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AU2001268596A1 - Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene - Google Patents

Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene

Info

Publication number
AU2001268596A1
AU2001268596A1 AU2001268596A AU6859601A AU2001268596A1 AU 2001268596 A1 AU2001268596 A1 AU 2001268596A1 AU 2001268596 A AU2001268596 A AU 2001268596A AU 6859601 A AU6859601 A AU 6859601A AU 2001268596 A1 AU2001268596 A1 AU 2001268596A1
Authority
AU
Australia
Prior art keywords
base material
reaction
nitrobenzene
aniline
coupling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001268596A
Inventor
Antonio L. Devera
Roger Keranan Rains
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Flexsys America LP
Original Assignee
Flexsys America LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flexsys America LP filed Critical Flexsys America LP
Publication of AU2001268596A1 publication Critical patent/AU2001268596A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
    • B01J2531/985—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases in a water / organic solvent system

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

This invention provides a composition suitable for use in a reaction zone where aniline is reacted with nitrobenzene to obtain intermediates of 4-aminodiphenylamine comprising a solid support having interior channels with base material employed in the reaction loaded into the channels. The cross-sectional dimensions of the channels are such as to provide a restricted transition state with regard to the reaction and to improve the selectivity of the reaction in favor of the intermediates. The invention also provides a method for loading the base material in the solid support. The invention further provides a process for carrying out the above reaction using the above composition.
AU2001268596A 2000-06-21 2001-06-20 Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene Abandoned AU2001268596A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/598,155 US6495723B1 (en) 2000-06-21 2000-06-21 Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene
US09598155 2000-06-21
PCT/US2001/019666 WO2001098252A2 (en) 2000-06-21 2001-06-20 Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene

Publications (1)

Publication Number Publication Date
AU2001268596A1 true AU2001268596A1 (en) 2002-01-02

Family

ID=24394460

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001268596A Abandoned AU2001268596A1 (en) 2000-06-21 2001-06-20 Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene

Country Status (14)

Country Link
US (1) US6495723B1 (en)
EP (1) EP1294675B1 (en)
JP (1) JP2004500981A (en)
KR (1) KR100841873B1 (en)
CN (1) CN1285566C (en)
AT (1) ATE346033T1 (en)
AU (1) AU2001268596A1 (en)
BR (1) BR0111872A (en)
CA (1) CA2413409A1 (en)
DE (1) DE60124709D1 (en)
MX (1) MXPA03000083A (en)
RU (1) RU2280506C2 (en)
TW (1) TW593221B (en)
WO (1) WO2001098252A2 (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8486223B2 (en) * 2003-07-04 2013-07-16 Jiangsu Sinorgchem Technology Co., Ltd. Falling film evaporator
JP4500302B2 (en) * 2003-07-04 2010-07-14 チアンス・シノケム・テクノロジー・カンパニー・リミテッド Method for producing 4-aminodiphenylamine
US8686188B2 (en) 2003-07-04 2014-04-01 Jiangsu Sinorgchem Technology Co., Ltd. Process for preparing 4-aminodiphenylamine
WO2005003079A1 (en) 2003-07-04 2005-01-13 Shi, Guangqiang A method for producing 4-aminodiphenylamine
WO2005103025A1 (en) * 2004-04-21 2005-11-03 Novogen Research Pty Ltd Isoflavene synthetic method and catalyst
JP4876707B2 (en) * 2006-05-10 2012-02-15 住友化学株式会社 Method for producing 4-nitrosodiphenylamine and 4-nitrodiphenylamine
CN104962309B (en) * 2008-03-04 2017-09-26 马萨诸塞大学 The catalysis pyrolysis of solid hydrocarbon material and the bio-fuel and aromatic compound of correlation
CN101381315B (en) * 2008-10-17 2010-12-08 山西翔宇化工有限公司 Preparation method of p-aminodiphenylamine
WO2011031320A2 (en) 2009-09-09 2011-03-17 University Of Massachusetts Systems and processes for catalytic pyrolysis of biomass and hydrocarbonaceous materials for production of aromatics with optional olefin recycle, and catalysts having selected particle size for catalytic pyrolysis
CN102259029B (en) * 2010-05-24 2014-12-10 江苏圣奥化学科技有限公司 Solid alkali catalyst
US8835341B2 (en) 2011-09-07 2014-09-16 Chevron Phillips Chemical Company Lp Processed support and methods of making and using same
US9708243B2 (en) 2012-03-07 2017-07-18 Nocil Limited Process for preparing 4-aminodiphenylamine
EP2698198A1 (en) * 2012-08-14 2014-02-19 Saudi Basic Industries Corporation Method for pre-treating a catalyst composition with water or alcohol vapour in nitrogen gas at temperatures below their boiling point
RU2502725C1 (en) * 2012-10-22 2013-12-27 Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации Method of producing n-alkyl-n'-phenyl-para-phenylenediamines
RU2553984C2 (en) * 2013-02-28 2015-06-20 Олег Александрович ГОДЗОЕВ Method of obtaining 4-aminodiphenylamine and its alkylated derivatives
CN103232402B (en) * 2013-06-04 2015-09-16 山西翔宇化工有限公司 A kind of method of Hydrolysis kinetics azophenlyene from 4-aminodiphenylamine waste material
CN103992281B (en) * 2014-05-29 2016-07-06 山西翔宇化工有限公司 A kind of method extracting high-purity azophenlyene from 4-aminodiphenylamine by-product waste material
CN108558675A (en) * 2018-04-25 2018-09-21 南通理工学院 Synthesis method of 4-aminodiphenylamine
CN110624602A (en) * 2018-06-25 2019-12-31 中国石油化工股份有限公司 Preparation method and application of solid base catalyst
CN110627660A (en) * 2018-06-25 2019-12-31 中国石油化工股份有限公司 Preparation method of solid alkali RT base
US20240124683A1 (en) 2022-09-28 2024-04-18 The Goodyear Tire & Rubber Company Rubber - forming additives from biomass through syngas production
US20240117149A1 (en) 2022-09-28 2024-04-11 The Goodyear Tire & Rubber Company Rubber - forming additives from end of life tires through syngas production
US20250163236A1 (en) 2023-11-21 2025-05-22 The Goodyear Tire & Rubber Company Production of rubber compositions from end of life tires
CN119751312B (en) * 2024-12-27 2026-01-16 南京大学 Method for selectively preparing azoxybenzene or 1, 2-diphenyl hydrazine through nitrobenzene hydrogenation

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US3509042A (en) * 1961-10-05 1970-04-28 Mobil Oil Corp Shape selective zeolite having a metal component therein
US3393066A (en) 1964-09-21 1968-07-16 Exxon Research Engineering Co Process for reduction of iron ore in staged fluid beds without bogging
BE789273A (en) 1971-09-28 1973-03-26 Bayer Ag PROCESS FOR PREPARING NITRODIPHENYLAMINE DERIVATIVES
GB1440767A (en) 1972-11-24 1976-06-23 Ici Ltd Oxidation process for the manufacture of 4-aminodiphenylamine and related higher amines
DE2633811C2 (en) 1976-07-28 1983-11-10 Bayer Ag, 5090 Leverkusen Process for the preparation of nitrodiphenylamines
DE2713602C3 (en) 1977-03-28 1980-03-20 Akzo Gmbh, 5600 Wuppertal Process for the production of nitrosobenzene
US5182090A (en) * 1977-04-04 1993-01-26 Mobil Oil Corp. Synthesis of large crystal size zsm-5
US4187248A (en) 1977-11-23 1980-02-05 Monsanto Company Making a nitrodiarylamine by reacting an alkali metal salt of a formamide with a nitrohaloarene
US4187249A (en) 1977-12-27 1980-02-05 Monsanto Company Promoting the reaction of sodium salts of formyl derivatives of aromatic amines to form nitrodiarylamines
US4209463A (en) 1977-12-27 1980-06-24 Monsanto Company Promoting the formation of nitrodiarylamines from nitrohaloarenes, activated aryl amines and sodium carbonates
US4140716A (en) 1978-01-05 1979-02-20 Monsanto Company Process for making an amide of formic acid and forming nitrodiarylamine therefrom
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DE19709124A1 (en) 1997-03-06 1998-09-10 Bayer Ag Process for the preparation of 4-aminodiphenylamine
US5977411A (en) * 1997-06-10 1999-11-02 Flexsys America L.P. Catalytic hydrogeneration of nitrobenzene to 4-aminodiphenylamine in the presence of a hydroxyl compound and a solvent
TW500712B (en) * 1997-08-06 2002-09-01 Bayer Ag Process for the preparation of 4-aminodiphenylamine
US6140538A (en) * 1998-05-18 2000-10-31 Flexsys America L.P. Process for preparing 4-aminodiphenylamines

Also Published As

Publication number Publication date
CN1437573A (en) 2003-08-20
TW593221B (en) 2004-06-21
KR20030017553A (en) 2003-03-03
CN1285566C (en) 2006-11-22
EP1294675B1 (en) 2006-11-22
DE60124709D1 (en) 2007-01-04
KR100841873B1 (en) 2008-06-27
RU2280506C2 (en) 2006-07-27
BR0111872A (en) 2003-07-29
JP2004500981A (en) 2004-01-15
CA2413409A1 (en) 2001-12-27
ATE346033T1 (en) 2006-12-15
WO2001098252A2 (en) 2001-12-27
EP1294675A2 (en) 2003-03-26
US6495723B1 (en) 2002-12-17
MXPA03000083A (en) 2003-05-27
WO2001098252A3 (en) 2002-03-14

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