AR248411A1 - Preparacion de un componente solido granulado esferico para la (co)polimerizacion de etileno, catalizador y procedimiento para la (co)polimerizacion. - Google Patents
Preparacion de un componente solido granulado esferico para la (co)polimerizacion de etileno, catalizador y procedimiento para la (co)polimerizacion.Info
- Publication number
- AR248411A1 AR248411A1 AR92322726A AR32272692A AR248411A1 AR 248411 A1 AR248411 A1 AR 248411A1 AR 92322726 A AR92322726 A AR 92322726A AR 32272692 A AR32272692 A AR 32272692A AR 248411 A1 AR248411 A1 AR 248411A1
- Authority
- AR
- Argentina
- Prior art keywords
- solid
- solid component
- suspension
- catalyst
- polymerization
- Prior art date
Links
- 239000007787 solid Substances 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 2
- 239000005977 Ethylene Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 239000000725 suspension Substances 0.000 abstract 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- -1 ALUMINUM ALKYL HALIDE Chemical class 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
UN COMPONENTE SOLIDO DE CATALIZADOR SUMAMENTE ACTIVO EN LA (CO)POLIMERIZACION DE ETILENO QUE CONTIENE TITANIO, MAGNESIO, ALUMINIO, CLORO Y GRUPOS ALCOXI, Y QUE SE OBTIENE POR MEDIO DE UN PROCEDIMIENTO DONDE: (I) UN SOPORTE GRANULADO SOLIDO DE CLORURO DE MAGNESIO, OBTENIDO SECANDO POR SPRAY UNA SOLUCION ALCOHOLICA DE CLORURO DE MAGNESIO, SE SUSPENDE EN UN SOLVENTE DE HIDROCARBURO LIQUIDO Y SE AGREGAN A LA SUSPENSION ASI OBTENIDA UN ALCOHOL ALIFATICO Y UN TETRAALCOXIDO DE TITANIO; (II) LA SUSPENSION DEL PASO (I) SE CALIENTA HASTA OBTENER UNA SOLUCION HOMOGENEA Y LA SOLUCION SE ENFRIA PARA PRECIPITAR UN SOLIDO GRANULADO; (III) EL SOLIDO GRANULADO OBTENIDO EN EL PASO (II), EN LA SUSPENSION RELATIVA, SE PONE EN CONTACTO Y REACCIONA CON UN HALURO DE ALQUILO DE ALUMINIO, Y (IV) EL CATALIZADOR COMPONENTE SOLIDO SE RECUPERA DE LOS PRODUCTOS DE REACCION DEL PASO (III).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI911933A IT1251785B (it) | 1991-07-12 | 1991-07-12 | Procedimento per la preparazione di un componente solido di catalizzatore per la (co)polimerizzazione di etilene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR248411A1 true AR248411A1 (es) | 1995-08-18 |
Family
ID=11360336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AR92322726A AR248411A1 (es) | 1991-07-12 | 1992-07-13 | Preparacion de un componente solido granulado esferico para la (co)polimerizacion de etileno, catalizador y procedimiento para la (co)polimerizacion. |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US5382557A (es) |
| EP (1) | EP0522650B1 (es) |
| JP (1) | JP3310696B2 (es) |
| KR (1) | KR950001279B1 (es) |
| CN (1) | CN1030082C (es) |
| AR (1) | AR248411A1 (es) |
| AT (1) | ATE127811T1 (es) |
| AU (1) | AU652456B2 (es) |
| BR (1) | BR9202660A (es) |
| CA (1) | CA2073657C (es) |
| DE (1) | DE69204768T2 (es) |
| DK (1) | DK0522650T3 (es) |
| DZ (1) | DZ1594A1 (es) |
| EG (1) | EG20533A (es) |
| ES (1) | ES2077342T3 (es) |
| FI (1) | FI104081B (es) |
| GR (1) | GR3017820T3 (es) |
| IT (1) | IT1251785B (es) |
| MX (1) | MX9204063A (es) |
| NO (1) | NO179330C (es) |
| RU (1) | RU2081884C1 (es) |
| SA (1) | SA92130164B1 (es) |
| TN (1) | TNSN92057A1 (es) |
| ZA (1) | ZA925064B (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1252069B (it) * | 1991-11-25 | 1995-05-29 | Enichem Elastomers | Processo per la preparazione di copolimeri elastomerici dell'etilene |
| DE4417475A1 (de) * | 1994-05-19 | 1995-11-23 | Hoechst Ag | Verfahren zur Herstellung einer Katalysatorkomponente für die Polymerisation von Ethylen und 1-Olefinen zu ultrahochmolekularen Ethylenpolymeren |
| IT1269805B (it) * | 1994-05-20 | 1997-04-15 | Enichem Spa | Catalizzatore per la (co)polimerizzazione dell'etilene e procedimento per il suo ottenimento |
| DE60007060T2 (de) * | 1999-06-04 | 2004-09-16 | Lg Chemical Ltd. | Verfahren zur herstellung von polyolefin-polymerisationskatalysatoren |
| JP4934898B2 (ja) * | 2000-03-30 | 2012-05-23 | 住友化学株式会社 | オレフィン重合用固体触媒成分、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| CN1119354C (zh) * | 2000-05-19 | 2003-08-27 | 中国石油化工集团公司 | 一种氯化镁-醇载体及其制备的烯烃聚合催化剂组分 |
| PT1273595E (pt) | 2001-06-20 | 2006-10-31 | Borealis Tech Oy | Preparacao de um componente catalisador para polimerizacao de olefina |
| AU2003238067A1 (en) | 2002-07-23 | 2004-02-09 | Basell Poliolefine Italia S.P.A. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
| EP1611164B1 (en) * | 2003-03-27 | 2012-05-09 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
| EP1778744B1 (en) * | 2004-08-09 | 2015-03-25 | Union Carbide Chemicals & Plastics Technology LLC | Robust spray-dried ziegler-natta procatalyst and polymerization process employing same |
| CN1315885C (zh) * | 2005-04-26 | 2007-05-16 | 浙江大学 | 低载钛MgCl2/AlCl3复合载体丙烯聚合催化剂及其制备方法 |
| CN100513438C (zh) * | 2005-10-31 | 2009-07-15 | 中国石油化工股份有限公司 | 用于乙烯聚合或共聚合的催化剂、制法及应用 |
| US7388060B2 (en) * | 2006-01-04 | 2008-06-17 | China Petroleum & Chemical Corporation | Catalyst component for olefin (co)polymerization, preparation thereof, a catalyst comprising the same and use thereof |
| FI121820B (fi) | 2006-05-15 | 2011-04-29 | Ramtec Oy | Seulakauha ja seulakauhan voimansiirtomoduli |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA920299A (en) * | 1968-08-01 | 1973-01-30 | Mitsui Petrochemical Industries | Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier |
| LU64420A1 (es) * | 1971-12-08 | 1973-07-16 | ||
| BE791676A (fr) * | 1971-12-08 | 1973-05-21 | Solvay | Procédé pour la polymérisation des oléfines |
| LU65587A1 (es) * | 1972-06-22 | 1973-12-27 | ||
| IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| US4520121A (en) * | 1983-10-28 | 1985-05-28 | Inkrott Kenneth E | Magnesium halide hydrates and polymerization catalysts prepared therefrom |
| IT1203330B (it) * | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
-
1991
- 1991-07-12 IT ITMI911933A patent/IT1251785B/it active IP Right Grant
-
1992
- 1992-07-07 DK DK92202059.9T patent/DK0522650T3/da active
- 1992-07-07 ES ES92202059T patent/ES2077342T3/es not_active Expired - Lifetime
- 1992-07-07 AT AT92202059T patent/ATE127811T1/de active
- 1992-07-07 EP EP92202059A patent/EP0522650B1/en not_active Expired - Lifetime
- 1992-07-07 AU AU19485/92A patent/AU652456B2/en not_active Ceased
- 1992-07-07 DE DE69204768T patent/DE69204768T2/de not_active Expired - Lifetime
- 1992-07-07 ZA ZA925064A patent/ZA925064B/xx unknown
- 1992-07-08 DZ DZ920084A patent/DZ1594A1/fr active
- 1992-07-08 FI FI923150A patent/FI104081B/fi not_active IP Right Cessation
- 1992-07-09 NO NO922708A patent/NO179330C/no not_active IP Right Cessation
- 1992-07-10 TN TNTNSN92057A patent/TNSN92057A1/fr unknown
- 1992-07-10 RU SU925052137A patent/RU2081884C1/ru active
- 1992-07-10 MX MX9204063A patent/MX9204063A/es not_active IP Right Cessation
- 1992-07-10 CA CA002073657A patent/CA2073657C/en not_active Expired - Lifetime
- 1992-07-10 US US07/911,465 patent/US5382557A/en not_active Expired - Lifetime
- 1992-07-11 CN CN92105657A patent/CN1030082C/zh not_active Expired - Lifetime
- 1992-07-11 EG EG37892A patent/EG20533A/xx active
- 1992-07-11 KR KR1019920012391A patent/KR950001279B1/ko not_active Expired - Lifetime
- 1992-07-13 AR AR92322726A patent/AR248411A1/es active
- 1992-07-13 BR BR929202660A patent/BR9202660A/pt not_active IP Right Cessation
- 1992-07-13 JP JP18540892A patent/JP3310696B2/ja not_active Expired - Lifetime
- 1992-10-14 SA SA92130164A patent/SA92130164B1/ar unknown
-
1995
- 1995-10-19 GR GR950402914T patent/GR3017820T3/el unknown
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