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AR087830A1 - Derivados de isotiazolina como compuestos insecticidas - Google Patents

Derivados de isotiazolina como compuestos insecticidas

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Publication number
AR087830A1
AR087830A1 ARP120103336A AR087830A1 AR 087830 A1 AR087830 A1 AR 087830A1 AR P120103336 A ARP120103336 A AR P120103336A AR 087830 A1 AR087830 A1 AR 087830A1
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Argentina
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alkyl
substituted
haloalkyl
aryl
heterocyclyl
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English (en)
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Syngenta Participations Ag
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Application filed by Syngenta Participations Ag filed Critical Syngenta Participations Ag
Publication of AR087830A1 publication Critical patent/AR087830A1/es

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/22—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/56—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/22—Esters of monothiocarboxylic acids having carbon atoms of esterified thiocarboxyl groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/32—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D275/00—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings
    • C07D275/02—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D291/00—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms
    • C07D291/02—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms not condensed with other rings
    • C07D291/04—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D331/00—Heterocyclic compounds containing rings of less than five members, having one sulfur atom as the only ring hetero atom
    • C07D331/04—Four-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

La presente también proporciona composiciones que comprenden los compuestos de fórmula (1), intermediarios útiles en la preparación de los compuestos de fórmula (1) y métodos para usar los compuestos de fórmula (1) para controlar insectos, ácaros, nematodos y moluscos. Reivindicación 1: Un compuesto de fórmula (1) donde P es un resto de formula (2), heterociclilo o heterociclilo sustituido por uno a cinco Z; Y¹, Y², Y³ e Y⁴ son independientemente uno del otro C-H, C-R⁵, o nitrógeno; G¹ es oxígeno o azufre; R¹ es hidrógeno, alquilo C₁₋₈, alcoxi C₁₋₈-, alquil C₁₋₈carbonilo-, o alcoxi C₁₋₈carbonilo-; R² es alquilo C₁₋₈ o alquilo C₁₋₈ sustituido por uno a cinco R⁶, cicloalquilo C₃₋₁₀ o cicloalquilo C₃₋₁₀ sustituido por uno a cinco R⁷, aril-alquileno C₁₋₄- o aril-alquileno C₁₋₄- donde el grupo funcional arilo está sustituido por uno a cinco R⁸, heterociclil-alquileno C₁₋₄- o heterociclil-alquileno C₁₋₄- donde el grupo funcional heterociclilo está sustituido por uno a cinco R⁸, aril-N(R²⁰)- o aril-N(R²⁰)- donde el grupo funcional arilo está sustituido por uno a cinco R⁸, heterociclil-N(R²⁰)- o heterociclil-N(R²⁰)- donde el grupo funcional heterociclilo está sustituido por uno a cinco R⁸, arilo o arilo sustituido por uno a cinco R⁸, heterociclilo o heterociclilo sustituido por uno a cinco R⁸, alquil C₁₋₈aminocarbonil-alquileno C₁₋₄, haloalquil C₁₋₈aminocarbonil-alquileno C₁₋₄, cicloalquil C₃₋₈-aminocarbonil-alquileno C₁₋₄, alquil C₁₋₈aminocarbonilo-, haloalquil C₁₋₈aminocarbonilo, cicloalquil C₃₋₈-aminocarbonilo, alquil C₁₋₆-O-N=CH-, haloalquil C₁₋₆-O-N=CH-; o R¹ y R² juntos representan el grupo de fórmula (3); G² es O(R¹³), N(R¹⁴)(R¹⁵) o S(R¹⁶); G³ es N(R¹⁷)(R¹⁸) o S(R¹⁹); X⁴ es haloalquilo C₁₋₈; R⁴ es arilo o arilo sustituido por uno a cinco R⁹, o heteroarilo o heteroarilo sustituido por uno a cinco R⁹; cada R⁵ es independientemente halógeno, ciano, nitro, alquilo C₁₋₈, haloalquilo C₁₋₈, alquenilo C₁₋₈, haloalquenilo C₁₋₈, alquinilo C₁₋₈, haloalquinilo C₁₋₈, cicloalquilo C₃₋₁₀, alcoxi C₁₋₈-, haloalcoxi C₁₋₈-, alquil C₁₋₈tio-, haloalquil C₁₋₈tio-, alquil C₁₋₈sulfinilo-, haloalquil C₁₋₈sulfinilo-, alquil C₁₋₈sulfonilo-, o haloalquil C₁₋₈sulfonilo-; o dos R⁵ en átomos adyacentes de carbono forman juntos un puente -CH=CH-CH=CH-; cada R⁶ es independientemente halógeno, ciano, nitro, hidroxi, amino, alquil C₁₋₈amino, (alquil C₁₋₈)₂amino, alquil C₁₋₈carbonilamino, haloalquil C₁₋₈carbonilamino, alcoxi C₁₋₈-, haloalcoxi C₁₋₈-, ariloxi o ariloxi sustituido por uno a cinco R¹⁰, ariloxi-alquileno C₁₋₄ o ariloxi-alquileno C₁₋₄ donde el grupo funcional arilo está sustituido por uno a cinco R¹⁰, alquil C₁₋₈carbonilo-, alcoxi C₁₋₈carbonilo-, mercapto, alquil C₁₋₈tio-, haloalquil C₁₋₈tio-, alquil C₁₋₈sulfinilo-, haloalquil C₁₋₈sulfinilo-, alquil C₁₋₈sulfonilo-, haloalquil C₁₋₈sulfonilo-, aril-alquil C₁₋₄tio o aril-alquil C₁₋₄tio donde el grupo funcional arilo está sustituido por uno a cinco R¹⁰; cada R⁷ es independientemente halógeno, alquilo C₁₋₈, alquenilo C₁₋₈, alquinilo C₁₋₈, alquil C₁₋₈-O-N=, haloalquil C₁₋₈-O-N=; alcoxi C₁₋₈, alcoxicarbonil C₁₋₈; cada R⁸ es independientemente halógeno, ciano, nitro, oxo, alquilo C₁₋₈, haloalquilo C₁₋₈, cianoalquilo C₁₋₈, alquenilo C₂₋₈, haloalquenilo C₂₋₈, alquinilo C₂₋₈, haloalquinilo C₂₋₈, cicloalquilo C₃₋₁₀, cicloalquil C₃₋₁₀-alquileno C₁₋₄, hidroxi, alcoxi C₁₋₈-, haloalcoxi C₁₋₈-, mercapto, alquil C₁₋₈tio-, haloalquil C₁₋₈tio-, alquil C₁₋₈sulfinilo-, haloalquil C₁₋₈sulfinilo-, alquil C₁₋₈sulfonilo-, haloalquil C₁₋₈sulfonilo-, alquil C₁₋₈aminosulfonilo, (alquil C₁₋₈)₂aminosulfonilo-, alquil C₁₋₈carbonilo-, alcoxi C₁₋₈carbonilo-, arilo o arilo sustituido por uno a cinco R¹⁰, heterociclilo o heterociclilo sustituido por uno a cinco R¹⁰, aril-alquileno C₁₋₄ o aril-alquileno C₁₋₄ donde el grupo funcional arilo está sustituido por uno a cinco R¹⁰, heterociclil-alquileno C₁₋₄ o heterociclil-alquileno C₁₋₄ donde el grupo funcional heterociclilo está sustituido por uno a cinco R¹⁰, ariloxi o ariloxi sustituido por uno a cinco R¹⁰, ariloxi-alquileno C₁₋₄ o ariloxi-alquileno C₁₋₄ donde el grupo funcional arilo está sustituido por uno a cinco R¹⁰; cada R⁹ es independientemente halógeno, ciano, nitro, alquilo C₁₋₈, haloalquilo C₁₋₈, alquenilo C₂₋₈, haloalquenilo C₂₋₈, alquinilo C₂₋₈, haloalquinilo C₂₋₈, hidroxi, alcoxi C₁₋₈-, haloalcoxi C₁₋₈-, mercapto, alquil C₁₋₈tio-, haloalquil C₁₋₈tio-, alquil C₁₋₈sulfinilo-, haloalquil C₁₋₈sulfinilo-, alquil C₁₋₈sulfonilo-, haloalquil C₁₋₈sulfonilo-, alquil C₁₋₈carbonilo-, alcoxi C₁₋₈carbonilo-, arilo o arilo sustituido por uno a cinco R¹⁰, o heterociclilo o heterociclilo sustituido por uno a cinco R¹⁰; cada R¹⁰ es independientemente halógeno, ciano, nitro, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄-, o haloalcoxi C₁₋₄-; cada Z es independientemente halógeno, alquilo C₁₋₁₂ o alquilo C₁₋₁₂ sustituido por uno a cinco R⁶, nitro, alcoxi C₁₋₁₂ o alcoxi C₁₋₁₂ sustituido por uno a cinco R⁶, ciano, alquil C₁₋₁₂sulfinilo, alquil C₁₋₁₂sulfonilo, haloalquil C₁₋₁₂sulfinilo, haloalquil C₁₋₁₂sulfonilo, hidroxilo o tiol; R¹³, R¹⁶ y R¹⁹ son independientemente alquilo C₁₋₄; R¹⁴, R¹⁵, R¹⁷, y R¹⁸ son independientemente hidrógeno o alquilo C₁₋₄; R²⁰ es hidrógeno o alquilo C₁₋₄; o una sal u N-óxido de estos.
ARP120103336 2011-09-13 2012-09-11 Derivados de isotiazolina como compuestos insecticidas AR087830A1 (es)

Applications Claiming Priority (2)

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EP11181057 2011-09-13
EP12175166 2012-07-05

Publications (1)

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AR087830A1 true AR087830A1 (es) 2014-04-23

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ID=46727234

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Country Status (7)

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US (1) US9078444B2 (es)
EP (2) EP2755969B1 (es)
CN (1) CN103842358A (es)
AR (1) AR087830A1 (es)
BR (2) BR122018069466B1 (es)
UY (1) UY34318A (es)
WO (1) WO2013037626A1 (es)

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EP2755969B1 (en) 2017-01-18
BR112014005683B1 (pt) 2018-12-04
EP3190110B1 (en) 2020-01-08
BR122018069466B1 (pt) 2019-04-02
BR112014005683A2 (pt) 2017-03-28
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CN103842358A (zh) 2014-06-04
US20140378415A1 (en) 2014-12-25

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