AR106411A1 - Proceso para convertir el gas de síntesis a olefinas sobre un catalizador bifuncional de óxido de cromo / óxido de zinc - sapo 34 - Google Patents
Proceso para convertir el gas de síntesis a olefinas sobre un catalizador bifuncional de óxido de cromo / óxido de zinc - sapo 34Info
- Publication number
- AR106411A1 AR106411A1 ARP160103194A ARP160103194A AR106411A1 AR 106411 A1 AR106411 A1 AR 106411A1 AR P160103194 A ARP160103194 A AR P160103194A AR P160103194 A ARP160103194 A AR P160103194A AR 106411 A1 AR106411 A1 AR 106411A1
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst
- olefins
- sapo
- zinc oxide
- converting
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 239000011787 zinc oxide Substances 0.000 title abstract 2
- 241000269350 Anura Species 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 230000001588 bifunctional effect Effects 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
- 238000010977 unit operation Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/04—Ethylene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Un proceso para preparar olefinas C₂ y C₃ comprende poner en contacto una corriente de alimentación, que incluye hidrógeno, monóxido de carbono y un catalizador bifuncional en una reacción bajo ciertas condiciones específicas. El catalizador incluye como componentes (1) óxidos metálicos mixtos de óxido de cromo y óxido de zinc, y (2) un tamiz molecular SAPO-34. El producto resultante de la reacción es relativamente alto en las olefinas inferiores objetivo y relativamente bajo en los productos menos deseados, que incluyen parafinas C₂ y C₃, hidrocarburos C₄⁺, oxigenados y metano, por lo tanto se reduce o se elimina la necesidad de ciertas separaciones previamente comunes y costosas. El catalizador bifuncional como se utiliza en el proceso inventivo también ofrece mejoras en la vida del catalizador en comparación con algunos catalizadores de metanol a olefinas. El proceso se puede llevar a cabo como una sola operación unitaria.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562248585P | 2015-10-30 | 2015-10-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR106411A1 true AR106411A1 (es) | 2018-01-10 |
Family
ID=56936538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP160103194A AR106411A1 (es) | 2015-10-30 | 2016-10-19 | Proceso para convertir el gas de síntesis a olefinas sobre un catalizador bifuncional de óxido de cromo / óxido de zinc - sapo 34 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10329209B2 (es) |
| EP (1) | EP3368499B1 (es) |
| CN (1) | CN108137431B (es) |
| AR (1) | AR106411A1 (es) |
| BR (1) | BR112018006841B1 (es) |
| CA (1) | CA3003620C (es) |
| ES (1) | ES2745530T3 (es) |
| PT (1) | PT3368499T (es) |
| WO (1) | WO2017074558A1 (es) |
| ZA (1) | ZA201803044B (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR110362A1 (es) | 2016-12-22 | 2019-03-20 | Dow Global Technologies Llc | Proceso para convertir gas de síntesis en olefinas usando un catalizador bifuncional de óxido de cromozinc - sapo-34 |
| CN109701628A (zh) * | 2017-10-26 | 2019-05-03 | 中国石油化工股份有限公司 | 含磷铝分子筛的复合催化剂及其在合成气一步法制烯烃的应用 |
| PT3703857T (pt) | 2017-10-30 | 2024-07-25 | Dow Global Technologies Llc | Produção seletiva e estável de olefinas através de um catalisador híbrido |
| CN107803219B (zh) * | 2017-11-16 | 2021-03-02 | 中国科学院山西煤炭化学研究所 | 一种由合成气直接制低碳烯烃催化剂及制备方法和应用 |
| US11884605B2 (en) | 2018-06-29 | 2024-01-30 | Dow Global Technologies Llc | Hybrid catalysts comprising a zeolite and a mixed metal oxide component for converting syngas into C2 and C3 olefins |
| EP3814001A1 (en) | 2018-06-29 | 2021-05-05 | Dow Global Technologies LLC | <sup2/>? <sub2/>?2?hybrid catalysts comprising a mixed metal oxide component for production of cand c <ns1:sub>3</ns1:sub>?hydrocarbons |
| CA3113222A1 (en) * | 2018-09-18 | 2020-03-26 | Dow Global Technologies Llc | Process for preparing c2-c5 hydrocarbons using a hybrid catalyst |
| CN109261199B (zh) * | 2018-09-27 | 2021-03-19 | 太原理工大学 | 一种高稳定性合成气直接制低碳烯烃的催化剂、制备方法及其应用 |
| US11999671B2 (en) * | 2018-12-21 | 2024-06-04 | Dalian Institute Of Chemical Physics, Cas | Method for preparing light olefin through catalytic syngas with high selectivity by heteroatom-doped zeolite |
| EP3902780B1 (en) | 2018-12-28 | 2022-12-28 | Dow Global Technologies LLC | Catalysts comprising a zirconia and gallium oxide component for production of c2 to c4 olefins |
| WO2020139600A2 (en) | 2018-12-28 | 2020-07-02 | Dow Global Technologies Llc | Methods for producing c2 to c5 paraffins using a hybrid catalyst comprising gallium metal oxide |
| WO2020210092A1 (en) | 2019-04-10 | 2020-10-15 | Exxonmobil Chemical Patents Inc. | Multicomponent catalysts for syngas conversion to light hydrocarbons |
| CN112108180A (zh) * | 2019-06-21 | 2020-12-22 | 中国科学院大连化学物理研究所 | 一种合成气直接转化制低碳烯烃的催化剂及其制备方法 |
| CN110479363A (zh) * | 2019-08-29 | 2019-11-22 | 太原理工大学 | 一种高性能ZnCr/SAPO-34双功能催化剂的制备方法及其应用 |
| CN112694377A (zh) * | 2019-10-22 | 2021-04-23 | 中国石油化工股份有限公司 | 一种由合成气直接制烯烃的工艺方法 |
| CN112934254B (zh) * | 2019-12-11 | 2023-06-20 | 中国科学院大连化学物理研究所 | 一种催化正庚烷转化的双功能催化剂及其制备方法 |
| AR120551A1 (es) | 2019-12-19 | 2022-02-23 | Dow Global Technologies Llc | Procesos para la producción de olefinas c₂ a c₄ |
| CN113816816B (zh) * | 2020-06-19 | 2022-10-28 | 中国科学院大连化学物理研究所 | 一种甲醇和/或二甲醚制取低碳烯烃的方法 |
| CN116057029A (zh) | 2020-06-30 | 2023-05-02 | 陶氏环球技术有限责任公司 | 用于在杂化催化剂的存在下制备c2至c3烃的方法 |
| CN114433221B (zh) * | 2020-10-20 | 2024-01-30 | 中国石油化工股份有限公司 | 一种改性的金属氧化物-分子筛复合物及其制法和应用 |
| CN117324034B (zh) * | 2022-06-24 | 2025-11-25 | 中国石油化工股份有限公司 | 合成气一步法生产烯烃的催化剂及其制备方法和应用 |
| CN116408137B (zh) * | 2023-03-07 | 2024-10-29 | 中国石油大学(华东) | 用于石脑油制烯烃的催化剂及其制备方法和应用 |
| US20250011259A1 (en) * | 2023-07-07 | 2025-01-09 | Greyrock Technology, Llc | Process and catalysts for the production of ethylene and propylene from low-carbon syngas |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5714662A (en) * | 1995-08-10 | 1998-02-03 | Uop | Process for producing light olefins from crude methanol |
| US7166757B2 (en) | 2004-07-30 | 2007-01-23 | Exxonmobil Chemical Patents Inc. | Conversion of oxygenates to olefins |
| WO2006016444A1 (ja) | 2004-08-10 | 2006-02-16 | Japan Gas Synthesize, Ltd. | 液化石油ガス製造用触媒、および、この触媒を用いた液化石油ガスの製造方法 |
| US20070244000A1 (en) * | 2006-04-13 | 2007-10-18 | Michel Molinier | Producing olefin product from syngas |
| KR100904297B1 (ko) * | 2007-10-26 | 2009-06-25 | 한국화학연구원 | 연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법 |
| CN101747160B (zh) | 2008-11-28 | 2013-06-05 | 中国石油化工股份有限公司 | 一种由合成气制备甲醇、二甲醚和低碳烯烃的方法 |
| US7943673B2 (en) | 2008-12-10 | 2011-05-17 | Chevron U.S.A. Inc. | Process for conversion of synthesis gas to hydrocarbons using a zeolite-methanol catalyst system |
| US8513315B2 (en) | 2009-12-30 | 2013-08-20 | Chevron U.S.A. Inc. | CO2 injection into synthesis feed gas to reduce or eliminate net CO2 production during isosynthesis over ZnO-Cr2O3 plus ZSM-5 hybrid catalyst combinations |
| US9126876B2 (en) | 2011-04-04 | 2015-09-08 | Dow Global Technologies Llc | Fischer-Tropsch process for converting synthesis gas to a lower olefin |
| CN102320912B (zh) * | 2011-06-03 | 2014-04-16 | 神华集团有限责任公司 | 最大化含氧化合物转化制备低碳烯烃工艺中的乙烯和丙烯总收率的方法 |
| CN103508828A (zh) | 2012-06-30 | 2014-01-15 | 中国科学院大连化学物理研究所 | 一种合成气制乙烷和丙烷的方法 |
| JP6006879B2 (ja) | 2012-09-26 | 2016-10-12 | ダリアン インスティテュート オブ ケミカル フィジックス，チャイニーズ アカデミー オブ サイエンシズ | Ｓａｐｏ−３４分子篩及びその合成方法 |
| CN103071528A (zh) * | 2013-01-21 | 2013-05-01 | 浙江大学 | 核壳结构催化剂及由合成气一步法制取低碳烯烃的方法 |
| CN104437532B (zh) * | 2013-09-24 | 2017-03-15 | 中国石油化工股份有限公司 | 固定床制低碳烯烃催化剂、制备方法及其用途 |
| CN104549343B (zh) * | 2013-10-28 | 2017-07-14 | 中国石油化工股份有限公司 | 合成气制低碳烯烃催化剂、制备方法及其用途 |
-
2016
- 2016-09-07 ES ES16766441T patent/ES2745530T3/es active Active
- 2016-09-07 CN CN201680059754.1A patent/CN108137431B/zh active Active
- 2016-09-07 WO PCT/US2016/050490 patent/WO2017074558A1/en not_active Ceased
- 2016-09-07 US US15/769,871 patent/US10329209B2/en active Active
- 2016-09-07 BR BR112018006841-1A patent/BR112018006841B1/pt active IP Right Grant
- 2016-09-07 EP EP16766441.6A patent/EP3368499B1/en active Active
- 2016-09-07 PT PT167664416T patent/PT3368499T/pt unknown
- 2016-09-07 CA CA3003620A patent/CA3003620C/en active Active
- 2016-10-19 AR ARP160103194A patent/AR106411A1/es active IP Right Grant
-
2018
- 2018-05-09 ZA ZA2018/03044A patent/ZA201803044B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017074558A1 (en) | 2017-05-04 |
| CA3003620A1 (en) | 2017-05-04 |
| PT3368499T (pt) | 2019-10-08 |
| BR112018006841B1 (pt) | 2020-12-15 |
| CN108137431A (zh) | 2018-06-08 |
| US20180305272A1 (en) | 2018-10-25 |
| US10329209B2 (en) | 2019-06-25 |
| ZA201803044B (en) | 2019-07-31 |
| CA3003620C (en) | 2023-10-24 |
| ES2745530T3 (es) | 2020-03-02 |
| BR112018006841A2 (pt) | 2018-10-16 |
| EP3368499A1 (en) | 2018-09-05 |
| EP3368499B1 (en) | 2019-08-07 |
| CN108137431B (zh) | 2021-04-23 |
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