AU2002220807A1 - Method for catalytic dimerization of isocyanates - Google Patents
Method for catalytic dimerization of isocyanatesInfo
- Publication number
- AU2002220807A1 AU2002220807A1 AU2002220807A AU2080702A AU2002220807A1 AU 2002220807 A1 AU2002220807 A1 AU 2002220807A1 AU 2002220807 A AU2002220807 A AU 2002220807A AU 2080702 A AU2080702 A AU 2080702A AU 2002220807 A1 AU2002220807 A1 AU 2002220807A1
- Authority
- AU
- Australia
- Prior art keywords
- isocyanates
- optionally
- eliminating
- reaction
- reaction medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000012948 isocyanate Substances 0.000 title abstract 3
- 150000002513 isocyanates Chemical class 0.000 title abstract 3
- 238000006471 dimerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 3
- 239000012429 reaction media Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007809 chemical reaction catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000006074 cyclodimerization reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000000415 inactivating effect Effects 0.000 abstract 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000003930 superacid Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
- C08G18/168—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
- C08G18/027—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing urethodione groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
The invention concerns a method for preparing polyisocyanates by cyclodimerization of isocyanate functions borne by initial monomer isocyanates. The invention is characterised in that it comprises steps which consist in: a) providing a reaction medium comprising initial monomer isocyanates, optionally in the presence of a solvent; b) adding to said reaction mixture a (cyclo)dimerization catalyst comprising a compound of the family of super acids; c) heating the reaction medium to a temperature ranging between 0° C. and 300° C., advantageously between 20° C. and 200° C. until the desired rate of transformation is obtained; d) optionally inactivating or eliminating the reaction catalyst; and e) optionally eliminating the unreacted monomer.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0014965A FR2897613B1 (en) | 2000-11-20 | 2000-11-20 | PROCESS FOR THE PREPARATION OF DIMERED POLYISOCYANATES |
| FR0014966 | 2000-11-20 | ||
| FR0014965 | 2000-11-20 | ||
| FR0014966A FR2816939B1 (en) | 2000-11-20 | 2000-11-20 | CATALYTIC DIMERIZATION OF ISOCYANATES |
| PCT/FR2001/003648 WO2002040567A1 (en) | 2000-11-20 | 2001-11-20 | Method for catalytic dimerization of isocyanates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2002220807A1 true AU2002220807A1 (en) | 2002-05-27 |
Family
ID=26212739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002220807A Abandoned AU2002220807A1 (en) | 2000-11-20 | 2001-11-20 | Method for catalytic dimerization of isocyanates |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7297752B2 (en) |
| EP (1) | EP1352006B1 (en) |
| CN (1) | CN1274736C (en) |
| AT (1) | ATE365757T1 (en) |
| AU (1) | AU2002220807A1 (en) |
| BR (1) | BR0115453A (en) |
| DE (1) | DE60129163T2 (en) |
| WO (1) | WO2002040567A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10336184A1 (en) * | 2003-08-07 | 2005-02-24 | Bayer Materialscience Ag | New catalysts for selective isocyanate dimerization |
| DE102008000352A1 (en) | 2008-02-20 | 2009-08-27 | Rhein Chemie Rheinau Gmbh | Cast polyamide preparation using special activators |
| WO2010035666A1 (en) * | 2008-09-26 | 2010-04-01 | Dic株式会社 | Urethane-forming reaction catalyst and method for producing urethane material |
| EP2386600B1 (en) | 2010-04-15 | 2013-06-19 | LANXESS Deutschland GmbH | Cross-linking agent for nitrile rubbers containing isocyanate groups |
| CA3037434C (en) * | 2016-10-19 | 2025-06-10 | Hydro-Quebec | Sulphamic acid derivatives and processes for preparing them |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4031036A (en) | 1975-06-09 | 1977-06-21 | Minnesota Mining And Manufacturing Company | Use of bis(fluoroaliphaticsulfonyl) imides in cationic polymerization |
| DE3030513A1 (en) * | 1980-08-13 | 1982-03-18 | Chemische Werke Hüls AG, 4370 Marl | METHOD FOR PRODUCING AN ISOCYANURATE-FREE URETDION FROM ISOPHORONE DIISOCYANATE AND THE URETDION THEREFORE PRODUCED |
| US4618707A (en) * | 1985-11-25 | 1986-10-21 | Ashland Oil, Inc. | Preparation of menthane diisocyanate by addition of isocyanic acid to terpinyl monoisocyanates |
| JPH01275616A (en) | 1988-04-27 | 1989-11-06 | Kyowa Yuka Kk | polyurethane composition |
| DE4117384A1 (en) | 1991-05-28 | 1992-12-03 | Bayer Ag | METHOD FOR THE PRODUCTION OF LIQUID, STORAGE-STABLE CARBODIIMIDE AND / OR URETONIMIN GROUPS HAVING ORGANIC ISOCYANATES, AND THE USE THEREOF FOR THE PRODUCTION OF POLYURETHANE PLASTICS |
| DE4218540A1 (en) * | 1992-06-05 | 1993-12-09 | Basf Ag | Process for the production of polyisocanates containing uretdione groups |
| US5461135A (en) * | 1994-09-23 | 1995-10-24 | Olin Corporation | Polyisocyanates containing uretidione and allophanate groups, a process for their production, and their use in one and two component coating compositions |
| DE19735043A1 (en) | 1997-08-13 | 1999-02-18 | Bayer Ag | Process for the production of light-colored uretdione polyisocyanates |
| JP3560313B2 (en) | 1998-09-29 | 2004-09-02 | 花王株式会社 | Polyurethane |
| ES2238233T3 (en) * | 1999-10-08 | 2005-09-01 | Mitsui Takeda Chemicals, Inc. | CURABLE ADHESIVE COMPOSITION OF TWO COMPONENTS, WITHOUT SOLVENT. |
-
2001
- 2001-11-20 AU AU2002220807A patent/AU2002220807A1/en not_active Abandoned
- 2001-11-20 CN CNB018191134A patent/CN1274736C/en not_active Expired - Fee Related
- 2001-11-20 BR BR0115453-2A patent/BR0115453A/en not_active Application Discontinuation
- 2001-11-20 AT AT01996571T patent/ATE365757T1/en not_active IP Right Cessation
- 2001-11-20 EP EP01996571A patent/EP1352006B1/en not_active Expired - Lifetime
- 2001-11-20 US US10/432,050 patent/US7297752B2/en not_active Expired - Lifetime
- 2001-11-20 DE DE60129163T patent/DE60129163T2/en not_active Expired - Lifetime
- 2001-11-20 WO PCT/FR2001/003648 patent/WO2002040567A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN1274736C (en) | 2006-09-13 |
| US7297752B2 (en) | 2007-11-20 |
| ATE365757T1 (en) | 2007-07-15 |
| EP1352006B1 (en) | 2007-06-27 |
| US20040014970A1 (en) | 2004-01-22 |
| DE60129163D1 (en) | 2007-08-09 |
| CN1474841A (en) | 2004-02-11 |
| DE60129163T2 (en) | 2008-02-28 |
| WO2002040567A1 (en) | 2002-05-23 |
| EP1352006A1 (en) | 2003-10-15 |
| BR0115453A (en) | 2004-01-06 |
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