AR105901A1 - DERIVATIVES OF 1,3-TIAZOL-4-ONA WITH PESTICIDE PROFIT, ITS COMPOSITIONS AND PEST CONTROL PROCESSES - Google Patents

Abstract

The disclosure refers to the field of molecules that have pesticidal utility against the pests of the Arthropod, Mollusc and Nematode Edges, to the processes to produce such molecules, to the intermediates used in such processes, to the pesticidal compositions containing such molecules and to the processes for using such pesticidal compositions against such pests. These pesticidal compositions can be used, for example, as acaricides, molluscicidal acaricidal insecticides and nematicides. Claim 1: A molecule having the formula (1) in which: (A) Ar¹ is selected from the group consisting of: furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, or thienyl, wherein each furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, and thienyl may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁ ₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C ( O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-OC ₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, and phenoxy, in which each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂ , C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O ) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl , C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, and phenoxy; (B) Het is a 5 or 6 membered heterocyclic, saturated or unsaturated ring, which contains one or more heteroatoms independently selected from nitrogen, sulfur or oxygen, and where Ar¹ and L¹ are not ortho with each other, but may they are meta or para, such as, for a five member ring they are 1.3, and for a six member ring they are either 1.3 or 1.4, in which each heterocyclic ring can be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, oxo, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋ ₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O- C₁₋ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O -C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, and phenoxy, in the that each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br I, CN, NO₂, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S ( O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O ) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C ( O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, and phenoxy; (C) L¹ is selected from the group consisting of: N (Rˣ) -C₁₋₄ alkyl, N (Rˣ) -C₃₋₈ cycloalkyl, N (Rˣ) -C₂₋₆ alkenyl, N (Rˣ) -C₂₋ ₆ alkynyl, N (Rˣ) -S (O) ₙ-C₁₋₄ alkyl, C₁₋₄ alkyl-N (Rˣ) -C₁₋₄ alkyl, C₁₋₄ alkyl-N (Rˣ) -C₁₋₄ alkyl, C₁ ₋₄ alkyl-N (Rˣ), C₃₋₈ cycloalkyl-N (Rˣ), C₂₋₆ alkynyl-N (Rˣ), C₁₋₄ alkyl-S (O) ₙ-N (Rˣ), C (O) - N (Rˣ), C (S) -N (Rˣ), N (Rˣ) -C (O), N (Rˣ) -C (S), C (O) -N (Rˣ) -C₁₋₄ alkyl, C (S) -N (Rˣ) -C₁₋₄ alkyl, C₁₋₄ alkyl-N (Rˣ) -C (O), and C₁₋₄ alkyl-N (Rˣ) C (S), in which each alkyl , cycloalkyl, alkenyl, and alkynyl may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃ ₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, and C₂₋₆ alkynyl; (D) Ar² is selected from the group consisting of: furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, or thienyl, wherein each furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, and thienyl may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂ ₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) - NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl , C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆alkenyl, C₁₋₄ alkyl-O-C₁ ₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C ₋₄ -C (O) O-C₁₋₄ alkyl, phenyl, and phenoxy alkyl, wherein each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O -C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl -C (= O) O-C₁₋₄ alkyl, phenyl, and phenoxy; (E) R¹⁵ is selected from the group consisting of: H, C₁₋₄ alkyl, C₃₋₈ cycloalkyl, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, C (O) -NRˣRʸ, C (O) -phenyl, C₁₋₄ alkyl-NRˣRʸ, C (O) O-C₁₋₄ alkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) -C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) O-C₁₋₄ alkyl, wherein each alkyl, cycloalkyl, alkenyl, alkynyl, and phenyl may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, oxo, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalqui lo, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl , C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋ ₆alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl -C (O) O-C₁₋₄ alkyl, phenyl, and phenoxy; (F) Q¹ is selected from the group consisting of: O and S; (G) Q² is selected from the group consisting of: O and S; (H) R¹⁶ is selected from the group consisting of: (K), H, C₁₋₄ alkyl, C₃₋₈ cycloalkyl, C₂₋₆ alkenyl, C₂₋₆ alkynyl, C (O) -C₁₋₄ alkyl, C₁ ₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C₁₋₄ alkylphenyl, C₁₋₄ alkyl-O-phenyl, C (O) - (Het-1 ), (Het-1), C₁₋₄ alkyl- (Het-1), C₁₋₄ alkyl-OC (O) -C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) C₁₋₄ alkyl, C₁₋ ₄ alkyl-OC (O) O-C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) -NRˣRʸ, C₁₋₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl- (Het-1) , C₁₋₄ alkyl-C (O) - (Het-1), C₁₋₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl (NRˣRʸ) -C (O) OH, C₁₋₄ alkyl- C (O) -N (Rˣ) C₁₋₄ alkyl-NRˣRʸ, C₁₋₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl-N (Rˣ) -C (O) O-C₁₋₄ alkyl , C₁₋₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl (N (Rˣ) -C (O) O-C₁₋₄ alkyl) -C (O) OH, C₁₋₄ alkyl-C ( O) - (Het-1) -C (O) O-C₁₋₄ alkyl, C₁₋₄ alq uyl-OC (O) O-C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) -C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) -C₃₋₈ cycloalkyl, C₁₋₄ alkyl-OC ( O) - (Het-1), C₁₋₄ alkyl-OC (O) -C₁₋₄ alkyl-N (Rˣ) -C (O) O-C₁₋₄ alkyl, C₁₋₄ alkyl-NRˣRʸ, C₁₋₄ alkyl-S (O) ₙ- (Het-1), and C₁₋₄ alkyl-O- (Het-1), in which each alkyl, cycloalkyl, alkenyl, alkynyl, phenyl, and (Het-1) may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, NRˣRʸ, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C ( O) H, C (O) OH, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) - C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁ ₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, phenoxy, Si (C₁₋₄ alkyl) ₃, S (O) ₙ-NRˣRʸ, and (Het-1); (I) R¹⁷ is selected from the group consisting of: (K), H, C₁₋₄ alkyl, C₃₋₈ cycloalkyl, C₂₋₆ alkenyl, C₂₋₆ alkynyl, C (O) -C₁₋₄ alkyl, C₁ ₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C₁₋₄ alkylphenyl, C₁₋₄ alkyl-O-phenyl, C (O) - (Het-1 ), (Het-1)), C₁₋₄ alkyl- (Het-1), C₁₋₄ alkyl-OC (O) -C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) -C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) O-C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) -NRˣRʸ, C₁₋₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl- (Het- 1), C₁₋₄ alkyl-C (O) - (Het-1), C₁₋₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl- (NRˣRʸ) -C (O) OH, C₁₋ ₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl-NRˣRʸ, C₁₋₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl-N (Rˣ) -C (O) O-C₁ ₋₄ alkyl, C₁₋₄ alkyl-C (O) -N (Rˣ) C₁₋₄ alkyl (N (Rˣ) -C (O) O-C₁₋₄ alkyl) C (O) OH, C₁₋₄ alkyl- C (O) - (Het-1) -C (O) O-C₁₋₄ alkyl, C₁₋₄ a alkyl-OC (O) O-C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) -C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) -C₃₋₈ cycloalkyl, C₁₋₄ alkyl-OC ( O) - (Het-1), C₁₋₄ alkyl-OC (O) -C₁₋₄ alkyl-N (Rˣ) -C (O) O-C₁₋₄ alkyl, C₁₋₄ alkyl-NRˣRʸ, C₁₋₄ alkyl-S (O) ₙ- (Het-1), and C₁₋₄ alkyl-O- (Het-1), in which each alkyl, cycloalkyl, alkenyl, alkynyl, phenyl, and (Het-1) may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, NRˣRʸ, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋ ₄ alkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-haloalkyl, C (O) H, C (O) OH, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋ ₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C ₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋ ₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, phenoxy, Si (C₁₋₄ alkyl) ₃, S ( O) ₙ-NRˣRʸ, and (Het-1); (J) L² is selected from the group consisting of: C₃₋₈ cycloalkyl, phenyl, C₁₋₄ alkylphenyl, C₁₋₄ alkyl-O-phenyl, C₂₋₆ alkenyl-O-phenyl, (Het-1), C₁ ₋₄ alkyl- (Het-1), and C₁₋₄ alkyl-O- (Het-1), in which each alkyl, cycloalkyl, alkenyl, phenyl, and (Het-1) may be optionally substituted with -one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, NRˣRʸ, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C ( O) H, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₁₋₄ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, O-C₁₋₄ alkyl, S-C₁₋₄ alkyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O ) O-C₁₋₄ alkyl, phenyl, phenoxy, and (Het-1), wherein each alkyl, cycloalkyl, alkenyl, phenyl, and (Het-1) substituent may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, NRˣRʸ, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) H, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O- C₁₋₄ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₁₋₄ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, O-C₁ ₄ alkyl, S-C₁₋₄ alkyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, phenoxy, and (Het -one); (K) R¹⁶ and R¹⁷ together with Cˣ (Q²) (Nˣ), form a saturated or unsaturated heterocyclic ring of 4 to 7 members which may contain one or more heteroatoms of the group consisting of nitrogen, sulfur, and oxygen, in the that each heterocyclic ring may be optionally substituted with one or more substituents independently selected from the group consisting of: oxo, R¹⁸, and R¹⁹, wherein R¹⁸ and R¹⁹ are each independently selected from the group consisting of: H, F , Cl, Br, I, CN, NO₂, oxo, thioxo, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) H, C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) C₃₋₈ cycloalkyl, C (O) O-C₃ ₋₈ c icloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl , C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, and (Het-1); (L) Rˣ and Rʸ are each independently selected from the group consisting of: H, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) H, C (O ) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C₃₋₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋₄ alkyl-OC ( O) -C₁₋₄ alkyl, C₁₋₄ alkyl-OC (O) O-C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl- C (O) O-C₁₋₄ alkyl, and phenyl, wherein each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl, and phenyl may be optionally substituted with one or more s independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂ ₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂-C₁₋₄ haloalkyl, C (O) H , C (O) -C₁₋₄ alkyl, C (O) O-C₁₋₄ alkyl, C (O) -C₁₋₄ haloalkyl, C (O) O-C₁₋₄ haloalkyl, C (O) -C₃₋ ₈ cycloalkyl, C (O) O-C₃₋₈ cycloalkyl, C (O) -C₂₋₆ alkenyl, C (O) O-C₂₋₆ alkenyl, C₁₋₄ alkyl-O-C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) ₙ-C₁₋₄ alkyl, C (O) -C₁₋₄ alkyl-C (O) O-C₁₋₄ alkyl, phenyl, and (Het-1); (M) (Het-1) is a 5 or 6 membered heterocyclic, saturated or unsaturated ring, which contains one or more heteroatoms independently selected from the group consisting of: nitrogen, sulfur or oxygen, in which each heterocyclic ring it may be optionally substituted with one or more substituents independently selected from the group consisting of: H, F, Cl, Br, I, CN, NO₂, oxo, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₈ cycloalkyl, C₁ ₋₄ alkoxy, C₁₋₄ haloalkoxy, C₂₋₆ alkenyl, C₂₋₆ alkynyl, S (O) ₙ-C₁₋₄ alkyl, S (O) ₙ-C₁₋₄ haloalkyl, OSO₂-C₁₋₄ alkyl, OSO₂- C₁₋₄ haloalkyl, C (O) -NRˣRʸ, C₁₋₄ alkyl-NRˣRʸ, C (O) -C₁₋₄ alkyl,