AT49942B - Process for the preparation of mixtures of aromatic nitro compounds from solvent naphtha. - Google Patents
Process for the preparation of mixtures of aromatic nitro compounds from solvent naphtha.Info
- Publication number
- AT49942B AT49942B AT49942DA AT49942B AT 49942 B AT49942 B AT 49942B AT 49942D A AT49942D A AT 49942DA AT 49942 B AT49942 B AT 49942B
- Authority
- AT
- Austria
- Prior art keywords
- mixtures
- solvent naphtha
- preparation
- nitro compounds
- aromatic nitro
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 5
- 239000002904 solvent Substances 0.000 title claims description 4
- -1 aromatic nitro compounds Chemical class 0.000 title claims 2
- 239000000203 mixture Substances 0.000 title claims 2
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000006396 nitration reaction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
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Auf diese Weise Können die Rückstandsäuren wiederholt zu Vornitrierungen der Solvent- naphtha ausgenützt werden. Sollten sie durch das bei Reaktion entstandene Wasser soweit verdünnt werden, dass sie nicht mehr zur Vornitrierung geeignet sind, so werden sie mit den bei der Fertignitrierung der öligen Nitrokörper erhaltenen Rückstandsäuren versetzt, Sollten sich grössere Mengen von Rückstandaäuro anhäufen, so werden sie in bekannter Weise regeneriert.
Aus dem obigen geht hervor, dass das neue Verfahren im wesentlichen darin besteht, dass man die im Patente Nr. 49941 verwendete, gewöhnliche Schwefelsäure durch rauchende Schwefelsäure ersetzt, welche bei einem mit der gewöhnlichen Schwefelsäure fast gleichen Preise eine erheblich stärkere Wasserentziehung bewirkt, was bei der Nitrierung der oben genannten in der Solventnaphtha neu aufgefundenen Kohlenwasserstoffe sich als vorteilhaft erwiesen hat.
Das neue Verfahren hat sich gegenüber dem des Verfahrens des Patentes Nr. 49941 demnach auch als wirtschaftlicher Fortschritt herausgestellt.
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In this way, the residual acids can be used repeatedly for prenitration of the solvent naphtha. If they are diluted by the water produced during the reaction to such an extent that they are no longer suitable for pre-nitration, they are mixed with the residual acids obtained during the final nitration of the oily nitro bodies regenerated.
From the above it can be seen that the new process essentially consists in replacing the common sulfuric acid used in Patent No. 49941 with fuming sulfuric acid, which, at a price almost the same as that of the common sulfuric acid, causes a considerably greater dehydration the nitration of the above-mentioned hydrocarbons newly found in solvent naphtha has proven advantageous.
The new process has therefore also proven to be an economic advance compared to the process of patent no. 49941.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT49941T | 1907-08-16 | ||
| AT49942T | 1910-09-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT49942B true AT49942B (en) | 1911-09-25 |
Family
ID=25601747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT49942D AT49942B (en) | 1907-08-16 | 1910-09-07 | Process for the preparation of mixtures of aromatic nitro compounds from solvent naphtha. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT49942B (en) |
-
1910
- 1910-09-07 AT AT49942D patent/AT49942B/en active
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