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AR130119A1 - Análogos del ácido (2,4-diclorofenoxi)acético - Google Patents

Análogos del ácido (2,4-diclorofenoxi)acético

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Publication number
AR130119A1
AR130119A1 ARP230102056A ARP230102056A AR130119A1 AR 130119 A1 AR130119 A1 AR 130119A1 AR P230102056 A ARP230102056 A AR P230102056A AR P230102056 A ARP230102056 A AR P230102056A AR 130119 A1 AR130119 A1 AR 130119A1
Authority
AR
Argentina
Prior art keywords
inhibitors
disubstituted
mono
heteroaryl
aryl
Prior art date
Application number
ARP230102056A
Other languages
English (en)
Inventor
Jeremy Kister
Mei Li
David Michael Simpson
Bin Wei
Original Assignee
Corteva Agriscience Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corteva Agriscience Llc filed Critical Corteva Agriscience Llc
Publication of AR130119A1 publication Critical patent/AR130119A1/es

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    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/708Ethers
    • C07C69/712Ethers the hydroxy group of the ester being etherified with a hydroxy compound having the hydroxy group bound to a carbon atom of a six-membered aromatic ring
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    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
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    • C07C259/10Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups without replacement of the other oxygen atom of the carboxyl group, e.g. hydroxamic acids having carbon atoms of hydroxamic groups bound to carbon atoms of six-membered aromatic rings
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Abstract

Esta divulgación incluye compuestos y composiciones pesticidas, y métodos agrícolas relacionados. Reivindicación 1: Un compuesto según la fórmula (1), caracterizado porque X es: un compuesto del grupo de fórmulas (2); donde R¹ es independientemente hidrógeno, alquilo C₁-C₁₆, heteroalquilo C₁-C₁₆, arilo C₅-C₁₀, heteroarilo C₅-C₁₀; alquilcarbonilo, alcoxicarbonilo, ariloxicarbonilo, heteroariloxicarbnoilo, alquilaminocarbonilo disustituido o mono-, heteroarilaminocarbonilo disustituido o mono-, alquiltiocarbonilo, ariltiocarbonilo o heteroariltiocarbonilo; R² es independientemente hidrógeno, alquilo C₁-C₁₆, heteroalquilo C₁-C₁₆, arilo C₅-C₁₀, heteroarilo C₅-C₁₀; alquilcarbonilo, alcoxicabonilo, ariloxicabonilo, heteroariloxicabonilo, alquilaminocarbonilo mono- o disustituido, arilaminocarbonilo mono- o disustituido, heteroarilaminocarbonilo mono- o disustituido, alquiltiocarbonilo, ariltiocarbonilo, heteroariltiocarbonilo; R³ es independientemente hidrógeno, alquilo C₁-C₁₆, heteroalquilo C₁-C₁₆, arilo C₅-C₁₀, heteroarilo C₅-C₁₀; alquilcarbonilo, alcoxicabonilo, ariloxicabonilo, heteroariloxicabonilo, alquilaminocarbonilo mono- o disustituido, arilaminocarbonilo mono- o disustituido, heteroarilaminocarbonilo mono- o disustituido, alquiltiocarbonilo, ariltiocarbonilo, heteroariltiocarbonilo; R¹ y R² juntos forman un enlace doble sustituido, un anillo de 3 miembros, un anillo de 4 miembros, un anillo de 5 miembros, un anillo de 6 miembros o un anillo de 7 miembros; A es independientemente O, Si, NR y S(O)ₘ; A² es independientemente O, N, S(O)ₘ, alquilo sustituido, heteroalquilo, alquenilo, alquinilo, arilo, heteroarilo, alquilarilo, alquilheteroarilo; Y es independientemente O, N, S; Z es independientemente O, N, S(O)ₘ, alquilo sustituido, alquenilo, alquinilo, arilo, heteroarilo, alquilcarbonilo, alcoxicarbonilo, ariloxicarbonilo, heteroariloxicarbonilo, alquilaminocarbonilo disustituido o mono-, arilaminocarbonilo disustituido o mono-, heteroarilaminocarbonilo disustituido o mono-, alquiltiocarbonilo, ariltiocarobnilo, heteroariltiocarbonilo, -N=R⁴R⁵, R⁴ y R5 es independientemente heteroarilo, arilo, heteroalquilo, alquilo, alcoxi o amino sustituido; n es 1, 2 o 3; y m es 0, 1 o 2; donde el compuesto muestra actividad plaguicida con la condición de que el compuesto no sea un éster isooctílico de 2,4-D. Reivindicación 24: El compuesto según cualquiera de las reivindicaciones anteriores, caracterizado porque la actividad pesticida es actividad herbicida. Reivindicación 26: La composición de la reivindicación 25, caracterizada porque el segundo herbicida se selecciona del grupo que consiste en acetolactato sintasa (ALS), inhibidores de acetohidroxiácido sintasa (AHAS), inhibidores del fotosistema II, inhibidores de acetil CoA carboxilasa (ACCase), auxinas sintéticas, inhibidores del transporte de auxina, inhibidores del fotosistema I, inhibidores de 5-enolpiruvilshikimato-3-fosfato (EPSP) sintasa, inhibidores de glutamina sintetasa, inhibidores del ensamblaje de microtúbulos, inhibidores de mitosis, inhibidores de ácidos grasos de cadena muy larga (VLCFA), inhibidores de la síntesis de ácidos grasos y lípidos, inhibidores de protoporfirinógeno oxidasa (PPO), inhibidores de la biosíntesis de carotenoides, inhibidores de fitoeno desaturasas (PDS), inhibidores de 4-hidroxifenil-piruvato-dioxigenasa (HPPD), inhibidores de biosíntesis de celulosa, herbicidas con varios modos de acción y herbicidas no clasificados. Reivindicación 27: La composición según la reivindicación 25, caracterizada porque el primer herbicida se selecciona del grupo que consiste en: los compuestos del grupo de fórmulas (3). Reivindicación 39: Un método para controlar vegetación no deseada caracterizado porque comprende poner en contacto la vegetación o el locus donde esta se encuentra con una cantidad con eficacia herbicida de un compuesto según cualquiera de las reivindicaciones, o aplicarla al suelo para prevenir la aparición de vegetación. Reivindicación 42: Un método para controlar vegetación no deseada en un cultivo que se ha vuelto tolerante o resistente al ácido 2,4-diclorofenoxiacético, caracterizado porque comprende poner en contacto la vegetación o el locus donde esta se encuentra con una cantidad con eficacia herbicida de un compuesto según una cualquiera de las reivindicaciones anteriores, o aplicarla al suelo para prevenir la aparición de vegetación.
ARP230102056A 2022-08-03 2023-08-03 Análogos del ácido (2,4-diclorofenoxi)acético AR130119A1 (es)

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US3598872A (en) * 1968-04-08 1971-08-10 Ansul Co O-chlorinated-phenoxyacetyl-n,n-diethylhydroxylamine
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