AR082485A1 - Un proceso de purga a base de acido tereftalico - Google Patents
Un proceso de purga a base de acido tereftalicoInfo
- Publication number
- AR082485A1 AR082485A1 ARP110103005A ARP110103005A AR082485A1 AR 082485 A1 AR082485 A1 AR 082485A1 AR P110103005 A ARP110103005 A AR P110103005A AR P110103005 A ARP110103005 A AR P110103005A AR 082485 A1 AR082485 A1 AR 082485A1
- Authority
- AR
- Argentina
- Prior art keywords
- flow
- purge
- water
- concentrated
- rich
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000002253 acid Substances 0.000 title 1
- 238000010926 purge Methods 0.000 abstract 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 8
- 239000000725 suspension Substances 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 4
- 238000001704 evaporation Methods 0.000 abstract 4
- 230000008020 evaporation Effects 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 238000000605 extraction Methods 0.000 abstract 3
- 239000012065 filter cake Substances 0.000 abstract 3
- 238000001914 filtration Methods 0.000 abstract 3
- 238000002156 mixing Methods 0.000 abstract 3
- 230000001590 oxidative effect Effects 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- 238000005406 washing Methods 0.000 abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000012452 mother liquor Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000007670 refining Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/50—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/14—Monocyclic dicarboxylic acids
- C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
- C07C63/24—1,3 - Benzenedicarboxylic acid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
El proceso se refiere a la forma de mejorar la velocidad de filtrado de purga de ácido tereftálico mediante el control del porcentaje de agua en la suspensión de alimentación del filtro y a la recuperación de un catalizador metálico de un flujo de purga oxidante que se produce en la síntesis de ácido carboxílico, típicamente ácido tereftálico, mientras se utiliza el filtrado a presión.Reivindicación 1: Un proceso de purga a base de ácido tereftálico que comprende: (a) someter un flujo de purga oxidante que se forma en un proceso a base de ácido tereftálico a la evaporación en una primera zona de evaporación para producir un primer flujo de vapor y un flujo de purga concentrado; donde dicho flujo de purga oxidante comprende un ácido carboxílico, un catalizador de metal, impurezas, agua y un solvente; donde dicho solvente comprende ácido acético; y (b) agregar agua a dicho flujo de purga concentrado en una primera zona de mezclado para producir un flujo de purga concentrado rico en agua; (c) someter dicho flujo de purga concentrado rico en agua a evaporación en una segunda zona de evaporación para producir un segundo flujo rico en vapor y un flujo de suspensión de purga concentrada; y (d) agregar agua a la suspensión de purga súper concentrada en una segunda zona de mezclado para producir una suspensión de purga súper concentrada rica en agua; (e) filtrar dicha suspensión de purga súper concentrada rica en agua en una zona de separación de sólidos y líquidos para formar una torta de filtro y el licor madre; (f) lavar dicha torta de filtro con un material de lavado en dicha zona de separación de sólidos y líquidos para formar una torta de filtro lavada, y el filtrado de lavado; (g) agregar agua a dicho licor madre en una tercera zona de mezclado para recuperar el catalizador de metal y, luego, someter una mezcla acuosa formada de esta manera a la extracción con un solvente de extracción para producir un flujo de extracción y un flujo refinado que comprende un catalizador de metal.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/860,135 US8167974B2 (en) | 2010-08-20 | 2010-08-20 | Terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR082485A1 true AR082485A1 (es) | 2012-12-12 |
Family
ID=45593006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP110103005A AR082485A1 (es) | 2010-08-20 | 2011-08-18 | Un proceso de purga a base de acido tereftalico |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US8167974B2 (es) |
| EP (1) | EP2606156B1 (es) |
| JP (1) | JP5973438B2 (es) |
| KR (1) | KR101943115B1 (es) |
| CN (1) | CN103168108B (es) |
| AR (1) | AR082485A1 (es) |
| BR (1) | BR112013003893B1 (es) |
| CA (1) | CA2808095C (es) |
| EA (1) | EA027339B1 (es) |
| ES (1) | ES2681655T3 (es) |
| LT (1) | LT2606156T (es) |
| MX (1) | MX2013001960A (es) |
| MY (1) | MY159964A (es) |
| PL (1) | PL2606156T3 (es) |
| PT (1) | PT2606156T (es) |
| TR (1) | TR201810739T4 (es) |
| TW (1) | TWI554330B (es) |
| UA (1) | UA113395C2 (es) |
| WO (1) | WO2012024167A1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8466312B2 (en) * | 2010-08-20 | 2013-06-18 | Grupo Petrotemex, S.A. De C.V. | Terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
| US20140175025A1 (en) * | 2012-12-21 | 2014-06-26 | Eastman Chemical Company | Generation of low-solids second mother liquor from terephthalic acid production filter |
| US9943834B2 (en) * | 2014-05-08 | 2018-04-17 | Eastman Chemical Company | Furan-2,5-dicarboxylic acid purge process |
| CN110092715A (zh) * | 2019-06-06 | 2019-08-06 | 恒力石化（大连）有限公司 | 一种回收pta残渣中的ba和催化剂的系统 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4939297A (en) * | 1989-06-05 | 1990-07-03 | Eastman Kodak Company | Extraction process for removal of impurities from terephthalic acid filtrate |
| US7196215B2 (en) * | 2001-06-04 | 2007-03-27 | Eastman Chemical Company | Process for the production of purified terephthalic acid |
| US6779456B2 (en) * | 2002-07-01 | 2004-08-24 | Special Devices, Inc. | Initiator with a bridgewire configured in an enhanced heat-sinking relationship |
| US7161027B2 (en) * | 2002-12-09 | 2007-01-09 | Eastman Chemical Company | Process for the oxidative purification of terephthalic acid |
| US7410632B2 (en) * | 2003-06-05 | 2008-08-12 | Eastman Chemical Company | Extraction process for removal of impurities from mother liquor in the synthesis of carboxylic acid |
| US7381386B2 (en) * | 2003-06-05 | 2008-06-03 | Eastman Chemical Company | Extraction process for removal of impurities from mother liquor in the synthesis of carboxylic acid |
| US7282151B2 (en) * | 2003-06-05 | 2007-10-16 | Eastman Chemical Company | Process for removal of impurities from mother liquor in the synthesis of carboxylic acid using pressure filtration |
| US20070203359A1 (en) * | 2006-03-01 | 2007-08-30 | Philip Edward Gibson | Versatile oxidation byproduct purge process |
| JP2010126455A (ja) * | 2008-11-26 | 2010-06-10 | Mitsubishi Chemicals Corp | 芳香族カルボン酸の製造方法 |
-
2010
- 2010-08-20 US US12/860,135 patent/US8167974B2/en active Active
-
2011
- 2011-08-12 ES ES11818589.1T patent/ES2681655T3/es active Active
- 2011-08-12 KR KR1020137006909A patent/KR101943115B1/ko active Active
- 2011-08-12 EP EP11818589.1A patent/EP2606156B1/en active Active
- 2011-08-12 PL PL11818589T patent/PL2606156T3/pl unknown
- 2011-08-12 LT LTEP11818589.1T patent/LT2606156T/lt unknown
- 2011-08-12 TR TR2018/10739T patent/TR201810739T4/tr unknown
- 2011-08-12 MY MYPI2013000523A patent/MY159964A/en unknown
- 2011-08-12 MX MX2013001960A patent/MX2013001960A/es active IP Right Grant
- 2011-08-12 BR BR112013003893-4A patent/BR112013003893B1/pt active IP Right Grant
- 2011-08-12 CN CN201180050626.8A patent/CN103168108B/zh active Active
- 2011-08-12 PT PT118185891T patent/PT2606156T/pt unknown
- 2011-08-12 WO PCT/US2011/047500 patent/WO2012024167A1/en not_active Ceased
- 2011-08-12 CA CA2808095A patent/CA2808095C/en active Active
- 2011-08-12 EA EA201390263A patent/EA027339B1/ru not_active IP Right Cessation
- 2011-08-12 JP JP2013524885A patent/JP5973438B2/ja active Active
- 2011-08-18 AR ARP110103005A patent/AR082485A1/es active IP Right Grant
- 2011-08-19 TW TW100129863A patent/TWI554330B/zh active
- 2011-12-08 UA UAA201303397A patent/UA113395C2/uk unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20120042752A1 (en) | 2012-02-23 |
| LT2606156T (lt) | 2018-08-10 |
| BR112013003893B1 (pt) | 2019-02-26 |
| EP2606156B1 (en) | 2018-07-04 |
| JP2013537550A (ja) | 2013-10-03 |
| TW201213012A (en) | 2012-04-01 |
| EA027339B1 (ru) | 2017-07-31 |
| EP2606156A4 (en) | 2014-03-19 |
| JP5973438B2 (ja) | 2016-08-23 |
| CA2808095A1 (en) | 2012-02-23 |
| WO2012024167A1 (en) | 2012-02-23 |
| EA201390263A1 (ru) | 2013-08-30 |
| PT2606156T (pt) | 2018-08-01 |
| KR20130090897A (ko) | 2013-08-14 |
| ES2681655T3 (es) | 2018-09-14 |
| US8167974B2 (en) | 2012-05-01 |
| UA113395C2 (xx) | 2017-01-25 |
| CA2808095C (en) | 2018-09-25 |
| TR201810739T4 (tr) | 2018-08-27 |
| CN103168108A (zh) | 2013-06-19 |
| TWI554330B (zh) | 2016-10-21 |
| MY159964A (en) | 2017-02-15 |
| EP2606156A1 (en) | 2013-06-26 |
| KR101943115B1 (ko) | 2019-01-28 |
| MX2013001960A (es) | 2013-05-09 |
| WO2012024167A8 (en) | 2013-03-21 |
| CN103168108B (zh) | 2016-06-01 |
| PL2606156T3 (pl) | 2018-11-30 |
| BR112013003893A2 (pt) | 2016-06-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |