AR093431A1 - MICRABIOCIDES PIRAZOL DERIVATIVES - Google Patents
MICRABIOCIDES PIRAZOL DERIVATIVESInfo
- Publication number
- AR093431A1 AR093431A1 ARP130104128A ARP130104128A AR093431A1 AR 093431 A1 AR093431 A1 AR 093431A1 AR P130104128 A ARP130104128 A AR P130104128A AR P130104128 A ARP130104128 A AR P130104128A AR 093431 A1 AR093431 A1 AR 093431A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- cycloalkyl
- aryl
- alkoxy
- halogen
- Prior art date
Links
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 12
- 229910052736 halogen Inorganic materials 0.000 abstract 8
- 150000002367 halogens Chemical group 0.000 abstract 8
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 6
- 125000003118 aryl group Chemical group 0.000 abstract 6
- 229910052739 hydrogen Inorganic materials 0.000 abstract 6
- 239000001257 hydrogen Substances 0.000 abstract 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 6
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 5
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract 5
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 5
- 125000006555 (C3-C5) cycloalkyl group Chemical group 0.000 abstract 4
- 125000004414 alkyl thio group Chemical group 0.000 abstract 4
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 4
- 125000001072 heteroaryl group Chemical group 0.000 abstract 4
- 125000000623 heterocyclic group Chemical group 0.000 abstract 4
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 3
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000005133 alkynyloxy group Chemical group 0.000 abstract 3
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 abstract 2
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000004390 alkyl sulfonyl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000004391 aryl sulfonyl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- -1 cyano, amino Chemical group 0.000 abstract 2
- 125000004446 heteroarylalkyl group Chemical group 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 1
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 1
- 206010061217 Infestation Diseases 0.000 abstract 1
- 150000001204 N-oxides Chemical class 0.000 abstract 1
- 125000003302 alkenyloxy group Chemical group 0.000 abstract 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000005135 aryl sulfinyl group Chemical group 0.000 abstract 1
- 125000005110 aryl thio group Chemical group 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 1
- 125000005149 cycloalkylsulfinyl group Chemical group 0.000 abstract 1
- 125000005144 cycloalkylsulfonyl group Chemical group 0.000 abstract 1
- 125000005366 cycloalkylthio group Chemical group 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 244000005700 microbiome Species 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 230000003032 phytopathogenic effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D498/10—Spiro-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D498/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
- C07D498/20—Spiro-condensed systems
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Abstract
La presente también se refiere a métodos para emplear los compuestos de fórmula (1) con el fin de controlar o prevenir la infestación de plantas, el material de propagación de estas, cultivos recolectados o materiales inertes por parte de microorganismos fitopatógenos o responsables de la descomposición u organismos potencialmente dañinos para el ser humano. Reivindicación 1: Un compuesto de fórmula (1) donde G¹ y G² son independientemente O ó S; T es CR¹² o N; Y¹ e Y² son independientemente CR¹³ o N; n es 1 ó 2; p es 1 ó 2, siempre que, cuando n sea 2, p sea 1; R¹ y R² son cada uno independientemente alquilo C₁₋₄, cicloalquilo C₃₋₅ o haloalquilo C₁₋₄; R³, R⁴, R⁵, R⁶, R⁷ y R⁸ son cada uno independientemente hidrógeno, hidroxi, halógeno, ciano, alquilo C₁₋₄, alcoxi C₁₋₄, cicloalquilo C₃₋₅ o haloalquilo C₁₋₄; R⁹ y R¹⁰ son cada uno independientemente hidrógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, cicloalquilo C₃₋₅, arilo o heteroarilo, donde arilo y heteroarilo están opcionalmente sustituidos con uno o más R¹⁴; o R⁹ y R¹⁰, junto con los átomos de carbono a los cuales están unidos, forman un anillo heterocíclico o isocíclico de 5 a 10 miembros que comprende opcionalmente uno o dos miembros anulares seleccionados entre O, N, S o un grupo carbonilo, estando dicho anillo heterocíclico o isocíclico opcionalmente sustituido con uno o más R¹⁴; X es O ó N-R¹⁵; R¹¹ es hidrógeno, alquilo C₁₋₄, cicloalquilo C₃₋₅, alquenilo C₂₋₈, alquinilo C₂₋₈, (cicloalquil C₃₋₅)-(alquilo C₁₋₄), arilo, alquilsulfonilo C₁₋₄, arilsulfonilo, heteroarilo, arilalquilo y heteroarilalquilo donde alquilo, cicloalquilo y alquenilo están sustituidos opcionalmente con halógeno, y donde arilo, heteroarilo, arilalquilo y heteroarilalquilo están opcionalmente sustituidos con uno o más R¹⁴; R¹² es hidrógeno, halógeno o hidroxilo; R¹³ es hidrógeno, halógeno, ciano, alquilo C₁₋₄ o alcoxi C₁₋₄; cada R¹⁴ es independientemente halógeno, ciano, amino, nitro, hidroxilo, mercapto, alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, cicloalquilo C₃₋₈, (cicloalquil C₃₋₈)-(alquilo C₁₋₄), (cicloalquil C₃₋₈)-(alcoxi C₁₋₄), (cicloalquil C₃₋₈)-(alquiltio C₁₋₄), alcoxi C₁₋₈, cicloalcoxi C₃₋₈, alqueniloxi C₁₋₈, alquiniloxi C₂₋₈, alquiltio C₁₋₈, alquilsulfonilo C₁₋₈, alquilsulfinilo C₁₋₈, cicloalquiltio C₃₋₈, cicloalquilsulfonilo C₃₋₈, cicloalquilsulfinilo C₃₋₈, arilo, ariloxi, ariltio, arilsulfonilo, arilsulfinilo, aril-(alquilo C₁₋₄), aril-(alcoxi C₁₋₄), aril-(alquiltio C₁₋₄), heterociclilo, heterociclil-(alquilo C₁₋₄), heterociclil-(alcoxi C₁₋₄), heterociclil-(alquiltio C₁₋₄), NH(alquilo C₁₋₈), N(alquilo C₁₋₈)₂, (alquil C₁₋₄) carbonilo, (cicloalquil C₃₋₈)carbonilo, (alquenil C₂₋₈)carbonilo, (alquinil C₂₋₈)carbonilo, donde alquilo, alquenilo, alquinilo, cicloalquilo, alcoxi, alqueniloxi, alquiniloxi y cicloalcoxi están opcionalmente sustituidos con halógeno, y donde arilo y heterociclilo están opcionalmente sustituidos con uno o más R¹⁶; o R¹⁴ es C=NOR¹¹; cada R¹⁵ es independientemente hidrógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, cicloalquilo C₃₋₆, alquilsulfonilo C₁₋₄, donde alquilo, cicloalquilo y alquilsulfonilo están opcionalmente sustituidos con halógeno; y cada R¹⁶ es independientemente halógeno, ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄ o haloalcoxi C₁₋₄; o una de sus sales o N-óxidos.This also refers to methods for using the compounds of formula (1) in order to control or prevent plant infestation, plant propagation material, harvested crops or inert materials by phytopathogenic microorganisms or responsible for decomposition or organisms potentially harmful to humans. Claim 1: A compound of formula (1) wherein G¹ and G² are independently O or S; T is CR¹² or N; Y¹ and Y² are independently CR¹³ or N; n is 1 or 2; p is 1 or 2, provided that, when n is 2, p is 1; R¹ and R² are each independently C₁₋₄ alkyl, C₃₋₅ cycloalkyl or C₁₋₄ haloalkyl; R³, R⁴, R⁵, R⁶, R⁷ and R⁸ are each independently hydrogen, hydroxy, halogen, cyano, C₁₋₄ alkyl, C₁₋₄ alkoxy, C₃₋₅ cycloalkyl or C₁₋₄ haloalkyl; R⁹ and R¹⁰ are each independently hydrogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₅ cycloalkyl, aryl or heteroaryl, where aryl and heteroaryl are optionally substituted with one or more R¹⁴; or R⁹ and R¹⁰, together with the carbon atoms to which they are attached, form a 5- to 10-membered heterocyclic or isocyclic ring optionally comprising one or two annular members selected from O, N, S or a carbonyl group, said being heterocyclic or isocyclic ring optionally substituted with one or more R¹⁴; X is O or N-R¹⁵; R¹¹ is hydrogen, C₁₋₄ alkyl, C₃₋₅ cycloalkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, (C₁₋₄ cycloalkyl) - (C₁₋₄ alkyl), aryl, C₁₋₄ alkylsulfonyl, arylsulfonyl, heteroaryl, arylalkyl and heteroarylalkyl where alkyl, cycloalkyl and alkenyl are optionally substituted with halogen, and where aryl, heteroaryl, arylalkyl and heteroarylalkyl are optionally substituted with one or more R¹⁴; R² is hydrogen, halogen or hydroxyl; R¹³ is hydrogen, halogen, cyano, C₁₋₄ alkyl or C₁₋₄ alkoxy; each R¹⁴ is independently halogen, cyano, amino, nitro, hydroxyl, mercapto, C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₃₋₈ cycloalkyl, (C₃₋₈ cycloalkyl) - (C₁₋₄ alkyl), (C₃₋₈ cycloalkyl) - (C₁₋₄ alkoxy), (C₃₋₈ cycloalkyl) - (C₁₋₄ alkylthio), C₁₋₈ alkoxy, C₁₋₈ alkynyloxy, C₂₋₈ alkynyloxy, C₁ alkylthio ₋₈, C₁₋₈ alkylsulfonyl, C₁₋₈ alkylsulfinyl, C₃₋₈ cycloalkylthio, C₃₋₈ cycloalkylsulfonyl, C₃₋₈ cycloalkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, arylsulfinyl, aryl- (C₁₋₄ alkyl), aryl- ( C₁₋₄ alkoxy), aryl- (C₁₋₄ alkylthio), heterocyclyl, heterocyclyl- (C₁₋₄ alkyl), heterocyclyl- (C₁₋₄ alkoxy), heterocyclyl- (Cilt alkylthio), NH (C₁₋₈ alkyl ), N (C₁₋₈ alkyl) ₂, (C₁₋₄ alkyl) carbonyl, (C₃₋₈ cycloalkyl) carbonyl, (C₂₋₈ alkenyl) carbonyl, (C₂ alkynyl ₋₈) carbonyl, where alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, alkenyloxy, alkynyloxy and cycloalkoxy are optionally substituted with halogen, and where aryl and heterocyclyl are optionally substituted with one or more R¹⁶; or R¹⁴ is C = NOR¹¹; each R¹⁵ is independently hydrogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₃₋₆ cycloalkyl, C₁₋₄ alkylsulfonyl, where alkyl, cycloalkyl and alkylsulfonyl are optionally substituted with halogen; and each R¹⁶ is independently halogen, cyano, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy or C₁₋₄ haloalkoxy; or one of its salts or N-oxides.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12192391 | 2012-11-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR093431A1 true AR093431A1 (en) | 2015-06-10 |
Family
ID=47146284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP130104128A AR093431A1 (en) | 2012-11-13 | 2013-11-11 | MICRABIOCIDES PIRAZOL DERIVATIVES |
Country Status (4)
| Country | Link |
|---|---|
| AR (1) | AR093431A1 (en) |
| TW (1) | TW201427975A (en) |
| UY (1) | UY35133A (en) |
| WO (1) | WO2014075874A1 (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ629795A (en) | 2012-02-02 | 2016-06-24 | Actelion Pharmaceuticals Ltd | 4-(benzoimidazol-2-yl)-thiazole compounds and related aza derivatives |
| SG11201600504TA (en) | 2013-07-22 | 2016-02-26 | Actelion Pharmaceuticals Ltd | 1-(piperazin-1-yl)-2-([1,2,4]triazol-1-yl)-ethanone derivatives |
| AR099789A1 (en) | 2014-03-24 | 2016-08-17 | Actelion Pharmaceuticals Ltd | DERIVATIVES OF 8- (PIPERAZIN-1-IL) -1,2,3,4-TETRAHYDRO-ISOQUINOLINE |
| WO2016024350A1 (en) | 2014-08-13 | 2016-02-18 | 株式会社エス・ディー・エス バイオテック | Condensed 11-membered ring compounds and agricultural and horticultural fungicide containing same |
| JP6337218B2 (en) | 2015-01-15 | 2018-06-06 | イドーシア ファーマシューティカルズ リミテッドＩｄｏｒｓｉａ Ｐｈａｒｍａｃｅｕｔｉｃａｌｓ Ｌｔｄ | Hydroxyalkyl-piperazine derivatives as CXCR3 receptor modulators |
| AR103399A1 (en) | 2015-01-15 | 2017-05-10 | Actelion Pharmaceuticals Ltd | DERIVATIVES OF (R) -2-METHYL-PIPERAZINE AS CXCR3 RECEIVER MODULATORS |
| WO2016202761A1 (en) | 2015-06-17 | 2016-12-22 | Bayer Cropscience Aktiengesellschaft | Active compound combinations |
| JP6371915B2 (en) * | 2015-09-18 | 2018-08-08 | 株式会社エス・ディー・エス バイオテック | Process for producing 4- (4-formylthiazolyl) piperidine compound |
| CN108602765B (en) | 2016-02-08 | 2022-05-03 | 高文有限公司 | Method for producing 1, 2-benzenedimethanol compound |
| KR102605762B1 (en) | 2016-02-08 | 2023-11-27 | 고완 크롭 프로텍션 리미티드 | Bactericidal composition |
| TW201838974A (en) | 2017-04-19 | 2018-11-01 | 印度商Ｐｉ工業公司 | Heterocyclic compounds with microbicidal properties |
| WO2019048988A1 (en) | 2017-09-08 | 2019-03-14 | Pi Industries Ltd. | NOVEL FUNGICIDE HETEROCYCLIC COMPOUNDS |
| CA3073637A1 (en) | 2017-09-08 | 2019-03-14 | Pi Industries Ltd | Novel fungicidal heterocyclic compounds |
| CN118063453B (en) * | 2024-02-21 | 2025-02-07 | 南京吉星生物技术开发有限公司 | Benzimidazole derivatives, preparation methods and applications thereof, and agricultural fungicides |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008013622A2 (en) * | 2006-07-27 | 2008-01-31 | E. I. Du Pont De Nemours And Company | Fungicidal azocyclic amides |
| ES2531256T3 (en) * | 2007-01-25 | 2015-03-12 | Du Pont | Fungicidal amides |
-
2013
- 2013-10-21 WO PCT/EP2013/071985 patent/WO2014075874A1/en not_active Ceased
- 2013-11-11 TW TW102140853A patent/TW201427975A/en unknown
- 2013-11-11 AR ARP130104128A patent/AR093431A1/en unknown
- 2013-11-12 UY UY0001035133A patent/UY35133A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| TW201427975A (en) | 2014-07-16 |
| UY35133A (en) | 2014-06-30 |
| WO2014075874A1 (en) | 2014-05-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |