AR087461A1 - Uso de un catalizador que comprende una zeolita modificada con fosforo en un proceso de deshidratacion de alcohol - Google Patents
Uso de un catalizador que comprende una zeolita modificada con fosforo en un proceso de deshidratacion de alcoholInfo
- Publication number
- AR087461A1 AR087461A1 ARP120102856A ARP120102856A AR087461A1 AR 087461 A1 AR087461 A1 AR 087461A1 AR P120102856 A ARP120102856 A AR P120102856A AR P120102856 A ARP120102856 A AR P120102856A AR 087461 A1 AR087461 A1 AR 087461A1
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst
- optionally
- zeolite
- phosphorus
- vaporization
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 230000018044 dehydration Effects 0.000 title abstract 2
- 238000006297 dehydration reaction Methods 0.000 title abstract 2
- 230000008016 vaporization Effects 0.000 abstract 6
- 229910052698 phosphorus Inorganic materials 0.000 abstract 4
- 239000011574 phosphorus Substances 0.000 abstract 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 3
- 238000009834 vaporization Methods 0.000 abstract 3
- 239000010457 zeolite Substances 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000005229 chemical vapour deposition Methods 0.000 abstract 1
- 238000011067 equilibration Methods 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- -1 phosphorus modified zeolite Chemical class 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/28—Phosphorising
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente se refiere, en una primera realización, al uso de un catalizador para convertir al menos un alcohol en olefinas livianas en un proceso de deshidratación para producir una olefina que tiene el mismo número de átomos de carbono que el alcohol, en el que dicho catalizador comprende una zeolita modificada con fósforo y es realizada por medio de un procedimiento que comprende las siguientes etapas en este orden, a) proveer una zeolita que comprende al menos un anillo de diez miembros en la estructura, opcionalmente vaporizar dicha zeolita, b) mezclar dicha zeolita de la etapa a) con al menos un componente seleccionado entre uno o más ligantes y aditivos de conformación, después conformar dicha mezcla, c) opcionalmente realizar un intercambio iónico, d) opcionalmente vaporizar el catalizar conformado, de modo opcional antes de la etapa c), siendo al menos una entre dicha vaporización de la etapa d) y la vaporización de la etapa a) obligatoria, e) introducir fósforo en el catalizador para introducir al menos 0,1% en peso de fósforo, realizándose dicha introducción mediante impregnación seca o deposición química al vapor, f) opcionalmente introducir un metal, opcionalmente en forma simultánea con la etapa e), g) opcionalmente lavar el catalizador, h) opcionalmente calcinar el catalizador, i) vaporizar el catalizador, que también se denomina como etapa de equilibrado. En una segunda realización puede introducirse el fósforo por cualesquier medio y en la etapa i) la severidad de vaporización (X) es al menos aproximadamente 2. En dicha segunda realización, el catalizador ventajosamente es vaporizado a una temperatura superior a 625ºC, preferentemente en el intervalo 700 a 800ºC. El metal de la etapa f) es ventajosamente calcio.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11290360 | 2011-08-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR087461A1 true AR087461A1 (es) | 2014-03-26 |
Family
ID=46579032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP120102856A AR087461A1 (es) | 2011-08-03 | 2012-08-03 | Uso de un catalizador que comprende una zeolita modificada con fosforo en un proceso de deshidratacion de alcohol |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9862653B2 (es) |
| EP (1) | EP2739390B1 (es) |
| KR (1) | KR101948358B1 (es) |
| CN (1) | CN103842079B (es) |
| AR (1) | AR087461A1 (es) |
| BR (1) | BR112014002420B1 (es) |
| CA (1) | CA2842386A1 (es) |
| DK (1) | DK2739390T3 (es) |
| EA (1) | EA028628B1 (es) |
| ES (1) | ES2868140T3 (es) |
| PL (1) | PL2739390T3 (es) |
| TW (1) | TW201318702A (es) |
| UA (1) | UA112781C2 (es) |
| WO (1) | WO2013017496A1 (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112014002583B1 (pt) * | 2011-08-03 | 2020-11-10 | Total Research & Technology Feluy | catalisador compreendendo uma zeólita modificada por fósforo, com uma estrutura parcialmente alpo |
| EA028645B1 (ru) * | 2011-08-03 | 2017-12-29 | Тотал Ресерч & Технолоджи Фелай | Способ приготовления катализатора на основе модифицированного фосфором цеолита и применение такого цеолита |
| BR112016014313A8 (pt) * | 2013-12-20 | 2020-06-02 | Basf Se | catalisadores para a conversão de oxigenados em olefinas, processo para preparar um catalisador, processo para converter oxigenados em olefinas e uso de um catalisador |
| US10472300B2 (en) | 2014-12-31 | 2019-11-12 | Total Research & Technology Feluy | Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of sulfur containing compounds |
| US10544067B2 (en) | 2014-12-31 | 2020-01-28 | Total Research & Technology Feluy | Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of organic acids |
| US10894750B2 (en) | 2015-02-23 | 2021-01-19 | Versalis S.P.A. | Process for the dehydration of oxygenated compounds |
| CN106146235B (zh) * | 2015-05-15 | 2019-06-18 | 内蒙古丰汇化工有限公司 | 由甲醇一步法制备烃类产品的方法 |
| WO2018004993A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Reduction of greenhouse gas emission |
| WO2018004994A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Fluidized bed membrane reactor |
| WO2018004992A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Conversion of methane to dimethyl ether |
| EP3555033A1 (en) * | 2016-12-14 | 2019-10-23 | ExxonMobil Research and Engineering Company | Production of high octane hydrocarbon from isobutane via tert-butanol |
| IT201700074911A1 (it) | 2017-07-04 | 2019-01-04 | Versalis Spa | Procedimento per la produzione di olefine da alcoli |
| JP2021511200A (ja) * | 2018-01-12 | 2021-05-06 | アルベマール コーポレーション | １を超えるシリカ材料が関与するプロセスによって調製されるｆｃｃ触媒 |
| CN108636448A (zh) * | 2018-04-18 | 2018-10-12 | 佛山市飞程信息技术有限公司 | 一种用于乙醇脱水制乙烯的催化剂 |
| IT201900015069A1 (it) | 2019-08-27 | 2021-02-27 | Versalis Spa | Catalizzatore comprendente coke e procedimento per la produzione di dieni. |
| CN114405538B (zh) * | 2022-01-27 | 2023-03-21 | 吉林大学 | 一种多级孔Fe/ZSM-5分子筛及其制备方法和应用 |
| FR3144023A1 (fr) | 2022-12-22 | 2024-06-28 | IFP Energies Nouvelles | Catalyseur a base d’une zeolithe et d’une structure alpo et presentant un volume macroporeux eleve |
| FR3151854A1 (fr) | 2023-07-31 | 2025-02-07 | Totalenergies Onetech | Procédé de fabrication d’un carburéacteur à partir de biomasse présentant une économie d’atome optimisée |
| CN118217961B (zh) * | 2024-03-21 | 2025-10-21 | 福州大学 | 一种高稳定性用于高碳伯醇脱水制α-烯烃的催化剂及其制备方法和应用 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3274124A (en) | 1964-01-02 | 1966-09-20 | Universal Oil Prod Co | Process of preparing a silica-alumina supported group viii metal hydrocracking catalyst |
| US3909450A (en) | 1973-12-26 | 1975-09-30 | Universal Oil Prod Co | Method of catalyst manufacture |
| US3972832A (en) | 1974-09-23 | 1976-08-03 | Mobil Oil Corporation | Phosphorus-containing zeolite catalyst |
| US4356338A (en) * | 1979-07-27 | 1982-10-26 | Mobil Oil Corporation | Extending catalyst life by treating with phosphorus and/or steam |
| US4318801A (en) * | 1979-09-04 | 1982-03-09 | Gulf Research & Development Company | Supported nickel-molybdenum catalyst, preparation thereof, and hydrodesulfurization of hydrocarbon fractions using same |
| US4988659A (en) | 1988-11-23 | 1991-01-29 | Chevron Research Company | Silica/alumina cogel catalysts |
| US5231064A (en) | 1991-03-12 | 1993-07-27 | Mobil Oil Corp. | Cracking catalysts comprising phosphorus and method of preparing and using the same |
| US5171921A (en) | 1991-04-26 | 1992-12-15 | Arco Chemical Technology, L.P. | Production of olefins |
| EP0568913A3 (en) | 1992-05-03 | 1995-03-22 | Dalian Chemical Physics Inst | Process for the conversion of methanol to light olefins and catalysts used therefor. |
| US6423879B1 (en) * | 1997-10-02 | 2002-07-23 | Exxonmobil Oil Corporation | Selective para-xylene production by toluene methylation |
| EP1117750B1 (en) * | 1998-09-28 | 2004-06-30 | BP Corporation North America Inc. | Process for manufacturing olefins using a pentasil zeolite based catalyst |
| US6797851B2 (en) | 2001-08-30 | 2004-09-28 | Exxonmobil Chemical Patents Inc. | Two catalyst process for making olefin |
| US7408092B2 (en) | 2004-11-12 | 2008-08-05 | Uop Llc | Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst |
| US20110098519A1 (en) | 2007-08-13 | 2011-04-28 | Kanaparthi Ramesh | Modified catalyst composition for conversion of alcohol to alkene |
| EP2082802A1 (en) | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining a catalyst composite |
| CN103274884A (zh) | 2008-02-07 | 2013-09-04 | 道达尔石油化学产品研究弗吕公司 | 由乙醇制造烯烃的方法 |
| US20110105815A1 (en) | 2008-02-07 | 2011-05-05 | Total Petrochemicals Research Feluy | Process to Make Olefins from Ethanol |
| JP5497667B2 (ja) * | 2008-02-07 | 2014-05-21 | トタル リサーチ アンド テクノロジー フエリユイ | 結晶性シリケート上でのアルコールの脱水 |
| KR101217984B1 (ko) | 2008-02-07 | 2013-01-02 | 토탈 리서치 앤드 테크놀로지 펠루이 | 비활성 성분의 존재 하에서의 알코올의 탈수 |
| EP2348004A1 (en) * | 2010-01-25 | 2011-07-27 | Total Petrochemicals Research Feluy | Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process |
| BR112014002583B1 (pt) * | 2011-08-03 | 2020-11-10 | Total Research & Technology Feluy | catalisador compreendendo uma zeólita modificada por fósforo, com uma estrutura parcialmente alpo |
| EA028645B1 (ru) * | 2011-08-03 | 2017-12-29 | Тотал Ресерч & Технолоджи Фелай | Способ приготовления катализатора на основе модифицированного фосфором цеолита и применение такого цеолита |
-
2012
- 2012-07-25 CA CA2842386A patent/CA2842386A1/en not_active Abandoned
- 2012-07-25 BR BR112014002420-0A patent/BR112014002420B1/pt active IP Right Grant
- 2012-07-25 WO PCT/EP2012/064579 patent/WO2013017496A1/en not_active Ceased
- 2012-07-25 KR KR1020147002726A patent/KR101948358B1/ko active Active
- 2012-07-25 CN CN201280048602.3A patent/CN103842079B/zh active Active
- 2012-07-25 ES ES12738463T patent/ES2868140T3/es active Active
- 2012-07-25 DK DK12738463.4T patent/DK2739390T3/da active
- 2012-07-25 EA EA201490359A patent/EA028628B1/ru not_active IP Right Cessation
- 2012-07-25 EP EP12738463.4A patent/EP2739390B1/en active Active
- 2012-07-25 PL PL12738463T patent/PL2739390T3/pl unknown
- 2012-07-25 US US14/236,726 patent/US9862653B2/en active Active
- 2012-07-25 UA UAA201402014A patent/UA112781C2/uk unknown
- 2012-08-03 AR ARP120102856A patent/AR087461A1/es not_active Application Discontinuation
- 2012-08-03 TW TW101127921A patent/TW201318702A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2739390B1 (en) | 2021-03-10 |
| EA028628B1 (ru) | 2017-12-29 |
| DK2739390T3 (da) | 2021-03-29 |
| US9862653B2 (en) | 2018-01-09 |
| BR112014002420A2 (pt) | 2017-10-31 |
| WO2013017496A1 (en) | 2013-02-07 |
| UA112781C2 (uk) | 2016-10-25 |
| CN103842079A (zh) | 2014-06-04 |
| KR20140046456A (ko) | 2014-04-18 |
| US20140243570A1 (en) | 2014-08-28 |
| KR101948358B1 (ko) | 2019-02-14 |
| BR112014002420B1 (pt) | 2024-01-09 |
| CN103842079B (zh) | 2016-12-28 |
| EA201490359A1 (ru) | 2014-08-29 |
| PL2739390T3 (pl) | 2021-10-11 |
| TW201318702A (zh) | 2013-05-16 |
| ES2868140T3 (es) | 2021-10-21 |
| EP2739390A1 (en) | 2014-06-11 |
| CA2842386A1 (en) | 2013-02-07 |
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