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AU2001210762A1 - Sulfonated perfluorocyclobutane ion-conducting membranes - Google Patents

Sulfonated perfluorocyclobutane ion-conducting membranes

Info

Publication number
AU2001210762A1
AU2001210762A1 AU2001210762A AU1076201A AU2001210762A1 AU 2001210762 A1 AU2001210762 A1 AU 2001210762A1 AU 2001210762 A AU2001210762 A AU 2001210762A AU 1076201 A AU1076201 A AU 1076201A AU 2001210762 A1 AU2001210762 A1 AU 2001210762A1
Authority
AU
Australia
Prior art keywords
unsubstituted
substituted
polymer
conducting membranes
saturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001210762A
Inventor
Krzysztof A. Lewinski
Shane S. Mao
David A Ylitalo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of AU2001210762A1 publication Critical patent/AU2001210762A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Conductive Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Fuel Cell (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Disclosed are sulfonated aromatic perfluorocyclobutane polymers meeting a condition selected from: a) the equivalent weight of the polymer is 5000 or less, and b) the proton conductivity of the polymer at 25° C. is 0.01 Siemens per centimeter (S/cm) or higher, and methods of making same, especially sulfonated aromatic perfluorocyclobutane polymers which comprise units according to the formula:wherein -B- is 1,2-perfluorocyclobutylene (C4F6); each -X- is independently selected from the group consisting of: a bond, -O-, -S-, -SO-, -SO2-, -CO-, -NH-, -NR1-, and -R2-, wherein R1 is C1-C25 substituted or unsubstituted, saturated or unsaturated alkyl or aryl and R2 is C1-C25 substituted or unsubstituted, saturated or unsaturated alkylene or arylene; -Ar- is a substituted or unsubstituted C1-C30 at least divalent aromatic hydrocarbon group; n is a non-negative integer chosen independently for each of said repeating units such that the average for the polymer is greater than 0. They are particularly useful in ion conducting membranes for use in electrochemical cells.
AU2001210762A 2000-06-05 2000-10-10 Sulfonated perfluorocyclobutane ion-conducting membranes Abandoned AU2001210762A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09587522 2000-06-05
US09/587,522 US6559237B1 (en) 2000-06-05 2000-06-05 Sulfonated perfluorocyclobutane ion-conducting membranes
PCT/US2000/027939 WO2001094427A1 (en) 2000-06-05 2000-10-10 Sulfonated perfluorocyclobutane ion-conducting membranes

Publications (1)

Publication Number Publication Date
AU2001210762A1 true AU2001210762A1 (en) 2001-12-17

Family

ID=24350141

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001210762A Abandoned AU2001210762A1 (en) 2000-06-05 2000-10-10 Sulfonated perfluorocyclobutane ion-conducting membranes

Country Status (9)

Country Link
US (1) US6559237B1 (en)
EP (1) EP1290041B1 (en)
JP (1) JP2003535929A (en)
KR (1) KR100650483B1 (en)
AT (1) ATE267218T1 (en)
AU (1) AU2001210762A1 (en)
CA (1) CA2407665A1 (en)
DE (1) DE60010937T2 (en)
WO (1) WO2001094427A1 (en)

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US7985805B2 (en) * 2008-05-09 2011-07-26 GM Global Technology Operations LLC Polyelectrolyte membranes comprised of blends of PFSA and sulfonated PFCB polymers
US8003732B2 (en) * 2008-08-25 2011-08-23 GM Global Technology Operations LLC Gradient reinforced proton exchange membrane
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KR101012124B1 (en) 2008-12-17 2011-02-07 한국화학연구원 Sulfonated copolymers containing perfluorocyclobutane groups, preparation methods thereof and uses thereof
KR101017649B1 (en) * 2008-12-30 2011-02-25 한국화학연구원 Subsequent fonned copolymer containing perfluorocyclobutane group, preparation method thereof and use thereof
US20110045381A1 (en) * 2009-08-18 2011-02-24 Gm Global Technology Operations, Inc. Hydrocarbon PEM Membranes with Perfluorosulfonic Acid Groups for Automotive Fuel Cells
US8053530B2 (en) * 2009-08-26 2011-11-08 GM Global Technology Operations LLC Polyelectrolyte membranes made of poly(perfluorocyclobutanes) with pendant perfluorosulfonic acid groups and blends with poly(vinylidene fluoride)
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Also Published As

Publication number Publication date
KR100650483B1 (en) 2006-11-30
EP1290041B1 (en) 2004-05-19
DE60010937D1 (en) 2004-06-24
ATE267218T1 (en) 2004-06-15
EP1290041A1 (en) 2003-03-12
CA2407665A1 (en) 2001-12-13
US6559237B1 (en) 2003-05-06
KR20030007864A (en) 2003-01-23
WO2001094427A1 (en) 2001-12-13
DE60010937T2 (en) 2005-06-16
JP2003535929A (en) 2003-12-02

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