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AR075638A1 - Catalizador de hidrogeno selectivo y metodos para elaborar y usar el mismo - Google Patents

Catalizador de hidrogeno selectivo y metodos para elaborar y usar el mismo

Info

Publication number
AR075638A1
AR075638A1 ARP100100603A AR075638A1 AR 075638 A1 AR075638 A1 AR 075638A1 AR P100100603 A ARP100100603 A AR P100100603A AR 075638 A1 AR075638 A1 AR 075638A1
Authority
AR
Argentina
Prior art keywords
catalyst
palladium
supported
composition
contacting
Prior art date
Application number
Other languages
English (en)
Inventor
Zongxuan Hong
Tin Tack P Cheung
Original Assignee
Chevron Phillips Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co filed Critical Chevron Phillips Chemical Co
Publication of AR075638A1 publication Critical patent/AR075638A1/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
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    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • B01J37/024—Multiple impregnation or coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
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    • B01J2231/60—Reduction reactions, e.g. hydrogenation
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    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
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    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
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    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
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    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La presente invencion se refiere a una composicion que comprende un catalizador de hidrogenacion soportado que comprende paladio y un compuesto organofosforoso, el catalizador de hidrogenacion soportado siendo capaz de hidrogenar selectivamente hidrocarburos altamente insaturados a hidrocarburos insaturados. Un método para elaborar un catalizador de hidrogenacion selectivo que comprende, contactar un soporte con un compuesto que contiene paladio para formar una composicion soportada de paladio, contactar la composicion soportada de paladio con un compuesto organofosforoso para formar un precursor de catalizador, y reducir el precursor de catalizador para formar el catalizador. Un método para hidrogenar selectivamente hidrocarburos altamente insaturados a una composicion enriquecida de hidrocarburo que comprende, contactar un catalizador soportado que comprende paladio y un compuesto organofosforoso con una alimentacion que comprende hidrocarburo altamente insaturado bajo condiciones adecuadas para hidrogenar al menos, una porcion de la alimentacion de hidrocarburo altamente insaturado para formar la composicion enriquecida de hidrocarburo insaturado.
ARP100100603 2009-03-04 2010-03-02 Catalizador de hidrogeno selectivo y metodos para elaborar y usar el mismo AR075638A1 (es)

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US15749109P 2009-03-04 2009-03-04

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AR075638A1 true AR075638A1 (es) 2011-04-20

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ARP100100603 AR075638A1 (es) 2009-03-04 2010-03-02 Catalizador de hidrogeno selectivo y metodos para elaborar y usar el mismo
ARP170101561A AR108966A2 (es) 2009-03-04 2017-06-07 Método para hidrogenar selectivamente hidrocarburos altamente insaturados a una composición enriquecida de hidrocarburos insaturados

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Country Status (14)

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US (3) US8633127B2 (es)
EP (2) EP2403642B1 (es)
JP (1) JP5511853B2 (es)
KR (1) KR101697799B1 (es)
AR (2) AR075638A1 (es)
AU (1) AU2010221662B2 (es)
BR (1) BRPI1009225A2 (es)
CA (2) CA3000442A1 (es)
ES (1) ES2645100T3 (es)
IL (1) IL214927A0 (es)
MX (2) MX336180B (es)
PH (1) PH12015500779B1 (es)
SG (3) SG10201505698TA (es)
WO (1) WO2010101736A2 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2010221662B2 (en) 2009-03-04 2015-04-02 Chevron Phillips Chemical Company Lp Selective hydrogenation catalyst and methods of making and using same
US8969598B2 (en) 2011-06-24 2015-03-03 Eastman Chemical Company Production of cyclic acetals or ketals using liquid-phase acid catalysts
US9388105B2 (en) 2011-06-24 2016-07-12 Eastman Chemical Company Production of hydroxy ether hydrocarbons by liquid phase hydrogenolysis of cyclic acetals or cyclic ketals
US9000229B2 (en) 2011-06-24 2015-04-07 Eastman Chemical Company Production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US8829207B2 (en) 2011-06-24 2014-09-09 Eastman Chemical Company Production of cyclic acetals by reactive distillation
US8829206B2 (en) 2011-06-24 2014-09-09 Eastman Chemical Company Production of cyclic acetals or ketals using solid acid catalysts
US9056313B2 (en) 2011-06-24 2015-06-16 Eastman Chemical Company Catalysts for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US8785697B2 (en) 2011-06-24 2014-07-22 Eastman Chemical Company Nickel modified catalyst for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US9108188B2 (en) 2012-03-07 2015-08-18 Chevoron Phillip Chemical Company, LP Selective hydrogenation catalyst and methods of making and using same
KR20160052588A (ko) * 2013-09-06 2016-05-12 셰브론 필립스 케미컬 컴퍼니 엘피 쌍봉 지지체를 포함하는 선택적 수소화 촉매 및 이의 제조 및 사용 방법
JP6075506B2 (ja) * 2014-04-22 2017-02-08 宇部興産株式会社 水素化触媒及びその製造方法、並びにそれを用いたシクロヘキサノン又はその誘導体の製造方法
US9511359B2 (en) * 2014-11-14 2016-12-06 Chevron Phillips Chemical Company Lp Selective hydrogenation catalyst and methods of making and using same
US9758446B2 (en) 2015-11-16 2017-09-12 Chevron Phillips Chemical Company Lp Selective hydrogenation using a flow index
US10245583B1 (en) * 2017-09-12 2019-04-02 Chevron Phillips Chemical Company, Lp Use of charge-containing molecules linked with covalent bonds to enhance acetylene hydrogenation catalysts
US10232360B1 (en) * 2017-09-12 2019-03-19 Chevron Phillips Chemical Company, Lp Use of organic dopants to enhance acetylene hydrogenation catalysts

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1154937A (en) * 1966-08-10 1969-06-11 Ici Ltd Hydrogenation Process
US3625755A (en) * 1969-04-14 1971-12-07 Du Pont Supported metal salt/phosphine complexes and metallized products therefrom
US3635841A (en) * 1969-06-16 1972-01-18 Engelhard Min & Chem Novel anthraquinone hydrogenation catalyst
US3947495A (en) * 1974-07-01 1976-03-30 National Distillers And Chemical Corporation Process for the preparation of acrylic and methacrylic acids
US4120901A (en) * 1977-08-31 1978-10-17 Monsanto Company Production of primary and secondary amines by reaction of ammonia with conjugated diene in the presence of Pd/phosphine catalyst and primary or secondary aliphatic alcohol solvent medium
US4204997A (en) * 1979-03-19 1980-05-27 Monsanto Company Asymmetric amination of 1,3-dienes
US4418227A (en) * 1979-08-29 1983-11-29 Allied Corporation Improved process for hydrogenating aldehydes and ketones by employing anionic group VIII metal hydride compositions as hydrogenation catalysts
US4325834A (en) * 1980-11-21 1982-04-20 Air Products And Chemicals, Inc. Heterogeneous catalyst supports
US4484015A (en) 1981-05-06 1984-11-20 Phillips Petroleum Company Selective hydrogenation
US4404124A (en) 1981-05-06 1983-09-13 Phillips Petroleum Company Selective hydrogenation catalyst
US4384981A (en) * 1981-08-24 1983-05-24 Occidental Research Corporation Hydrogenation process utilizing novel catalyst
GB8314001D0 (en) * 1983-05-20 1983-06-29 Shell Int Research Preparation of alphahaloalkyl esters
US4713363A (en) * 1984-12-27 1987-12-15 The Dow Chemical Company High surface area supported noble metal catalysts and process for their preparation
DE3538129A1 (de) * 1985-10-26 1987-04-30 Bayer Ag Traegerkatalysatoren und hydrierverfahren unter verwendung dieser traegerkatalysatoren
FR2596390B1 (fr) * 1986-03-27 1989-02-17 Rhone Poulenc Chimie Procede de (co)dimerisation catalytique d'un acrylate d'alkyle inferieur et composition catalytique
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
KR0148012B1 (ko) * 1989-03-03 1998-08-17 오노 알버어스 신규한 포스핀으로 구성되는 촉매시스템 및 이를 이용한 아세틸렌형 또는 올레핀형 불포화화합물의 카르보닐화방법
GB9002491D0 (en) * 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
GB9111583D0 (en) * 1991-05-30 1991-07-24 Shell Int Research Carbonylation catalyst system
US5482596A (en) 1994-01-27 1996-01-09 Albemarle Corporation Mixed ligand catalyst for preparing aryl-substituted aliphatic carboxylic esters
US5600032A (en) * 1994-06-29 1997-02-04 Mitsubishi Chemical Corporation Method for producing an unsaturated alcohol
US5475173A (en) * 1994-07-19 1995-12-12 Phillips Petroleum Company Hydrogenation process and catalyst therefor
EP0811629B1 (en) * 1995-02-24 2003-05-02 Nissan Chemical Industries, Limited Optically active bidentate phosphine ligand/palladium complex
FR2735399B1 (fr) * 1995-06-16 1997-07-25 Inst Francais Du Petrole Nouvelle composition catalytique a base de complexes de metaux de transition et procede pour l'hydrogenation des composes insatures
CZ21198A3 (cs) * 1995-07-25 1998-07-15 Clariant Gmbh Katalyzátory k provádění křížových kopulačních reakcí
JP3409072B2 (ja) * 1996-09-11 2003-05-19 日産ガードラー触媒株式会社 オレフィン化合物類中の高不飽和炭化水素化合物選択水素添加用触媒
US5962741A (en) * 1996-11-19 1999-10-05 Novartis Ag Process for the production of aromatic halogen-amino compounds
CN1117629C (zh) * 1997-04-07 2003-08-13 Dsm有限公司 羰基化催化剂体系
DE19734974A1 (de) * 1997-08-13 1999-02-25 Hoechst Ag Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat
DE19753464A1 (de) * 1997-12-02 1999-06-10 Basf Ag Palladium-Cluster und ihre Verwendung als Katalysatoren
US6005123A (en) 1998-04-16 1999-12-21 Arco Chemical Technology, L.P. Epoxidation process
FR2778341B1 (fr) * 1998-05-07 2000-06-09 Inst Francais Du Petrole Catalyseur a base d'un metal noble du groupe viii contenant du bore et/ou du silicium et son utilisation en hydrotraitement de charge hydrocarbonees
US6127588A (en) * 1998-10-21 2000-10-03 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
DE19913352A1 (de) * 1999-03-24 2000-09-28 Basf Ag Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phospinamiditliganden
US6821412B1 (en) * 1999-08-30 2004-11-23 Cosmo Oil Co., Ltd. Catalyst for hydrotreating of gas oil and method for hydrotreating of gas oil
WO2001034612A2 (en) * 1999-11-10 2001-05-17 The Penn State Research Foundation Chiral phosphines, transition metal complexes thereof and uses thereof in asymmetric reactions
DE10037961A1 (de) * 2000-07-27 2002-02-07 Aventis Res & Tech Gmbh & Co Neue Phosphanliganden, deren Herstellung und ihre Verwendung in katalytischen Reaktionen
CN1151888C (zh) 2001-12-06 2004-06-02 中国科学院大连化学物理研究所 一种由烯烃氢甲酰化制取各类有机醛的催化剂及其制备方法
US6921733B2 (en) * 2002-01-16 2005-07-26 Brookhaven Science Associates, Llc Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor
US6831035B2 (en) * 2002-01-22 2004-12-14 Eastman Kodak Company Stabilization of fluorophosphite-containing catalysts
JP4013217B2 (ja) * 2002-01-31 2007-11-28 高砂香料工業株式会社 新規なホスフィン化合物、その化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉合成用触媒。
AU2003201857A1 (en) * 2002-03-22 2003-10-08 Kuraray Co., Ltd. Bisphosphine, process for producing the same, and use thereof
JP4148702B2 (ja) * 2002-06-04 2008-09-10 高砂香料工業株式会社 新規なジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒
DE10247633A1 (de) * 2002-10-11 2004-04-29 Studiengesellschaft Kohle Mbh Mischungen von chiralen Monophosphor-Verbindungen als Ligandensysteme für die asymmetrische Übergangsmetallkatalyse
WO2004037869A2 (en) * 2002-10-25 2004-05-06 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin oligomerizations
JP4231274B2 (ja) * 2002-11-12 2009-02-25 高砂香料工業株式会社 ホスフィン化合物、該化合物を配位子とする遷移金属錯体及び該錯体を含む不斉合成用触媒
CN1207257C (zh) * 2002-12-31 2005-06-22 曲阜师范大学 一种强酸性离子交换树脂催化合成异山梨醇的方法
WO2004074220A1 (en) * 2003-02-18 2004-09-02 Chevron Phillips Chemical Company Acetylene hydrogenation catalyst with segregated palladium skin
DE602004005449T2 (de) * 2003-06-05 2007-11-29 Eastman Chemical Co., Kingsport Geträgerte metall-phosphin-aminophosphin-katalysatoren
US20040260131A1 (en) * 2003-06-23 2004-12-23 Chevron Phillips Chemical Company ("Cpchem") Selective hydrocarbon hydrogenation catalyst and process
US7919431B2 (en) * 2003-09-03 2011-04-05 Synfuels International, Inc. Catalyst formulation for hydrogenation
US7199076B2 (en) * 2003-12-19 2007-04-03 Chevron Phillips Chemical Company Lp Methods of making and using a selective hydrogenation catalyst
US7408089B2 (en) * 2004-03-19 2008-08-05 Catalytic Distillation Technologies Ni catalyst, process for making catalysts and selective hydrogenation process
SG164387A1 (en) * 2005-07-27 2010-09-29 Chevron Phillips Chemical Co A selective hydrogenation catalyst and methods of making and using same
US7586010B2 (en) * 2006-12-21 2009-09-08 Eastman Chemical Company Phosphonite-containing catalysts for hydroformylation processes
AU2010221662B2 (en) 2009-03-04 2015-04-02 Chevron Phillips Chemical Company Lp Selective hydrogenation catalyst and methods of making and using same

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US20100228065A1 (en) 2010-09-09
US9221727B2 (en) 2015-12-29
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IL214927A0 (en) 2011-11-30
BRPI1009225A2 (pt) 2019-04-16
JP2012519582A (ja) 2012-08-30
US20150197464A1 (en) 2015-07-16
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