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AR101495A1 - Compuestos condensados de 11 miembros y fungicidas agrícolas / hortícolas que los contienen - Google Patents

Compuestos condensados de 11 miembros y fungicidas agrícolas / hortícolas que los contienen

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Publication number
AR101495A1
AR101495A1 ARP150102576A ARP150102576A AR101495A1 AR 101495 A1 AR101495 A1 AR 101495A1 AR P150102576 A ARP150102576 A AR P150102576A AR P150102576 A ARP150102576 A AR P150102576A AR 101495 A1 AR101495 A1 AR 101495A1
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AR
Argentina
Prior art keywords
alkyl
haloalkyl
carbonyl
amino
cycloalkyl
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Application number
ARP150102576A
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English (en)
Inventor
Sakaguchi Takatoshi
Kawano Tsuyoshi
Bamba Makoto
Horikoshi Daisuke
Wada Hiroshi
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Sds Biotech Corp
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Publication date
Application filed by Sds Biotech Corp filed Critical Sds Biotech Corp
Publication of AR101495A1 publication Critical patent/AR101495A1/es

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00—Fungicides
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    • C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C251/44—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups being part of a ring other than a six-membered aromatic ring
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/84—Hydrazones having doubly-bound carbon atoms of hydrazone groups being part of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
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    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/53—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and hydroxy groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63—Esters of sulfonic acids
    • C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
    • C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
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    • C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
    • C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
    • C07C309/66—Methanesulfonates
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    • C07C309/72—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/73—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/08—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
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    • C07—ORGANIC CHEMISTRY
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    • C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/22—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/40—Halogenated unsaturated alcohols
    • C07C33/46—Halogenated unsaturated alcohols containing only six-membered aromatic rings as cyclic parts
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/23—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing hydroxy or O-metal groups
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    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
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    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings

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  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Reivindicación 1: Un compuesto o una de sus sales de acuerdo con la fórmula (1), caracterizado porque, A es un grupo seleccionado del grupo de fórmulas (2); T es ya sea CH o un átomo de nitrógeno; R¹ es un átomo de hidrógeno, alquilo C₁₋₆, alquenilo C₂₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, halógeno, ciano o hidroxi; cada uno de R², R³, R⁴ y R⁵ es, de modo independiente, un átomo de hidrógeno, alquilo C₁₋₆, cicloalquilo C₃₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, halógeno, ciano o hidroxilo o R² junto con R³ y R⁴ junto con R⁵ se toman, de modo independiente, junto con un átomo de carbono al que están unidos, para formar un grupo carbonilo (C=O); R⁶ es oxo, alquilo C₁₋₆, alquenilo C₂₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, halógeno, ciano o hidroxi; n es 0 - 2; cada uno de X¹, X², X³ y X⁴ es, de modo independiente, un átomo de hidrógeno, halógeno, ciano, hidroxi, nitro, formilo, mercapto, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, haloalquenilo C₂₋₆, haloalquinilo C₂₋₆, alcoxi C₁₋₆, alquenil C₂₋₆-oxi, alquinil C₂₋₆-oxi, haloalcoxi C₁₋₆, haloalquenil C₂₋₆-oxi, haloalquinil C₂₋₆-oxi, carboxi, carbamoílo, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₈, cicloalcoxi C₃₋₆, halocicloalcoxi C₃₋₈, alquinil C₃₋₆-alcoxi, haloalquinil C₃₋₆-alcoxi, alcoxialquilo C₂₋₆, cicloalcoxialquilo C₄₋₁₀, haloalcoxialquilo C₂₋₆, halocicloalcoxialquilo C₄₋₁₀, alcoxialcoxialquilo C₃₋₈, alcoxialcoxi C₂₋₆, cicloalquil C₄₋₁₀-alcoxi, hidroxialquilo C₁₋₆, cicloalquil C₄₋₁₀-alquilo, alquilcicloalquilo C₄₋₁₀, cicloalquilcicloalquilo C₆₋₁₄, halocicloalquilalquilo C₄₋₁₀, halocicloalquilcicloalquilo C₆₋₁₄, haloalquilcicloalquilo C₄₋₁₀, alquilcicloalquilalquilo C₅₋₁₀, cicloalquenilo C₃₋₈, halocicloalquenilo C₃₋₈, -SR²⁵, -S(O)R²⁵, -S(O)₂R²⁵, -OS(O)₂R²⁵, -(alquil C₁₋₆)S(O)₂R²⁵, alquiltioalquilo C₂₋₆, alquilsulfinilalquilo C₂₋₆, alquilsulfonilalquilo C₂₋₆, alquil C₂₋₆-carbonilo, haloalquil C₂₋₆-carbonilo, cicloalquil C₄₋₈-carbonilo, alcoxi C₂₋₆-carbonilo, haloalcoxi C₂₋₆-carbonilo, cicloalcoxi C₄₋₈-carbonilo, cicloalquil C₅₋₁₀-alcoxicarbonilo, alquil C₂₋₆-carboniloxi, haloalquil C₂₋₆-carboniloxi, cicloalquil C₄₋₈-carboniloxi, alcoxicarbonil C₂₋₆-oxi, haloalcoxicarbonil C₂₋₆-oxi, cicloalcoxi C₄₋₈-carboniloxi, alquil C₃₋₆-carbonilalcoxi, -NR²⁶R²⁷, alquilaminoalquilo C₂₋₆, (dialquilamino)alquilo C₃₋₈, haloalquilaminoalquilo C₂₋₆, cicloalquilaminoalquilo C₄₋₁₀, alquil C₁₋₆-sulfonilamino, haloalquil C₁₋₆-sulfonilamino, alquil C₂₋₆-aminocarbonilo, (dialquil C₃₋₁₀-amino)carbonilo, cicloalquil C₄₋₈-aminocarbonilo, dialquil C₂₋₈-hidroxiamino, (dialquil C₂₋₈-amino)hidroxi, trialquil C₃₋₁₀-hidrazinilo, trialquil C₃₋₁₀-sililo, trialquil C₄₋₁₀-sililalquilo, trialquil C₅₋₁₀-sililalquinilo, trialquil C₃₋₁₀-sililoxi, trialquil C₄₋₁₂-sililalquiloxi, trialquil C₅₋₁₂-sililalcoxialquilo, trialquil C₅₋₁₂-sililalquiniloxi, alquil C₂₋₆-sulfoniloxialquilo, haloalquil C₂₋₆-sulfoniloxialquilo, -C(=NOR²⁸)R²⁹, -C(=NR³⁰)R²⁹, cianoalquilo C₂₋₆, fenilo, fenoxi o bencilo o X¹ junto con X², X² junto con X³, y X³ junto con X⁴ forman una cadena de alquileno C₂₋₆ que pueden incluir un átomo de oxígeno, un átomo de azufre, un átomo de nitrógeno o se toman junto con un átomo de carbono al que están unidos para formar un anillo tiofeno, un anillo piridina, un anillo pirrol, un anillo imidazol, un anillo benceno, un anillo naftaleno, un anillo pirimidina, un anillo furano, un anillo pirazina, un anillo pirazol o un anillo oxazol; R²⁵ es alquilo C₁₋₈, cicloalquilo C₃₋₈, haloalquilo C₁₋₆, halocicloalquilo C₃₋₈, alquil C₁₋₆-amino, fenilo o bencilo y fenilo o bencilo se puede sustituir con al menos un R³¹; R³¹ es alquilo C₁₋₆, cicloalquilo C₃₋₈, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, cicloalcoxi C₃₋₈, halocicloalquilo C₃₋₈, alquil C₁₋₆-tio, alquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, haloalquil C₁₋₆-tio, haloalquil C₁₋₆-sulfinilo, haloalquil C₁₋₆-sulfonilo, halógeno, ciano o hidroxi; cada uno de R²⁶ y R²⁷ es, de modo independiente, un átomo de hidrógeno, alquilo C₁₋₆, cicloalquilo C₃₋₈, haloalquilo C₁₋₆, halocicloalquilo C₃₋₈, alcoxi C₁₋₆, dialquil C₂₋₈-amino, alquil C₂₋₆-carbonilo, haloalquil C₂₋₆-carbonilo, cicloalquil C₄₋₈-carbonilo, alcoxi C₂₋₆-carbonilo, haloalcoxi C₂₋₆-carbonilo o (dialquil C₃₋₁₀-amino)carbonilo; R²⁸ es un átomo de hidrógeno, alquilo C₁₋₆, haloalquilo C₁₋₆ o bencilo; R²⁹ es un átomo de hidrógeno, alquilo C₁₋₆, cicloalquilo C₃₋₈, haloalquilo C₁₋₆, halocicloalquilo C₃₋₈, cicloalquil C₄₋₁₀-alquilo, fenilo o bencilo; R³⁰ es alquilo C₁₋₆, cicloalquilo C₃₋₈, haloalquilo C₁₋₆, halocicloalquilo C₃₋₈, fenilo o bencilo; cada uno de R⁷ y R⁸ es, de modo independiente, alquilo C₁₋₄, cicloalquilo C₃₋₆ o haloalquilo C₁₋₄; E es -CR³²R³³- o -NR³⁴-; cada uno de R⁹, R¹⁰, R¹¹, R¹², R³² y R³³ es, de modo independiente, un átomo de hidrógeno, halógeno, ciano, hidroxi, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, haloalquenilo C₂₋₆, haloalquinilo C₂₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, cicloalquilo C₃₋₆, alquil C₁₋₆-tio, alquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, haloalquil C₁₋₆-tio, haloalquil C₁₋₆-sulfinilo o haloalquil C₁₋₆-sulfonilo; R³⁴ es un átomo de hidrógeno, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, haloalquenilo C₂₋₆, haloalquinilo C₂₋₆, alcoxialquilo C₂₋₆, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, alquiltioalquilo C₂₋₆, alquilsulfinilalquilo C₂₋₆, alquilsulfonilalquilo C₂₋₆, alquil C₂₋₆-carbonilo, haloalquil C₂₋₆-carbonilo, alcoxi C₂₋₆-carbonilo, alcoxicarbonilalquilo C₃₋₆, alquil C₂₋₆-aminocarbonilo, (dialquil C₃₋₆-amino)carbonilo, alquil C₁₋₆-sulfonilo o haloalquil C₁₋₆-sulfonilo; G¹, G² y G³ es un átomo de oxígeno o un átomo de azufre; cada uno de R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷, R²⁰, R²¹, R²², R²³ y R²⁴ es, de modo independiente, un átomo de hidrógeno, halógeno, ciano, hidroxi, amino, nitro, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, haloalquenilo C₂₋₆, haloalquinilo C₂₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, cicloalquil C₄₋₁₀-alquilo, alquilcicloalquilo C₄₋₁₀, alquilcicloalquilalquilo C₅₋₁₀, alcoxialquilo C₂₋₆, hidroxialquilo C₁₋₆, alquil C₁₋₆-tio, haloalquil C₁₋₆-tio, alquil C₁₋₆-sulfinilo, haloalquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, haloalquil C₁₋₆-sulfonilo, alquil C₁₋₆-amino, dialquil C₂₋₈-amino, cicloalquil C₃₋₆-amino, alquil C₂₋₆-carbonilo, haloalquil C₂₋₆-carbonilo, alcoxi C₂₋₆-carbonilo, haloalcoxi C₂₋₆-carbonilo, alquil C₂₋₆-carboniloxi, alquil C₂₋₆-carboniltio, alquil C₂₋₆-aminocarbonilo, (dialquil C₂₋₈-amino)carbonilo o trialquil C₃₋₆-sililo; R¹⁸ es un átomo de hidrógeno, alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alquil C₁₋₃-tio, halógeno, ciano o hidroxi; R¹⁹ es un átomo de hidrógeno, halógeno, ciano, hidroxi, formilo, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, haloalquenilo C₂₋₆, haloalquinilo C₂₋₆, alcoxi C₁₋₆, alquenil C₂₋₆-oxi, alquinil C₂₋₆-oxi, haloalcoxi C₁₋₆, haloalquenil C₂₋₆-oxi, haloalquinil C₂₋₆-oxi, carboxi, carbamoílo, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₈, cicloalcoxi C₃₋₆, halocicloalcoxi C₃₋₈, alcoxialquilo C₂₋₆, cicloalquilalquilo C₄₋₆, alquilcicloalquilo C₄₋₆, halocicloalquilalquilo C₄₋₆, cicloalquenilo C₃₋₈, halocicloalquenilo C₃₋₈, alquil C₁₋₆-tio, haloalquil C₁₋₆-tio, cicloalquil C₃₋₆-tio, alquiltioalquilo C₂₋₆, alquilsulfinilalquilo C₂₋₆, alquilsulfonilalquilo C₂₋₆, alquil C₂₋₆-carbonilo, haloalquil C₂₋₆-carbonilo, cicloalquil C₄₋₈-carbonilo, alcoxi C₂₋₆-carbonilo, haloalcoxi C₂₋₆-carbonilo, cicloalcoxi C₄₋₆-carbonilo, cicloalquil C₅₋₁₀-alcoxicarbonilo, alquil C₂₋₆-carboniloxi, haloalquil C₂₋₆-carboniloxi, alquil C₁₋₆-amino, dialquil C₁₋₆-amino, haloalquil C₁₋₆-amino, halodialquil C₁₋₆-amino, cicloalquil C₃₋₆-amino, alquilaminoalquilo C₂₋₆, (dialquil C₃₋₆-amino)alquilo, haloalquilaminoalquilo C₂₋₆, alquil C₁₋₆-sulfonilamino, haloalquil C₁₋₆-sulfonilamino, alquil C₂₋₆-carbonilamino, haloalquil C₂₋₆-carbonilamino, alquil C₂₋₆-aminocarbonilo o (dialquil C₃₋₁₀-amino)carbonilo; o R¹⁸ y R¹⁹ se toman junto con un átomo de carbono al que están unidos para formar un anillo de 3 - 7 miembros que contiene miembros seleccionados de átomo de carbono y a lo sumo 4 heteroátomos seleccionados, de modo independiente, de a lo sumo 2 átomos de oxigeno, a lo sumo 2 átomos de azufre, a lo sumo 2 átomos de nitrógeno y a lo sumo 2 átomos de silicio, en donde a lo sumo 3 miembros de átomos de carbono pueden estar sustituidos con oxo o tioxo, un miembro de átomos de azufre se selecciona, de modo independiente, de S(=O)ₚ(=NR³⁵)q, un miembro de átomos de silicio se selecciona, de modo independiente, de SiR³⁶R³⁷ y un anillo puede estar opcionalmente sustituido con a lo sumo 4 sustituyentes seleccionados, de modo independiente, de halógeno, ciano, alquilo C₁₋₂, haloalquilo C₁₋₂, alcoxi C₁₋₂ o haloalcoxi C₁₋₂ en un miembro de átomo de carbono y ciano, alquilo C₁₋₂ o alcoxi C₁₋₂ en un miembro del átomo de nitrógeno; R³⁵ se selecciona, de modo independiente, de un átomo de hidrógeno, ciano, alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alquil C₁₋₆-amino, dialquil C₂₋₆ amino, haloalquil C₁₋₆-amino o fenilo; cada uno de p y q es, de modo independiente, 0, 1 ó 2, en donde una suma de p y q es 0, 1 ó 2; cada uno de R³⁶ y R³⁷ es, de modo independiente, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, cicloalquil C₄₋₁₀-alquilo, alquilcicloalquilo C₄₋₇ o alquilcicloalquilalquilo C₅₋₇; Z es un átomo de oxígeno, un átomo de azufre, -N(R³⁸)-, -C(R³⁹)₂-, -OC(R³⁹)₂-, -SC(R³⁹)₂- o -N(R³⁸)C(R³⁹)₂-, en donde un enlace izquierdo es un enlace con un átomo de nitrógeno de A-3 del grupo de fórmulas (2) y un enlace derecho es un enlace con un átomo de carbono de A-3 del grupo de fórmulas (2); R³⁸ es un átomo de hidrógeno, ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxialquilo C₂₋₄, alquiltioalquilo C₂₋₄, alquil C₂₋₄-carbonilo, haloalquil C₂₋₄-carbonilo, alcoxi C₂₋₄-carbonilo, alquil C₂₋₄-aminocarbonilo, (dialquil C₃₋₅-amino)carbonilo, alquil C₁₋₄-sulfonilo o haloalquil C₁₋₄-sulfonilo; R¹⁸ y R³⁸ se toman junto con un átomo de carbono y un átomo de nitrógeno a los que están unidos para formar un anillo de 5 - 7 miembros parcialmente insaturado que contiene miembros además de los átomos de unión seleccionados de átomo de carbono y a lo sumo 5 heteroátomos seleccionados, de modo independiente, de a lo sumo 1 átomo de oxígeno, a lo sumo 1 átomo de azufre, a lo sumo 3 átomos de nitrógeno y un anillo puede estar opcionalmente sustituido con a lo sumo 3 sustituyentes seleccionados, de modo independiente, de halógeno, ciano, nitro, alquilo C₁₋₂, haloalquilo C₁₋₂, alcoxi C₁₋₂ o haloalcoxi C₁₋₂ en un miembro de átomo de carbono y ciano, alquilo C₁₋₂ o alcoxi C₁₋₂ en un miembro del átomo de nitrógeno; R³⁹ es, de modo independiente, un átomo de hidrógeno, alquilo C₁₋₆ o haloalquilo C₁₋₆; G⁴ es -OR⁴⁰, -SR⁴¹, -NR⁴²R⁴³ o R⁴⁴; cada uno de R⁴⁰ y R⁴¹ es, de modo independiente, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, haloalquenilo C₂₋₆, haloalquinilo C₂₋₆, alcoxialquilo C₂₋₆, cicloalcoxialquilo C₄₋₈, alcoxialcoxialquilo C₃₋₆, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, alquilaminoalquilo C₂₋₆, (dialquil C₃₋₆-amino)alquilo, haloalquilaminoalquilo C₂₋₆, cicloalquilaminoalquilo C₄₋₈, cicloalquilalquilo C₄₋₈, alquilcicloalquilo C₄₋₈, halocicloalquilalquilo C₄₋₈, alquilcicloalquilalquilo C₅₋₈, alquiltioalquilo C₂₋₆, alquilsulfinilalquilo C₂₋₆, alquilsulfonilalquilo C₂₋₆, alquil C₂₋₆-carbonilo, haloalquil C₂₋₆-carbonilo, cicloalquil C₄₋₈-carbonilo, alcoxi C₂₋₆-carbonilo, alquil C₂₋₆-aminocarbonilo, (dialquil C₃₋₆-amino)carbonilo o cicloalquil C₄₋₈-aminocarbonilo; R⁴² es un átomo de hidrógeno, ciano, amino, hidroxi, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆, haloalquenilo C₂₋₆, haloalquinilo C₂₋₆, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alcoxialquilo C₂₋₆, alquil C₁₋₆-amino, dialquil C₂₋₈-amino, haloalquil C₁₋₆-amino, halodialquil C₂₋₈-amino, cicloalquilalquilo C₄₋₈, alquil C₁₋₆-sulfonilo, haloalquil C₁₋₆-sulfonilo, alquil C₂₋₆-carbonilo o haloalquil C₂₋₆-carbonilo; R⁴³ es un átomo de hidrógeno, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, haloalquilo C₁₋₆ o cicloalquilo C₃₋₆; R⁴² y R⁴³ se toman junto con un átomo de nitrógeno al que están unidos para poder formar un anillo pirrolidina, un anillo piperidina o un anillo morfolina; R⁴⁴ es un átomo de hidrógeno, ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxialquilo C₂₋₄, alquil C₂₋₄-carbonilo, alcoxi C₂₋₄-carbonilo, alquil C₂₋₄, aminocarbonilo, (dialquil C₃₋₆-amino)carbonilo, haloalquil C₁₋₆-amino o halodialquil C₂₋₈-amino}.
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