AR107555A1 - Proceso integrado de producción de litio - Google Patents
Proceso integrado de producción de litioInfo
- Publication number
- AR107555A1 AR107555A1 ARP170100306A ARP170100306A AR107555A1 AR 107555 A1 AR107555 A1 AR 107555A1 AR P170100306 A ARP170100306 A AR P170100306A AR P170100306 A ARP170100306 A AR P170100306A AR 107555 A1 AR107555 A1 AR 107555A1
- Authority
- AR
- Argentina
- Prior art keywords
- lithium
- medium
- aqueous
- compartment
- protons
- Prior art date
Links
- 229910052744 lithium Inorganic materials 0.000 title abstract 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title abstract 7
- 238000004519 manufacturing process Methods 0.000 title abstract 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract 9
- 239000002609 medium Substances 0.000 abstract 6
- 238000005868 electrolysis reaction Methods 0.000 abstract 4
- 238000000746 purification Methods 0.000 abstract 4
- 239000000243 solution Substances 0.000 abstract 4
- -1 lithium cations Chemical class 0.000 abstract 3
- 230000008384 membrane barrier Effects 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/14—Alkali metal compounds
- C25B1/16—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/32—Carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
Un proceso de producción de hidróxido de litio que integra una etapa de depuración de litio con un proceso de producción de hidróxido de litio realizado en una celda de electrólisis de compartimiento doble. Un método para producir una solución acuosa con litio a partir de un medio con carga de litio, en el que el método comprende: (a) suministrar una celda de electrólisis de compartimiento doble con un ánodo, un cátodo y una barrera de membrana colocada entre medio, en la que dicha barrera de membrana es permeable para cationes de litio (Li⁺) y protones (H⁺), (b) depurar el medio con carga de litio mediante una solución de depuración acuosa para extraer dichos cationes de litio del medio a la solución acuosa de depuración, con lo cual se produce una solución intermedia acuosa con litio junto con un medio depurado. (c) introducir dicha solución intermedia acuosa con litio en un compartimiento anódico de dicha celda de electrólisis de compartimiento doble, para formar un anolito, (d) introducir un medio acuoso en un compartimiento catódico de dicha celda electrólisis de compartimiento doble para formar un catolito, (e) utilizar dicha celda para: (i) generar gas de oxígeno a dicho ánodo, (ii) producir dichos protones (H⁺) en dicho anolito y (iii) generar gas de hidrógeno e hidróxido (OH⁻) en el cátodo, y para que una parte de estos cationes de litio y una parte de estos protones atraviese la barrera de membrana, con lo cual dichos protones reaccionan con el hidróxido para producir agua en el catolito, (f) retirar una corriente de producto acuoso de dicho compartimiento catódico, en el que dicha corriente de producto contiene valores de hidróxido de litio disuelto y (g) reciclar una corriente de descarga con dicho anolito, del compartimiento anódico, para uso en la depuración del medio con carga de litio.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1602259.2A GB201602259D0 (en) | 2016-02-08 | 2016-02-08 | Integrated Lithium production process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR107555A1 true AR107555A1 (es) | 2018-05-09 |
Family
ID=55641990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP170100306A AR107555A1 (es) | 2016-02-08 | 2017-02-07 | Proceso integrado de producción de litio |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US10975478B2 (es) |
| AR (1) | AR107555A1 (es) |
| AU (1) | AU2017218724B2 (es) |
| CA (1) | CA3009934C (es) |
| CL (1) | CL2018001813A1 (es) |
| GB (1) | GB201602259D0 (es) |
| WO (1) | WO2017137885A1 (es) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013177680A1 (en) | 2012-05-30 | 2013-12-05 | Nemaska Lithium Inc. | Processes for preparing lithium carbonate |
| CA3014124A1 (en) | 2013-03-15 | 2014-09-18 | Nemaska Lithium Inc. | Use of electrochemical cell for preparing lithium hydoxide |
| KR102132463B1 (ko) | 2013-10-23 | 2020-08-06 | 네마스카 리튬 인코포레이션 | 리튬 카보네이트의 제조방법 |
| CN106103806B (zh) | 2014-02-24 | 2019-07-12 | 内玛斯卡锂业有限公司 | 处理含锂材料的方法 |
| GB201602259D0 (en) * | 2016-02-08 | 2016-03-23 | Bateman Advanced Technologies Ltd | Integrated Lithium production process |
| CA2940509A1 (en) | 2016-08-26 | 2018-02-26 | Nemaska Lithium Inc. | Processes for treating aqueous compositions comprising lithium sulfate and sulfuric acid |
| JP7542949B2 (ja) | 2016-11-14 | 2024-09-02 | ライラック ソリューションズ，インク． | コーティングされたイオン交換粒子を用いたリチウム抽出 |
| US11253848B2 (en) | 2017-08-02 | 2022-02-22 | Lilac Solutions, Inc. | Lithium extraction with porous ion exchange beads |
| CA3071649C (en) | 2017-08-02 | 2025-05-20 | Lilac Solutions, Inc. | ION EXCHANGE SYSTEM FOR LITHIUM EXTRACTION |
| CN111867980B (zh) * | 2017-11-22 | 2021-10-01 | 内玛斯卡锂业有限公司 | 制备各种金属的氢氧化物和氧化物以及其衍生物的方法 |
| WO2019160982A1 (en) * | 2018-02-17 | 2019-08-22 | Lilac Solutions, Inc. | Integrated system for lithium extraction and conversion |
| US10648090B2 (en) | 2018-02-17 | 2020-05-12 | Lilac Solutions, Inc. | Integrated system for lithium extraction and conversion |
| EP3759257A4 (en) | 2018-02-28 | 2021-11-24 | Lilac Solutions, Inc. | ION EXCHANGE REACTOR WITH PARTICLE TRAPS FOR LITHIUM EXTRACTION |
| MX2021011625A (es) | 2019-03-29 | 2022-01-27 | Lithium Americas Corp | Metodo de extraccion de litio a partir de arcilla sedimentaria. |
| MA55712A (fr) | 2019-04-19 | 2022-02-23 | Umicore Nv | Procédé de préparation de précurseurs de batterie |
| US12275650B2 (en) | 2019-05-22 | 2025-04-15 | Nemaska Lithium Inc. | Processes for preparing hydroxides and oxides of various metals and derivatives thereof |
| US11643703B2 (en) | 2019-06-18 | 2023-05-09 | Schlumberger Technology Corporation | Method of recovering alkali metals from an aqueous source |
| CA3166921A1 (en) | 2020-01-09 | 2021-07-15 | Lilac Solutions, Inc. | Process for separating undesirable metals |
| EP4162087A4 (en) | 2020-06-09 | 2024-11-06 | Lilac Solutions, Inc. | LITHIUM EXTRACTION IN THE PRESENCE OF SCALANTS |
| CN112142076B (zh) * | 2020-09-08 | 2022-06-24 | 中国科学院青海盐湖研究所 | 一种吸附法从卤水中提取锂的方法 |
| CA3199218A1 (en) | 2020-11-20 | 2022-05-27 | David Henry SNYDACKER | Lithium production with volatile acid |
| AR125722A1 (es) | 2021-04-23 | 2023-08-09 | Lilac Solutions Inc | Dispositivos de intercambio iónico para la extracción de litio |
| US12151211B2 (en) | 2021-07-19 | 2024-11-26 | Aqueous Resources LLC | Electro-pressure membrane method for recovery and concentration of lithium from aqueous sources |
| AU2022327715A1 (en) * | 2021-08-11 | 2024-03-07 | Tenova Advanced Technologies Ltd. | Process for producing lithium salts |
| WO2023192192A1 (en) | 2022-03-28 | 2023-10-05 | Lilac Solutions, Inc. | Lithium extraction enhanced by an alternate phase |
| WO2023192623A2 (en) | 2022-04-01 | 2023-10-05 | Lilac Solutions, Inc. | Extraction of lithium with chemical additives |
| US20240240280A1 (en) * | 2023-01-18 | 2024-07-18 | Lithium Nevada Corporation | Solvent extraction for selective lithium recovery |
| CN116837229B (zh) * | 2023-08-31 | 2023-11-28 | 中国科学院过程工程研究所 | 一种基于流动电极电化学选择性提锂的系统及方法和应用 |
| WO2025162887A1 (en) | 2024-02-01 | 2025-08-07 | Basf Se | Process and device for the electrolysis of lithium brines |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2980498A (en) * | 1957-01-29 | 1961-04-18 | Dow Chemical Co | Recovery of lithium from lithium bearing ores |
| EP0076094A3 (en) * | 1981-09-29 | 1983-08-24 | Rtr Riotinto Til Holding S.A. | Extraction |
| US6555078B1 (en) | 1996-09-26 | 2003-04-29 | Fmc Corporation | Method of preparing lithium salts |
| MX2010011560A (es) * | 2008-04-22 | 2011-04-27 | Chemetall Foote Corp | Metodo para hacer hidroxido de litio de alta pureza y acido clorhidrico. |
| US8741150B2 (en) * | 2008-09-29 | 2014-06-03 | Korea Institute Of Geosciences And Mineral Resources | Lithium recovery device using separator reservoir, lithium recovery method and lithium adsorption/desorption system using the same |
| CA2809241A1 (en) | 2008-11-17 | 2010-05-20 | Rockwood Lithium Inc. | Bipolar electrodialysis apparatus for separating ionic species in a lithium containing stream |
| US10190030B2 (en) * | 2009-04-24 | 2019-01-29 | Alger Alternative Energy, Llc | Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium |
| US9034294B1 (en) * | 2009-04-24 | 2015-05-19 | Simbol, Inc. | Preparation of lithium carbonate from lithium chloride containing brines |
| RS54914B1 (sr) | 2011-11-03 | 2016-10-31 | Advance Lithium Projects Ltd | Postupci uklanjanja jona metala iz vodenih rastvora |
| EP2811040B1 (en) * | 2012-02-03 | 2018-04-04 | Sumitomo Metal Mining Co., Ltd. | Lithium recovery method |
| AU2013252439B2 (en) | 2012-04-23 | 2018-04-19 | Nemaska Lithium Inc. | Processes for preparing lithium hydroxide |
| CA3014124A1 (en) * | 2013-03-15 | 2014-09-18 | Nemaska Lithium Inc. | Use of electrochemical cell for preparing lithium hydoxide |
| KR102132463B1 (ko) | 2013-10-23 | 2020-08-06 | 네마스카 리튬 인코포레이션 | 리튬 카보네이트의 제조방법 |
| KR102099714B1 (ko) | 2013-10-23 | 2020-04-13 | 네마스카 리튬 인코포레이션 | 리튬 하이드록사이드 제조 공정 및 시스템 |
| CN106103806B (zh) * | 2014-02-24 | 2019-07-12 | 内玛斯卡锂业有限公司 | 处理含锂材料的方法 |
| GB201602259D0 (en) * | 2016-02-08 | 2016-03-23 | Bateman Advanced Technologies Ltd | Integrated Lithium production process |
-
2016
- 2016-02-08 GB GBGB1602259.2A patent/GB201602259D0/en not_active Ceased
-
2017
- 2017-02-07 AR ARP170100306A patent/AR107555A1/es active IP Right Grant
- 2017-02-07 AU AU2017218724A patent/AU2017218724B2/en active Active
- 2017-02-07 CA CA3009934A patent/CA3009934C/en active Active
- 2017-02-07 US US16/073,795 patent/US10975478B2/en active Active
- 2017-02-07 WO PCT/IB2017/050644 patent/WO2017137885A1/en not_active Ceased
-
2018
- 2018-07-03 CL CL2018001813A patent/CL2018001813A1/es unknown
-
2021
- 2021-03-12 US US17/199,463 patent/US12509781B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US10975478B2 (en) | 2021-04-13 |
| AU2017218724A1 (en) | 2018-07-12 |
| WO2017137885A1 (en) | 2017-08-17 |
| US12509781B2 (en) | 2025-12-30 |
| US20190032227A1 (en) | 2019-01-31 |
| CL2018001813A1 (es) | 2018-10-19 |
| GB201602259D0 (en) | 2016-03-23 |
| CA3009934A1 (en) | 2017-08-17 |
| CA3009934C (en) | 2024-02-13 |
| US20210198793A1 (en) | 2021-07-01 |
| AU2017218724B2 (en) | 2022-10-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |