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AR070740A1 - Plaguicidas, un proceso de preparacion del compuesto, una composicion en base al compuesto y un procedimiento de aplicacion del mismo - Google Patents

Plaguicidas, un proceso de preparacion del compuesto, una composicion en base al compuesto y un procedimiento de aplicacion del mismo

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Publication number
AR070740A1
AR070740A1 ARP090100737A ARP090100737A AR070740A1 AR 070740 A1 AR070740 A1 AR 070740A1 AR P090100737 A ARP090100737 A AR P090100737A AR P090100737 A ARP090100737 A AR P090100737A AR 070740 A1 AR070740 A1 AR 070740A1
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Argentina
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alkyl
haloalkyl
aryl
alkoxy
heterocyclyl
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ARP090100737A
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English (en)
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Dow Agrosciences Llc
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    • C07C381/10—Compounds containing sulfur atoms doubly-bound to nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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    • A01N47/44—Guanidine; Derivatives thereof
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    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
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    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
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    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07C2601/14—The ring being saturated
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    • C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
    • C07C2603/12—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings only one five-membered ring
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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Estos compuestos pueden ser aplicados a una semilla que se ha transformado genéticamente o bien a un animal. Reivindicacion 1: Un compuesto que posee la siguiente formula (1) en donde: (a) R1 es alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, heterociclilo, o alquilo C0-8-C(=O)OR8, donde cada uno de ellos puede estar independientemente sustituido con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)-alquilo C1-6, C(=O)-haloalquilo C1-6, arilo, hidroxialquilo C1-6, NR9R10, y heterociclilo; (b) R2 es alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, heterociclilo, o alquilo C0-8-C(=O)OR8, donde cada uno de ellos puede estar independientemente sustituido con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2) , S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O- alquilo C1-6, C(=O)-alquilo C1-6, C(=O)-haloalquilo C1-6, arilo, hidroxialquilo C1-6, NR9R10, y heterociclilo, y en donde R2 y R5 pueden formar también un anillo de 4, 5 o 6 miembros; (c) R3 es F, Cl, Br, I, alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, H, heterociclilo, C(=O)-alquilo C1-6, C(=O)-arilo C1-6, o alquilo C0-8-C(=O)OR8, donde cada uno de ellos puede estar independientemente sustituido (excepto H, F, Cl, Br, I) con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)-alquilo C1-6, C(=O)-haloalquilo C1-6, arilo (donde dicho arilo puede estar sustituido con uno o más sustituyentes seleccionados de F, Cl, Br, I, o alcoxi C1-8) hidroxialquilo C1-6, NR9R10, y heterociclilo, y en donde R3 y R4 pueden formar también un anillo de 4, 5 o 6 miembros; (d) R4 es F, Cl, Br, I, alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, H, heterociclilo, C(=O)-alquilo C1-6, C(=O)-arilo C1-6, o alquilo C0-8-C(=O)OR8, donde cada uno de ellos puede estar independientemente sustituido (excepto H, F, Cl, Br, I) con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)-alquilo C1-6, C(=O)-haloalquilo C1-6, arilo (donde dicho arilo puede estar sustituido con uno o más sustituyentes seleccionados de F, Cl, Br, I, o alcoxi C1-8) hidroxialquilo C1-6, NR9R10, y heterociclilo, y en donde R3 y R4 pueden formar también un anillo de 4, 5 o 6 miembros; (e) R5 es alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, H, heterociclilo, o alquilo C0-8-C(=O)OR8, donde cada uno de ellos puede estar independientemente sustituido (excepto H) con una o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)-alquilo C1-6, C(=O)-haloalquilo C1-6, arilo, cicloalquilo C3-8, hidroxialquilo C1-6, NR9R10, y heterociclilo, y en donde R2 y R5 pueden formar también un anillo de 4, 5 o 6 miembros, y en donde R5 y R6 pueden formar también un anillo de 3, 4, 5, o 6 miembros; (f) R6 es alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, H, heterociclilo, o alquilo C0-8-C(=O)OR8, donde cada uno de ellos puede estar independientemente sustituido (excepto H) con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)-alquilo C1-6, C(=O)-haloalquilo C1-6, arilo, cicloalquilo C3-8, hidroxialquilo C1-6, NR9R10, y heterociclilo, y en donde R2 y R5 pueden formar también un anillo de 4, 5 o 6 miembros, y en donde R5 y R6 pueden formar también un anillo de 3, 4, 5, o 6 miembros; (g) n es 0 a 4; (h) X es NR8, O, o S; (i) J es N o CR7; (j) R7 es H, F, Cl, Br, I, alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, heterociclilo, o alquilo C0-8-C(=O)OR8, donde cada uno de ellos puede estar independientemente sustituido (excepto H, F, Cl, Br, I) con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)- alquilo C1-6, C(=O)-haloalquilo C1-6, arilo, hidroxialquilo C1-6, NR9R10 y heterociclilo; (k) R8 es H, OH, OC(=O)-alquilo C1-6, alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, o heterociclilo, donde dada uno de ellos puede estar independientemente sustituido con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, cicloalquilo C3-8, halocicloalquilo C3-8, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1- alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)-alquilo C1-6, C(=O)-haloalquilo C1-6, arilo (donde dicho arilo puede estar sustituido con uno o más sustituyentes seleccionados de F, Cl, Br, I, o alcoxi C1-8), hidroxialquilo C1-6, y heterociclilo; (l) R9 es alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, o heterociclilo, donde cada uno de ellos puede estar independientemente sustituido con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)-alquilo C1-6, C(=O)-haloalquilo C1-6, arilo, hidroxialquilo C1-6, y heterociclilo, y en donde R9 y R10 pueden formar también un anillo de 4, 5 o 6 miembros; y (m) R10 es alquenilo C2-8, alqueniloxi C2-8, alqueniltio C2-8, alcoxi C1-8, alquilo C1-8, alquiltio C1-8, alquinilo C2-8, alquiniloxi C2-8, alquiniltio C2-8, arilo, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalqueniltio C3-8, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquiltio C3-8, o heterociclilo, donde cada uno de ellos puede estar independientemente sustituido con uno o más de los siguientes sustituyentes, F, Cl, Br, I, CN, NO2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, haloalquiltio C1-6, S(=O)n1-alquilo C1-6 (donde n1=0-2), S(=O)n1-haloalquilo C1-6 (donde n1=0-2), OSO2-haloalquilo C1-6, C(=O)O-alquilo C1-6, C(=O)- alquilo C1-6, C(=O)-haloalquilo C1-6, arilo, hidroxialquilo C1-6, y heterociclilo, y en donde R9 y R10 pueden formar también un anillo de 4, 5 o 6 miembros.
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