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AR111286A1 - HETEROBICYCLIC REPLACED DIHYDROISOXAZOLS AND ITS USE TO PROTECT PLANTS - Google Patents

HETEROBICYCLIC REPLACED DIHYDROISOXAZOLS AND ITS USE TO PROTECT PLANTS

Info

Publication number
AR111286A1
AR111286A1 ARP180100612A ARP180100612A AR111286A1 AR 111286 A1 AR111286 A1 AR 111286A1 AR P180100612 A ARP180100612 A AR P180100612A AR P180100612 A ARP180100612 A AR P180100612A AR 111286 A1 AR111286 A1 AR 111286A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
halogen
cycloalkyl
ora
Prior art date
Application number
ARP180100612A
Other languages
Spanish (es)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR111286A1 publication Critical patent/AR111286A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

Composiciones que los comprenden, combinaciones de compuestos activos que los comprenden, y su uso para proteger plantas en crecimiento contra ataque o la infestación por parte de plagas de invertebrados, además, semillas que comprenden dichos compuestos. Reivindicación 1: Compuestos caracterizados por la fórmula (1), en donde X¹ es O ó S; B¹, B² y B³ son, independientemente entre sí, N y CRB, siempre que, como máximo, uno de B¹, B² y B³ sea N; RB es H, Cl, F, Br, CF₃ u OCF₃; Y junto con el átomo de carbono de CR² y los átomos de C² y C³ del X¹ adyacente que contiene un anillo forma carbo- o heterociclo saturado o parcialmente insaturado de 5 a 7 miembros en donde el heterociclo contiene 1 a 3 heteroátomos seleccionados de N, O ó S; R¹ es H, halógeno, CN, NO₂, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquenilo, C₄₋₆-cicloalquinilo, ORᵃ, NRᵃRᵇ, NO₂, C(=O)ORᵃ, C(=O)N(Rᵃ)₂ o S(O)ₘRᵃ; cuyos grupos R¹ son no sustituidos o sustituidos con uno o más Rᵃ; o 2 R¹ geminales pueden formar juntos un grupo =O, =C(R¹ᵃ)₂, =NOH o =NOCH₃; Rᵃ y Rᵇ, independientemente entre sí, son H, C₁₋₆-alquilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₁₋₆-alquil-S(O)ₘ-C₁₋₆-alquilo, C₁₋₆-alquil-S(O)ₘ-C₁₋₆-haloalquilo, C₃₋₆-cicloalquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₂₋₆-alqueniloxi, C₂₋₆-alquiniloxi, S(O)ₘ-C₁₋₆-alquilo, S(O)ₘ-C₁₋₆-haloalquilo, cuyos grupos son no sustituidos o sustituidos con uno o más Rᶜ; Rᶜ es halógeno, ciano, C₁₋₄-alquilo o C₁₋₄ haloalquilo; m es 0, 1 ó 2; R¹ᵃ es H, halógeno, C₁₋₄-alquilo o C₁₋₄-haloalquilo; n es 1, 2, 3 ó 4; # es un enlace directo, o forma, junto con CR² y NR³, un anillo de azetidina; si # es un enlace directo: R² es H, halógeno, CN, NO₂, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₃₋₆-cicloalquilo, ORᵃ, NRᵃRᵇ, NO₂; y R³ es un grupo como se define para Rᵃ; R⁴ es un grupo como se define para Rᵃ; o C₁₋₆-alquil-S(O)ₘ-C₁₋₆-alquilo, C₁₋₆-alquil-S(O)ₘ-C₁₋₆-haloalquilo, C₃₋₆-cicloalquil-C₁₋₄-alquilo, heterociclilo de 3 a 7 miembros unido directamente o a través de espaciador de C₁₋₄-alquileno, cuyos heterociclos contienen 1 a 3 heteroátomos seleccionados de N, O ó S, en donde átomos de S como miembros del anillo están presentes como S, SO o SO₂; y cuyos grupos de R⁴ son no sustituidos o sustituidos con uno o más Rᶜ; R⁵ᵃ y R⁵ᵇ, independientemente entre sí, son H, halógeno u OH; y los N-óxidos, estereoisómeros y las sales de aquellos aceptables en la agricultura o veterinaria.Compositions comprising them, combinations of active compounds that comprise them, and their use to protect growing plants against attack or infestation by invertebrate pests, in addition, seeds comprising said compounds. Claim 1: Compounds characterized by the formula (1), wherein X¹ is O or S; B¹, B² and B³ are, independently of each other, N and CRB, provided that, at most, one of B¹, B² and B³ is N; RB is H, Cl, F, Br, CF₃ or OCF₃; And together with the carbon atom of CR² and the C² and C³ atoms of the adjacent X¹ containing a ring form saturated or partially unsaturated carbo- or heterocycle of 5 to 7 members wherein the heterocycle contains 1 to 3 heteroatoms selected from N, O or S; R¹ is H, halogen, CN, NO₂, C₁₋₆-alkyl, C₁₋₆-haloalkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₁₋₆-alkoxy, C₁₋₆-haloalkoxy, C₃₋₆- cycloalkyl, C₃₋₆-cycloalkenyl, C₄₋₆-cycloalkynyl, ORᵃ, NRᵃRᵇ, NO₂, C (= O) ORᵃ, C (= O) N (Rᵃ) ₂ or S (O) ₘRᵃ; whose groups R¹ are unsubstituted or substituted with one or more Rᵃ; or 2 R¹ geminals can together form a group = O, = C (R¹ᵃ) ₂, = NOH or = NOCH₃; Rᵃ and Rᵇ, independently of each other, are H, C₁₋₆-alkyl, C₁₋₆-alkoxy, C₁₋₆-haloalkoxy, C₁₋₆-alkyl-S (O) ₘ-C₁₋₆-alkyl, C₁₋₆ -alkyl-S (O) ₘ-C₁₋₆-haloalkyl, C₃₋₆-cycloalkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₂₋₆-alkenyloxy, C₂₋₆-alkynyloxy, S (O) ₘ -C₁₋₆-alkyl, S (O) ₘ-C₁₋₆-haloalkyl, whose groups are unsubstituted or substituted with one or more Rᶜ; Rᶜ is halogen, cyano, C₁₋₄-alkyl or C₁₋₄ haloalkyl; m is 0, 1 or 2; R¹ᵃ is H, halogen, C₁₋₄-alkyl or C₁₋₄-haloalkyl; n is 1, 2, 3 or 4; # is a direct bond, or form, together with CR² and NR³, an azetidine ring; If # is a direct link: R² is H, halogen, CN, NO₂, C₁₋₆-alkyl, C₁₋₆-haloalkyl, C₁₋₆-alkoxy, C₁₋₆-haloalkoxy, C₃₋₆-cycloalkyl, ORᵃ, NRᵃRᵇ , NO₂; and R³ is a group as defined for Rᵃ; R⁴ is a group as defined for Rᵃ; or C₁₋₆-alkyl-S (O) ₘ-C₁₋₆-alkyl, C₁₋₆-alkyl-S (O) ₘ-C₁₋₆-haloalkyl, C₃₋₆-cycloalkyl-C₁₋₄-alkyl, heterocyclyl 3 to 7 members attached directly or through a C₁₋₄-alkylene spacer, whose heterocycles contain 1 to 3 heteroatoms selected from N, O or S, where S atoms as ring members are present as S, SO or SO₂ ; and whose groups of R⁴ are unsubstituted or substituted with one or more Rᶜ; R⁵ᵃ and R⁵ᵇ, independently of each other, are H, halogen or OH; and the N-oxides, stereoisomers and salts of those acceptable in agriculture or veterinary.

ARP180100612A 2017-03-16 2018-03-15 HETEROBICYCLIC REPLACED DIHYDROISOXAZOLS AND ITS USE TO PROTECT PLANTS AR111286A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP17161239 2017-03-16

Publications (1)

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AR111286A1 true AR111286A1 (en) 2019-06-26

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Country Status (2)

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AR (1) AR111286A1 (en)
WO (1) WO2018166855A1 (en)

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