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AR121900A1 - 2-(HET)ARYL SUBSTITUTED CONDENSED HETEROCYCLE DERIVATIVES AS PESTICIDES - Google Patents

2-(HET)ARYL SUBSTITUTED CONDENSED HETEROCYCLE DERIVATIVES AS PESTICIDES

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Publication number
AR121900A1
AR121900A1 ARP210101067A ARP210101067A AR121900A1 AR 121900 A1 AR121900 A1 AR 121900A1 AR P210101067 A ARP210101067 A AR P210101067A AR P210101067 A ARP210101067 A AR P210101067A AR 121900 A1 AR121900 A1 AR 121900A1
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Argentina
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alkyl
cycloalkyl
halogenalkyl
alkoxy
sulfinyl
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ARP210101067A
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Spanish (es)
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Rdiger Fischer
Laura Hoffmeister
Steffen Mller
Matthieu Willot
Kerstin Ilg
Peter Lsel
Marc Linka
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Bayer Ag
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/761,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P5/00Nematocides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00Arthropodicides
    • A01P7/04Insecticides
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/50Surfactants; Emulsifiers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D498/00Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D498/02Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D498/04Ortho-condensed systems

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

La invención se refiere a nuevos compuestos de la fórmula (1), en donde A¹, A², A³, X, Y, V, R¹, R², R³, R⁵, R⁶ y n tienen los significados antes mencionados, a su uso como acaricidas y/o insecticidas para el combate de parásitos animales y a procedimientos y productos intermedios para su preparación. Reivindicación 1: Compuestos de la fórmula (1) en donde A¹ representa nitrógeno, =N⁺(O⁻)- o =C(R⁴ᵃ)-, A² representa nitrógeno, =N⁺(O⁻)- o =C(R⁴ᵇ)-, A³ representa nitrógeno, =N⁺(O⁻)- o =C(R⁴ᶜ)-, X representa oxígeno o azufre, Y representa oxígeno o azufre, R¹ representa alquilo (C₁-C₆), halogenalquilo (C₁-C₆), alquenilo (C₂-C₆), halogenalquenilo (C₂-C₆), alquinilo (C₂-C₆), halogenalquinilo (C₂-C₆), cicloalquilo (C₃-C₈), halogencicloalquilo (C₃-C₈), cicloalquilo (C₃-C₆)-alquilo (C₁-C₆), cicloalquilo (C₃-C₆)-halogenalquilo (C₁-C₆), alquilo (C₁-C₆)-cicloalquilo (C₃-C₈), halogenalquil (C₁-C₆)-cicloalquilo (C₃-C₈), cicloalquilo (C₃-C₈)-cicloalquilo (C₃-C₈), espiro-cicloalquilo (C₃-C₈)-cicloalquilo (C₃-C₈), bicicloalquilo (C₄-C₁₂), cianoalquilo (C₁-C₆), hidroxialquilo (C₁-C₆), alcoxi (C₁-C₆)-alquilo (C₁-C₆), cianoalquenilo (C₂-C₆), cicloalquilo (C₃-C₆)-alquenilo (C₂-C₆), cianoalquinilo (C₂-C₆), cicloalquilo (C₃-C₆)-alquinilo (C₂-C₆), halogenalcoxi (C₁-C₆)-alquilo (C₁-C₆), alquenil (C₂-C₆)-oxi-alquilo (C₁-C₆), halogenalquenil (C₂-C₆)-oxi-alquilo (C₁-C₆), alquinil (C₂-C₆)-oxi-alquilo (C₁-C₄), halogenalquinil (C₂-C₆)-oxi-alquilo (C₁-C₆), alquilo (C₁-C₆)-tio-alquilo (C₁-C₆), alquilo (C₁-C₆)-sulfinil-alquilo (C₁-C₆), alquilo (C₁-C₆)-sulfonil-alquilo (C₁-C₆), halogenalquilo (C₁-C₆)-tio-alquilo (C₁-C₆), halogenalquilo (C₁-C₆)-sulfinil-alquilo (C₁-C₆), halogenalquilo (C₁-C₆)-sulfonil-alquilo (C₁-C₆) o tri-alquilo (C₁-C₆)-sililo, R², R⁴ᵃ, R⁴ᵇ, R⁴ᶜ representan, de modo independiente entre sí, hidrógeno, ciano, halógeno, alquilo (C₁-C₄), halogenalquilo (C₁-C₄), cianoalquilo (C₁-C₄), alcoxi (C₁-C₄)-alquilo (C₁-C₄), alquenilo (C₂-C₄), halogenalquenilo (C₂-C₄), cianoalquenilo (C₂-C₄), alquinilo (C₂-C₄), halogenalquinilo (C₂-C₄), cianoalquinilo (C₂-C₄), alcoxi (C₁-C₄), halogenalcoxi (C₁-C₄), alquil (C₁-C₄)-tio, halogenalquil (C₁-C₄)-tio, alquil (C₁-C₄)-sulfinilo, halogenalquil (C₁-C₄)-sulfinilo, alquil (C₁-C₄)-sulfonilo o halogenalquil (C₁-C₄)-sulfonilo, R³ representa hidrógeno, ciano, halógeno, nitro, hidroxi, amino, SCN, tri-alquilo (C₁-C₆)-sililo, cicloalquilo (C₃-C₈), cicloalquilo (C₃-C₈)-cicloalquilo (C₃-C₈), alquilo (C₁-C₆)-cicloalquilo (C₃-C₈), halogencicloalquilo (C₃-C₈), cianocicloalquilo (C₃-C₈), alquilo (C₁-C₆), halogenalquilo (C₁-C₆), cianoalquilo (C₁-C₆), hidroxialquilo (C₁-C₆), alcoxi (C₁-C₆)-alquilo (C₁-C₆), alquenilo (C₂-C₆), halogenalquenilo (C₂-C₆), cianoalquenilo (C₂-C₆), alquinilo (C₂-C₆), halogenalquinilo (C₂-C₆), cianoalquinilo (C₂-C₆), alcoxi (C₁-C₆), halogenalcoxi (C₁-C₆), cianoalcoxi (C₁-C₆), alquil (C₁-C₆)-hdroxiimino, alcoxi (C₁-C₆)-imino, alquilo (C₁-C₆)-alcoxi (C₁-C₆)-imino, halogenalquil (C₁-C₆)-alcoxi (C₁-C₆)-imino, alquilo (C₁-C₆)-tio, halogenalquilo (C₁-C₆)-tio, alquilo (C₁-C₆)-sulfinilo, halogenalquilo (C₁-C₆)-sulfinilo, alquilo (C₁-C₆)-sulfonilo, halogenalquilo (C₁-C₆)-sulfonilo, alquilo (C₁-C₆)-carbonilo, alquilo (C₁-C₆)-tiocarbonilo, halogenalquilo (C₁-C₆)-carbonilo, alquilo (C₁-C₆)-carboniloxi, alcoxi (C₁-C₆)-carbonilo, halogenalcoxi (C₁-C₆)-carbonilo, aminocarbonilo, alquilo (C₁-C₆)-aminocarbonilo, alquil (C₁-C₆)-aminotiocarbonilo, di-alquilo (C₁-C₆)-aminocarbonilo, di-alquilo (C₁-C₆)-aminotiocarbonilo, cicloalquil (C₃-C₈)-aminocarbonilo, alquilo (C₁-C₆)-sulfonilamino, alquil (C₁-C₆)-amino, di-alquil (C₁-C₆)-amino, aminosulfonilo, alquilo (C₁-C₆)-aminosulfonilo, di-alquilo (C₁-C₆)-aminosulfonilo, alquilo (C₁-C₆)-sulfoximino, aminotiocarbonilo, alquil (C₁-C₆)-aminotiocarbonilo, di-alquilo (C₁-C₆)-aminotiocarbonilo, cicloalquil (C₃-C₈)-amino o NHCO-alquilo (C₁-C₆) (alquil (C₁-C₆)-carbonilamino), R⁵, R⁶ representan, de modo independiente entre sí, hidrógeno, ciano, halógeno, alquilo (C₁-C₆), halogenalquilo (C₁-C₆), alquenilo (C₂-C₆), halogenalquenilo (C₂-C₆), alquinilo (C₂-C₆), halogenalquinilo (C₂-C₆), cicloalquilo (C₃-C₆), cicloalquilo (C₃-C₆)-cicloalquilo (C₃-C₆), alquilo (C₁-C₆)-cicloalquilo (C₃-C₆), alcoxi (C₁-C₆), halogenalcoxi (C₁-C₆), alcoxi (C₁-C₆)-imino, alquilo (C₁-C₆)-tio, halogenalquilo (C₁-C₆)-tio, alquilo (C₁-C₆)-sulfinilo, halogenalquilo (C₁-C₆)-sulfinilo, alquilo (C₁-C₆)-sulfonilo, halogenalquilo (C₁-C₆)-sulfonilo, alquilo (C₁-C₆)-sulfoniloxi, alquilo (C₁-C₆)-carbonilo, halogenalquilo (C₁-C₆)-carbonilo, aminocarbonilo, alquilo (C₁-C₆)-aminocarbonilo, di-alquilo (C₁-C₆)-aminocarbonilo, alquilo (C₁-C₆)-sulfonilamino, aminosulfonilo, alquilo (C₁-C₆)-aminosulfonilo o di-alquil (C₁-C₆)-aminosulfonilo, n representa 0, 1 ó 2, V representa un anillo saturado, parcialmente saturado o heteroaromático opcionalmente mono- o polisustituido, igual o diferente, en el que al menos un átomo de C está reemplazado por un heteroátomo o representa un anillo saturado o parcialmente saturado carbocíclico opcionalmente mono- o polisustituido, igual o distinto, o representa un anillo aromático opcionalmente mono- o polisustituido, en donde opcionalmente puede contener en cada caso al menos un grupo carbonilo y/o en donde como sustituyentes, se tienen en cuenta: hidrógeno, ciano, halógeno, alquilo (C₁-C₆), halogenalquilo (C₁-C₆), alquenilo (C₂-C₆), halogenalquenilo (C₂-C₆), alquinilo (C₂-C₆), halogenalquinilo (C₂-C₆), cicloalquilo (C₃-C₆), halogencicloalquilo (C₃-C₈), cianocicloalquilo (C₃-C₈), cicloalquilo (C₃-C₆)-cicloalquilo (C₃-C₆), alquilo (C₁-C₆)-cicloalquilo (C₃-C₆), alcoxi (C₁-C₆), halogenalcoxi (C₁-C₆), alcoxi (C₁-C₆)-imino, alquilo (C₁-C₆)-tio, halogenalquilo (C₁-C₆)-tio, alquilo (C₁-C₆)-sulfinilo, halogenalquilo (C₁-C₆)-sulfinilo, alquilo (C₁-C₆)-sulfonilo, halogenalquilo (C₁-C₆)-sulfonilo, alquilo (C₁-C₆)-carbonilo, halogenalquilo (C₁-C₆)-carbonilo, aminocarbonilo, alquilo (C₁-C₆)-aminocarbonilo, di-alquilo (C₁-C₆)-aminocarbonilo, alquilo (C₁-C₆)-sulfonilamino, aminosulfonilo, alquilo (C₁-C₆)-aminosulfonilo o di-alquilo (C₁-C₆)-aminosulfonilo.The invention relates to new compounds of the formula (1), in which A¹, A², A³, X, Y, V, R¹, R², R³, R⁵, R⁶ and n have the aforementioned meanings, their use as acaricides and / or insecticides to combat animal parasites and procedures and intermediate products for their preparation. Claim 1: Compounds of formula (1) wherein A¹ represents nitrogen, =N⁺(O⁻)- or =C(R⁴ᵃ)-, A² represents nitrogen, =N⁺(O⁻)- or =C(R⁴ᵇ) -, A³ represents nitrogen, =N⁺(O⁻)- or =C(R⁴ᶜ)-, X represents oxygen or sulfur, Y represents oxygen or sulfur, R¹ represents (C₁-C₆)alkyl, (C₁-C₆)halogenalkyl, (C₂-C₆) alkenyl, (C₂-C₆) halogenalkenyl, (C₂-C₆) alkynyl, (C₂-C₆) halogenalkynyl, (C₃-C₈) cycloalkyl, (C₃-C₈) halogencycloalkyl, (C₃-C₆) cycloalkyl-alkyl (C₁-C₆), (C₃-C₆)cycloalkyl-(C₁-C₆)halogenalkyl, (C₁-C₆)alkyl-(C₃-C₈)cycloalkyl, (C₁-C₆)halogenalkyl-(C₃-C₈)cycloalkyl, cycloalkyl ( C₃-C₈)-cycloalkyl (C₃-C₈), spiro-cycloalkyl (C₃-C₈)-cycloalkyl (C₃-C₈), bicycloalkyl (C₄-C₁₂), cyanoalkyl (C₁-C₆), hydroxyalkyl (C₁-C₆), alkoxy (C₁-C₆)-(C₁-C₆)-alkyl, (C₂-C₆)-cyanoalkenyl, (C₃-C₆)-cycloalkyl-(C₂-C₆)-alkenyl, (C₂-C₆-cyanoalkynyl), (C₃-C₆)-cycloalkyl-alkynyl ( C₂-C₆), (C₁-C₆)halogalkoxy-(C₁-C₆)alkyl, (C₂-C₆)alkenyl-oxy -(C₁-C₆)-alkyl, (C₂-C₆)-halogenalkenyl-(C₁-C₆)-oxy-alkyl, (C₂-C₆)-alkynyl-(C₁-C₄)-oxy-alkyl, (C₂-C₆)-halogenalkynyl-oxy-alkyl (C 1 -C 6 ), (C 1 -C 6 )-alkyl-thio-(C 1 -C 6 )-alkyl, (C 1 -C 6 )-alkyl-sulfinyl-(C 1 -C 6 )-alkyl, (C 1 -C 6 )-alkyl-sulfonyl-(C 1 -C₆), (C₁-C₆)halogenalkyl-(C₁-C₆)alkylthio, (C₁-C₆)halogenalkyl-(C₁-C₆)sulfinyl-(C₁-C₆)halogenalkyl-(C₁-C₆)sulfonyl-alkyl ) or tri-(C₁-C₆)-alkylsilyl, R², R⁴ᵃ, R⁴ᵇ, R⁴ᶜ independently of one another stand for hydrogen, cyano, halogen, (C₁-C₄)alkyl, (C₁-C₄)halogenalkyl, cyanoalkyl ( (C₁-C₄), (C₁-C₄) alkoxy-(C₁-C₄) alkyl, (C₂-C₄) alkenyl, (C₂-C₄) halogenalkenyl, (C₂-C₄) cyanoalkenyl, (C₂-C₄) alkynyl, (C₂) halogenalkynyl -C₄), (C₂-C₄)cyanoalkynyl, (C₁-C₄)alkoxy, (C₁-C₄)haloalkoxy, (C₁-C₄)alkyl-thio, (C₁-C₄)halogenalkyl-thio, (C₁-C₄)alkyl- sulfinyl, (C₁-C₄)halogenalkyl-sulfinyl, (C₁-C₄)alkylsulfonyl or (C₁-C₄)halogenalkylsulfonyl, R³ represents hydrogen, cyano, h halogen, nitro, hydroxy, amino, SCN, tri-(C₁-C₆)alkylsilyl, (C₃-C₈)cycloalkyl, (C₃-C₈)cycloalkyl-(C₃-C₈)cycloalkyl, (C₁-C₆)alkyl-cycloalkyl (C₃-C₈), (C₃-C₈) halogencycloalkyl, (C₃-C₈) cyanocycloalkyl, (C₁-C₆) alkyl, (C₁-C₆) halogenalkyl, (C₁-C₆) cyanoalkyl, (C₁-C₆) hydroxyalkyl, alkoxy ( C₁-C₆)-(C₁-C₆)-alkyl, (C₂-C₆)alkenyl, (C₂-C₆)halogenyl, (C₂-C₆)cyanoalkenyl, (C₂-C₆)alkynyl, (C₂-C₆)haloalkynyl, (C₂)cyanoalkynyl -C₆), (C₁-C₆)alkoxy, (C₁-C₆)haloalkoxy, (C₁-C₆)cyanoalkoxy, (C₁-C₆)alkyl-hydroxyimino, (C₁-C₆)alkoxy-imino, (C₁-C₆)alkyl- (C₁-C₆)alkoxy-imino, (C₁-C₆)halogenalkyl-(C₁-C₆)alkoxy-imino, (C₁-C₆)alkyl-thio, (C₁-C₆)halogenalkyl-thio, (C₁-C₆)alkyl- sulfinyl, (C₁-C₆)-halogenalkyl-sulfinyl, (C₁-C₆)-alkyl-sulfonyl, (C₁-C₆)-halogenalkyl-sulfonyl, (C₁-C₆)-alkylcarbonyl, (C₁-C₆)-alkyl-thiocarbonyl, (C₁-halogenalkyl -C₆)-carbonyl, (C₁-C₆)-alkylcarbonyloxy, (C₁-C₆)alkoxy-carbonyl, halogenalk (C 1 -C 6 )oxycarbonyl, aminocarbonyl, (C 1 -C 6 )alkylaminocarbonyl, (C 1 -C 6 )alkylaminothiocarbonyl, di(C 1 -C 6 )alkylaminocarbonyl, di(C 1 -C 6 )alkylaminothiocarbonyl , (C₃-C₈)-cycloalkylaminocarbonyl, (C₁-C₆)alkylsulfonylamino, (C₁-C₆)alkylamino, di-(C₁-C₆)alkylamino, aminosulfonyl, (C₁-C₆)alkylaminosulfonyl, di-(C 1 -C 6 )-alkylaminosulfonyl, (C 1 -C 6 )-alkyl-sulfoximino, aminothiocarbonyl, (C 1 -C 6 )-alkylaminothiocarbonyl, di-(C 1 -C 6 )-alkyl-aminothiocarbonyl, (C 3 -C 8 )-cycloalkyl-amino or NHCO-(C₁-C₆)-alkyl ((C₁-C₆-alkyl)-carbonylamino), R⁵, R⁶ independently of one another stand for hydrogen, cyano, halogen, (C₁-C₆-alkyl), (C₁-C₆-halogen)alkyl , (C₂-C₆) alkenyl, (C₂-C₆) halogenalkenyl, (C₂-C₆) alkynyl, (C₂-C₆) halogenalkynyl, (C₃-C₆) cycloalkyl, (C₃-C₆) cycloalkyl-(C₃-C₆)cycloalkyl, (C₁-C₆)-alkyl-(C₃-C₆)-cycloalkyl-, (C₁-C₆-alkoxy), (C₁-C₆-halogalkoxy), (C₁-C₆)-alkoxy-imino, (C₁-C₆)-alkyl-thio, (C₁-C₁-halogenalkyl) C₆)-thio, (C₁-C₆)-alkylsulfinyl, (C₁-C₆)halogenalkyl-sulfinyl, (C₁-C₆)alkylsulfonyl, (C₁-C₆)halogenalkylsulfonyl, (C₁-C₆)alkylsulfonyloxy, (C₁-C₆)alkyl )-carbonyl, (C 1 -C 6 )haloalkyl-carbonyl, aminocarbonyl, (C 1 -C 6 )alkylaminocarbonyl, di-(C 1 -C 6 )alkyl-aminocarbonyl, (C 1 -C 6 )alkyl-sulfonylamino, aminosulfonyl, (C 1 - C₆)-aminosulfonyl or di-(C₁-C₆)alkyl-aminosulfonyl, n represents 0, 1 or 2, V represents an optionally mono- or polysubstituted saturated, partially saturated or heteroaromatic ring, the same or different, in which at least one C atom is replaced by a heteroatom or represents an optionally mono- or polysubstituted saturated or partially saturated carbocyclic ring, the same or different, or represents an optionally mono- or polysubstituted aromatic ring, where optionally it may contain in each case at least one group carbonyl and/or where as substituents, the following are taken into account: hydrogen, cyano, halogen, alkyl (C₁- C₆), (C₁-C₆) halogenalkyl, (C₂-C₆) alkenyl, (C₂-C₆) halogenalkenyl, (C₂-C₆) alkynyl, (C₂-C₆) halogenalkynyl, (C₃-C₆) cycloalkyl, (C₃-C₈) halogencycloalkyl ), (C₃-C₈)cyanocycloalkyl, (C₃-C₆)cycloalkyl-(C₃-C₆)cycloalkyl, (C₁-C₆)alkyl-(C₃-C₆)cycloalkyl, (C₁-C₆)alkoxy, (C₁-C₆)haloalkoxy , (C₁-C₆)alkoxy-imino, (C₁-C₆)alkyl-thio, (C₁-C₆)halogenalkyl-thio, (C₁-C₆)alkyl-sulfinyl, (C₁-C₆)halogenalkyl-sulfinyl, (C₁- C₆)-sulfonyl, (C₁-C₆)halogenalkylsulfonyl, (C₁-C₆)alkylcarbonyl, (C₁-C₆)halogenalkylcarbonyl, aminocarbonyl, (C₁-C₆)alkylaminocarbonyl, di-(C₁-C₆)alkyl )-aminocarbonyl, (C 1 -C 6 )alkylsulfonylamino, aminosulfonyl, (C 1 -C 6 )alkylaminosulfonyl or di(C 1 -C 6 )alkylaminosulfonyl.

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