AR071051A1 - Metodo y aparato para producir acido acetico con productividad mejorada - Google Patents
Metodo y aparato para producir acido acetico con productividad mejoradaInfo
- Publication number
- AR071051A1 AR071051A1 ARP080104444A ARP080104444A AR071051A1 AR 071051 A1 AR071051 A1 AR 071051A1 AR P080104444 A ARP080104444 A AR P080104444A AR P080104444 A ARP080104444 A AR P080104444A AR 071051 A1 AR071051 A1 AR 071051A1
- Authority
- AR
- Argentina
- Prior art keywords
- stream
- acetic acid
- column
- product stream
- liquid waste
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 18
- 238000000034 method Methods 0.000 title abstract 2
- 239000000047 product Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000010808 liquid waste Substances 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 239000012043 crude product Substances 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- WVKOKNQPFFEMSR-UHFFFAOYSA-N 2-hydroxyethenone Chemical compound OC=C=O WVKOKNQPFFEMSR-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012264 purified product Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Una aparato y método mejorados para producir ácido acético que incluyen recuperar producto del residuo de una columna de fracciones volátiles y alimentar el ácido de modo de así recuperado a fin de aumentar la productividad del sistema. La carga en la columna de fracciones volátiles es reducida y la carga en una columna deshidratante puede también reducirse en una realizacion preferida en donde el ácido recuperado es alimentado en forma continua sin otra eliminacion de agua. Reivindicacion 1: Un procedimiento de carbonilacion para producir ácido acético que comprende: (a) carbonilar metanol o sus derivados reactivos en presencia de agua, un catalizador seleccionado entre catalizadores de rodio, catalizadores de iridio y mezclas de los mismos, y un promotor de ioduro metilo para formar una mezcla de reaccion de ácido acético en un reactor; (b) separar la corriente de la mezcla de reaccion de ácido acético dentro de una corriente de reciclado de líquido y una primera corriente de producto crudo; (c) alimentar la corriente de primer producto crudo a una columna de fracciones volátiles; (d) destilar la corriente de producto crudo para eliminar los componentes de bajo punto de ebullicion y generar un corriente de primer producto purificado y una corriente de residuo líquido, en donde la corriente de residuo líquido consiste predominantemente de ácido acético; (e) vaporizar por lo menos una porcion de la corriente de residuo líquido para, proveer una corriente de segundo producto; y (f) alimentar la segunda corriente de producto en forma continua.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/974,106 US7902397B2 (en) | 2007-10-11 | 2007-10-11 | Method and apparatus for making acetic acid with improved productivity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR071051A1 true AR071051A1 (es) | 2010-05-26 |
Family
ID=40248051
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP080104444A AR071051A1 (es) | 2007-10-11 | 2008-10-10 | Metodo y aparato para producir acido acetico con productividad mejorada |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US7902397B2 (es) |
| EP (1) | EP2220022B1 (es) |
| JP (1) | JP5416126B2 (es) |
| KR (1) | KR101574359B1 (es) |
| CN (1) | CN101855194B (es) |
| AR (1) | AR071051A1 (es) |
| AU (1) | AU2008311337B2 (es) |
| BR (1) | BRPI0818045A2 (es) |
| CA (1) | CA2702069A1 (es) |
| CL (1) | CL2008002993A1 (es) |
| ES (1) | ES2552394T3 (es) |
| MX (1) | MX2010003945A (es) |
| MY (2) | MY165745A (es) |
| NZ (1) | NZ584548A (es) |
| RU (1) | RU2470909C2 (es) |
| TW (1) | TW200920734A (es) |
| UA (1) | UA97859C2 (es) |
| WO (1) | WO2009048509A1 (es) |
| ZA (1) | ZA201002509B (es) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2252871T3 (es) | 1997-11-07 | 2006-05-16 | Acist Medical Systems, Inc. | Sistema inyector angiografico con procesador multiple de fluidos. |
| US8575403B2 (en) | 2010-05-07 | 2013-11-05 | Celanese International Corporation | Hydrolysis of ethyl acetate in ethanol separation process |
| US8680342B2 (en) | 2010-05-07 | 2014-03-25 | Celanese International Corporation | Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water |
| JP5837576B2 (ja) * | 2010-05-18 | 2015-12-24 | セラニーズ・インターナショナル・コーポレーション | 過マンガン酸塩還元性化合物を除去することによって酢酸流を精製する方法 |
| US8664454B2 (en) | 2010-07-09 | 2014-03-04 | Celanese International Corporation | Process for production of ethanol using a mixed feed using copper containing catalyst |
| US9024083B2 (en) | 2010-07-09 | 2015-05-05 | Celanese International Corporation | Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed |
| US9272970B2 (en) | 2010-07-09 | 2016-03-01 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
| WO2012148509A1 (en) | 2011-04-26 | 2012-11-01 | Celanese International Corporation | Process for producing ethanol using a stacked bed reactor |
| US8710279B2 (en) | 2010-07-09 | 2014-04-29 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
| US8637698B2 (en) * | 2010-11-19 | 2014-01-28 | Celanese International Corporation | Production of acetic acid with an increased production rate |
| CN102070434B (zh) * | 2010-12-31 | 2013-07-17 | 河南省华鼎高分子合成树脂有限公司 | 马来酰亚胺类化合物生产过程中产出废液的处理方法 |
| US8592635B2 (en) | 2011-04-26 | 2013-11-26 | Celanese International Corporation | Integrated ethanol production by extracting halides from acetic acid |
| US8754268B2 (en) | 2011-04-26 | 2014-06-17 | Celanese International Corporation | Process for removing water from alcohol mixtures |
| US9073816B2 (en) | 2011-04-26 | 2015-07-07 | Celanese International Corporation | Reducing ethyl acetate concentration in recycle streams for ethanol production processes |
| US8895786B2 (en) | 2011-08-03 | 2014-11-25 | Celanese International Corporation | Processes for increasing alcohol production |
| US8686201B2 (en) | 2011-11-09 | 2014-04-01 | Celanese International Corporation | Integrated acid and alcohol production process having flashing to recover acid production catalyst |
| WO2013070210A1 (en) * | 2011-11-09 | 2013-05-16 | Celanese International Corporation | Integrated carbonylation and hydrogenation process to obtain ethanol having flashing to recover acid production catalyst |
| US8614359B2 (en) | 2011-11-09 | 2013-12-24 | Celanese International Corporation | Integrated acid and alcohol production process |
| US8853469B2 (en) | 2012-11-20 | 2014-10-07 | Celanese International Corporation | Combined column for separating products of different hydrogenation reactors |
| US9340481B1 (en) * | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
| US9908835B2 (en) * | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3337619A (en) * | 1964-02-12 | 1967-08-22 | Monsanto Co | Production of acetic acid and recovery by plural stage distillation |
| US3791935A (en) * | 1971-11-10 | 1974-02-12 | Monsanto Co | Purification of carboxylic acids |
| US4039395A (en) * | 1975-08-11 | 1977-08-02 | Monsanto Company | Purification of acetic acid |
| US4008131A (en) * | 1975-12-11 | 1977-02-15 | Monsanto Company | Purification of acetic acid |
| CA1228867A (en) * | 1984-05-03 | 1987-11-03 | G. Paull Torrence | Methanol carbonylation process |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| GB9306409D0 (en) * | 1993-03-26 | 1993-05-19 | Bp Chem Int Ltd | Process |
| US5672743A (en) * | 1993-09-10 | 1997-09-30 | Bp Chemicals Limited | Process for the production of acetic acid |
| US5696284A (en) * | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| US5783731A (en) * | 1995-09-11 | 1998-07-21 | Hoechst Celanese Corporation | Removal of carbonyl impurities from a carbonylation process stream |
| US5831120A (en) * | 1996-11-19 | 1998-11-03 | Watson; Derrick John | Process for the production of acetic acid |
| GB9626317D0 (en) | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| GB9626324D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| GB9626428D0 (en) | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| GB9626429D0 (en) | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| GB9819606D0 (en) * | 1998-09-08 | 1998-11-04 | Bp Chem Int Ltd | Carbonylation process |
| FR2826960B1 (fr) | 2001-07-03 | 2005-10-21 | Acetex Chimie | Procede de controle d'une production d'acide acetique et/ou d'acetate de methyle en continu |
| JP4732743B2 (ja) * | 2004-12-06 | 2011-07-27 | ダイセル化学工業株式会社 | 蒸留方法 |
| US7989659B2 (en) * | 2007-05-17 | 2011-08-02 | Celanese International Corporation | Method and apparatus for making acetic acid with improved light ends column productivity |
| US7619113B2 (en) * | 2007-09-27 | 2009-11-17 | Celanese International Corporation | Method and apparatus for making acetic acid with improved purification |
-
2007
- 2007-10-11 US US11/974,106 patent/US7902397B2/en not_active Expired - Fee Related
-
2008
- 2008-09-24 JP JP2010528862A patent/JP5416126B2/ja active Active
- 2008-09-24 AU AU2008311337A patent/AU2008311337B2/en not_active Ceased
- 2008-09-24 UA UAA201004159A patent/UA97859C2/ru unknown
- 2008-09-24 MX MX2010003945A patent/MX2010003945A/es active IP Right Grant
- 2008-09-24 BR BRPI0818045 patent/BRPI0818045A2/pt not_active IP Right Cessation
- 2008-09-24 CN CN200880115356.2A patent/CN101855194B/zh active Active
- 2008-09-24 NZ NZ584548A patent/NZ584548A/en not_active IP Right Cessation
- 2008-09-24 CA CA2702069A patent/CA2702069A1/en not_active Abandoned
- 2008-09-24 EP EP08837961.5A patent/EP2220022B1/en active Active
- 2008-09-24 RU RU2010118471/04A patent/RU2470909C2/ru not_active IP Right Cessation
- 2008-09-24 KR KR1020107010396A patent/KR101574359B1/ko active Active
- 2008-09-24 MY MYPI2013000414A patent/MY165745A/en unknown
- 2008-09-24 WO PCT/US2008/011076 patent/WO2009048509A1/en not_active Ceased
- 2008-09-24 ES ES08837961.5T patent/ES2552394T3/es active Active
- 2008-09-24 MY MYPI2010001605A patent/MY148933A/en unknown
- 2008-10-08 TW TW097138781A patent/TW200920734A/zh unknown
- 2008-10-09 CL CL2008002993A patent/CL2008002993A1/es unknown
- 2008-10-10 AR ARP080104444A patent/AR071051A1/es not_active Application Discontinuation
-
2010
- 2010-04-09 ZA ZA2010/02509A patent/ZA201002509B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2220022A1 (en) | 2010-08-25 |
| MY165745A (en) | 2018-04-23 |
| EP2220022B1 (en) | 2015-10-28 |
| MX2010003945A (es) | 2010-07-28 |
| CA2702069A1 (en) | 2009-04-16 |
| US7902397B2 (en) | 2011-03-08 |
| BRPI0818045A2 (pt) | 2015-03-31 |
| NZ584548A (en) | 2011-11-25 |
| ZA201002509B (en) | 2012-03-28 |
| RU2470909C2 (ru) | 2012-12-27 |
| AU2008311337A1 (en) | 2009-04-16 |
| ES2552394T3 (es) | 2015-11-27 |
| AU2008311337B2 (en) | 2012-08-23 |
| UA97859C2 (ru) | 2012-03-26 |
| WO2009048509A1 (en) | 2009-04-16 |
| KR101574359B1 (ko) | 2015-12-03 |
| TW200920734A (en) | 2009-05-16 |
| US20090099389A1 (en) | 2009-04-16 |
| CL2008002993A1 (es) | 2009-09-04 |
| JP5416126B2 (ja) | 2014-02-12 |
| MY148933A (en) | 2013-06-14 |
| CN101855194B (zh) | 2015-06-17 |
| JP2011500561A (ja) | 2011-01-06 |
| KR20100087160A (ko) | 2010-08-03 |
| RU2010118471A (ru) | 2011-11-20 |
| CN101855194A (zh) | 2010-10-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |