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AR133003A1 - BLOW-MOLDED ARTICLES - Google Patents

BLOW-MOLDED ARTICLES

Info

Publication number
AR133003A1
AR133003A1 ARP240101562A ARP240101562A AR133003A1 AR 133003 A1 AR133003 A1 AR 133003A1 AR P240101562 A ARP240101562 A AR P240101562A AR P240101562 A ARP240101562 A AR P240101562A AR 133003 A1 AR133003 A1 AR 133003A1
Authority
AR
Argentina
Prior art keywords
cdfls
lcbf
ethylene
minutes
blow
Prior art date
Application number
ARP240101562A
Other languages
Spanish (es)
Inventor
Yijian Lin
Fawzi G Hamad
Joseph L Deavenport
Mari S Rosen
Philip P Fontaine
Lanhe Zhang
Paul Balding
Jingwei Fan
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of AR133003A1 publication Critical patent/AR133003A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Se describe un artículo moldeado por soplado que comprende un interpolímero de etileno / a-olefina. El interpolímero de etileno / a-olefina tiene una densidad de 0,920 g/cc a 0,950 g/cc, un índice de fusión (I₂) de 0,5 g/10 minutos a 10,0 g/10 minutos, un índice de amplitud de distribución de comonómeros (CDBI) mayor que 55%. La a-olefina de etileno también tiene una CDFLS × LCBf × 100 mayor que 0,5 en donde la CDFLS y la LCBf se miden como se describe a continuación. También se describe un artículo moldeado por soplado que forma una botella mediante moldeo por soplado de un interpolímero de etileno / a-olefina que tiene una densidad de 0,920 g/cc a 0,950 g/cc, un índice de fusión (I₂) de 0,5 g/10 minutos a 10,0 g/10 minutos, un índice de amplitud de distribución de comonómero (CDBI) mayor que o igual a 55%, y un valor de CDFLS × LcBF × 100 mayor que 0,5, en donde la CDFLS se calcula midiendo una fracción de área de una distribución de peso molecular obtenida a partir de la distribución del peso molecular absoluto y la LCBf se mide como se describe a continuación.A blow molded article comprising an ethylene/α-olefin interpolymer is disclosed. The ethylene/α-olefin interpolymer has a density of 0.920 g/cc to 0.950 g/cc, a melt index (I₂) of 0.5 g/10 minutes to 10.0 g/10 minutes, a comonomer distribution breadth index (CDBI) greater than 55%. The ethylene α-olefin also has a CDFLS × LCBf × 100 greater than 0.5 wherein the CDFLS and LCBf are measured as described below. Also disclosed is a blow molded article that forms a bottle by blow molding an ethylene/α-olefin interpolymer having a density of 0.920 g/cc to 0.950 g/cc, a melt index (I₂) of 0.5 g/10 minutes to 10.0 g/10 minutes, a comonomer distribution breadth index (CDBI) greater than or equal to 55%, and a CDFLS × LcBF × 100 value greater than 0.5, wherein the CDFLS is calculated by measuring an area fraction of a molecular weight distribution obtained from the absolute molecular weight distribution and the LCBf is measured as described below.

ARP240101562A 2023-06-28 2024-06-18 BLOW-MOLDED ARTICLES AR133003A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US202363510777P 2023-06-28 2023-06-28

Publications (1)

Publication Number Publication Date
AR133003A1 true AR133003A1 (en) 2025-08-20

Family

ID=91953698

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP240101562A AR133003A1 (en) 2023-06-28 2024-06-18 BLOW-MOLDED ARTICLES

Country Status (2)

Country Link
AR (1) AR133003A1 (en)
WO (1) WO2025006475A1 (en)

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4798081A (en) 1985-11-27 1989-01-17 The Dow Chemical Company High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US7163907B1 (en) 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
US5008204A (en) 1988-02-02 1991-04-16 Exxon Chemical Patents Inc. Method for determining the compositional distribution of a crystalline copolymer
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (en) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー Addition polymerization catalyst
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
CA2113627A1 (en) 1991-07-18 1993-02-18 Prasadarao Meka Heat sealed article
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
AU1991297A (en) 1996-03-27 1997-10-17 Dow Chemical Company, The Solution polymerization process with dispersed catalyst activator
EP0889912B1 (en) 1996-03-27 2000-07-12 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
AU1773901A (en) 1999-12-10 2001-06-18 Dow Chemical Company, The Substituted group 4 metal complexes, catalysts and olefin polymerization process
ES2973122T3 (en) 2013-07-09 2024-06-18 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymers with improved granule fluidity
CA2868640C (en) * 2014-10-21 2021-10-26 Nova Chemicals Corporation Solution polymerization process
CN107923883B (en) 2015-08-28 2021-02-12 陶氏环球技术有限责任公司 Chromatography of polymers with reduced co-crystallization
CA2964565A1 (en) * 2017-04-19 2018-10-19 Nova Chemicals Corporation Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
CA2984825A1 (en) * 2017-11-07 2019-05-07 Nova Chemicals Corporation Manufacturing ethylene interpolymer products at higher production rate
WO2021188256A1 (en) * 2020-03-18 2021-09-23 Exxonmobil Chemical Patents Inc. Extrusion blow molded articles and processes for making same

Also Published As

Publication number Publication date
WO2025006475A1 (en) 2025-01-02

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