AU2008201777B2 - Water-absorbent resin and its production process - Google Patents

Description

AUSTRALIA Patents Act 1990 COMPLETE SPECIFICATION Standard Patent Applicant (s): NIPPON SHOKUBAI CO., LTD. Invention Title: WATER-ABSORBENT RESIN AND ITS PRODUCTION PROCESS The following statement is a full description of this invention, including the best method for performing it known to me/us: P58517 AU i PatSot_Fsng Apptcation 2008-4-21 doc (M) WO 2004/099265 PCT/JP2004/006509 DESCRIPTION Water-Absorbent Resin and Its Production Process 5 TECHNICAL FIELD The present invention relates to a water-absorbent resin and its production process. More specifically, the present invention relates to a water-absorbent resin having excellent performances and its production process which involves carrying out specific surface-crosslinking treatment. 10 BACKGROUND ART In recent years, water-absorbent resins are widely used as component materials of sanitary materials (e.g. disposable diapers, sanitary napkins, incontinent pads) for the purpose of causing the water-absorbent resins to absorb aqueous liquids such as body fluids. 15 Known examples of the above water-absorbent resins include: partially-neutralized and crosslinked poly(acrylic acids); hydrolyzed copolymers of starch-acrylonitrile; neutralized graft polymers of starch-acrylic acid; saponified copolymers of vinyl acetate-acrylic acid ester; hydrolyzed copolymers of acrylonitrile or acrylamide, or crosslinked polymers of these hydrolyzed copolymers; 20 crosslinked carboxymethyl cellulose; crosslinked copolymers of 2-acrylanido-2-methylpropanesulfonic acid (AMPS); crosslinked poly(ethylene oxide); crosslinked poly(allylamine); and crosslinked polyethylenimine. Examples of properties, which the above water-absorbent resins should have, include excellent properties when contacting with aqueous liquids (e.g. body fluids), 25 such as: water absorption quantity; absorption rate; liquid permeability; gel strength of swollen gel; and suction force to suck up water from base materials containing the aqueous liquids. The relations between these properties do not necessarily show positive 1A WO 2004/099265 PCT/JP2004/006509 correlations. For example, there has been a tendency such that, as the absorption properties without load become higher, those under load unfavorably decrease. Arts in which surface layers of the water-absorbent resins are crosslinked, which are called surface-crosslinking treatment arts, are known as processes for 5 well-balanced improvement of the properties of the water-absorbent resins. As crosslinking agents used for the surface-crosslinking treatment, there are known such as polyhydric alcohols, polyglycidyl ethers, haloepoxy compounds, polyaldehydes, polyanines, and polyvalent metal salts. As processes for crosslinking the surface layers of the water-absorbent resins with these crosslinking 10 agents, there are known the following representative processes such as: a process in which a surface-crosslink-treating agent and the water-absorbent resin are mixed together and then heated, wherein the surface-crosslink-treating agent is prepared by dissolving the crosslinking agent into water and a hydrophilic organic solvent (e.g. refer to patent documents 1 to 3 below); and a process in which the water-absorbent 15 resin is dispersed into a mixed solvent of water and the hydrophilic organic solvent, and then the crosslinking agent is added to the resultant dispersion to carry out their reaction (e.g. refer to patent document 4 below). On the other hand, the surface-crosslinking treatment is desired to be carried out without any hydrophilic organic solvent, for example, from the viewpoint of: 20 problems of environmental contamination due to waste liquids and/or waste gases discharged during the production; and use circumstances such that the water-absorbent resin is used for the sanitary materials which contact directly with human bodies. However, in the case where the water-absorbent resin is produced by using 25 water as the only solvent without the hydrophilic organic solvent when carrying out the surface-crosslinking treatment (e.g. refer to patent document 5 below), then there have been problems in that the properties, particularly, absorption properties, of the water-absorbent resin are unfavorably deteriorated when compared with the case 2 WO 2004/099265 PCT/JP2004/006509 where the hydrophilic organic solvent is used. Furthermore, hitherto, such as production conditions of the water-absorbent resins themselves and conditions of their surface treatment (as post-processing) have been studied, and many water-absorbent resins have been designed or produced with 5 attention directed to the aforementioned properties (e.g. water absorption quantity, absorption rate, liquid permeability, gel strength, suction force). However, from the viewpoint of practical uses for absorption of excreta and blood (e.g. diapers), it has recently been being found that there is a case where the absorption performances cannot be exercised on the desired high levels by merely satisfying these properties. 10 In other words, as to water-absorbent resins used in absorbent articles for absorption of excreta and blood, there have been problems in that the design or production of the optimum water-absorbent resin has not yet succeeded. [Patent Document 1] JP-A-270948/2001 (Kokai) 15 [Patent Document 2] JP-A-502221/1997 (Kohyo) [Patent Document 3] Japanese Patent No. 3305718 [Patent Document 4] 20 JP-B-048521/1986 (Kokoku) [Patent Document 5] JP-A-246403/1992 (Kokai) DISCLOSURE OF THE INVENTION OBJECTS OF THE INVENTION 25 Accordingly, objects of the present invention are: to provide a water-absorbent resin which exhibits excellent balances between water absorption performances; and further to provide a process by which a water-absorbent resin having excellent absorption properties can be produced even if no hydrophilic organic solvent is used, 3 WO 2004/099265 PCT/JP2004/006509 or even if its amount is extremely reduced, when carrying out the surface-crosslinking treatment in the process of producing the water-absorbent resin. Another object of the present invention is to provide a water-absorbent resin optimum to absorbent articles such as diapers. 5 SUMMARY OF THE INVENTION The present inventors diligently studied to solve the above problems. As a result, the present inventors directed their attention to an intermediate step of from the end of an operation of adding a surface-crosslink-treating agent to a water-absorbent resin powder till the beginning of an operation of carrying out 10 heating in the case where the production line of the water-absorbent resin includes a step of adding the surface-crosslink-treating agent to the water-absorbent resin powder and a step of heating the resultant mixture to thereby carry out surface-crosslinking treatment, wherein the surface-crosslink-treating agent includes a surface-crosslinking agent and water as essential components and wherein the 15 hydrophilic organic solvent content of the surface-crosslink-treating agent has been reduced. Then, the present inventors have found out that the time needed for this intermediate step has a great influence on the absorption properties of the produced water-absorbent resin. And then the present inventors have found out that the above problems can-be solved by setting the above time at a short time of within 5 20 minutes which cannot even be surmised from working modes having hitherto been known in public. In production plants of the water-absorbent resin, generally, such as various reactors and treatment apparatuses are linked together by intermediate steps of carrying out conveyance and, if necessary, storage (e.g. refer to the aforementioned 25 patent documents 1 to 3). As the plant scale becomes larger, the time which is spent on the intermediate steps increases unavoidably, too. Then, in cases of conventional production plants having common production scales (such that the production is in the range of tens of thousands of tons to hundreds of thousands of tons per year), it 4 - 5 has been usual that the intermediate steps are designed on such a scale that the stagnation time therein can be in the range of tens of minutes to several hours. The present invention has not been completed until it is found out to be important for producing the water-absorbent resin excellent in the absorption properties 5 by using the surface-crosslink-treating agent (which includes the surface-crosslinking agent and water as essential components and of which the hydrophilic organic solvent content has been reduced) that the time, which is spent on the intermediate step of from the end of the operation of adding the surface-crosslink-treating agent to the water absorbent resin powder till the beginning of the operation of carrying out heating, is set 10 at an extremely short time. According to the present inventors' findings, as to water-absorbent resins used in absorbent articles such as diapers, it is needless to say that, as has hitherto been known, it is necessary to see to particle diameter elements (i.e. mass-average particle diameter and ratio of powder having particle diameters of smaller than 150 pm) of the 15 water-absorbent resins. However, in addition thereto, it is also important to see to two utterly new parameters, namely, the total absorption capacity and the absorption efficiency under load. Such a production process as mentioned above can easily produce a water-absorbent resin further satisfying the above two parameters while satisfying the design standards as set with attention directed to the particle diameter 20 elements. The present invention provides a water-absorbent resin comprising sodium polyacrylate obtained by a process including the step of polymerizing and crosslinking a monomer component including acrylic acid and/or its sodium salt (neutralized material) as a main component, wherein the water-absorbent resin has a 25 mass-average particle diameter of 300 to 600 pm; includes a powder having particle diameters of smaller than 150 pm in an amount of 0 to 3 mass % relative to the water absorbent resin; and exhibits an absorption capacity of not less than 35 (g/g) without load, a total absorption capacity of not less than 70 (g/g) and an absorption efficiency of not less than 70 % under load, wherein the total absorption capacity and the absorption 30 efficiency under load are defined by the following equations based on values given by absorption of a 0.90 mass % aqueous sodium chloride solution (25 *C) for 1 hour: total absorption capacity (g/g) = absorption capacity (g/g) without load + monolayer absorption capacity (g/g) under load; and absorption efficiency (%) under load = monolayer absorption capacity 35 (g/g) under load x 100/absorption capacity (g/g) without load; wherein the water-absorbent resin has a residual monomer content of 0 to 400 mass ppm and the sodium polyacrylate has a neutralization degree of 50 to 90 N \Melbourne\Cases\Pateni\58000-58999\P58517 AU I\Specis\P58517 AU I Specification 2008-9.2 doc 09106/09 - 6 mol %. The present invention also provides a process for production of the above water absorbent resin which comprises: 5 a step (1) of polymerizing a monomer component including an acid-group containing unsaturated monomer as an essential component to thereby obtain a hydrogel polymer; a step (2) of drying and pulverizing the resultant hydrogel polymer to thereby obtain a water-absorbent resin powder; 10 a step (3) of adding a surface-crosslink-treating agent to the resultant water-absorbent resin powder, wherein the surface-crosslink-treating agent includes a surface-crosslinking agent and water as essential components and has a hydrophilic organic solvent content of 0 to 10 mass % relative to the surface-crosslink-treating agent; and 15 a step (4) of heating the resultant mixture to thereby carry out surface crosslinking treatment; wherein the time of from the end of the step (3) till the beginning of the step (4) is within 5 minutes. Furthermore, the present invention provides an absorbent article for 20 absorption of excreta and blood, which comprises the above water-absorbent resin. EFFECTS OF THE INVENTION The present invention can provide not only a water-absorbent resin which 25 N:\Melbournc\Cases\Patent\58000-58999\P58517 AU 1\Spccis\P58517 AU I Specification 2008-9-2 doc 09/06/09 WO 2004/099265 PCT/JP2004/006509 exhibits excellent balances between water absorption performances; but also a process by which the water-absorbent resin having excellent absorption properties can be produced even if no hydrophilic organic solvent is used, or even if its amount is extremely reduced, when carrying out the surface-crosslinking treatment in the 5 process of producing the water-absorbent resin. The present invention can further provide a water-absorbent resin optimum to absorbent articles such as diapers. DETAILED DESCRIPTION OF THE INVENTION Hereinafter, detailed descriptions are given about the present invention. However, the scope of the present invention is not bound to these descriptions. And 10 other than the following illustrations can also be carried out in the form of appropriate modifications of the following illustrations within the scope not departing from the spirit of the present invention. The process according to the present invention for production of a water-absorbent resin comprises: 15 a step (1) of polymerizing a monomer component including an acid-group-containing unsaturated monomer as an essential component to thereby obtain a hydrogel polymer; a step (2) of drying and pulverizing the resultant hydrogel polymer to thereby obtain a water-absorbent resin powder; 20 a step (3) of adding a surface-crosslink-treating agent to the resultant water-absorbent resin powder, wherein the surface-crosslink-treating agent includes a surface-crosslinking agent and water as essential components and has a hydrophilic organic solvent content of 0 to 10 mass % relative to the surface-crosslink-treating agent; and 25 a step (4) of heating the resultant mixture to thereby carry out surface-crosslinking treatment. The water-absorbent resin in the present invention refers to a water-swellable and water-insoluble crosslinked polymer which is formable into a hydrogel. The 7 WO 2004/099265 PCT/JP2004/006509 term "water-swellable" means being able to absorb water in a large amount of essentially not smaller than 5 times, favorably in the range of 50 to 1,000 times, of the own weight in ion-exchanged water. The term "water-insoluble" means that the uncrosslinked water-extractable component content (water-soluble polymer content) 5 (specified in USP 6,187,872) of the water-absorbent resin is favorably in the range of 0 to 50 mass %, more favorably 0 to 25 mass %, still more favorably 0 to 20 mass %, particularly favorably 0 to 15 mass %, most favorably 0 to 10 mass %, relative to the water-absorbent resin. Examples of the water-swellable and water-insoluble crosslinked polymer, 10 which constitutes the water-absorbent resin in the present invention, include one or two or more of such as: partially-neutralized polymers of poly(acrylic acids); hydrolyzed graft polymers of starch-acrylonitrile; graft polymers of starch-acrylic acid; saponified copolymers of vinyl acetate-acrylic acid ester; hydrolyzed copolymers of acrylonitrile or acrylamide, or crosslinked polymers of these 15 hydrolyzed copolymers; modified polymers of carboxyl-group-containing crosslinked polyvinyl alcohols; and crosslinked copolymers of isobutylene-maleic anhydride. However, there are preferred the partially-neutralized polymers of poly(acrylic acids) which are obtained by a process including the step of polymerizing and crosslinking a monomer component including acrylic acid and/or 20 its salt (neutralized material) as a main component. In the process according to the present invention for production of a water-absorbent resin, the hydrogel polymer has an acid group and/or its salt and is favorably obtained by a process including the step of polymerizing a monomer component including an acid-group-containing unsaturated monomer as an essential 25 component. Incidentally, the acid-group-containing unsaturated monomer encompasses, also, a monomer which will contain the acid group by being hydrolyzed after the polymerization (e.g. acrylonitrile). However, there is preferred an acid-group-containing unsaturated monomer which has already contained the acid 8 WO 2004/099265 PCT/JP2004/006509 group during the polymerization. In the present invention, it is favorable that the monomer component includes acrylic acid and/or its salt as a main component. In the case where the monomer component includes acrylic acid and/or its salt 5 as a main component, another monomer may be used jointly therewith. This jointly usable monomer is free of especial limitation if even its joint use permits the exercise of the effects of the present invention. However, examples thereof include water-soluble or hydrophobic unsaturated monomers such as: methacrylic acid, (anhydrous) maleic acid, fumaric acid, crotonic acid, itaconic acid, vinylsulfonic acid, 10 2-(meth)acrylamido-2-methylpropanesulfonic acid, (meth)acryloxyalkanesulfonic acids, and their alkaline metal salts and ammonium salts; and N-vinyl-2-pyrrolidone, N-vinylacetamide, (meth)acrylamide, N-isopropyl(meth)acrylamide, N,N-dimethyl(meth)acrylamide, 2-hydroxyethyl (meth)acrylate, methoxypolyethylene glycol (meth)acrylate, polyethylene glycol (meth)acrylate, 15 isobutylene, and lauryl (meth)acrylate. In the present invention, when the monomers other than the acrylic acid and/or its salt are used, the ratio of these monomers other than the acrylic acid and/or its salt is favorably in the range of 0 to 30 mol %, more favorably 0 to 10 mol %, relative to the total of the acrylic acid and/or its salt used as the main component. If the above 20 monomers other than the acrylic acid and/or its salt are used in such a ratio, then the effects of the present invention are sufficiently exercised, so that the absorption performances of the resultant water-absorbent resin are still more enhanced, and further that the water-absorbent resin can be obtained at still lower costs. In the process according to the present invention for production of a 25 water-absorbent resin, the hydrogel polymer has a crosslinked structure. This crosslinked structure may be a self-crosslinked-type one obtained without any crosslinking agent, but is preferably a crosslinked structure obtained by copolymerization or reaction with a crosslinking agent (internal-crosslinking agent 9 WO 2004/099265 PCT/JP2004/006509 for water-absorbent resins) having at least two polymerizable unsaturated groups and/or at least two reactive groups per molecule. Specific examples of the internal-crosslinking agents include N,N'-methylenebis(meth)acrylamide, (poly)ethylene glycol di(meth)acrylate, 5 (poly)propylene glycol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, glycerol tri(meth)acrylate, glycerol acrylate methacrylate, ethylene-oxide-modified trimethylolpropane tri(meth)acrylate, pentaerythritol hexa(meth)acrylatc, triallyl cyanurate, triallyl isocyanurate, triallyl phosphate, triallylamine, poly(meth)allyloxyalkanes, (poly)ethylene glycol diglycidyl ether, glycerol 10 diglycidyl ether, ethylene glycol, polyethylene glycol, propylene glycol, glycerol, pentaerythritol, ethylenediamine, ethylene carbonate, propylene carbonate, polyethylenimine, and glycidyl (meth)acrylate. The internal-crosslinking agents may be used either alone respectively or in appropriate combinations with each other. In addition, the internal-crosslinking 15 agents may be added to the reaction system either in a lump or divisionally. In the case where the intemal-crosslinking agents are used, it is favorable, for sufficiently exercising the effects of the present invention, that a compound having at least two polymerizable unsaturated groups is used during the polymerization. The amount of these intemal-crosslinking agents as used is favorably in the 20 range of 0.001 to 2 mol %, more favorably 0.005 to 0.5 mol %, still more favorably 0.01 to 0.2 mol %, particularly favorably 0.03 to 0.15 mol %, relative to the aforementioned monomer component (exclusive of the crosslinking agents). In the case where the amount of the above internal-crosslinking agent as used is smaller than 0.001 mol % or larger than 2 mol %, there are disadvantages in that there is a 25 possibility that the effects of the present invention cannot sufficiently be exercised, so there is a possibility that the resultant water-absorbent resin cannot exercise sufficient absorption properties. In the case where the internal-crosslinking agent is used to introduce the 10 WO 2004/099265 PCT/JP2004/006509 crosslinked structure into the inside of the polymer, it is enough that the internal-crosslinking agent is added to the reaction system before, on the way of, or after the polymerization of the monomer component, or after its neutralization. There is no especial limitation on the method for polymerizing the monomer 5 component in order to obtain the hydrogel polymer in the process according to the present invention for production of a water-absorbent resin. Examples thereof include aqueous solution polymerization, reversed-phase suspension polymerization, bulk polymerization, and precipitation polymerization. However, from such as viewpoints of the performance, the facility of polymerization control, and the 10 absorption properties of a swollen gel, it is favorable to carry out the aqueous solution polymerization or reversed-phase suspension polymerization in which the monomer component is used in the form of an aqueous solution. In the case where the monomer component is used in the form of an aqueous solution, the concentration of the monomer component in this aqueous solution 15 (which may hereinafter be referred to as aqueous monomer solution).depends on the temperature of the aqueous solution or the kind of the monomer component and is therefore not especially limited. However, this concentration is favorably in the range of 10 to 70 mass %, more favorably 20 to 60 mass %, relative to the aqueous monomer solution. In addition, when the above aqueous solution polymerization is 20 carried out, a solvent other than water may be used jointly therewith if necessary. The kind of this solvent which is jointly used is not especially limited. The reversed-phase suspension polymerization is a polymerization method in which the aqueous monomer solution is suspended in a hydrophobic organic solvent, and such a polymerization method is, for example, disclosed in US patents such as 25 USP 4,093,776, USP 4,367,323, USP 4,446,261, USP 4,683,274, and USP 5,244,735. The aqueous solution polymerization is a polymerization method in which the aqueous monomer solution is polymerized without any dispersing solvent, and such a polymerization method is, for example, disclosed in: US patents such as USP 11 WO 2004/099265 PCT/JP2004/006509 4,625,001, USP 4,873,299, USP 4,286,082, USP 4,973,632, USP 4,985,518, USP 5,124,416, USP 5,250,640, USP 5,264,495, USP 5,145,906, and USP 5,380,808; and European patents such as EP 0811636, EP 0955086, and EP 0922717. It is also possible that such as monomer components and initiators exemplified for these 5 polymerization methods are applied to the present invention. When the above polymerization is initiated, there can be used, for example, the following: radical polymerization initiators such as potassium persulfate, ammonium persulfate, sodium persulfate, t-butyl hydroperoxide, hydrogen peroxide, and 2,2'-azobis(2-amidinopropane) dihydrochloride; and photoinitiators such as 10 2-hydroxy-2-methyl-1-phenyl-propan-1-one. From the viewpoint of such as properties of the resultant water-absorbent resin, the amount of the polymerization initiator as used is favorably in the range of 0.001 to 2 mol % (relative to the entire monomer component), more favorably 0.01 to 0.1 mol % (relative to the entire monomer component). 15 The hydrogel polymer is obtained from the step of polymerizing the monomer component including the acid-group-containing unsaturated monomer as an essential component in the above way. After having been divided into small pieces if necessary, the hydrogel polymer obtained by the above polymerization is dried and pulverized. The pulverization 20 may be carried out before, at the same time as, or after the drying. Favorably, the hydrogel polymer is pulverized after the drying. In the present invention, favorably, the drying is carried out to the hydrogel polymer which is particulate (for example, its mass-average particle diameter is not larger than 2 cm, favorably not larger than 1 cm, more favorably not larger than 5 25 mm). As to methods for dividing the hydrogel polymer into small pieces in order to particulate it in the present invention, such as kneaders may be used to carry out the dividing into small pieces at the same time as the polymerization, or the dividing into small pieces may be carried out separately after the polymerization. The dividing 12 WO 2004/099265 PCT/JP2004/006509 into small pieces at the same time as the polymerization and the dividing into small pieces after the polymerization may be jointly used. Incidentally, in the case where the hydrogel polymer is not dried in the particulate form, for example, in the case where the hydrogel polymer is dried in such as a filmy form, there is a possibility 5 that the resultant properties may be inferior and that the resultant particle size may deviate from the favorable ranges. As to the particle diameters of the hydrogel polymer before the drying, its mass-average particle diameter is favorably in the range of 45 to 4,000 Rm, more favorably 50 to 2,000 pm, still more favorably 100 to 1,500 pm, particularly 10 favorably 200 to 1,000 ptm, from the viewpoint of the drying efficiency and the properties. Incidentally, in the case where the mass-average particle diameter of the hydrogel polymer deviates from the above range, there is a possibility of causing such as deterioration of the water absorption capacity and increase of the water-extractable component content as to the resultant water-absorbent resin. 15 Examples of devices suitable for the dividing into small pieces include: kneaders; lengthwise cutting type slitters with cutter blades; crosswise cutting type slitters with cutter blades; cutter type pulverizers with rotary blades; and meat choppers of predetermined opening diameters. In the process according to the present invention for production of a 20 water-absorbent resin, the hydrogel polymer gets dried indispensably. Incidentally, the drying in the present invention refers to bringing the above hydrogel polymer into a solid state where its solid content (defined by the drying loss at 180 *C in 3 hours) is not lower than 80 mass %, favorably not lower than 85 mass %, more favorably not lower than 90 mass %, particularly favorably not lower than 93 mass %, relative 25 to the dried polymer. Incidentally, the drying in the present invention does not necessarily need to give a dried polymer having a solid content of 100 mass % (water content of zero). The drying method usable in the present invention is not especially limited. 13 WO 2004/099265 PCT/JP2004/006509 For example, there can be used at least one of drying methods such as: hot-air drying; thin-film drying with such as drum driers; reduced-pressure drying methods; agitation drying; and fluidized-bed drying. It does not especially matter whether the drying is carried out continuously or batchwise. From the viewpoint of the 5 properties and the drying efficiency, the hot-air drying (particularly, continuous hot-air drying) is favorably used in the present invention. For example, static drying on a belt will do for it. From the viewpoint of the drying efficiency, the above hot-air drying will do, for example, if it is carried out in the following way: the particulate hydrogel 10 polymer is layered on a metal gauze or a punched metal with perforations or slits, and then hot air is passed through spaces between the layered particles in vertical or horizontal directions, preferably in vertical directions, to the gel. As to the metal gauze or perforation diameter, for example, in the case of the perforations or metal gauze, it will do if it has air-through openings of favorably about 0.1 to about 5 mm, 15 more favorably about 0.2 to about 2 mm. In addition, as to the layering of the gel on the metal gauze or punched metal, it will do from the viewpoint of the after-drying properties if the particulate hydrogel polymer is layered in a definite thickness of favorably 1 to 20 cm, more favorably 1.5 to 10 cm, still more favorably 2 to 8 cm. 20 When the above hydrogel polymer is dried, the drying temperature will do from the viewpoint of the properties and the productivity if it is set usually favorably at not lower than 100 *C, more favorably in the range of 110 to 230 *C, still more favorably 130 to 200 *C, particularly favorably 150 to 190 *C. Incidentally, the drying temperature is defined as temperature of the material or temperature of a heat 25 medium (e.g. hot air), but is favorably defined as the temperature of the heat medium. In addition, the drying temperature during the drying period may be constant or may appropriately be varied in the above temperature range on the way of the drying. Furthermore, when the hot-air drying is carried out, the dew point of the hot air is 14 WO 2004/099265 PCT/JP2004/006509 favorably in the range of 40 to 100 *C, more favorably 50 to 90 'C, still more favorably 60 to 85 *C, from the viewpoint of the properties and the energy efficiency. Incidentally, it is also mentioned herein that, after having been dried in the layered state, the particulate hydrogel polymer tends to be a blocky dried material 5 which has lost the flowability as a result of agglomeration between particles due to the drying. Such a blocky dried material is an agglomerate of dried polymer particles, but has continuous spaces and gas permeability into blocks. However, this blocky dried material lacks the flowability due to the agglomeration and therefore needs to be pulverized (disintegrated). 10 In the present invention, the hydrogel polymer is dried in the above way and further is pulverized as well. The pulverization may be carried out before, at the same time as, or after the drying. However, the hydrogel polymer is favorably pulverized after the drying and more favorably further classified after having been pulverized. 15 In the present invention, the drying and the pulverization, and further the classification if necessary, are favorably carried out in a mode of a series of steps, and the time of from an outlet of the drier to an inlet of the pulverizer is favorably within 10 minutes, more favorably within 5 minutes, still more favorably within 2 minutes. 20 In the present invention, the method for the pulverization is free of especial limitation if it can form the dried polymer or its agglomerate (blocky material) into a flowable powder, favorably a powder having a mass-average particle diameter of not larger than 2 mm. For example, there can be used at least one of: methods in which the pulverization is carried out with such as hammer type pulverizers, roll type 25 pulverizers, and jet stream type pulverizers; and hitherto publicly known various pulverization or disintegration methods. In addition, in the case where the agglomeration during the drying is weak, the dried polymer may be given vibration and thereby classified to loosen the agglomeration of the polymer, thus carrying out 15 WO 2004/099265 PCT/JP2004/006509 the pulverization even if no pulverizer is especially used. In the present invention, after the above pulverization, further the classification is, if necessary, favorably carried out, so that coarse particles and a fine powder are removed. The mass-average particle diameter of the water-absorbent resin powder, 5 as obtained in the above way, is determined appropriately for the object. However, in order to sufficiently exercise the effects of the present invention, the water-absorbent resin powder has a mass-average particle diameter in the range of favdrably 300 to 600 gm, more favorably 300 to 550 jim, particularly favorably 380 to 550 pim. In addition, the water-absorbent resin powder being finally obtained 10 includes a powder having particle diameters of smaller than 150 gm in an amount of favorably 0 to 10 mass %, more favorably 0 to 8 mass %, still more favorably 0 to 5 mass %, particularly favorably 0 to 3 mass %, relative to the water-absorbent resin powder. In addition, the water-absorbent resin powder being finally obtained includes particles having particle diameters of smaller than 150 jim and particles 15 having particle diameters of not smaller than 850 pim in a total amount of favorably 0 to 15 mass %, more favorably 0 to 10 mass %, still more favorably 0 to 5 mass %, relative to the water-absorbent resin powder. Particularly, in the present invention, it is favorable that the water-absorbent resin powder has a mass-average particle diameter of 300 to 600 pm and includes a 20 powder having particle diameters of smaller than 150 pm in an amount of favorably 0 to 10 mass %, more favorably 0 to 5 mass %, most favorably 0 to 3 mass %, relative to the water-absorbent resin powder. The bulk density of the water-absorbent resin powder diversely varies with the bulk density (g/cm 3 ) as unambiguously determined by the monomer composition. 25 However, in the case where the water-absorbent resin is sodium polyacrylate, particularly, sodium polyacrylate having a neutralization degree of 50 to 90 mol %, more particularly, sodium polyacrylate having a neutralization degree of 60 to 80 mol %, then its bulk density is usually favorably not less than 0.63 g/ml, particularly 16 WO 2004/099265 PCT/JP2004/006509 favorably not less than 0.65 g/ml. Incidentally, the bulk density will do if it is measured with a device according to JIS K-3362. In the present invention, by the pulverization, the water-absorbent resin powder comes into a less scaly, more roundish, and uniform shape, and therefore its bulk density tends to become higher. 5 Therefore, the bulk density is favorably adjusted so as to be in the range of 0.65 to 0.89 g/ml, more favorably 0.67 to 0.88 g/ml, still more favorably 0.73 to 0.87 g/ml, yet still more favorably 0.74 to 0.86 g/ml, yet still more favorably 0.75 to 0.85 g/ml, after the pulverization. In the case where the bulk density of the water-absorbent resin powder deviates from the above range after the pulverization, there is a 10 possibility that the effects of the present invention may not sufficiently be exercised. After the above pulverization, the coarse particles (e.g. 850 Rm-on product) and the fine powder (e.g. 150 pm-pass product) will do if they are appropriately recycled as the case may be. They will do if: the coarse particles are re-pulverized and the fine particles are removed or recovered, thereby giving the aforementioned 15 particle diameter distribution. However, in the present invention, because the particle diameter distribution is narrow, the necessity of the above recycling greatly reduces. Incidentally, methods for recycling the fine powder of the water-absorbent resin are disclosed in such as USP 4,950,692, USP 5,064,582, USP 5,264,495, USP 5,478,879, EP 0812873, EP 0885917, and EP 0844270. It is also possible to apply 20 these fine powder recycling methods to the present invention. In addition, the amount of the fine powder being recycled is favorably not larger than 30 mass %, more favorably not larger than 15 mass %, particularly favorably in the range of 1 to 10 mass %, most favorably 2 to 8 mass %, of the entirety. In the present invention, because the water-absorbent resin powder having the narrow particle diameter 25 distribution is obtained with high productivity by the pulverization, there are advantages in that a water-absorbent resin powder having a still narrower particle diameter distribution is obtained by recycling a small amount of fine powder. The water-absorbent resin powder, as obtained in the above way, exhibits an 17 WO 2004/099265 PCT/JP2004/006509 absorption capacity of favorably not less than 40 g/g, more favorably not less than 45 g/g, still more favorably not less than 50 g/g, particularly favorably not less than 55 g/g, for a 0.90 mass % aqueous sodium chloride solution (physiological saline solution) without load. As the absorption capacity of the above water-absorbent 5 resin powder which is a base polymer becomes higher, there increases the favorability for obtaining the water-absorbent resin having excellent absorption properties. In the process according to the present invention for production of a water-absorbent resin, there are included: the step (3) of adding a 10 surface-crosslink-treating agent to the resultant water-absorbent resin powder, wherein the surface-crosslink-treating agent includes a surface-crosslinking agent and water as essential components and has a hydrophilic organic solvent content of 0 to 10 mass % relative to the surface-crosslink-treating agent; and the step (4) of heating the resultant mixture to thereby carry out surface-crosslinking treatment. 15 The surface-crosslinking agents for carrying out the surface-crosslinking treatment are various and not especially limited. However, from the viewpoint of such as enhancement of the properties of the resultant water-absorbent resin, there are preferred such as: polyhydric alcohol compounds; epoxy compounds; polyamine compounds or products from their condensation with haloepoxy compounds; 20 oxazoline compounds; mono-, di-, or polyoxazolidinone compounds; cyclic urea compounds; polyvalent metal salts; and alkylene carbonate compounds. The surface-crosslinking agent usable in the present invention is not especially limited. However, for example, it is possible to use surface-crosslinking agents which are exemplified in such as USP 6,228,930, USP 6,071,976, and USP 25 6,254,990. Examples thereof include: polyhydric alcohol compounds (e.g. mono-, di-, tri-, tetra-, or polyethylene glycol, monopropylene glycol, 1,3-propanediol, dipropylene glycol, 2,3,4-trimethyl-1,3-pentanediol, polypropylene glycol, glycerol, polyglycerol, 2-butene-1,4-diol, 1,4-butanediol, 1,3-butanediol, 1,5-pentanediol, 18 WO 2004/099265 PCT/JP2004/006509 1,6-hexanediol, and 1,2-cyclohexanedimethanol); epoxy compounds (e.g. ethylene glycol diglycidyl ether and glycidol); polyamine compounds (e.g. eihylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, pentaethylenehexamine, polyethylenimine, and polyamidepolyamine); haloepoxy 5 compounds (e.g. epichlorohydrin, epibromohydrin, and ox-methylepichlorohydrin); condensation products between the above polyamine compounds and the above haloepoxy compounds; oxazolidinone compounds (e.g. 2-oxazolidinone); cyclic urea compounds; and alkylene carbonate compounds (e.g. ethylene carbonate). These may be used either alone respectively or in combinations with each other. For 10 sufficiently exercising the effects of the present invention, it is favorable to indispensably use the polyhydric alcohol compounds among these surface-crosslinking agents. As the polyhydric alcohol compounds, those which have 2 to 10 carbon atoms are favorable, and those which have 3 to 8 carbon atoms are more favorable. 15 The amount of the surface-crosslinking agent, being used, depends upon such as compounds being used and their combination, but is favorably in the range of 0.001 to 10 mass %, more favorably 0.01 to 5 mass %, relative to the water-absorbent resin powder. The surface-crosslink-treating agent, which is used in the process according to 20 the present invention for production of a water-absorbent resin, includes the aforementioned surface-crosslinking agent and water as essential components and has a hydrophilic organic solvent content of 0 to 10 mass % relative to the surface-crosslink-treating agent. The amount of the water, which is contained in the surface-crosslink-treating 25 agent in the present invention, depends upon water content of the water-absorbent resin powder being used, but is favorably in the range of 0.5 to 20 mass %, more favorably 0.5 to 10 mass %, particularly favorably 0.5 to 7 mass %, most favorably 0.5 to 4 mass %, relative to the water-absorbent resin powder. 19 WO 2004/099265 PCT/JP2004/006509 The hydrophilic organic solvent content of the surface-crosslink-treating agent in the present invention is in the range of 0 to 10 mass % and favorably 0 to 8 mass %, more favorably 0 to 5 mass %, still more favorably 0 to 3 mass %, yet still more favorably 0 to 1 mass %, particularly favorably 0 mass % (a substantially not 5 contained state), relative to the surface-crosslink-treating agent. By the process according to the present invention, the properties are enhanced, and the below-mentioned novel water-absorbent resin is obtained. Furthermore, as to this process, the use of the surface-crosslink-treating agent, of which the hydrophilic organic solvent content has been reduced, solves the problems of environmental 10 contamination due to waste liquids and/or waste gases discharged during the production, and further, gratifies the use circumstances such-that the water-absorbent resin is used for the sanitary materials which contact directly with human bodies. Hereupon, the hydrophilic organic solvent will do if it is an organic compound (usually having no or only one functional group) which does not make a crosslinking 15 reaction with the acid group, favorably the carboxyl group, possessed by the water-absorbent resin. Specific examples thereof include: alcohols (e.g. ethyl alcohol, propyl alcohol, isopropyl alcohol); ketones (e.g. acetone); ethers (e.g. dioxane, alkoxy(poly)ethylene glycols, tetrahydrofuran); amides * (e.g. 6-caprolactam); and sulfoxides (e.g. dimethyl sulfoxide). 20 In the present invention, the hydrophilic organic solvent refers to an organic compound which can dissolve into liquid water at normal temperature. Usually, its solubility is usually not less than 1 g, favorably not less than 10 g, in 100 g of water of normal temperature. In the present invention, the hydrophilic organic solvent needs to be a liquid at normal temperature. However, the solvent which exercises at 25 the maximum the effects intended in the present invention is a volatile hydrophilic organic solvent, for example, a hydrophilic organic solvent having a boiling point of favorably 50 to 170 *C, more favorably 60 to 150 *C, particularly favorably 60 to 130 *C. 20 WO 2004/099265 PCT/JP2004/006509 Incidentally, in the case where the crosslinking agent is an organic compound, the distinction between the crosslinking agent and the hydrophilic organic solvent is as follows. Usually, a compound which substantially does not make a crosslinking reaction with the water-absorbent resin (compound which substantially does not 5 change the properties of the water-absorbent resin) under certain selected reaction conditions is classified as the hydrophilic organic solvent. On the other hand, for example, in the case where a crosslinking reaction runs by mixing the water-absorbent resin with an organic compound or its aqueous solution and then heating them, this organic compound is defined as the crosslinking agent. 10 The surface-crosslink-treating agent in the present invention may further include components other than the above-mentioned, in the range not spoiling the effects of the present invention. Examples of such components include water-insoluble fine particle powders and surfactants. In the process according to the present invention for production of a 15 water-absorbent resin, the method for adding the surface-crosslink-treating agent to the water-absorbent resin powder is not especially limited. However, examples thereof include: a method in which the surface-crosslink-treating agent is dropwise added to the water-absorbent resin powder to mix them together; and a method in which the surface-crosslink-treating agent is sprayed to the water-absorbent resin 20 powder. When the surface-crosslink-treating agent is added to the water-absorbent resin powder, it is favorable to use a mixing apparatus in order to effectively carry out the addition. Although not especially limited, the usable mixing apparatus has great mixing power favorably for uniformly and surely mixing the water-absorbent resin 25 powder and the surface-crosslink-treating agent together. Examples of the mixing apparatus include cylinder type mixers, double-wall cone type mixers, V-character-shaped mixers, ribbon type mixers, screw type mixers, fluidized-furnace rotary disk type mixers, gas current type mixers, twin-arm kneaders, internal mixers, 21 WO 2004/099265 PCT/JP2004/006509 pulverizing type kneaders, rotary mixers, and screw type extruders. It does not matter whether the mixing speed is high or not. In the process according to the present invention for production of a water-absorbent resin, the water-absorbent resin powder favorably has a temperature 5 in the range of 40 to 80 *C, more favorably 45 to 80 *C, still more favorably 50 to 70 *C, when the surface-crosslink-treating agent is added thereto. In the case where the water-absorbent resin powder has a temperature of lower than 40 *C when the surface-crosslink-treating agent is added thereto, there are disadvantages in that, when the water-absorbent resin is produced under high-humidity environments, dew 10 condensation tends to occur to thus cause troubles. In the case where the water-absorbent resin powder has a temperature of higher than 80 *C when the surface-crosslink-treating agent is added thereto, there are disadvantages in that it tends to be impossible to uniformly carry out the surface-crosslinking treatment. In the process according to the present invention for production of a 15 water-absorbent resin, although not especially limited, the temperature of the surface-crosslink-treating agent when adding the surface-crosslink-treating agent to the water-absorbent resin powder is, favorably for sufficiently exercising the effects of the present invention, a temperature which substantially does not exceed that of the water-absorbent resin powder which undergoes the addition of the 20 surface-crosslink-treating agent. In the process according to the present invention for production of a water-absorbent resin, the surface-crosslinking treatment is carried out by heating after the surface-crosslink-treating agent has been added to the water-absorbent resin powder. 25 The heating temperature (temperature of the material or temperature of the heat medium) is favorably in the range of 60 to 260 *C, more favorably 80 to 240 *C, still more favorably 100 to 220 *C, particularly favorably 120 to 200 *C. The heating duration is favorably in the range of 1 to 120 minutes, more favorably 10 to 100 22 WO 2004/099265 PCT/JP2004/006509 minutes, still more favorably 20 to 90 minutes, particularly favorably 30 to 60 minutes. Favorable examples of combinations of the heating temperature and the heating duration include the following: at 180 *C for 1 to 90 minutes and at 200 *C for I to 60 minutes. 5 In the process according to the present invention for production of a water-absorbent resin, it is important that the heating is begun beyond 0 second and within 5 rpinutes from the end of the addition of the surface-crosslink-treating agent to the water-absorbent resin powder. Specifically, it is important that the time of from the end of the aforementioned step (3) till the beginning of the aforementioned 10 step (4) is beyond 0 second and within 5 minutes. This time is favorably within 4 minutes, more favorably within 3 minutes, still more favorably within 2 minutes, particularly favorably within 1 minute. The effects of the present invention are exercised by, in this way, beginning the heating within 5 minutes from the end of the addition of the surface-crosslink-treating agent to the water-absorbent resin powder. 15 In the case where the time of from the end of the addition of the surface-crosslink-treating agent to the water-absorbent resin powder till the beginning of the heating is beyond 5 minutes, the effects of the present invention cannot be exercised. Incidentally, in the present invention, the time of from the end of the addition 20 of the surface-crosslink-treating agent to the water-absorbent resin powder till the beginning of the heating refers specifically to the time of from the end of the step (3) (of adding the surface-crosslink-treating agent to the water-absorbent resin powder) till the beginning of the step (4) (of heating the resultant mixture to thereby carry out the surface-crosslinking treatment), for example, till the charging into an apparatus 25 for the step (4). In addition, in the case of the continuous production, the above time can easily be calculated from such as: the amount of the water-absorbent resin being fed (supplied) per unit time; the stagnation time of the water-absorbent resin in an apparatus for adding the surface-crosslink-treating agent thereto to mix them 23 WO 2004/099265 PCT/JP2004/006509 together; and the transportation time of till charging the resultant mixture into the apparatus for the step (4) of heating it to thereby carry out the surface-crosslinking treatment. Specifically, the above time may be determined by actually measuring or calculating the powder migration time of from an outlet of the mixer to an inlet of the 5 heater. As a method for surface-crosslinking the water-absorbent resin, working examples as set out in JP.-A-508517/1996 (Kohyo) disclose such as arts including the steps of: continuously mixing the water-absorbent resin powder (being fed at 1,000 kg/h) with a treating agent (surface-crosslinking agent); and then once storing the 10 resultant mixture; and then continuously heating the mixture. Like this, in conventional arts, generally, once intermediately storing the water-absorbent resin has been carried out as a cushion linking the steps together between the mixer for the surface-crosslinking agent and the subsequent reactor (heater). In addition, in the case where the water-absorbent resin is continuously 15 produced, the steps are linked together by use of transporters. However, as the production scale of the water-absorbent resin increases into the range of tens of thousands of tons to hundreds of thousands of tons per year, not less than a definite conveyance distance (conveyance time) between the steps has become necessary besides the above storage. Therefore, it has been the actual situation that there are 20 intermediate steps (for the conveyance or storage) of around ten to tens of minutes, as the case may be, several hours, between the steps. However, in order to use the specific surface-crosslink-treating agent which includes the surface-crosslinking agent and water as essential components and of which the hydrophilic organic solvent content has been reduced, the present 25 inventors have directed their attention to the intermediate step between the mixer for the surface-crosslink-treating agent and the subsequent reactor (heater) and then found out that the omission or simplification of such an intermediate step is important for enhancing the properties of the water-absorbent resin. This omission 24 WO 2004/099265 PCT/JP2004/006509 or simplification of the intermediate step enables not only the enhancement of the performances of the water-absorbent resin but also the reduction of the investment in plant and equipment. Examples of production facilities means for achieving the present invention 5 include a facilities layout such that the reactor (heater) is set below the apparatus for adding and mixing the surface-crosslink-treating agent. Specifically, the water-absorbent resin with which the surface-crosslink-treating agent has been mixed is discharged from the apparatus for carrying out the step (3) (of adding the surface-crosslink-treating agent to the water-absorbent resin powder), and then freely 10 falls, and then is charged into the surface treatment reactor (heater). Thereby the time of from the end of the step (3) till the beginning of the step (4) is shortened. The above process according to the present invention for production of a water-absorbent resin provides the below-mentioned novel water-absorbent resin. Specifically, this process provides the water-absorbent resin according to the 15 present invention which is a water-absorbent resin obtained by a process including the step of polymerizing and crosslinking a monomer component including acrylic acid and/or its salt (neutralized material) as a main component, with the water-absorbent resin being characterized by: having a mass-average particle diameter of 300 to 600 gm; including a powder having particle diameters of smaller 20 than 150 pm in an amount of 0 to 10 mass % relative to the water-absorbent resin; and exhibiting a total absorption capacity of not less than 70 (g/g) and an absorption efficiency of not less than 70 % under load. The fact that the above water-absorbent resin according to the present invention is novel has been confirmed not only by analyzing the current state of a 25 large number of commercially available products (e.g. water-absorbent resins, diapers) in the worldwide range, but also by comparatively evaluating many arts which have hitherto been proposed. The two novel parameters found out by the present inventors, namely, the total 25 WO 2004/099265 PCT/JP2004/006509 absorption capacity and the absorption efficiency under load, are defined by the below-mentioned equations based on values given by absorption of a 0.90 mass % aqueous sodium chloride solution (25 *C) for 1 hour. Detailed descriptions about the measurement of these values for 1 hour are given in the below-mentioned 5 detailed description of the preferred embodiments. Hereupon, the aforementioned equations are as follows: total absorption capacity (g/g) = absorption capacity (g/g) without load + monolayer absorption capacity (g/g) under load; and absorption efficiency (%) under load = monolayer absorption capacity (g/g) 10 under load x 100/absorption capacity (g/g) without load. The novel water-absorbent resin according to the present invention is a water-absorbent resin which has the aforementioned particle diameters and exhibits the total absorption capacity and the absorption efficiency under load in the aforementioned ranges. However, it is favorable that this resin is a 15 surface-crosslinked one and further has the below-mentioned particle diameter elements (mass-average particle diameter, ratio of powder having particle diameters of smaller than 150 pim, particle diameter distribution) and exhibits the absorption capacity without load, the monolayer absorption capacity under load, the total absorption capacity, and the absorption efficiency under load in the below-mentioned 20 ranges. The novel water-absorbent resin according to the present invention is favorably used jointly with additives (e.g. deodorants, inorganic powders). The water-absorbent resin according to the present invention is free of limitation in respect to its production process if it is controlled in respect to the particle diameter elements (mass-average particle diameter, ratio of powder having 25 particle diameters of smaller than 150 lam), the total absorption capacity, and the absorption efficiency under load. However, this resin can easily be obtained by a process including the steps of: polymerizing and crosslinking a monomer component including acrylic acid and/or its salt (neutralized material) as a main component; and 26 WO 2004/099265 PCT/JP2004/006509 then controlling the particle diameters of the resultant water-absorbent resin in the aforementioned range; and then surface-crosslinking the water-absorbent resin, when particularly processing the water-absorbent resin by the novel surface-crosslinking treatment aforementioned about the production process according to the present 5 invention. Hereinafter, further descriptions are given about the water-absorbent resin obtained by the production process according to the present invention or the novel water-absorbent resin according to the present invention. The water-absorbent resin, as obtained by carrying out the surface-crosslinking 10 treatment in the aforementioned way, is adjusted (regulated) to a specific particle size favorably for sufficiently exercising the effects of the present invention. This particle size is favorably such that: particles of smaller than 850 pm but not smaller than 150 pm comprise not less than 90 mass % of the entirety, and particles of not smaller than 300 pm comprise not less than 60 mass % of the 15 entirety; and more favorably such that: the particles of smaller than 850 pm but not smaller than 150 pm comprise not less than 95 mass %, still more favorably not less than 98 mass %, of the entirety. In addition, the particles of not smaller than 300 pm comprise more favorably not less than 65 mass %, still more favorably not less than 70 mass %, particularly favorably not less than 75 mass %, of the entirety. 20 The mass-average particle diameter of the water-absorbent resin in the present invention is favorably in the range of 200 to 700 pm, more favorably 300 to 600 pm, particularly favorably 380 to 550 pm, most favorably 400 to 500 pm. The mass-average particle diameter of the water-absorbent resin may be adjusted (regulated) by such as agglomeration, if necessary. 25 The water-absorbent resin in the present invention includes a powder having particle diameters of smaller than 150 pm in an amount of favorably 0 to 10 mass %, more favorably 0 to 8 mass %, still more favorably 0 to 5 mass %, particularly favorably 0 to 3 mass %, relative to the water-absorbent resin. 27 WO 2004/099265 PCT/JP2004/006509 In addition, as to the water-absorbent resin in the present invention, the logarithmic standard deviation (ac; the decrease of its value indicates that the particle diameter distribution becomes narrower) (which is determined in the below-mentioned way) of the particle diameter distribution is favorably in the range 5 of 0.25 to 0.50, more favorably 0.27 to 0.48, still more favorably 0.30 to 0.45. Logarithmic standard deviation of particle diameter distribution: This is a value obtained by a process including the steps of: classifying the water-absorbent resin with JIS standard sieves having mesh opening sizes of 850 pm, 710 pm, 600 pm, 500 pm, 425 pm, 300 pm, 212 jim, 150 pm, and 45 pm; and then plotting the 10 percentages R of the residues (remaining on these sieves) on a logarithmic probability paper; and then, from its result, determining a particle diameter X, when R = 84.1 mass % and a particle diameter X 2 when R = 15.9 mass %; and then introducing these determined values into the following equation. uaC= 0.5 x ln(X 2 /Xi) 15 For aC to be more than 0.50 indicates such a broad particle diameter distribution of a powder as to cause such as segregation and powder-supply amount errors in the handling of the powder. Therefore, such aC is not very favorable to practical use for such as diapers. On the other hand, for aC to be less than 0.25 indicates such a narrow particle diameter distribution of a powder as to: be favorable 20 for the handling of the powder; but involve the increase of the amounts of the coarse particles and fine powder being recycled for the adjustment (regulation) of the particle size; and thus cause the decrease of the production amount per unit time. Therefore, such aC is not very favorable. The water-absorbent resin in. the present invention exhibits an absorption 25 capacity of favorably not less than 33 g/g, more favorably not less than 35 g/g, still more favorably not less than 38 g/g, particularly favorably not less than 40 g/g, most favorably not less than 45 g/g, for a 0.90 mass % aqueous sodium chloride solution (physiological saline solution) without load. In the case where the absorption 28 WO 2004/099265 PCT/JP2004/006509 capacity for the 0.90 mass % aqueous sodium chloride solution (physiological saline solution) without load is less than 33 g/g, there is a possibility that the effects of the present invention cannot sufficiently be exercised. For example, the case of the use for diapers results in a small absorption amount and much leakage during practical 5 use. Incidentally, to increase the absorption capacity without load to more than 80 g/g involves decreasing the amounts of the intemal-crosslinking agent and surface-crosslinking agent being used, and thus has a possibility of hindering the effects of the present invention from being exercised sufficiently, and is therefore not very favorable. 10 The water-absorbent resin in the present invention exhibits a monolayer absorption capacity of favorably not less than 25 g/g, more favorably not less than 30 g/g, still more favorably not less than 35 g/g, for the 0.90 mass % aqueous sodium chloride solution (physiological saline solution) under a load of 1.9 kPa. In the case where the monolayer absorption capacity for the 0.90 mass % aqueous sodium 15 chloride solution (physiological saline solution) under the load of 1.9 kPa is less than 25 g/g, there is a possibility that the effects of the present invention cannot sufficiently be exercised. For example, an eruption of the skin (buttocks) is caused by liquids on surfaces of diapers during practical use. Incidentally, the monolayer absorption capacity under load has no especial upper limit. The high it is, the more 20 favorable it is. However, to increase this absorption capacity to not less than a definite value has a possibility of causing such as extreme deterioration of the productivity and, also in property aspects, increase of the water-extractable component content and the gel strength. Therefore, from the viewpoint of the cost performance (production cost per absorption capacity) and the balance between 25 properties, the upper limit may be about 60 g/g. The water-absorbent resin in the present invention exhibits a total absorption capacity of favorably not less than 70 g/g, more favorably not less than 74 g/g, still more favorably not less than 78 g/g, particularly favorably not less than 82 g/g. The 29 WO 2004/099265 PCT/JP2004/006509 total absorption capacity is the sum of the absorption capacity for the 0.90 mass % aqueous sodium chloride solution (physiological saline solution) without load and the monolayer absorption capacity for the 0.90 mass % aqueous sodium chloride solution (physiological saline solution) under the load of 1.9 kPa, and indicates the 5 total absorption capacity in a state without load and in a state under load. In the case where the total absorption capacity is less than 70 g/g, there is a possibility that the effects of the present invention cannot sufficiently be exercised. For example, the case of the use for diapers results in a small. absorption amount and much leakage during practical use, or an eruption of the skin (buttocks) is caused by liquids on 10 surfaces of diapers during practical use. Incidentally, to increase the total absorption capacity to more than 140 g/g involves carrying out the steps of such as polymerization, drying, pulverization, particle size adjustment (regulation), and surface-crosslinking with the productivity much dropped, and is therefore not very favorable in point of costs. 15 The water-absorbent resin in the present invention exhibits an absorption efficiency of favorably not less than 70 %, more favorably not less than 74 %, still more favorably not less than 78 %, particularly favorably not less than 82 %, under load. The absorption efficiency under load is the ratio in percentage of the monolayer absorption capacity for the 0.90 mass % aqueous sodium chloride 20 solution (physiological saline solution) under the load of 1.9 kPa to the absorption capacity for the 0.90 mass % aqueous sodium chloride solution (physiological saline solution) without load, and indicates an absorption property under load. If the absorption efficiency under load is high, then the absorption capacity little varies with the pressure. In the case where the absorption efficiency under load is less 25 than 70 %, there is a possibility that the effects of the present invention cannot sufficiently be exercised. For example, the case of the use for diapers results in a small absorption amount and much leakage during practical use, or an eruption of the skin (buttocks) is caused by liquids on surfaces of diapers during practical use. 30 WO 2004/099265 PCT/JP2004/006509 Incidentally, to increase the absorption efficiency under load to more than 150 % involves carrying out the steps of such as polymerization, drying, pulverization, particle size adjustment (regulation), and surface-crosslinking with the productivity much dropped, and is therefore not very favorable in point of costs. 5 The water-absorbent resin in the present invention particularly favorably exhibits the total absorption capacity of not less than 70 g/g and the absorption efficiency of not less than 70 % under load. The water content and water-extractable component content of the water-absorbent resin according to the present invention are in the aforementioned 10 ranges, and the residual monomer content of this resin is usually in the range of 0 to 1,000 mass ppm, favorably 0 to 500 mass ppm, more favorably 0 to 400 mass ppm. If necessary, the water-absorbent resin in the present invention may be provided with various functions by further adding thereto additives such as: deodorants; antibacterial agents; perfumes; various inorganic powders; foaming 15 agents; pigments; dyes; hydrophilic short fibers; plasticizers; pressure-sensitive adhesives; surfactants; manure; oxidants; reducing agents; chelating agents; antioxidants; water; water-soluble polymers; binders; and salts. Incidentally, as to the present invention, in the case where the additive is substantially united with the water-absorbent resin by adding the additive to the 20 water-absorbent resin to combine them together (due to such as absorption, adsorption, or mixing), the resultant material is a mixture in a sense. However, as long as this mixture of the water-absorbent resin and the additive (this mixture is commonly called "water-absorbing agent") satisfies the aforementioned ranges of the particle diameters, the total absorption capacity, and the absorption efficiency under 25 load, this mixture of the water-absorbent resin and the additive is also taken as the water-absorbent resin which is referred to in the present invention. In other words, in the present invention, the water-absorbent resin, which is obtained by a process including the step of polymerizing and crosslinking a monomer component including 31 WO 2004/099265 PCT/JP2004/006509 acrylic acid and/or its salt (neutralized material) as a main component, is a conception encompassing what is commonly . called "water-absorbing agent" obtained by combining the water-absorbent resin with the above additive. Then, the content of the water-absorbent resin in such a water-absorbing agent is favorably in 5 the range of 70 to 100 mass %, more favorably 80 to 100 mass %, particularly favorably 90 to 100 mass %, relative to the water-absorbing agent. The water-absorbing agent may contain water as a trace component. Favorable examples of the deodorant include: extracts from leaves of Theaceae plants, which are cited as examples in USP 6,469,080 and WO 2003/104349; 10 composite hydrous oxides of zinc-silicon or zinc-aluminum, which are cited as examples in the specification of Japanese Patent Application No. 280373/2003; and specific zeolite cited as examples in the specification of Japanese Patent Application No. 001778/2004. The amount of the deodorant being used is favorably in the range of 0.001 to 10 mass parts, more favorably 0.05 to 5 mass parts, particularly 15 favorably 0.1 to 3 mass parts, per 100 mass parts of the water-absorbent resin. The case where the amount of the deodorant being added is smaller than 0.001 mass part has a possibility of resulting in failure to obtain the desired deodorization effect and is therefore not very favorable. On the other hand, the addition of the deodorant in an amount of larger than 10 mass parts has a merit of giving a material excellent in 20 the deodorization effect, but greatly increases the price of the resultant water-absorbent resin composition itself and is therefore, in point of costs, not very favorable to the use of the resultant water-absorbent resin for disposable sanitary materials/absorbent articles (e.g. disposable diapers/sanitary napkins). For the purpose of improving the handling easiness of the water-absorbent 25 resin under a high humidity, it is also favorable to add thereto either a fine particulate silicon dioxide powder as the inorganic powder or a fine particulate polyvalent-metal stearate powder as the salt. The amount of these additives being used is favorably in the range of 0.01 to 10 mass parts, more favorably 0.05 to 5 mass parts, 32 WO 2004/099265 PCT/JP2004/006509 particularly favorably 0.1 to 1 mass part, per 100 mass parts of the water-absorbent resin. The case where the amount of the fine particulate silicon dioxide powder and/or fine particulate polyvalent-metal stearate powder being added is smaller than 0.01 mass part has a possibility of resulting in failure to obtain the desired effect of 5 improving the handling easiness under a high humidity and is therefore not very favorable. On the other hand, the addition of the fine particulate silicon dioxide powder and/or fine particulate polyvalent-metal stearate powder in an amount of larger than 10 mass parts has a merit of giving a material excellent in the handling easiness under a high humidity, but greatly increases the price of the resultant 10 water-absorbent resin composition itself and is therefore, in point of costs, not very favorable to the use of the resultant water-absorbent resin for disposable sanitary material s/absorbent articles (e.g. disposable diapers/sanitary napkins). As to the water-absorbent resin in the present invention, the shape of its particles may be such an irregularly pulverized shape as obtained by the production 15 process according to the present invention, but may be, for example, a shape as it is obtained by the reversed-phase suspension polymerization, namely, such as a spherical shape. However, as to the reversed-phase suspension polymerization, the shape of the resultant water-absorbent resin is a spherical shape or a shape of its agglomerate and 20 therefore often provides insufficient results with regard to mixing with or fixation to (hold on) pulp and is particularly unsuitable for recently trendy diapers containing water-absorbent resins in high concentrations. Thus, the shape of the water-absorbent resin according to the present invention is favorably an irregularly pulverized shape (i.e. a shape of a pulverized powder). 25 The water-absorbent resin obtained by the production process according to the present invention and the novel water-absorbent resin according to the present invention are usable for various uses of water-absorbent resins, for example, for sanitary materials, engineering works and building, solidification of waste liquids, 33 WO 2004/099265 PCT/JP2004/006509 agriculture and plants, and foods. Incidentally, in the present invention, the absorbent article refers to a terminal consumer product which is a molding that contains a water-absorbent resin, and the absorbent article is represented by disposable diapers, sanitary napkins, and 5 incontinent pads. Such an absorbent article favorably uses, for its molding, a fibrous material. As to the water-absorbent resin according to the present invention, if the mass ratio of the water-absorbent resin to the total of the water-absorbent resin and the fibrous material is favorably in the range of 20 to 100 mass %, more favorably 30 to 90 mass %, particularly favorably 30 to 60 mass %, and if the 10 amount of the water-absorbent resin being used per one absorbent article is favorably in the range of 5 to 25 g, more favorably 8 to 15 g, then the water-absorbent resin can exercise the maximum effects in such an absorbent article. Furthermore, the more uniformly the water-absorbent resin according to the present invention and the fibrous material are mixed together (the less locally the water-absorbent resin is 15 distributed), the more this resin can exercise the maximum effects in such an absorbent article. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention is more specifically illustrated by the following Examples of some preferred embodiments in comparison with 20 Comparative Examples not according to the present invention. However, the present invention is not limited to the below-mentioned Examples. In the case where a commercially available water-absorbent resin (e.g. water-absorbent resin in a diaper) has already absorbed moisture in the distribution process, the measurement of the properties will do if it is carried out after the 25 water-absorbent resin has been dried (e.g. dried under a reduced pressure at 60 *C for 16 hours) so as to reach an equilibrium water-containing state (where the water content is, for example, around 5 mass %). Hereinafter, although detailed data are omitted, all the water-absorbent resins 34 WO 2004/099265 PCT/JP2004/006509 obtained in accordance with the present invention were substantially water-insoluble and had water contents of not higher than 7 mass % (solid contents of not lower than 93 mass %) and residual monomer contents of not higher than 400 mass ppm. Incidentally, the performances of the water-absorbent resins and absorbent 5 articles were measured by the following methods. (a) Absorption capacity without load: An amount of 0.2 g of water-absorbent resin was unifonnly placed into a nonwoven-fabric-made bag (60 mm x 80 mm) and then immersed into a 0.90 mass % aqueous sodium chloride solution (physiological saline solution) of which 10 the temperature had been adjusted to 25 *C. After 60 minutes, the bag was pulled up and then drained of water at 250 G with a centrifugal separator for 3 minutes, and then the mass W 2 (g) of the bag was measured. In addition, the same procedure as the above was carried out without the water-absorbent resin, and the resultant mass W, (g) was measured. Then, the absorption capacity (g/g) without load was 15 calculated from these masses W, and W 2 in accordance with the following equation: Absorption capacity (g/g) without load = ((mass W 2 (g) - mass W 1 (g))/mass (g) of water-absorbent resin) - 1 (b) Monolayer absorption capacity under load: Onto a stainless metal gauze of 400 meshes (mesh opening size: 38 pim) at the 20 bottom of a plastic supporting cylinder of 60 mm in inner diameter (wherein the metal gauze had been fused to one edge (bottom) of a cylindrical section of the supporting cylinder), there was uniformly spread 0.20 g of water-absorbent resin, and further thereon, there was mounted a piston (cover plate), wherein the piston had an outer diameter of only a little smaller than 60 mm and made no gap with the inner 25 wall surface of the supporting cylinder, but was not hindered from moving up and down. Then, the total mass W 3 (g) of the supporting cylinder, the water-absorbent resin, and the piston was measured. On this piston, there was mounted a load as adjusted so that a load of 20 g/cm 2 (1.96 kPa) including the piston could uniformly 35 WO 2004/099265 PCT/JP2004/006509 be applied to the water-absorbent resin. Thereby one set of measurement apparatus had been completed. A glass filter plate of 90 mm in diameter was mounted inside a Petri dish of 150 mm in diameter, and then a 0.90 mass % aqueous sodium chloride solution (physiological saline solution) of 25 *C was added up to the same level as 5 the upside of the glass filter plate, on which a filter paper of 9 cm in diameter (No.2 of Toyo Filter Paper Co., Ltd.) was then mounted so that its entire surface would be wetted, and further, an excess of liquid was removed. The above one set of measurement apparatus was mounted on the above wet filter paper, thereby allowing the water-absorbent resin to absorb the liquid under 10 load. If the liquid surface went down from the upside of the glass filter plate, then the liquid was added to keep the liquid surface level on a constant level. Then, 1 hour later, the one set of measurement apparatus was removed by being lifted to re-measure the mass W 4 (g) excluding the load (total mass of the supporting cylinder, the swollen water-absorbent resin, and the piston). 15 Then, the monolayer absorption capacity (g/g) under load was calculated from these masses W 3 and W 4 in accordance with the following equation: Monolayer absorption capacity (g/g) under load = (mass W 4 (g) - mass W 3 (g))/mass (g) of water-absorbent resin (c) Mass(weight)-average particle diameter (D50): 20 Water-absorbent resins were classified with JIS standard sieves having mesh opening sizes of such as 850 pm, 600 pm, 500 jm, 425 Wm, 300 pm, 212 Jim, 150 pm, 106 pm, and 75 pm. Then, the percentages of the residues on these sieves were plotted on a logarithmic probability paper. Therefrom, the mass-average particle diameter (D50) was read. 25 As to the sieve classification, 10.00 g of water-absorbent resin powder or water-absorbent resin was placed onto JIS standard sieves (having mesh opening sizes of such as 850 pm, 600 pim, 500 gm, 425 pm, 300 jim, 212 pm, 150 jm, 106 pim, and 75 pm) (The IIDA TESTING SIEVE: inner diameter = 80 mm) and then 36 WO 2004/099265 PCT/JP2004/006509 classified with a ROTAP type sieve shaker (ES-65 type sieve shaker produced by lida Seisakusho K.K.) for 10 minutes. Incidentally, as described in such as USP 5,051,259, the mass-average particle diameter (D50) refers to the particle diameter of a standard sieve having a definite mesh opening size and corresponding to 50 5 mass % of the entire particles and, in the below-mentioned Examples, was calculated by use of JIS standard sieves having mesh opening sizes of 850 gm, 600 jm, 300 pm, and 150 gm. (d) Absorption efficiency under load: The absorption capacity without load and monolayer absorption capacity under 10 load of the water-absorbent resin were measured by the methods as mentioned in (a) and (b) above. Then, the absorption efficiency (%) under load was calculated in accordance with the following equation: Absorption efficiency (%) under load = monolayer absorption capacity (g/g) under load x 100/absorption capacity (g/g) without load 15 (e) Total absorption capacity: The absorption capacity without load and monolayer absorption capacity under load of the water-absorbent resin were measured by the methods as mentioned in (a) and (b) above. Then, the total absorption capacity (g/g) was calculated in accordance with the following equation: 20 Total absorption capacity (g/g) = monolayer absorption capacity (g/g) under load + absorption capacity (g/g) without load (f) Evaluation of absorbent article (test for wet-back amount): The absorbent articles as obtained from the below-mentioned Examples and Comparative Examples were used. A load of 1.96 kPa was applied to the entirety 25 of each absorbent article, and then they were left intact at room temperature. An amount of 75 g of a 0.90 mass % aqueous sodium chloride solution (physiological saline solution) as adjusted to 37 *C was injected into a central portion of the absorbent article through a cylinder of 70 mm in diameter and 100 mm in height. 37 WO 20041099265 PCT/JP2004/006509 The absorbent article was left put under the load for 1 hour, and then the same operation was repeated. Then, 30 minutes later than the fourth-time injection of the physiological saline solution (total amount of physiological saline solution injected = 300 g), the load was removed from the absorbent article, and then a paper towel 5 (manufacturer: Oji Paper-Manufacturing Co., Ltd.; Kitchen Towel Extra-Dry, 30-ply as cut into the size of 120 mm x 450 mm) was mounted on the absorbent article, and then a load of 37 g/cm 2 (3.63 kPa) was applied thereto for 1 minute to measure the amount of the liquid backing to the paper towel. [Production Example 1]: 10 A reaction liquid was prepared by dissolving 2.1 g of polyethylene glycol diacrylate (molar-number-average degree of addition polymerization of ethylene oxide: 8) into 5,500 g of an aqueous solution of sodium acrylate having a neutralization degree of 75 mol % (monomer concentration: 38 mass %). Next, dissolved oxygen was removed from this reaction liquid under a nitrogen gas 15 atmosphere for 30 minutes. Next, the above reaction liquid was supplied to a reactor as prepared by lidding a jacketed stainless twin-arm kneader of 10 liters in capacity having two sigma-type blades. While the reaction liquid was kept at 30 'C, air in the system was displaced with nitrogen gas. Subsequently, while the reaction liquid was stirred, 2.46 g of sodium persulfate and 0.10 g of L-ascorbic acid were 20 added thereto. As a result, polymerization started after about 1 minute. Then, the polymerization was carried out in the range of 30 to 90 *C, and the resultant hydrogel polymer was got out 60 minutes later than the start of the polymerization. The resultant hydrogel polymer was what had been divided into small pieces having diameters of about 5 mm. This hydrogel polymer having been divided into small 25 pieces was spread-onto a metal gauze of 50 meshes (mesh opening size: 300 im) and then dried with hot air of 170 *C for 50 minutes. Next, the dried product was pulverized with a vibratory mill and then classified and regulated with a metal gauze of 20 meshes (mesh opening size: 850 pm), thus obtaining a water-absorbent resin 38 WO 2004/099265 PCT/JP2004/006509 powder (1) of an irregularly pulverized shape, which exhibited an absorption capacity of 57 (g/g) without load and had a mass-average particle diameter of 425 Am and included a powder having particle diameters of smaller than 150 pm in an amount of 2 mass % relative to the water-absorbent resin powder. 5 [Production Example 2]: A reaction liquid was prepared by dissolving 2.2 g of polyethylene glycol diacrylate (molar-number-average degree of addition polymerization of ethylene oxide: 8) into 5,500 g of an aqueous solution of sodium acrylate having a neutralization degree of 75 mol % (monomer concentration: 36 mass %). Next, 10 dissolved oxygen was removed from this reaction liquid under a nitrogen gas atmosphere for 30 minutes. Next, the above reaction liquid was supplied to a reactor as prepared by lidding a jacketed stainless twin-arm kneader of 10 liters in capacity having two sigma-type blades. While the reaction liquid was kept at 30 *C, air in the system was displaced with nitrogen gas. Subsequently, while the reaction 15 liquid was stirred, 2.46 g of sodium persulfate and 0.10 g of L-ascorbic acid were added thereto. As a result, polymerization started after about 1 minute. Then, the polymerization was carried out in the range of 30 to 90 *C, and the resultant hydrogel polymer was got out 60 minutes later than the start of the polymerization. The resultant hydrogel polymer was what had been divided into small pieces having 20 diameters of about 5 mm. This hydrogel polymer having been divided into small pieces was spread onto a metal gauze of 50 meshes (mesh opening size: 300 rm) and then dried with hot air of 170 'C for 50 minutes. Next, the dried product was pulverized with a vibratory mill and then classified and regulated with a metal gauze of 20 meshes (mesh opening size: 850 pm), thus obtaining a water-absorbent resin 25 powder (2) of an irregularly pulverized shape, which exhibited an absorption capacity of 56 (g/g) without load and had a mass-average particle diameter of 370 pm and included a powder having particle diameters of smaller than 150 pm in an amount of 5 mass % relative to the water-absorbent resin powder. 39 WO 2004/099265 PCT/JP2004/006509 [Example 1]: An amount of 100 mass parts of the water-absorbent resin powder (1), having been obtained from Production Example 1 and having a powder temperature of 60 *C, was mixed with a surface-crosslink-treating agent (having been prepared from 5 0.4 mass part of propylene glycol, 0.02 mass part of ethylene glycol diglycidyl ether, 0.25 mass part of 1,4-butanediol, and 2.5 mass parts of water) by Lodige Mixer. Then, 2 minutes later, the resultant mixture was placed into a heating treatment apparatus having an adjusted temperature of 195 *C and then heat-treated for 45 minutes, thus obtaining a water-absorbent resin (1). 10 Shown in Table I are the absorption capacity without load, monolayer absorption capacity under load, absorption efficiency under load, total absorption capacity, particle diameter distribution, and mass-average particle diameter of the resultant water-absorbent resin (1). [Example 2]: 15 An amount of 100 mass parts of the water-absorbent resin powder (2), having been obtained from Production Example 2 and having a powder temperature of 60 *C, was mixed with a surface-crosslink-treating agent (having been prepared from 0.4 mass part of propylene glycol, 0.02 mass part of ethylene glycol diglycidyl ether, 0.25 mass part of 1,4-butanediol, and 2.5 mass parts of water) by Lodige Mixer. 20 Then, 1 minute later, the resultant mixture was placed into a heating treatment apparatus having an adjusted temperature of 195 *C and then heat-treated for 45 minutes, thus obtaining a water-absorbent resin (2). Shown in Table 1 are the absorption capacity without load, monolayer absorption capacity under load, absorption efficiency under load, total absorption 25 capacity, particle diameter distribution, and mass-average particle diameter of the resultant water-absorbent resin (2). [Comparative Example 1]: An amount of 100 mass parts of the water-absorbent resin powder (1), having 40 WO 2004/099265 PCT/JP2004/006509 been obtained from Production Example 1 and having a powder temperature of 60 IC, was mixed with a surface-crosslink-treating agent (having been prepared from 0.4 mass part of propylene glycol, 0.02 mass part of ethylene glycol diglycidyl ether, 0.25 mass part of 1,4-butanediol, and 2.5 mass parts of water) by Lodige Mixer. 5 Then, I hour later, the resultant mixture was placed into a heating treatment apparatus having an adjusted temperature of 195 'C and then heat-treated for 55 minutes, thus obtaining a comparative water-absorbent resin (1). Shown in Table I are the absorption capacity without load, monolayer absorption capacity under load, absorption efficiency under load, total absorption 10 capacity, particle diameter distribution, and mass-average particle diameter of the resultant comparative water-absorbent resin (1). [Comparative Example 2]: An amount of 100 mass parts of the water-absorbent resin powder (2), having been obtained from Production Example 2 and having a powder temperature of 15 60 *C, was mixed with a surface-crosslink-treating agent (having been prepared from 0.4 mass part of propylene glycol, 0.02 mass part of ethylene glycol diglycidyl ether, 0.25 mass part of 1,4-butanediol, and 2.5 mass parts of water) by Lodige Mixer. Then, 10 minutes later, the resultant mixture was placed into a heating treatment apparatus having an adjusted temperature of 195 *C and then heat-treated for 55 20 minutes, thus obtaining a comparative water-absorbent resin (2). Shown in Table 1 are the absorption capacity without load, monolayer absorption capacity under load, absorption efficiency under load, total absorption capacity, particle diameter distribution, and mass-average particle diameter of the resultant comparative water-absorbent resin (2). 25 [Comparative Example 3]: An amount of 100 mass parts of the water-absorbent resin powder (2), having been obtained from Production Example 2 and having a powder temperature of 60 *C, was mixed with a surface-crosslink-treating agent (having been prepared from 41 WO 2004/099265 PCT/JP2004/006509 0.4 mass part of propylene glycol, 0.02 mass part of ethylene glycol diglycidyl ether, 0.25 mass part of 1,4-butanediol, and 2.5 mass parts of water) by Lodige Mixer. Then, 20 minutes later, the resultant mixture was placed into a heating treatment apparatus having an adjusted temperature of 195 *C and then heat-treated for 55 5 minutes, thus obtaining a comparative water-absorbent resin (3). Shown in Table 1 are the absorption capacity without load, monolayer absorption capacity under load, absorption efficiency under load, total absorption capacity, -particle diameter distribution, and mass-average particle diameter of the resultant comparative water-absorbent resin (3). 10 [Example 3]: An amount of 50 mass parts of the water-absorbent resin (1) (having been obtained from Example 1) and 50 mass parts of wood-pulverized pulp were mixed together by a mixer in a dry manner. Next, the resultant mixture was pneumatically molded on a wire screen (formed into 400 meshes (mesh opening size: 38 pm)) with 15 a batch type pneumatic molding apparatus and thereby shaped into a web of a size of 120 mm x 400 mm. Furthermore, this web was pressed by a pressure of 196.14 kPa for 5 seconds, thus obtaining an absorbent structure having a basis weight of about 0.05 g/cm 2 . Subsequently, so-called a back sheet made of liquid-impermeable 20 polypropylene (liquid-impermeable sheet), the above absorbent structure, a surface sheet of a nonwoven fabric made of liquid-permeable polypropylene (liquid-permeable sheet) were stuck on each other in that order with a double-coated tape, thus obtaining a sanitary absorbent article (i.e. disposable diaper) (1). The mass of this absorbent article (1) was 45 g. 25 The resultant absorbent article (1) was tested for the wet-back amount. The result is shown in Table 2. [Example 4]: An absorbent article (2) was obtained in the same way as of Example 3 except 42 WO 2004/099265 PCT/JP2004/006509 that the water-absorbent resin (1) was replaced with the water-absorbent resin (2) (having been obtained from Example 2). The resultant absorbent article (2) was tested for the wet-back amount. The result is shown in Table 2. 5 (Comparative Examples 4 to 6]: Comparative absorbent articles (1), (2), and (3) were obtained in the same way as of Example 3 except that the water-absorbent resin (1) was replaced with the comparative water-absorbent resins (1), (2), and (3) (having been obtained from Comparative Examples 1, 2, and 3). 10 The resultant comparative absorbent articles (1), (2), and (3) were tested for the wet-back amount. The results are shown in Table 2. 43 WO 2004/099265 PCT/JP2004/006509 ('4 o r4 ('4 'n 000 CuC 0 0 0 0 C: 0' Lm. (' '9 .4I > .0 - ~ * ~ .ff 44 WO 2004/099265 PCT/JP2004/006509 Table 2 Water-absorbent Wet-back resin used amount Example 3 Water-absorbent 8 resin (1) Example 4 Water-absorbent 7 resin (2) Comparative Comparative 14 Example 4 water-absorbent resin (1) Comparative Comparative 18 Example 5 water-absorbent resin (2) Comparative Comparativo 16 Example 6 water-absorbont resin (3) i 5 [Example 5]: A reaction liquid was prepared by dissolving 2.5 g of polyethylene glycol diacrylate (molar-number-average degree of addition polymerization of ethylene oxide: 8) into 5,500 g of an aqueous solution of sodium acrylate having a 10 neutralization degree of 75 mol % (monomer concentration: 38 mass %). Next, dissolved oxygen was removed from this reaction liquid in the same way as of Production Example 1 and then supplied to the same reactor as used in Production Example 1. While the reaction liquid was kept at 30 *C, air in the system was displaced with nitrogen gas. Subsequently, while the reaction liquid was stirred, 15 2.98 g of sodium persulfate and 0.015 g of L-ascorbic acid were added thereto. As a result, polymerization started after about 1 minute. Then, the polymerization was carried out in the range of 25 to 90 *C, and the resultant hydrogel polymer was got out 60 minutes later than the start of the polymerization. The resultant hydrogel polymer was what had been divided into particles having particle diameters of about 20 1 to about 5 mm. This hydrogel polymer was dried in the same way as of Production Example 1. Next, the dried product was pulverized with a roll mill and then classified with a metal gauze of 850 pm in mesh opening size and then further classified with a metal gauze of 150 pim in mesh opening size in order to remove a 45 WO 2004/099265 PCT/JP2004/006509 fine powder from the classified material, thus obtaining a water-absorbent resin powder (3) of an irregularly pulverized shape, which exhibited an absorption capacity of 55 g/g without load and had a mass-average particle diameter of about 420 [im and included a powder having particle diameters of smaller than 150 pm in 5 an amount of 0.8 mass % relative to the water-absorbent resin powder. Next, 100 mass parts of the water-absorbent resin powder (3), having been obtained in the above way and having a powder temperature of 60 *C, was mixed with an aqueous surface-crosslinking agent solution (having been prepared from 0.5 mass part of propylene glycol, 0.02 mass part of ethylene glycol diglycidyl ether, 0.3 10 mass part of 1,4-butanediol, and 2.5 mass parts of water) by Lodige Mixer. Then, I minute later, the resultant mixture was placed into a heating treatment apparatus having an adjusted temperature of 195 *C and then heat-treated for 40 minutes, thus obtaining a water-absorbent resin (3). Shown in Table 3 are the absorption capacity without load, monolayer 15 absorption capacity under load, absorption efficiency under load, total absorption capacity, and mass-average particle diameter (D50) (determined by the classification with the JIS standard sieves having mesh opening sizes of 850 pm, 600 pm, 300 pm, and 150 pm) of the resultant water-absorbent resin (3). In addition shown in Table 4 is the logarithmic standard deviation (a() of the particle diameter distribution 20 (determined by the classification with the JIS standard sieves having mesh opening sizes of 850 pm, 710 pm, 600 pm, 500 pm, 425 pm, 300 pm, 212 pm, 150 pm, and 45 pm) of the resultant water-absorbent resin (3). Incidentally, in Table 4, there are also listed the particle diameter distributions and their logarithmic standard deviations (a() of the water-absorbent resins obtained 25 from Examples 1 and 2 and Comparative Examples 1 to 3. 46 WO 2004/099265 PCT/JP2004/006509 0' ~ 00 0 00 - .~ *?:47 WO 2004/099265 PCT/JP2004/006509 'm C-4 00 C4 t . oo a*0 00 0D CD4 CD (D CD C>- q: Q - (24 0; e-; Cf2 D El 0%G 00 CL.. Cl -8 C14 Url 00 -So 000 C C0 A a ... la . C4 0W%~ , ( -CL - -. 48 WO 2004/099265 PCT/JP2004/006509 [Example 6]: An absorbent article (3) was obtained in the same way as of Example 3 except that the water-absorbent resin (1) was replaced with the water-absorbent resin (3) (having been obtained from Example 5). 5 The resultant absorbent article (3) was tested for the wet-back amount in the same way as of Example 3. As a result, the wet-back amount was 8 g. [Example 7]: An amount of 35 mass parts of the water-absorbent resin (3) (having been obtained from Example 5) and 65 mass parts of wood-pulverized pulp were mixed 10 together by a mixer in a dry manner. Next, the resultant mixture was shaped into a web of a size of 120 mm x 400 mm with the same apparatus as used in Example 3. Furthermore, this web was pressed under the same conditions as of Example 3, thus obtaining an absorbent structure having a basis weight of about 0.04 g/cm 2 . Subsequently, an absorbent article (4) having a mass of 37 g was obtained in 15 the same way as of Example 3. The resultant absorbent article (4) was tested for the wet-back amount in the same way as of Example 3. As a result, the wet-back amount was 25 g. [Comparative Example 7]: A comparative absorbent article (4) was obtained in the same way as of 20 Example 7 except that the water-absorbent resin (3) was replaced with the comparative water-absorbent resin (1) (having been obtained from Comparative Example 1). The resultant comparative absorbent article (4) was tested for the wet-back amount in the same way as of Example 3. As a result, the wet-back amount was 39 25 g. INDUSTRIAL APPLICATION The water-absorbent resin in the present invention has excellent absorption properties and therefore can be utilized for a wide range of uses. Particularly, 49 - 50 because the water-absorbent resin obtained by the production process according to the present invention involves using no hydrophilic organic solvent in the surface crosslinking treatment, this resin is favourable for sanitary materials/absorbent articles (e.g. disposable diapers/sanitary napkins) and can be used favourably for the sanitary materials by being combined with hydrophilic fibrous materials (e.g. pulverized pulp). It is to be understood that, if any prior art publication is referred to herein, such reference does not constitute an admission that the publication forms a part of the common general knowledge in the art, in Australia or any other country. In the claims which follow and in the preceding description of the invention, except where the context requires otherwise due to express language or necessary implication, the word "comprise" or variations such as "comprises" or "comprising" is used in an inclusive sense, i.e. to specify the presence of the stated features but not to preclude the presence or addition of further features in various embodiments of the invention. N \MI e \ AIASpecI\P5X5I 7 AU Dm- -1 Repla Pyc Apnl 0, do 21AARM

Claims (18)

1. A water-absorbent resin which is a water-absorbent resin comprising sodium polyacrylate obtained by a process including the step of polymerizing and 5 crosslinking a monomer component including acrylic acid and/or its sodium salt (neutralized material) as a main component, wherein the water-absorbent resin has a mass-average particle diameter of 300 to 600 ptm; includes a powder having particle diameters of smaller than 150 ptm in an amount of 0 to 3 mass % relative to the water absorbent resin; and exhibits an absorption capacity of not less than 35 (g/g) without 10 load, a total absorption capacity of not less than 70 (g/g) and an absorption efficiency of not less than 70 % under load, wherein the total absorption capacity and the absorption efficiency under load are defined by the following equations based on values given by absorption of a 0.90 mass % aqueous sodium chloride solution (25 *C) for 1 hour: total absorption capacity (g/g) = absorption capacity (g/g) without load + 15 monolayer absorption capacity (g/g) under load; and absorption efficiency (%) under load = monolayer absorption capacity (g/g) under load x 100/absorption capacity (g/g) without load; wherein the water-absorbent resin has a residual monomer content of 0 to 400 mass ppm and the sodium polyacrylate has a neutralization degree of 50 to 90 20 mol%.

2. A water-absorbent resin according to claim 1, which has a mass-average particle diameter of 380 to 550 pm. 25

3. A water-absorbent resin according to claim I or 2, wherein the particles have an irregularly pulverized shape.

4. A water-absorbent resin according to any one of claims I to 3, which exhibits an absorption capacity of not less than 40 g/g without load. 30

5. A water-absorbent resin according to any one of claims I to 4, which has a logarithmic standard deviation a4 of particle diameter distribution in the range of 0.25 to 0.50, wherein the logarithmic standard deviation a, is defined by the following mathematical expression: 35 a4 = 0.5 x ln (X 2 /X ) N \Melbourne\Cases\Patent\580O0-58999\P58517.AU \Specis\P58517.AU.I Specification 2008-9-2 doc 09/06/09 - 52 where: X, denotes a particle diameter when R = 84.1 mass % obtained by a process including the steps of classifying the water-absorbent resin with JIS standard sieves having mesh opening sizes of 850 pm, 710 pm, 600 pm, 500 pm, 425 pm, 300 pm, 212 pm, 150 pm, and 45 pm and then plotting the percentages R of the residues on a 5 logarithmic probability paper; and X 2 denotes a particle diameter when R = 15.9 mass % determined by the same method as X I.

6. A water-absorbent resin according to any one of claims I to 5, which has a particle size such that particles of smaller than 850 pm but not smaller than 150 pm 10 comprise not less than 90 mass % of the entirety, and particles of not smaller than 300 pm comprise not less than 60 mass % of the entirety.

7. A water-absorbent resin according to any one of claims I to 6, which includes an inorganic powder in an amount of 0.01 to 10 mass parts per 100 mass parts is of the water-absorbent resin.

8. A water-absorbent resin according to any one of claims I to 7, which includes a deodorant in an amount of 0.001 to 10 mass parts per 100 mass parts of the water-absorbent resin. 20

9. A water-absorbent resin according to any one of claims 1 to 8, which exhibits a total absorption capacity of not less than 78 g/g.

10. A water-absorbent resin according to any one of claims I to 9, wherein 25 the sodium polyacrylate has a neutralization degree of 60 to 80 mol %.

11. A water-absorbent resin according to any one of claims I to 10, which has an uncrosslinked water-extractable component content (water-soluble polymer content) of 0 to 10 mass % relative to the water-absorbent resin. 30

12. A process for production of a water-absorbent resin according to any one of claims 1 to 11, which comprises: a step (1) of polymerising a monomer component including an acid group-containing unsaturated monomer as an essential component to thereby obtain a 35 hydrogel polymer; a step (2) of drying and pulverizing the resultant hydrogel polymer to thereby obtain a water-absorbent resin powder; N \Melbourne\Cases\Patent\58000.58999\P58517.AU. I\Specis\P58517 AU I Specification 2008.9-2 doc 09/06109 - 53 a step (3) of adding a surface-crosslink-treating agent to the resultant water-absorbent resin powder, wherein the surface-crosslink-treating agent includes a surface-crosslinking agent and water as essential components and has a hydrophilic organic solvent content of 0 to 10 mass % relative to the surface-crosslink-treating 5 agent; and a step (4) of heating the resultant mixture to thereby carry out surface crosslinking treatment; wherein the time of from the end of the step (3) till the beginning of the step (4) is within 5 minutes. 10

13. A process for production of a water-absorbent resin according to claim 12, wherein the water-absorbent resin powder has a temperature in the range of 40 to 80'C when the surface-crosslink-treating agent is added thereto. 15

14. A process for production of a water-absorbent resin according to claim 12 or 13, wherein the water-absorbent resin powder exhibits an absorption capacity of not less than 40 g/g without load.

15. A process for production of a water-absorbent resin according to any one 20 of claims 12 to 14, wherein the monomer component includes acrylic acid and/or its salt (neutralized material) as a main component.

16. An absorbent article for absorption of excreta and blood, which comprises the water-absorbent resin according to any one of claims I to 11. 25

17. An absorbent article according to claim 16, which further comprises an fibrous material, wherein the mass ratio of the water-absorbent resin to total of the water-absorbent resin and the fibrous material is in the range of 20 to 100 mass %, and the amount of the water-absorbent resin per one absorbent article is in the range of 5 to 30 25g.

18. A water-absorbent resin, a process for its production, or an absorbent article for absorption of excreta and blood comprising it, substantially as herein described with reference to the accompanying examples, excluding comparative 35 examples. N:\Melboune\Cases\Patent\58000-58999\P585 17 AU I\Specis\P58517 AU I Specification 2008.9-2.doc 09/06/09