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AR061824A1 - Metodo para soportar un material catalizador de sintesis de hidrocarburos - Google Patents

Metodo para soportar un material catalizador de sintesis de hidrocarburos

Info

Publication number
AR061824A1
AR061824A1 ARP070102995A ARP070102995A AR061824A1 AR 061824 A1 AR061824 A1 AR 061824A1 AR P070102995 A ARP070102995 A AR P070102995A AR P070102995 A ARP070102995 A AR P070102995A AR 061824 A1 AR061824 A1 AR 061824A1
Authority
AR
Argentina
Prior art keywords
catalyst material
substrate
catalyst
layer
supporting
Prior art date
Application number
ARP070102995A
Other languages
English (en)
Inventor
Gerardus Petrus Lambert Niesen
Marinus Johannes Reynhout
David Schaddenhorst
Abderrahmane Chettouf
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of AR061824A1 publication Critical patent/AR061824A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/395—Thickness of the active catalytic layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0228—Coating in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

Un método para soportar un material de catalizador de síntesis de hidrocarburos que incluye un metal catalíticamente activo y un material vehículo sobre un sustrato que incluye las etapas de: (a) aplicar material catalizador sobre el sustrato; y (b) calentar material catalizador para formar una capa de material catalizador fija al sustrato, con las siguientes características: el vehículo catalizador es un oxido refractario inorgánico poroso o su precursor; el material catalizador aplicado en la etapa (a) incluye 60 a 90% p de disolvente, calculado como peso total de capa de material catalizador; cuando se somete el material catalizador a la etapa de calentamiento (b) la misma incluye máxime 10% p de disolvente, calculada como el peso total de capa de material catalizador; en la etapa de calentamiento (b) se calienta el material catalizador a temperaturas en el rango de 250°C a 800°C; las fisuras con espesores submilimétricos se forman uniformemente en la capa; luego de la etapa (b) el material catalizador posee un espesor de 5 a 200 micrones. El control del fraccionamiento del material catalizador en el sustrato, especialmente la presencia de fisuras a distancias regulares de forma tal que existen capas de catalizador continuas en la superficie del sustrato, lo cual reduce la formacion de estrés.
ARP070102995A 2006-07-10 2007-07-05 Metodo para soportar un material catalizador de sintesis de hidrocarburos AR061824A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06116920 2006-07-10

Publications (1)

Publication Number Publication Date
AR061824A1 true AR061824A1 (es) 2008-09-24

Family

ID=37600796

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP070102995A AR061824A1 (es) 2006-07-10 2007-07-05 Metodo para soportar un material catalizador de sintesis de hidrocarburos

Country Status (7)

Country Link
US (1) US8518849B2 (es)
EP (1) EP2038058A2 (es)
AR (1) AR061824A1 (es)
AU (1) AU2007274365B2 (es)
MY (1) MY164481A (es)
WO (1) WO2008006786A2 (es)
ZA (1) ZA200810502B (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7741243B2 (en) * 2007-10-05 2010-06-22 Canon Kabushiki Kaisha Production method of catalyst layer
EP2341120A1 (en) * 2009-12-29 2011-07-06 Shell Internationale Research Maatschappij B.V. Coating method for structured catalysts
WO2011080198A2 (en) * 2009-12-29 2011-07-07 Shell Internationale Research Maatschappij B.V. Coating method for structured catalysts
US9844767B2 (en) * 2015-08-28 2017-12-19 Korea Institute Of Science And Technology Catalyst filter comprising nano metallic catalyst sprayed on the surface of support

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4595703A (en) * 1984-06-29 1986-06-17 Exxon Research And Engineering Co. Preparation of hydrocarbons from synthesis gas
US5204302A (en) * 1991-09-05 1993-04-20 Technalum Research, Inc. Catalyst composition and a method for its preparation
US5422331A (en) * 1994-02-25 1995-06-06 Engelhard Corporation Layered catalyst composition
KR100447463B1 (ko) * 1995-06-16 2004-10-14 쉘 인터내셔날 리써취 마트샤피지 비.브이. 탄화수소의제조를위한촉매및방법
US5985220A (en) * 1996-10-02 1999-11-16 Engelhard Corporation Metal foil having reduced permanent thermal expansion for use in a catalyst assembly, and a method of making the same
JP2003507161A (ja) * 1999-08-17 2003-02-25 バッテル・メモリアル・インスティチュート フィッシャー・トロプシュ合成の触媒構造及び方法
AU2001287603B2 (en) * 2000-07-25 2004-11-25 Shell Internationale Research Maatschappij B.V. A reactor comprising a packed bed of supported catalyst or supported catalyst precursor, and a use of the reactor
US7452844B2 (en) * 2001-05-08 2008-11-18 Süd-Chemie Inc High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis
US6713519B2 (en) * 2001-12-21 2004-03-30 Battelle Memorial Institute Carbon nanotube-containing catalysts, methods of making, and reactions catalyzed over nanotube catalysts
US7129194B2 (en) * 2004-09-23 2006-10-31 Corning Incorporated Catalyst system with improved corrosion resistance
EP1965918A1 (en) 2005-12-16 2008-09-10 Shell Internationale Research Maatschappij B.V. Process for preparing a hydrocarbon synthesis catalyst

Also Published As

Publication number Publication date
ZA200810502B (en) 2009-06-24
AU2007274365B2 (en) 2010-08-26
WO2008006786A3 (en) 2008-03-06
MY164481A (en) 2017-12-29
EP2038058A2 (en) 2009-03-25
AU2007274365A1 (en) 2008-01-17
WO2008006786A2 (en) 2008-01-17
US20090312179A1 (en) 2009-12-17
US8518849B2 (en) 2013-08-27

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