AR074443A1 - Proceso para la preparacion de copolimeros con radicales al azar, y composiciones de sustancia activa que se pueden obtener a partir de ellos - Google Patents
Proceso para la preparacion de copolimeros con radicales al azar, y composiciones de sustancia activa que se pueden obtener a partir de ellosInfo
- Publication number
- AR074443A1 AR074443A1 ARP090104631A AR074443A1 AR 074443 A1 AR074443 A1 AR 074443A1 AR P090104631 A ARP090104631 A AR P090104631A AR 074443 A1 AR074443 A1 AR 074443A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkylaminoalkyl
- alkyl
- aryl
- alkylaminoaryl
- hydroxyalkyl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 239000013543 active substance Substances 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 3
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 2
- 125000004171 alkoxy aryl group Chemical group 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000005160 aryl oxy alkyl group Chemical group 0.000 abstract 2
- 150000005840 aryl radicals Chemical class 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000002671 adjuvant Substances 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000000278 alkyl amino alkyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 239000011877 solvent mixture Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1812—C12-(meth)acrylate, e.g. lauryl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
- C08F220/585—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine and containing other heteroatoms, e.g. 2-acrylamido-2-methylpropane sulfonic acid [AMPS]
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Polymerisation Methods In General (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
Un proceso para la preparación de copolímeros con radicales al azar que comprende: a) al menos un ácido sulfónico con insaturaciones olefínicas de la fórmula (1) donde n es 0 a 10; X es NR5; R1 es H o metilo; R2, R3 de modo independiente entre sí son H o alquilo C1-6 y R5 es H, alquilo, arilo, alquilarilo, alcoxialquilo, ariloxialquilo, alcoxiarilo, hidroxialquilo, di-alquilaminoalquilo, di-alquilaminoarilo, di-arilaminoalquilo, alquilarilaminoalquilo o alquilarilaminoarilo, es posible que los radicales arilo estén monosustituido o polisustituidos, sus sales o mezclas de ácido y sales y b) al menos dos monómeros con insaturaciones olefínicas de la fórmula (2) estructuralmente diferentes donde Y es O o NR7; R5 es H o metilo; R6 es alquilo, hidroxialquilo, di-alquilaminoalquilo o di-alquilaminoarilo y R7 es H, alquilo, arilo, alquilarilo, arilalquilo, alcoxialquilo, ariloxialquilo, alcoxiarilo, hidroxialquilo, di-alquilaminoalquilo, di-alquilaminoarilo, di-arilaminoalquilo, alquilarilaminoalquilo o alquilarilaminoarilo, es posible que los radicales arilo estén monosustituido o polisustituidos, y c) si corresponde, uno o más monómeros con insaturaciones olefínicas que difieren estructuralmente de los componentes (a) y (b), d) al menos un iniciador se disuelven (i) en una mezcla de solventes que comprende agua y un solvente orgánico hidrosoluble con un punto de ebullición menor de 140sC o (ii) se disuelven en uno o más alcoholes puros por calentamiento, y se polimerizan, en solución, donde el polímero formado permanece en solución. Los copolímeros que se pueden obtener por el proceso son adecuados como adyuvantes de la formulación en las composiciones de sustancia activa agroquímica.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08170501 | 2008-12-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR074443A1 true AR074443A1 (es) | 2011-01-19 |
Family
ID=40910804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP090104631 AR074443A1 (es) | 2008-12-02 | 2009-12-01 | Proceso para la preparacion de copolimeros con radicales al azar, y composiciones de sustancia activa que se pueden obtener a partir de ellos |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US20110237439A1 (es) |
| EP (1) | EP2373695B1 (es) |
| JP (1) | JP5957224B2 (es) |
| KR (1) | KR20110103991A (es) |
| CN (1) | CN102300881B (es) |
| AR (1) | AR074443A1 (es) |
| AU (1) | AU2009324248A1 (es) |
| BR (1) | BRPI0917068B1 (es) |
| CA (1) | CA2745249C (es) |
| EA (1) | EA201100876A1 (es) |
| IL (1) | IL213255A0 (es) |
| MX (1) | MX2011005723A (es) |
| TW (1) | TW201028086A (es) |
| UA (1) | UA106218C2 (es) |
| UY (1) | UY32284A (es) |
| WO (1) | WO2010063672A2 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112013012174B1 (pt) * | 2010-11-25 | 2018-02-14 | Basf Se | Composição concentrada emulsionável, processo para preparar a composição e método para controlar fungos fitopatogênicos |
| CN103547149B (zh) * | 2011-05-13 | 2015-04-08 | 巴斯夫欧洲公司 | 作为分散剂用于农业化学制剂的丙烯酸酯-丙烯酰胺-amps三元共聚物 |
| WO2013061157A1 (en) * | 2011-10-27 | 2013-05-02 | Basf Se | Water dispersible granules |
| US20140357489A1 (en) * | 2011-12-05 | 2014-12-04 | Basf Se | Emulsifiable concentrate comprising pesticide, dimethyl sulfoxide, benzyl alcohol, alkyl lactate |
| JP6290172B2 (ja) * | 2012-04-04 | 2018-03-07 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | アミド、ポリアルキレングリコール(メタ)アクリレート、及びアルキル(メタ)アクリレートのコポリマーを含む農業製剤 |
| US9700048B2 (en) | 2012-04-04 | 2017-07-11 | Basf Se | Agroformulation comprising copolymer of vinyllactam, N-alkyl acrylamide, and alkyl (meth)acrylate |
| ES2718662T3 (es) * | 2012-09-04 | 2019-07-03 | Dow Agrosciences Llc | Composiciones y métodos para mejorar la compatibilidad de las sales de herbicidas solubles en agua |
| JP2017206441A (ja) * | 2014-09-22 | 2017-11-24 | Jsr株式会社 | 殺菌性組成物 |
| AR103333A1 (es) * | 2014-12-31 | 2017-05-03 | Valent Usa Corp | Formulaciones de premezclas insecticidas estables |
| CN111565768B (zh) * | 2018-02-20 | 2022-09-02 | 泰尔茂株式会社 | 医疗器械 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3473185D1 (en) * | 1984-10-02 | 1988-09-08 | Agfa Gevaert Nv | Liquid developer for development of electrostatic images |
| US5612429A (en) * | 1992-04-21 | 1997-03-18 | National Starch And Chemical Investment Holding Corporation | Process for the polymerization of polymers in non-aqueous liquid media |
| US6683143B1 (en) * | 2000-05-04 | 2004-01-27 | Kimberly Clark Worldwide, Inc. | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
| DE10351004A1 (de) * | 2003-10-30 | 2005-05-25 | Basf Ag | Nanopartikuläre Wirkstoffformulierungen |
| US20060147505A1 (en) * | 2004-12-30 | 2006-07-06 | Tanzer Richard W | Water-dispersible wet wipe having mixed solvent wetting composition |
| BRPI0622303B1 (pt) * | 2005-04-18 | 2016-03-01 | Basf Se | copolímeros cp na forma de um polímero obtido por polimerização com radical de pelo menos três monômeros m diferentes monoetilenicamente insaturados |
| EP1739108B1 (en) * | 2005-06-29 | 2008-04-23 | Rohm and Haas Company | Thickener for aqueous systems |
| WO2008040786A1 (de) * | 2006-10-05 | 2008-04-10 | Basf Se | Kammpolymere und ihre verwendung zur herstellung von wirk- oder effektstoffformulierungen |
-
2009
- 2009-11-30 UA UAA201108290A patent/UA106218C2/ru unknown
- 2009-11-30 AU AU2009324248A patent/AU2009324248A1/en not_active Abandoned
- 2009-11-30 US US13/132,117 patent/US20110237439A1/en not_active Abandoned
- 2009-11-30 EA EA201100876A patent/EA201100876A1/ru unknown
- 2009-11-30 BR BRPI0917068-5A patent/BRPI0917068B1/pt active IP Right Grant
- 2009-11-30 MX MX2011005723A patent/MX2011005723A/es active IP Right Grant
- 2009-11-30 KR KR1020117015243A patent/KR20110103991A/ko not_active Ceased
- 2009-11-30 CN CN200980155818.8A patent/CN102300881B/zh active Active
- 2009-11-30 JP JP2011537996A patent/JP5957224B2/ja active Active
- 2009-11-30 CA CA2745249A patent/CA2745249C/en active Active
- 2009-11-30 EP EP20090760533 patent/EP2373695B1/de active Active
- 2009-11-30 WO PCT/EP2009/066042 patent/WO2010063672A2/de not_active Ceased
- 2009-12-01 AR ARP090104631 patent/AR074443A1/es not_active Application Discontinuation
- 2009-12-02 TW TW98141178A patent/TW201028086A/zh unknown
- 2009-12-02 UY UY32284A patent/UY32284A/es unknown
-
2011
- 2011-05-31 IL IL213255A patent/IL213255A0/en unknown
-
2014
- 2014-10-21 US US14/519,307 patent/US20150105437A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| IL213255A0 (en) | 2011-07-31 |
| AU2009324248A1 (en) | 2011-06-23 |
| UA106218C2 (ru) | 2014-08-11 |
| WO2010063672A2 (de) | 2010-06-10 |
| EP2373695A2 (de) | 2011-10-12 |
| JP5957224B2 (ja) | 2016-07-27 |
| EP2373695B1 (de) | 2013-01-09 |
| TW201028086A (en) | 2010-08-01 |
| US20110237439A1 (en) | 2011-09-29 |
| US20150105437A1 (en) | 2015-04-16 |
| MX2011005723A (es) | 2011-07-29 |
| BRPI0917068A2 (pt) | 2016-02-16 |
| CN102300881A (zh) | 2011-12-28 |
| BRPI0917068B1 (pt) | 2019-07-02 |
| UY32284A (es) | 2010-06-30 |
| EA201100876A1 (ru) | 2012-01-30 |
| CN102300881B (zh) | 2015-04-08 |
| KR20110103991A (ko) | 2011-09-21 |
| WO2010063672A3 (de) | 2010-08-05 |
| CA2745249A1 (en) | 2010-06-10 |
| JP2012510534A (ja) | 2012-05-10 |
| CA2745249C (en) | 2017-01-10 |
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