AR067286A1 - Proceso de craqueo catalitico para la produccion de diesel a partir de semillas de oleaginosas - Google Patents
Proceso de craqueo catalitico para la produccion de diesel a partir de semillas de oleaginosasInfo
- Publication number
- AR067286A1 AR067286A1 ARP080101293A ARP080101293A AR067286A1 AR 067286 A1 AR067286 A1 AR 067286A1 AR P080101293 A ARP080101293 A AR P080101293A AR P080101293 A ARP080101293 A AR P080101293A AR 067286 A1 AR067286 A1 AR 067286A1
- Authority
- AR
- Argentina
- Prior art keywords
- reactors
- diesel oil
- production
- cracking
- processes
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 8
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000002283 diesel fuel Substances 0.000 abstract 3
- 238000004231 fluid catalytic cracking Methods 0.000 abstract 3
- 238000005336 cracking Methods 0.000 abstract 2
- 235000013311 vegetables Nutrition 0.000 abstract 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 1
- 239000003225 biodiesel Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
- C10G3/55—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
- C10G3/57—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds according to the fluidised bed technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1014—Biomass of vegetal origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1048—Middle distillates
- C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1048—Middle distillates
- C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/307—Cetane number, cetane index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La presente comprende un proceso para craqueo termocatalítico, para la produccion de aceite diesel a partir de una carga de origen vegetal constituida de semillas de oleaginosas, en refinerías que tienen un mínimo de dos reactores de craqueo catalítico fluido (FCC). Al menos uno de los reactores procesa gas oil pesado o residuos en condiciones convencionales, mientras, que al menos uno de los reactores procesa la carga de origen vegetal constituida de semillas de oleaginosas, en condiciones adecuadas para la produccion de aceite diesel. El proceso utiliza el mismo catalizador utilizado en el proceso de craqueo catalítico fluido, el cual procesa simultáneamente carga convencional. El aceite diesel, o biodiesel, producido mediante dicho proceso tiene calidad superior, presenta numero de cetano mayor de 40, ya que las reacciones de craqueo se producen a temperaturas bajas y los productos obtenidos son menos oxidados y, en consecuencia, más puros que los productos obtenidos mediante la tecnología existente.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0702541-6A BRPI0702541A2 (pt) | 2007-06-21 | 2007-06-21 | processo de craqueamento catalÍtico para produÇço de diesel a partir de sementes de oleaginosas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR067286A1 true AR067286A1 (es) | 2009-10-07 |
Family
ID=39846829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP080101293A AR067286A1 (es) | 2007-06-21 | 2008-03-28 | Proceso de craqueo catalitico para la produccion de diesel a partir de semillas de oleaginosas |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8231777B2 (es) |
| EP (1) | EP2009079B1 (es) |
| AR (1) | AR067286A1 (es) |
| BR (1) | BRPI0702541A2 (es) |
| CA (1) | CA2635521C (es) |
| ES (1) | ES2827286T3 (es) |
| PT (1) | PT2009079T (es) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090077864A1 (en) * | 2007-09-20 | 2009-03-26 | Marker Terry L | Integrated Process of Algae Cultivation and Production of Diesel Fuel from Biorenewable Feedstocks |
| US7999143B2 (en) * | 2007-09-20 | 2011-08-16 | Uop Llc | Production of diesel fuel from renewable feedstocks with reduced hydrogen consumption |
| US7982078B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen |
| US7999142B2 (en) | 2007-09-20 | 2011-08-16 | Uop Llc | Production of diesel fuel from biorenewable feedstocks |
| US8003834B2 (en) * | 2007-09-20 | 2011-08-23 | Uop Llc | Integrated process for oil extraction and production of diesel fuel from biorenewable feedstocks |
| US7982075B2 (en) * | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with lower hydrogen consumption |
| US7982076B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks |
| US7915460B2 (en) * | 2007-09-20 | 2011-03-29 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with heat integration |
| US7982077B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen |
| US20090162264A1 (en) * | 2007-12-21 | 2009-06-25 | Mccall Michael J | Production of Aviation Fuel from Biorenewable Feedstocks |
| US8742183B2 (en) * | 2007-12-21 | 2014-06-03 | Uop Llc | Production of aviation fuel from biorenewable feedstocks |
| US8193399B2 (en) * | 2008-03-17 | 2012-06-05 | Uop Llc | Production of diesel fuel and aviation fuel from renewable feedstocks |
| US8198492B2 (en) | 2008-03-17 | 2012-06-12 | Uop Llc | Production of transportation fuel from renewable feedstocks |
| US8193400B2 (en) * | 2008-03-17 | 2012-06-05 | Uop Llc | Production of diesel fuel from renewable feedstocks |
| US8039682B2 (en) | 2008-03-17 | 2011-10-18 | Uop Llc | Production of aviation fuel from renewable feedstocks |
| US8058492B2 (en) | 2008-03-17 | 2011-11-15 | Uop Llc | Controlling production of transportation fuels from renewable feedstocks |
| CN102057019B (zh) * | 2008-04-06 | 2014-07-02 | 环球油品公司 | 来自生物质衍生热解油的燃料和混合燃料成分 |
| US8329968B2 (en) * | 2008-04-06 | 2012-12-11 | Uop Llc | Production of blended gasoline aviation and diesel fuels from renewable feedstocks |
| US8324438B2 (en) * | 2008-04-06 | 2012-12-04 | Uop Llc | Production of blended gasoline and blended aviation fuel from renewable feedstocks |
| US8329967B2 (en) * | 2008-04-06 | 2012-12-11 | Uop Llc | Production of blended fuel from renewable feedstocks |
| US8304592B2 (en) * | 2008-06-24 | 2012-11-06 | Uop Llc | Production of paraffinic fuel from renewable feedstocks |
| US8766025B2 (en) | 2008-06-24 | 2014-07-01 | Uop Llc | Production of paraffinic fuel from renewable feedstocks |
| US20090321311A1 (en) * | 2008-06-27 | 2009-12-31 | Uop Llc | Production of diesel fuel from renewable feedstocks containing phosphorus |
| US7982079B2 (en) | 2008-09-11 | 2011-07-19 | Uop Llc | Integrated process for production of diesel fuel from renewable feedstocks and ethanol denaturizing |
| US8921627B2 (en) * | 2008-12-12 | 2014-12-30 | Uop Llc | Production of diesel fuel from biorenewable feedstocks using non-flashing quench liquid |
| US8471079B2 (en) * | 2008-12-16 | 2013-06-25 | Uop Llc | Production of fuel from co-processing multiple renewable feedstocks |
| US8283506B2 (en) * | 2008-12-17 | 2012-10-09 | Uop Llc | Production of fuel from renewable feedstocks using a finishing reactor |
| US8314274B2 (en) * | 2008-12-17 | 2012-11-20 | Uop Llc | Controlling cold flow properties of transportation fuels from renewable feedstocks |
| US8471081B2 (en) | 2009-12-28 | 2013-06-25 | Uop Llc | Production of diesel fuel from crude tall oil |
| US8900443B2 (en) | 2011-04-07 | 2014-12-02 | Uop Llc | Method for multi-staged hydroprocessing using quench liquid |
| WO2012139181A1 (pt) * | 2011-04-15 | 2012-10-18 | Petróleo Brasileiro S.A. - Petrobas | Processo de fcc para a maximização de diesel utilizando dois conversores distintos |
| JP6262749B2 (ja) | 2012-10-19 | 2018-01-17 | サウジ アラビアン オイル カンパニー | 原油の高過酷度接触分解方法 |
| US20140163285A1 (en) | 2012-12-10 | 2014-06-12 | Exxonmobil Research And Engineering Company | Catalytic cracking process for biofeeds |
| US9527054B2 (en) * | 2014-05-09 | 2016-12-27 | Uop Llc | Apparatuses and methods for cracking hydrocarbons |
| EP4361281A3 (en) | 2014-07-03 | 2024-08-21 | The Fynder Group, Inc. | Acidophilic fusarium oxysporum strains, methods of their production and methods of their use |
| EP3423561B2 (en) | 2016-03-01 | 2024-02-28 | The Fynder Group, Inc. | Filamentous fungal biomats, methods of their production and methods of their use |
| MX2017010802A (es) | 2017-08-23 | 2019-03-07 | Mexicano Inst Petrol | Proceso y catalizador zeolitico para la desintegracion catalitica de crudo ligero no convencional tipo shale/tight oil y mezclas con gasoleo de vacio. |
| PH12023550290A1 (en) | 2017-08-30 | 2024-06-24 | The Fynder Group Inc | Edible composition with filamentous fungi and bioreactor system for the cultivation thereof |
| KR20210134354A (ko) | 2019-02-27 | 2021-11-09 | 더 파인더 그룹, 인크. | 사상 진균 입자를 포함하는 식품 재료 및 막 바이오반응기 디자인 |
| KR20220024666A (ko) | 2019-06-18 | 2022-03-03 | 더 파인더 그룹, 인크. | 진균 직물 재료 및 가죽 유사체 |
| US12152202B2 (en) | 2022-12-29 | 2024-11-26 | ExxonMobil Technology and Engineering Company | FCC processing with reduced CO2 emissions |
| US12195676B2 (en) | 2022-12-29 | 2025-01-14 | ExxonMobil Technology and Engineering Company | FCC processing with reduced CO2 emissions |
| US12516251B2 (en) | 2023-08-04 | 2026-01-06 | ExxonMobil Technology and Engineering Company | Oxygen fired FCC regenerator with CO2 capture |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR8304794A (pt) | 1983-09-02 | 1985-04-09 | Petroleo Brasileiro Sa | Processo para a producao de gasolina de lata octanagem |
| EP1230003A2 (en) * | 1999-06-01 | 2002-08-14 | Astion Development APS | A method of producing organic emulsifiers and organic surfactants, products produced by said method, and the use of such products |
| GB0003111D0 (en) | 2000-02-10 | 2000-03-29 | Novartis Ag | Organic compounds |
| US7612221B2 (en) * | 2002-04-02 | 2009-11-03 | The United States Of America As Represented By The Secretary Of Agriculture | Production of fatty acid alkyl esters |
| US7112229B2 (en) | 2003-07-18 | 2006-09-26 | Petroleo Brasileiro S.A. -Petrobras | Process for producing biodiesel fuel using triglyceride-rich oleagineous seed directly in a transesterification reaction in the presence of an alkaline alkoxide catalyst |
| DE10339957B3 (de) | 2003-08-25 | 2005-01-13 | Peiner Träger GmbH | Doppel-T-förmiges Spundwandprofil aus Stahl und Werkzeug zur Herstellung des Spundwandprofils |
| BRPI0500591A (pt) * | 2005-02-18 | 2006-10-03 | Petroleo Brasileiro Sa | processo para a hidroconversão de óleos vegetais |
| BRPI0502577B1 (pt) * | 2005-07-07 | 2015-11-03 | Petroleo Brasileiro Sa | processo de craqueamento catalítico para produção de diesel a partir de óleos vegetais |
| JP2009526114A (ja) * | 2006-02-09 | 2009-07-16 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 流動接触分解方法 |
-
2007
- 2007-06-21 BR BRPI0702541-6A patent/BRPI0702541A2/pt not_active Application Discontinuation
-
2008
- 2008-03-28 AR ARP080101293A patent/AR067286A1/es active IP Right Grant
- 2008-06-17 US US12/213,296 patent/US8231777B2/en active Active
- 2008-06-20 PT PT82521444T patent/PT2009079T/pt unknown
- 2008-06-20 EP EP08252144.4A patent/EP2009079B1/en active Active
- 2008-06-20 ES ES08252144T patent/ES2827286T3/es active Active
- 2008-06-20 CA CA2635521A patent/CA2635521C/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20080313955A1 (en) | 2008-12-25 |
| BRPI0702541A2 (pt) | 2009-02-10 |
| CA2635521C (en) | 2014-08-19 |
| ES2827286T3 (es) | 2021-05-20 |
| PT2009079T (pt) | 2020-09-01 |
| EP2009079A2 (en) | 2008-12-31 |
| CA2635521A1 (en) | 2008-12-21 |
| US8231777B2 (en) | 2012-07-31 |
| EP2009079B1 (en) | 2020-08-19 |
| EP2009079A3 (en) | 2009-01-14 |
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