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AR077456A1 - PREPARATION OF 4 - ((1R, 3S) -6-CHLORO-3-PHENYL-INDAN- 1IL) -1,2,2- TRIMETHYL-PIPERAZINE AND 1 - ((1R, 3S) -6-CHLORINE-3- PHENYL -INDAN-1-IL-) -3,3-DIMETIL- PIPERAZINA - Google Patents

PREPARATION OF 4 - ((1R, 3S) -6-CHLORO-3-PHENYL-INDAN- 1IL) -1,2,2- TRIMETHYL-PIPERAZINE AND 1 - ((1R, 3S) -6-CHLORINE-3- PHENYL -INDAN-1-IL-) -3,3-DIMETIL- PIPERAZINA

Info

Publication number
AR077456A1
AR077456A1 ARP100102420A ARP100102420A AR077456A1 AR 077456 A1 AR077456 A1 AR 077456A1 AR P100102420 A ARP100102420 A AR P100102420A AR P100102420 A ARP100102420 A AR P100102420A AR 077456 A1 AR077456 A1 AR 077456A1
Authority
AR
Argentina
Prior art keywords
indan
phenyl
piperazine
chloro
trimethyl
Prior art date
Application number
ARP100102420A
Other languages
Spanish (es)
Original Assignee
Lundbeck & Co As H
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lundbeck & Co As H filed Critical Lundbeck & Co As H
Publication of AR077456A1 publication Critical patent/AR077456A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D241/00Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/04Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P25/00Drugs for disorders of the nervous system
    • A61P25/18Antipsychotics, i.e. neuroleptics; Drugs for mania or schizophrenia
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P43/00Drugs for specific purposes, not provided for in groups A61P1/00-A61P41/00

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Animal Behavior & Ethology (AREA)
  • Medicinal Chemistry (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Psychiatry (AREA)
  • Biomedical Technology (AREA)
  • Neurology (AREA)
  • Neurosurgery (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

Un proceso para la elaboracion de 4-((1R,3S)-6-cloro-3-fenil-indan-1-il)-1,2,2-trimetil-piperazina o una sal farmacéuticamente aceptable del mismo y un proceso para la elaboracion de 1-((1R,3S)-6-cloro-3-fenil-indan-1-il)-3,3-dimetil-piperazina o una sal farmacéuticamente aceptable del mismo. Reivindicacion 1: Un proceso para la elaboracion de 4-((1R,3S)-6-cloro-3-fenil-indan-1-il)-1,2,2-trimetil-piperazina o una sal farmacéuticamente aceptable del mismo que comprende el paso de mezclar trans 4-(6-cloro-3-fenil-indan-1-il)-1,2,2-trimetil-piperazina con ácido (+)-L-tartárico en un solvente polar para obtener 4-((1R,3S)-6-cloro-3-fenil-indan-1-il)-1,2,2-trimetil-piperazina o una sal farmacéuticamente aceptable del mismo. Reivindicacion 5: Un proceso para la elaboracion de 4-((1R,3S)-6-cloro-3-fenil-indan-1-il)-1,2,2-trimetil-piperazina o una sal farmacéuticamente aceptable del mismo que comprende los pasos de a) mezclar trans 4-(6-cloro-3-fenil-indan-1-il)-1,2,2-trimetil-piperazina y ácido (+)-L-tartárico en un solvente polar; b) opcionalmente calentar la mezcla que se obtuvo a una temperatura apropiada a fin de obtener una solucion del trans 4-(6-cloro-3-fenil-indan-1-il)-1,2,2-trimetil-piperazina y ácido (+)-L-tartárico; c) enfriar la solucion que se obtuvo en b) hasta la precipitacion; d) aislar el precipitado que se obtuvo en c); e) opcionalmente secar el precipitado que se obtuvo en d); para obtener 4-((1R,3S)-6-cloro-3-fenil-indan-1-il)-1,2,2-trimetil-piperazina o una sal farmacéuticamente aceptable del mismo. Reivindicacion 14: Un proceso para la elaboracion de 1-((1R,3S)-6-cloro-3-fenil-indan-1-il)-3,3-dimetil-piperazina o una sal farmacéuticamente aceptable del mismo que comprende el paso de mezclar trans 1-(6-cloro-3-fenil-indan-1-il)-3,3-dimetil-piperazina con ácido (-)-D-tartárico en un solvente polar para obtener 1-((1R,3S)-6-cloro-3-fenil-indan-1-il)-3,3-dimetil-piperazina o una sal farmacéuticamente aceptable del mismo. Reivindicacion 18: Un proceso para la elaboracion de 1-((1R,3S)-6-cloro-3-fenil-indan-1-il)-3,3-dimetil-piperazina o una sal farmacéuticamente aceptable del mismo que comprende los pasos de a) mezclar trans 1-(6-cloro-3-fenil-indan-1-il)-3,3-dimetil-piperazina y ácido (-)-D-tartárico en un solvente polar; b) opcionalmente calentar la mezcla que se obtuvo a una temperatura apropiada a fin de obtener una solucion del trans 1-((6-cloro-3-fenil-indan-1-il)-3,3-dimetil-piperazina y ácido (-)-D-tartárico; c) enfriar la solucion que se obtuvo en b) hasta precipitacion; d) aislar el precipitado que se obtuvo en c); e) opcionalmente secar el precipitado que se obtuvo en d); para obtener 1-((1R,3S)-6-cloro-3-fenil-indan-1-il)-3,3-dimetil-piperazina o una sal farmacéuticamente aceptable del mismo.A process for the preparation of 4 - ((1R, 3S) -6-chloro-3-phenyl-indan-1-yl) -1,2,2-trimethyl-piperazine or a pharmaceutically acceptable salt thereof and a process for the preparation of 1 - ((1R, 3S) -6-chloro-3-phenyl-indan-1-yl) -3,3-dimethyl-piperazine or a pharmaceutically acceptable salt thereof. Claim 1: A process for the preparation of 4 - ((1R, 3S) -6-chloro-3-phenyl-indan-1-yl) -1,2,2-trimethyl-piperazine or a pharmaceutically acceptable salt thereof It comprises the step of mixing trans 4- (6-chloro-3-phenyl-indan-1-yl) -1,2,2-trimethyl-piperazine with (+) - L-tartaric acid in a polar solvent to obtain 4- ((1R, 3S) -6-Chloro-3-phenyl-indan-1-yl) -1,2,2-trimethyl-piperazine or a pharmaceutically acceptable salt thereof. Claim 5: A process for the preparation of 4 - ((1R, 3S) -6-chloro-3-phenyl-indan-1-yl) -1,2,2-trimethyl-piperazine or a pharmaceutically acceptable salt thereof it comprises the steps of a) mixing trans 4- (6-chloro-3-phenyl-indan-1-yl) -1,2,2-trimethyl-piperazine and (+) - L-tartaric acid in a polar solvent; b) optionally heating the mixture obtained at an appropriate temperature in order to obtain a solution of trans 4- (6-chloro-3-phenyl-indan-1-yl) -1,2,2-trimethyl-piperazine and acid (+) - L-tartaric; c) cooling the solution obtained in b) to precipitation; d) isolate the precipitate that was obtained in c); e) optionally drying the precipitate obtained in d); to obtain 4 - ((1R, 3S) -6-chloro-3-phenyl-indan-1-yl) -1,2,2-trimethyl-piperazine or a pharmaceutically acceptable salt thereof. Claim 14: A process for the preparation of 1 - ((1R, 3S) -6-chloro-3-phenyl-indan-1-yl) -3,3-dimethyl-piperazine or a pharmaceutically acceptable salt thereof comprising the step of mixing trans 1- (6-chloro-3-phenyl-indan-1-yl) -3,3-dimethyl-piperazine with (-) - D-tartaric acid in a polar solvent to obtain 1 - ((1R, 3S) -6-Chloro-3-phenyl-indan-1-yl) -3,3-dimethyl-piperazine or a pharmaceutically acceptable salt thereof. Claim 18: A process for the preparation of 1 - ((1R, 3S) -6-chloro-3-phenyl-indan-1-yl) -3,3-dimethyl-piperazine or a pharmaceutically acceptable salt thereof comprising the steps of a) mixing trans 1- (6-chloro-3-phenyl-indan-1-yl) -3,3-dimethyl-piperazine and (-) - D-tartaric acid in a polar solvent; b) optionally heating the mixture obtained at an appropriate temperature in order to obtain a solution of trans 1 - ((6-chloro-3-phenyl-indan-1-yl) -3,3-dimethyl-piperazine and acid ( -) - D-tartaric acid; c) cool the solution obtained in b) until precipitation; d) isolate the precipitate that was obtained in c); e) optionally drying the precipitate obtained in d); to obtain 1 - ((1R, 3S) -6-chloro-3-phenyl-indan-1-yl) -3,3-dimethyl-piperazine or a pharmaceutically acceptable salt thereof.

ARP100102420A 2009-07-07 2010-07-06 PREPARATION OF 4 - ((1R, 3S) -6-CHLORO-3-PHENYL-INDAN- 1IL) -1,2,2- TRIMETHYL-PIPERAZINE AND 1 - ((1R, 3S) -6-CHLORINE-3- PHENYL -INDAN-1-IL-) -3,3-DIMETIL- PIPERAZINA AR077456A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DKPA200900835 2009-07-07

Publications (1)

Publication Number Publication Date
AR077456A1 true AR077456A1 (en) 2011-08-31

Family

ID=43428803

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP100102420A AR077456A1 (en) 2009-07-07 2010-07-06 PREPARATION OF 4 - ((1R, 3S) -6-CHLORO-3-PHENYL-INDAN- 1IL) -1,2,2- TRIMETHYL-PIPERAZINE AND 1 - ((1R, 3S) -6-CHLORINE-3- PHENYL -INDAN-1-IL-) -3,3-DIMETIL- PIPERAZINA

Country Status (9)

Country Link
US (1) US8501947B2 (en)
EP (1) EP2451789A1 (en)
JP (1) JP2012532153A (en)
CN (1) CN102471289A (en)
AR (1) AR077456A1 (en)
AU (1) AU2010268892B2 (en)
CA (1) CA2766607A1 (en)
TW (1) TW201102370A (en)
WO (1) WO2011003423A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2823103A1 (en) * 2011-01-07 2012-07-12 H. Lundbeck A/S Method for resolution of 4-((1r,3s)-6-chloro-3-phenyl-indan-1-yl)-1,2,2-trimethyl-piperazine and 1-((1r,3s)-6-chloro-3-phenyl-indan-1-yl)-3,3-dimethyl-piperazine
DK3135656T3 (en) 2011-06-20 2019-04-23 H Lundbeck As DEUTERATED 1-PIPERAZINO-3-PHENYL INDANES FOR TREATMENT OF schizophrenia
AR094054A1 (en) 2012-12-19 2015-07-08 H Lundbeck As 6-CHLORINE-3- (FENIL-D₅) -INDEN-1-ONA AND USE OF THE SAME
WO2020114853A1 (en) 2018-12-03 2020-06-11 H. Lundbeck A/S Prodrugs of 4-((1r,3s)-6-chloro-3-phenyl-2,3-dihydro-1h-inden-1-yl)-1,2,2-trimethylpiperazine and 4-((1/r,3s)-6-chloro-3-(phenyl-d5)-2,3-dihydro-1h-inden-1-yl)-2,2-dimethy-1-(methyl-d3)piperazine

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK55192D0 (en) 1992-04-28 1992-04-28 Lundbeck & Co As H 1-piperazino-1,2-dihydroindene derivatives
US7767683B2 (en) * 2003-08-18 2010-08-03 H. Lundbeck A/S Hydrogen succinate salts of trans-4-((1R, 3S)-6-chloro-3-phenylindan-1-YL)-1,2,2-trimethylpiperazine and the use as a medicament
TWI453198B (en) 2005-02-16 2014-09-21 Lundbeck & Co As H Process for making the trans-1-( (1r , 3s)- 6-chloro - 3 -phenylindan-1- yl ) - 3 , 3 - dimethylpiperazine and salts thereof and for making 4 -((1r , 3s )-6- chloro- 3- phenylindan -1- yl )-1, 2 , 2 -trimethylpiperazine and salts thereof
WO2006086985A1 (en) 2005-02-16 2006-08-24 H. Lundbeck A/S Tartrate and malate salts of trans-1-((1r,3s)-6-chloro-3-phenylindan-1-yl)-3,3-dimethylpiperazine
TW200640891A (en) * 2005-02-16 2006-12-01 Lundbeck & Co As H Tartrate and malate salts of a pharmarceutical compound

Also Published As

Publication number Publication date
TW201102370A (en) 2011-01-16
JP2012532153A (en) 2012-12-13
AU2010268892A1 (en) 2012-02-02
US20120142923A1 (en) 2012-06-07
CA2766607A1 (en) 2011-01-13
CN102471289A (en) 2012-05-23
EP2451789A1 (en) 2012-05-16
US8501947B2 (en) 2013-08-06
AU2010268892B2 (en) 2015-03-26
WO2011003423A1 (en) 2011-01-13

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