AU2001282569A1 - Negative electrode for lithium secondary cell and method for producing the same - Google Patents
Negative electrode for lithium secondary cell and method for producing the sameInfo
- Publication number
- AU2001282569A1 AU2001282569A1 AU2001282569A AU8256901A AU2001282569A1 AU 2001282569 A1 AU2001282569 A1 AU 2001282569A1 AU 2001282569 A AU2001282569 A AU 2001282569A AU 8256901 A AU8256901 A AU 8256901A AU 2001282569 A1 AU2001282569 A1 AU 2001282569A1
- Authority
- AU
- Australia
- Prior art keywords
- producing
- negative electrode
- same
- lithium secondary
- secondary cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
- B22F7/08—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools with one or more parts not made from powder
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
- H01M4/623—Binders being polymers fluorinated polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
- H01M4/662—Alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/665—Composites
- H01M4/667—Composites in the form of layers, e.g. coatings
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/80—Porous plates, e.g. sintered carriers
- H01M4/801—Sintered carriers
- H01M4/803—Sintered carriers of only powdered material
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- H—ELECTRICITY
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/043—Processes of manufacture in general involving compressing or compaction
- H01M4/0435—Rolling or calendering
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/387—Tin or alloys based on tin
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/10—Battery-grid making
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000-265900 | 2000-09-01 | ||
| JP2000265900A JP4067268B2 (en) | 2000-09-01 | 2000-09-01 | Negative electrode for lithium secondary battery and method for producing the same |
| JP2000265901 | 2000-09-01 | ||
| JP2000-265901 | 2000-09-01 | ||
| JP2000401501 | 2000-12-28 | ||
| JP2000-401501 | 2000-12-28 | ||
| JP2001-254261 | 2001-08-24 | ||
| JP2001254261A JP4212263B2 (en) | 2000-09-01 | 2001-08-24 | Negative electrode for lithium secondary battery and method for producing the same |
| PCT/JP2001/007519 WO2002021616A1 (en) | 2000-09-01 | 2001-08-31 | Negative electrode for lithium secondary cell and method for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2001282569A1 true AU2001282569A1 (en) | 2002-03-22 |
Family
ID=27481580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2001282569A Abandoned AU2001282569A1 (en) | 2000-09-01 | 2001-08-31 | Negative electrode for lithium secondary cell and method for producing the same |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20040043294A1 (en) |
| EP (2) | EP1335438A4 (en) |
| KR (1) | KR100501142B1 (en) |
| CN (1) | CN1280930C (en) |
| AU (1) | AU2001282569A1 (en) |
| CA (1) | CA2420104C (en) |
| WO (1) | WO2002021616A1 (en) |
Families Citing this family (97)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003244188A1 (en) * | 2002-06-26 | 2004-01-19 | Sanyo Electric Co., Ltd. | Negative electrode for lithium secondary cell and lithium secondary cell |
| JP2004127535A (en) * | 2002-09-30 | 2004-04-22 | Sanyo Electric Co Ltd | Negative electrode for lithium secondary battery, and lithium secondary battery |
| JP4135074B2 (en) * | 2002-10-25 | 2008-08-20 | ソニー株式会社 | Negative electrode manufacturing method and battery manufacturing method |
| GB2395059B (en) | 2002-11-05 | 2005-03-16 | Imp College Innovations Ltd | Structured silicon anode |
| JP4088957B2 (en) * | 2002-11-19 | 2008-05-21 | ソニー株式会社 | Lithium secondary battery |
| KR100680650B1 (en) | 2002-11-29 | 2007-02-08 | 미츠이 마이닝 & 스멜팅 콤파니 리미티드 | Negative electrode for non-aqueous electrolyte secondary cell and method for manufacture thereof, and non-aqueous electrolyte secondary cell |
| JP3664253B2 (en) * | 2002-12-26 | 2005-06-22 | ソニー株式会社 | Secondary battery negative electrode and secondary battery using the same |
| WO2004086539A1 (en) | 2003-03-26 | 2004-10-07 | Canon Kabushiki Kaisha | Electrode material for lithium secondary battery and electrode structure having the electrode material |
| JP4027255B2 (en) * | 2003-03-28 | 2007-12-26 | 三洋電機株式会社 | Negative electrode for lithium secondary battery and method for producing the same |
| JP4140425B2 (en) * | 2003-04-10 | 2008-08-27 | ソニー株式会社 | Secondary battery |
| AU2003289402A1 (en) * | 2003-04-23 | 2004-11-19 | Mitsui Mining And Smelting Co., Ltd. | Negative electrode for nonaqueous electrolyte secondary battery, method for manufacturing same and nonaqueous electrolyte secondary battery |
| WO2004105152A2 (en) * | 2003-05-22 | 2004-12-02 | Matsushita Electric Industrial Co., Ltd. | Nonaqueous electrolyte secondary battery and method for producing same |
| JP3963466B2 (en) * | 2003-05-22 | 2007-08-22 | 松下電器産業株式会社 | Nonaqueous electrolyte secondary battery and manufacturing method thereof |
| JP4610213B2 (en) | 2003-06-19 | 2011-01-12 | 三洋電機株式会社 | Lithium secondary battery and manufacturing method thereof |
| TWI249868B (en) * | 2003-09-09 | 2006-02-21 | Sony Corp | Anode and battery |
| KR100570677B1 (en) * | 2003-09-26 | 2006-04-12 | 삼성에스디아이 주식회사 | Lithium secondary battery |
| JP4497904B2 (en) * | 2003-12-04 | 2010-07-07 | 三洋電機株式会社 | Lithium secondary battery and manufacturing method thereof |
| WO2005076389A2 (en) * | 2003-12-23 | 2005-08-18 | Carnegie Mellon University | Self-contained, alloy type, thin film anodes for lithium-ion batteries |
| JP4843936B2 (en) | 2004-01-20 | 2011-12-21 | ソニー株式会社 | Secondary battery and charging / discharging method thereof |
| JP5516300B2 (en) * | 2004-01-20 | 2014-06-11 | ソニー株式会社 | Secondary battery, charge / discharge method thereof, and charge / discharge control element thereof |
| US20060083986A1 (en) * | 2004-03-16 | 2006-04-20 | Wen Li | Battery with tin-based negative electrode materials |
| JP4780923B2 (en) * | 2004-03-30 | 2011-09-28 | 三洋電機株式会社 | Lithium secondary battery |
| CN100367545C (en) * | 2004-04-20 | 2008-02-06 | 三洋电机株式会社 | Electrode for lithium secondary battery and lithium secondary battery |
| JP2005310502A (en) * | 2004-04-20 | 2005-11-04 | Sanyo Electric Co Ltd | Manufacturing method of electrode for chemical cell, and cell |
| JP4078338B2 (en) * | 2004-04-20 | 2008-04-23 | 三洋電機株式会社 | Electrode for lithium secondary battery and lithium secondary battery |
| JP4868786B2 (en) * | 2004-09-24 | 2012-02-01 | 三洋電機株式会社 | Lithium secondary battery |
| WO2006043470A1 (en) * | 2004-10-21 | 2006-04-27 | Matsushita Electric Industrial Co., Ltd. | Negative electrode for battery and battery using same |
| KR100582557B1 (en) | 2004-11-25 | 2006-05-22 | 한국전자통신연구원 | A negative electrode for a lithium metal polymer secondary battery comprising a surface-patterned negative electrode current collector and a manufacturing method thereof |
| CN100438157C (en) * | 2005-08-29 | 2008-11-26 | 松下电器产业株式会社 | Negative electrode for non-aqueous electrolyte secondary battery, producing method therefor, and non-aqueous electrolyte secondary battery |
| JP2007095568A (en) * | 2005-09-29 | 2007-04-12 | Sanyo Electric Co Ltd | Lithium secondary battery and method of manufacturing same |
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| GB0713898D0 (en) | 2007-07-17 | 2007-08-29 | Nexeon Ltd | A method of fabricating structured particles composed of silcon or a silicon-based material and their use in lithium rechargeable batteries |
| GB0713895D0 (en) | 2007-07-17 | 2007-08-29 | Nexeon Ltd | Production |
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| US20090087731A1 (en) * | 2007-09-27 | 2009-04-02 | Atsushi Fukui | Lithium secondary battery |
| US10312518B2 (en) * | 2007-10-26 | 2019-06-04 | Murata Manufacturing Co., Ltd. | Anode and method of manufacturing the same, and secondary battery |
| CN101425572B (en) * | 2007-10-29 | 2011-12-14 | 比亚迪股份有限公司 | Anode plate for lithium ionic cell and preparation thereof |
| JP5361232B2 (en) * | 2008-03-28 | 2013-12-04 | 三洋電機株式会社 | Lithium secondary battery and manufacturing method thereof |
| TWI453306B (en) * | 2008-03-31 | 2014-09-21 | Permelec Electrode Ltd | Method for manufacturing electrode for electrolysis |
| EP2107137B1 (en) * | 2008-03-31 | 2014-10-08 | Permelec Electrode Ltd. | Manufacturing process of electrodes for electrolysis |
| US20090317726A1 (en) * | 2008-04-08 | 2009-12-24 | Sony Corporation | Anode and secondary battery |
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| GB201014706D0 (en) | 2010-09-03 | 2010-10-20 | Nexeon Ltd | Porous electroactive material |
| GB201014707D0 (en) | 2010-09-03 | 2010-10-20 | Nexeon Ltd | Electroactive material |
| US9048502B2 (en) | 2010-12-13 | 2015-06-02 | Sanyo Electric Co., Ltd. | Lithium secondary battery and method for producing the same |
| TWI478424B (en) * | 2010-12-13 | 2015-03-21 | Innot Bioenergy Holding Co | Method for manufaturing organic negative electrode |
| CN102127660B (en) * | 2011-02-28 | 2013-05-01 | 天津赫维科技有限公司 | Lithium aluminum alloy for secondary lithium battery and manufacturing method thereof |
| JP5450478B2 (en) | 2011-02-28 | 2014-03-26 | 株式会社日立製作所 | Non-aqueous secondary battery negative electrode and non-aqueous secondary battery |
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2001
- 2001-08-31 EP EP01961241A patent/EP1335438A4/en not_active Withdrawn
- 2001-08-31 WO PCT/JP2001/007519 patent/WO2002021616A1/en not_active Ceased
- 2001-08-31 EP EP10004070A patent/EP2219249A1/en not_active Withdrawn
- 2001-08-31 CN CNB018148255A patent/CN1280930C/en not_active Expired - Fee Related
- 2001-08-31 CA CA2420104A patent/CA2420104C/en not_active Expired - Fee Related
- 2001-08-31 AU AU2001282569A patent/AU2001282569A1/en not_active Abandoned
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| CA2420104A1 (en) | 2003-02-10 |
| CN1280930C (en) | 2006-10-18 |
| EP1335438A4 (en) | 2009-03-25 |
| US20040043294A1 (en) | 2004-03-04 |
| HK1059149A1 (en) | 2004-06-18 |
| EP1335438A1 (en) | 2003-08-13 |
| CN1449589A (en) | 2003-10-15 |
| WO2002021616A1 (en) | 2002-03-14 |
| EP2219249A1 (en) | 2010-08-18 |
| KR20030029156A (en) | 2003-04-11 |
| KR100501142B1 (en) | 2005-07-18 |
| CA2420104C (en) | 2012-10-30 |
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