking powder is preferred to be nano titanium dioxide. More preferred is iron, or manganese doped nano titanium dioxide. Infrared light shielding powders are preferred to be ATO, ITO and LaB 6 . The concentration of infrared light shielding powders in the nanodispersion is preferred to be 20 wt% - 40 wt%, while the concentration of UV blocking powders in the nanodispersion is preferred to be 10 wt% -30 wt%. The nanodispersion described herein has used two types of dispersants, wetting dispersant and hyperdispersant, such as modified acrylic polymer based dispersant, polyester based dispersant and fatty amine based dispersant, which can stabilize the dispersed particles through two mechanisms: electrostatic repulsion and steric hindrance. According to the feature of film formation materials, dispersants used herein can be either water-based or solvent based. The total amount of the dispersants is around 5 wt% - 30 wt% based on the weight of nanopowders. The nanodispersion described herein can be either solvent-based or water-based depending on the feature of the film formation materials. For solvent-based nanodispersions, the solvent is selected from ethanol, butanol, xylene, ethyl acetate, and the mixture thereof. The concentration of the continuous phase in nanodipsersions, which can be either water or solvent, is preferred to 40 wt% - 67 wt%. The nanodispersion used herein was produced by grinding of nanopoweders in special milling equipment, the solid content of which is in the range of 30 wt% to 50 wt%. The average particle size of the dispersed powders was around 50 nm to 150 nm, while the distribution in the range from 10 nm to 200 nm. As-prepared nanodispersion is thermaldynamically stable at ambient temperature for more than 6 months. The transparent, heat insulting, UV blocking coating described herein was prepared by blending nanodispersion, containing infrared light and UV shielding nanoparticles, with film formation materials. The concentration of nanodispersion is in the range of 10 wt% to 80 wt%, while the content of film formation materials ranges from 20 wt% to 80 wt%. As-preared coating is able to shielding more than 70% of the infrared light and 85% of the UV light. The film formation materials used herein can form films in the temperature range from 0 C to 200 C with or without the assistant of curing agent.
The film formation materials used herein are selected from (meth) acrylic polymer, polyurethane, alkyd resin, amino resin, organic silicone resin, inorganic silicate, the dispersions/latexes of above materials and the mixture thereof. For solvent based resin systems, such as (meth) acrylic polymer, polyurethane, alkyd resin, amino resin and organic silicone resin, certain amount of solvent, leveling agent, deformer and adhesion promoter can be added to form single-component or two-component clear coat. Organic silicone resin is preferred as the film formation material due to its excellent weathering property. For the dispersion/latexes of resins/polymers listed above, coalescing agent, thickener, leveling agent, substrate wetting agent, deformer, adhesion promoter and water can be added to form single-component or two-component clear coat. The transparent, heat-insulating, UV-blocking coating described in the present invention can be applied directly on various transparent materials, such as glass, polycarbonate, organic glass, polystyrene, polyester, and so on. The transparent, heat-insulating, UV-blocking coating described in the present invention can be casted on the surface of materials through blade coating, curtain coating, and spray coating processes to endow the covered materials with UV blocking and infrared shielding properties. Examples Example 1 Water-based, heat insulting, UV blocking dispersion Wetting dispersant (Disperbyk-190) and Hyperdispersant (Hyperdisper-5410) were mixed uniformly with water first and fed into a sand mill. ATO and TiO2 powders were added slowly into the as-prepared aqueous solution afterward. Then the powders were grinded in sand mill for 4h to obtain aqueous dispersion with average particle size of around 90 nm. The detailed formulation of the dispersion is illustrated as follows in weight percentage: Antimony tin oxide 25 TiO 2 15 Wetting dispersant 4 Hyperdispersant 4 Water 52 Example 2 Alcohol-based, heat insulting, UV blocking dispersion Wetting dispersant (Disperbyk-160) and Hyperdispersant (Hyperdisper-5410) were mixed uniformly with ethanol first and fed into a sand mill. ATO and TiO 2 powders were added slowly into the as-prepared solution afterward. Then the powders were grinded in sand mill for 8h to obtain dispersion with average particle size of around 90 nm. The detailed formulation of the dispersion is illustrated as follows in weight percentage: Antimony tin oxide 25 TiO 2 10 Wetting dispersant 4 Hyperdispersant 4 Ethanol 57 Example 3 Solvent-based, heat insulting, UV blocking dispersion Wetting dispersant (Disperbyk-161) and Hyperdispersant (BSK 32800SH) were mixed uniformly with xylene first and fed into a sand mill. ATO and TiO 2 powders were added slowly into the as-prepared solution afterward. Then the powders were grinded in sand mill for 8h to obtain dispersion with average particle size of around 100 nm. The detailed formulation of the dispersion is illustrated as follows in weight percentage: Indium tin oxide 25 Fe 2 0 3 10 Wetting dispersant 4 Hyperdispersant 5 Xylene 56 Example 4 Water-based, transparent, heat insulting, UV blocking coating The components listed below were mixed uniformly by a high-speed disperser to obtain clear binder. Subsequently, as-prepared binder was mixed with the water-based dispersion described in example 1 at the weight ratio of 100 to 40. Afterward, a 10 [tm thick transparent coating was casted on glass out of as-produced mixture, which has the visible light transmittance of 73%, solar energy transmittance of 42%, and UV light transmittance of 8%. Water borne acrylic/polyurethane dispersion 80 Dipropylene Glycol Monomethyl Ether 6 Water 11 Deformer (BYK-019) 0.9 Thickener (RM-8W) 1.5 Wetting agent (H- 140) 0.6 Example 5 Alcohol-based, transparent, heat insulting, UV blocking coating The components listed above were mixed uniformly by a high-speed disperser. Afterward, the paint was casted on glass substrate, which was dried at ambient temperature or at 80 C 120 C for 30min to obtain a 10 [tm thick, transparent heat insulating coating with the hardness of 3H, visible light transmittance of 68%, solar energy transmittance of 38%, and UV light transmittance of 11%. Silicone resin (solid content 40%) 60 Dispersion (Example 2) 40 Deformer(BYK-028) 0.4 Example 6 Solvent-based, transparent, heat insulting, UV blocking coating The components listed below were mixed uniformly by a high-speed disperser. Afterward, a 10 [tm thick, transparent heat insulating coating was casted on transparent polycarbonate substrate by spray coating. The key performance of such produced coating includes, hardness of 2H, visible light transmittance of 73%, solar energy transmittance of 40%, and UV light transmittance of 14%. Acrylic resin 50 Xylene 20 Dispersion (Example 3) 30 Leveling agent (BYK-302) 0.5 Deforner (BY K-071 ) 0.5
Claims (8)
1. A transparent, heat insulating, UV blocking coating comprising, by weight percentage, 20% to 50% film formation materials, 10% to 50% heat insulting and UV blocking dispersion, 0.1% to 1% additives and 15% to 40% solvent.
2. The transparent, heat insulating, UV blocking coating of claim 1, wherein the heat insulating and UV blocking dispersion are derived from heat insulating powders, which include ATO, ITO, LaB 6 , doped V0 2 , etc, and UV blocking powders, which include TiO 2 , ZnO, Fe 2 0 3 . Nano TiO 2 are preferred as UV blocking powders. Fe and Mn doped nano TiO 2 are more preferred as UV blocking powders. The particle size of the powders dispersed in the dispersion is in the range of 10 nm to 200 nm. Preferred particle size is in the range from 10 nm to 100 nm.
3. The nanodispersion of claim 2, wherein the continuous phase of the dispersion can be either water or organic solvent, which is preferred to be selected from ethanol, butanol, xylene, ethyl acetate and the mixture thereof. The solid content is preferred to be 10 wt% ~ 40 wt%. 3. The transparent, heat insulating, UV blocking coating of claim 1, wherein the film formation materials are resins that can attach to glass and form transparent films on glass surfaces at ambient temperature and high temperature, with or without curing agent.
4. The resin of claim 3 are selected from (meth)acrylic polymer, polyurethane, alkyd resin, amino resin, polyester, silicone resin, silicate, and water-based dispersions or latexes of them.
The resin is preferred to be one or a mixture out of (meth) acrylic polymer, polyurethane, amino resin, silicone resin and their dispersions or latexes.
6. The solvent of claim 1 can be water or organic solvent, such as ethanol, butanol, xylene, ethyl acetate, and so on.
7. The transparent, heat insulating, UV blocking coating of claim 1, wherein the additives include leveling agent, deformer, film formation materials, wetting agent, thickener.
8. The transparent, heat insulating, UV blocking coating of claim 1, wherein the solvent can be water or organic solvent, such as ethanol, butanol, xylene, ethyl acetate, and so on.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2014100870A AU2014100870A4 (en) | 2014-08-04 | 2014-08-04 | Transparent, heat-insulting, UV-blocking coatings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2014100870A AU2014100870A4 (en) | 2014-08-04 | 2014-08-04 | Transparent, heat-insulting, UV-blocking coatings |
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| AU2014100870A4 true AU2014100870A4 (en) | 2014-09-11 |
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| AU2014100870A Ceased AU2014100870A4 (en) | 2014-08-04 | 2014-08-04 | Transparent, heat-insulting, UV-blocking coatings |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936790A (en) * | 2017-10-30 | 2018-04-20 | 合肥林邦门业有限公司 | A kind of timber Water-borne Alkyd Coatings preparation method |
| CN108440905A (en) * | 2018-03-01 | 2018-08-24 | 合肥利裕泰玻璃制品有限公司 | A kind of wear resistant heat preserving fire prevention resistance vitaglass protective film and preparation method thereof |
| CN108531025A (en) * | 2018-03-01 | 2018-09-14 | 珠海市美筑新材料有限公司 | High temperature resistant antimildew and antibacterial type nanometer water baking vanish and preparation method thereof |
| CN109679469A (en) * | 2018-12-31 | 2019-04-26 | 新沂市中诺新材料科技有限公司 | A kind of preparation method of environmentally friendly cold coating |
| CN112159600A (en) * | 2019-06-16 | 2021-01-01 | 南京任氏环保材料有限公司 | Method for manufacturing reflective heat-insulation colored sand |
-
2014
- 2014-08-04 AU AU2014100870A patent/AU2014100870A4/en not_active Ceased
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936790A (en) * | 2017-10-30 | 2018-04-20 | 合肥林邦门业有限公司 | A kind of timber Water-borne Alkyd Coatings preparation method |
| CN108440905A (en) * | 2018-03-01 | 2018-08-24 | 合肥利裕泰玻璃制品有限公司 | A kind of wear resistant heat preserving fire prevention resistance vitaglass protective film and preparation method thereof |
| CN108531025A (en) * | 2018-03-01 | 2018-09-14 | 珠海市美筑新材料有限公司 | High temperature resistant antimildew and antibacterial type nanometer water baking vanish and preparation method thereof |
| CN108531025B (en) * | 2018-03-01 | 2020-04-24 | 珠海市美筑新材料有限公司 | High-temperature-resistant mildew-proof antibacterial nano water-based baking paint and preparation method thereof |
| CN109679469A (en) * | 2018-12-31 | 2019-04-26 | 新沂市中诺新材料科技有限公司 | A kind of preparation method of environmentally friendly cold coating |
| CN109679469B (en) * | 2018-12-31 | 2021-11-26 | 益帆涂料(无锡)有限公司 | Preparation method of environment-friendly resin coating |
| CN112159600A (en) * | 2019-06-16 | 2021-01-01 | 南京任氏环保材料有限公司 | Method for manufacturing reflective heat-insulation colored sand |
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