AR086883A1 - Agentes estructurantes y emulsionantes para formulaciones agricolas basadas en aceite - Google Patents
Agentes estructurantes y emulsionantes para formulaciones agricolas basadas en aceiteInfo
- Publication number
- AR086883A1 AR086883A1 ARP120102048A ARP120102048A AR086883A1 AR 086883 A1 AR086883 A1 AR 086883A1 AR P120102048 A ARP120102048 A AR P120102048A AR P120102048 A ARP120102048 A AR P120102048A AR 086883 A1 AR086883 A1 AR 086883A1
- Authority
- AR
- Argentina
- Prior art keywords
- oil
- condensate
- active ingredient
- surfactant
- fatty acid
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 9
- 239000004094 surface-active agent Substances 0.000 abstract 8
- 239000004480 active ingredient Substances 0.000 abstract 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 6
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 6
- 229930195729 fatty acid Natural products 0.000 abstract 6
- 239000000194 fatty acid Substances 0.000 abstract 6
- 150000004665 fatty acids Chemical class 0.000 abstract 6
- 238000009472 formulation Methods 0.000 abstract 6
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 5
- 239000000725 suspension Substances 0.000 abstract 5
- 229920001577 copolymer Polymers 0.000 abstract 4
- 239000005802 Mancozeb Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000009833 condensation Methods 0.000 abstract 2
- 230000005494 condensation Effects 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 abstract 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 abstract 1
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000005745 Captan Substances 0.000 abstract 1
- 239000005510 Diuron Substances 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 abstract 1
- 229940117949 captan Drugs 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920001521 polyalkylene glycol ether Polymers 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 238000004062 sedimentation Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/32—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/664—Polyesters containing oxygen in the form of ether groups derived from hydroxy carboxylic acids
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Reivindicación 1: Una formulación agrícola en suspensión en base de aceite que comprende un ingrediente activo suspendido en forma finamente dividida en un aceite; y al menos un tensioactivo seleccionado entre un condensado de polialquilenglicol-ácido graso o un condensado de éter de polialquilenglicol-ácido graso formado a partir de una reacción entre un compuesto de estructura de fórmula (1) y un compuesto de estructura de fórmula (2), donde: R1 = H o un radical de alquilo C1-30; A y B son grupos etileno o propileno en forma sucesiva o aleatoria; n = 0 ó > 1; y m = 0 ó > 1, y donde: n + m > 34; R2 = radical de alquileno o alquilo C8-30 (ramificado o lineal); y x = > 1.Reivindicación 2: Una formulación agrícola en suspensión en base de aceite de acuerdo con la reivindicaciones 1, donde el tensioactivo comprende un condensado dibloque de polietilenglicol que presenta un peso molecular mayor que 1.500 unidades de masa atómica y un copolímero de ácido polihidroxiesteárico con un rango de condensación mayor que 2 unidades. Reivindicación 3: Una formulación agrícola en suspensión en base de aceite de acuerdo con la reivindicación 1, donde el tensioactivo comprende al menos un condensado monobloque de un condensado de éter de polialquilenglicol-ácido graso, donde el éter de polialquilenglicol es un butiléter de copolímero de óxido de etileno-óxido de propileno que presenta un peso molecular mayor que 1.800 unidades de masa atómica y el condensado de ácido graso es un copolímero de ácido polihidroxiesteárico con un rango de condensación mayor que 2 unidades. Reivindicación 6: Una formulación agrícola en suspensión en base de aceite de acuerdo con la reivindicación 1, donde el ingrediente activo se selecciona entre Mancozeb, Diuron, Atrazine y Captan, o sus mezclas. Reivindicación 7: Una formulación agrícola en suspensión en base de aceite de acuerdo con la reivindicación 6, donde el ingrediente activo es Mancozeb. Reivindicación 16: Un método para la preparación de una formulación OD que comprende un ingrediente activo que comprende, a su vez, los siguientes pasos: a) preparación de una premezcla de solución de tensioactivos mediante la combinación de al menos un tensioactivo seleccionado entre un condensado de polialquilenglicol-ácido graso o un condensado de éter de polialquilenglicol-ácido graso de la presente con un tensioactivo y un aceite para dar un líquido; b) dispersión del ingrediente activo en la solución de tensioactivo mediante la agitación o bien, una mezcla de alto corte; c) trituración de la dispersión del ingrediente activo para lograr un tamaño de partícula promedio comprendido entre 1 y 12 mm; d) agregado de agentes emulsionantes tensioactivos; y e) ajuste opcional de la concentración final del contenido de ingrediente activo mediante el agregado adicional de aceite y otros ingredientes requeridos, donde los pasos a) a d) se llevan a cabo en cualquier orden. Reivindicación 17: El método de acuerdo con la reivindicación 16, donde el paso (e) incluye el agregado de un copolímero tipo goma como agente anti-sedimentación adicional.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2011902300A AU2011902300A0 (en) | 2011-06-10 | Structuring agents and emulsifiers for agricultural oil-based formulations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR086883A1 true AR086883A1 (es) | 2014-01-29 |
Family
ID=47295274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP120102048A AR086883A1 (es) | 2011-06-10 | 2012-06-08 | Agentes estructurantes y emulsionantes para formulaciones agricolas basadas en aceite |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20140206542A1 (es) |
| EP (1) | EP2717686B1 (es) |
| JP (1) | JP5969600B2 (es) |
| CN (1) | CN103501602B (es) |
| AR (1) | AR086883A1 (es) |
| AU (1) | AU2012267213B2 (es) |
| BR (1) | BR112013028190B1 (es) |
| CA (1) | CA2834202C (es) |
| ES (1) | ES2825823T3 (es) |
| MX (1) | MX2013012613A (es) |
| WO (1) | WO2012167322A1 (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2839744A1 (en) | 2013-08-23 | 2015-02-25 | Fine Agrochemicals Limited | Growth regulator concentrate and use thereof |
| CN104860941B (zh) * | 2014-02-25 | 2017-03-22 | 上海海雁医药科技有限公司 | 2,4‑二取代苯‑1,5‑二胺衍生物及其应用以及由其制备的药物组合物和药用组合物 |
| US10723930B2 (en) | 2015-08-28 | 2020-07-28 | Exxonmobil Chemical Patents Inc. | Viscoelastic fluid compositions, oil flowable/oil dispersion compositions, and drilling fluid compositions |
| BR102017010745A2 (pt) | 2016-05-24 | 2018-02-27 | Adama Makhteshim Ltd. | Formulação líquida de óleo fungicida, suspoemulsão fungicida e uso da formulação líquida de óleo fungicida |
| US12004509B2 (en) * | 2016-11-18 | 2024-06-11 | Indorama Ventures Oxides Australia Pty Limited | Co-formulation comprising a plant growth regulator and an oil, and methods of preparing and using said co-formulation |
| CA3017030A1 (en) * | 2016-11-18 | 2018-05-24 | Huntsman Corporation Australia Pty Limited | Co-formulation comprising a plant growth regulator and an oil, and methods of preparing and using said co-formulation |
| GB201621396D0 (en) * | 2016-12-15 | 2017-02-01 | Syngenta Participations Ag | Adjuvants |
| AU2017385510B2 (en) | 2016-12-29 | 2020-12-03 | Akzo Nobel Chemicals International B.V. | Thickened organic liquid compositions with polymeric rheology modifiers |
| US11162053B2 (en) | 2017-06-09 | 2021-11-02 | Ecolab Usa Inc. | Nonylphenol ethoxylate-free oil dispersant formulation |
| ES2963675T3 (es) | 2018-07-11 | 2024-04-01 | Fine Agrochemicals Ltd | Concentrado regulador del crecimiento de plantas y uso del mismo |
| IT201800010481A1 (it) | 2018-11-23 | 2020-05-23 | Lamberti Spa | Dispersioni in olio di ditiocarbammati |
| CN114176092A (zh) * | 2021-12-28 | 2022-03-15 | 利民化学有限责任公司 | 一种含有代森锰锌和丙硫菌唑的纳米油悬浮剂及其制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1469531A (en) * | 1973-06-25 | 1977-04-06 | Ici Ltd | Carboxylic acid-alkylene oxide adducts |
| AU7031674A (en) * | 1973-06-25 | 1976-01-08 | Ici Ltd | Novel compounds |
| DE2862369D1 (en) * | 1977-07-12 | 1984-03-08 | Ici Plc | Linear or branched ester-ether block copolymers and their use as surfactants either alone or in blends with conventional surfactants |
| GB2002400B (en) * | 1977-07-12 | 1982-01-20 | Ici Ltd | Block or graft copolymers and their use as surfactants |
| US5185395A (en) * | 1991-03-27 | 1993-02-09 | Exxon Chemical Patents Inc. | AMPS copolymer emulsions with improved stability |
| DE4442966A1 (de) * | 1994-12-02 | 1996-06-05 | Henkel Kgaa | Wasser-in-Öl-Emulsionen |
| ES2202744T3 (es) * | 1997-04-30 | 2004-04-01 | Rohm And Haas Company | Dispersiones estables de pesticida. |
| JP4259638B2 (ja) * | 1998-03-09 | 2009-04-30 | 日本曹達株式会社 | 懸濁状農薬組成物及びその製造方法 |
| WO2001087064A1 (en) * | 2000-05-15 | 2001-11-22 | Imperial Chemical Industries Plc | Agrochemical spray treatment and spray formulations |
| AU2002253085B2 (en) * | 2001-02-28 | 2006-03-09 | Intervet International B.V. | Injectable water-in-oil emulsions |
| DE10129855A1 (de) * | 2001-06-21 | 2003-01-02 | Bayer Ag | Suspensionskonzentrate auf Ölbasis |
| GB0610001D0 (en) * | 2006-05-19 | 2006-06-28 | Ici Plc | Structured Agrochemical Oil Based Systems |
| GB0709710D0 (en) * | 2007-05-21 | 2007-06-27 | Syngenta Ltd | Herbicidal compositions |
| ES2323399B2 (es) * | 2007-06-19 | 2010-02-26 | Gat Microencapsulation Ag | Suspensiones en aceites de sulfonilureas y combinaciones agroquimicas. |
| US20090062127A1 (en) * | 2007-08-30 | 2009-03-05 | Dow Agrosciences Llc | Stable emulsion formulation hindering interaction across the water-oil interface |
| US20110086760A1 (en) * | 2008-05-28 | 2011-04-14 | Victor Casana Giner | Suspension concentrates in oil of sulfonylureas and combinations with fluroxypyr or other agrochemicals |
| EP2225940B1 (en) * | 2009-03-05 | 2014-03-12 | GAT Microencapsulation GmbH | Oil dispersions of nAChR binding neonicotinoids |
| ES2656156T3 (es) * | 2010-04-26 | 2018-02-23 | Dow Agrosciences, Llc | Dispersiones en aceite agrícolas estabilizadas |
-
2012
- 2012-06-08 CN CN201280021421.1A patent/CN103501602B/zh not_active Expired - Fee Related
- 2012-06-08 CA CA2834202A patent/CA2834202C/en not_active Expired - Fee Related
- 2012-06-08 WO PCT/AU2012/000662 patent/WO2012167322A1/en not_active Ceased
- 2012-06-08 AR ARP120102048A patent/AR086883A1/es active IP Right Grant
- 2012-06-08 AU AU2012267213A patent/AU2012267213B2/en not_active Ceased
- 2012-06-08 EP EP12796939.2A patent/EP2717686B1/en not_active Not-in-force
- 2012-06-08 ES ES12796939T patent/ES2825823T3/es active Active
- 2012-06-08 MX MX2013012613A patent/MX2013012613A/es unknown
- 2012-06-08 JP JP2014513863A patent/JP5969600B2/ja not_active Expired - Fee Related
- 2012-06-08 BR BR112013028190-1A patent/BR112013028190B1/pt not_active IP Right Cessation
- 2012-06-08 US US14/115,362 patent/US20140206542A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CA2834202A1 (en) | 2012-12-13 |
| WO2012167322A1 (en) | 2012-12-13 |
| BR112013028190B1 (pt) | 2019-06-25 |
| US20140206542A1 (en) | 2014-07-24 |
| ES2825823T3 (es) | 2021-05-17 |
| AU2012267213B2 (en) | 2015-08-27 |
| MX2013012613A (es) | 2014-01-31 |
| EP2717686A1 (en) | 2014-04-16 |
| CN103501602B (zh) | 2016-08-17 |
| CA2834202C (en) | 2019-01-15 |
| CN103501602A (zh) | 2014-01-08 |
| JP5969600B2 (ja) | 2016-08-17 |
| EP2717686A4 (en) | 2014-11-26 |
| BR112013028190A2 (pt) | 2016-08-16 |
| JP2014516056A (ja) | 2014-07-07 |
| AU2012267213A1 (en) | 2013-10-31 |
| EP2717686B1 (en) | 2020-09-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |