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AR067116A1 - Compuestos derivados de piperazina utiles como agentes herbicidas y procedimiento para combatir el crecimiento indeseado de plantas. - Google Patents

Compuestos derivados de piperazina utiles como agentes herbicidas y procedimiento para combatir el crecimiento indeseado de plantas.

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AR067116A1
AR067116A1 ARP080102673A ARP080102673A AR067116A1 AR 067116 A1 AR067116 A1 AR 067116A1 AR P080102673 A ARP080102673 A AR P080102673A AR P080102673 A ARP080102673 A AR P080102673A AR 067116 A1 AR067116 A1 AR 067116A1
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Argentina
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alkyl
alkynyl
alkenyl
cycloalkyl
cycloalkenyl
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Basf Se
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/52—Two oxygen atoms
    • C07D239/54—Two oxygen atoms as doubly bound oxygen atoms or as unsubstituted hydroxy radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/48—Two nitrogen atoms
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    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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    • C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07D471/12—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains three hetero rings
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    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/10—Spiro-condensed systems

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Reivindicacion 1: Compuestos de piperazina de la formula 1 caracterizados porque A1, A2 son, de modo independiente entre sí, arilo o heteroarilo, en donde Ra está unido en posicion orto respecto del sitio de union de A1 con un átomo de C o átomo de N de A1, Y1 es oxigeno, azufre o un grupo NRi1, en donde Ri1 está seleccionado de hidrogeno, alquilo C1-6, alquenilo C3-6, alquinilo C3-6, cicloalquilo C3-6, cicloalquil C3-6-metilo, OH, alcoxi C1-6, alquenil C3-6-oxi, alquinil C3-6-oxi, cicloalcoxi C3-6 y cicloalquil C3-6-metoxi; Y2 es oxigeno, azufre o un grupo NRi2, en donde Ri2 está seleccionado de hidrogeno, alquilo C1-6, alquenilo C3-6, alquinilo C3-6, cicloalquilo C3-6, cicloalquil C3-6-metilo, OH, alcoxi C1-6, alquenil C3-6-oxi, alquinil C3-6-oxi, cicloalcoxi C3-6 y cicloalquil C3-6-metoxi; en donde las partes alifáticas o cíclicas mencionadas de los sustituyentes Y1 e Y2 no están sustituidas, pueden estar parcial o completamente halogenadas y/o pueden llevar uno a tres de los siguientes grupos: ciano, hidroxi, alquilo C1-4, halogenalquilo C1-4, cicloalquilo C3-6, alcoxi C1-4, alquil C1-4-tio, di-(alquil C1-4)-amino, alquil C1-4-carbonilo, hidroxicarbonilo, alcoxi C1-4-carbonilo, aminocarbonilo, alquil C1-4-aminocarbonilo, di-(alquil C1-4)aminocarbonilo o alquil C1-4-carboniloxi; Ra está seleccionado de halogeno, ciano, nitro, SF5, alquilo C1-6, cicloalquilo C3-6, alquenilo C2--6, cicloalquenilo C5-8, cicloalquinilo C5-8, cicloalquil C3-6-alquilo C1-6, cicloalquenil C5-8-alquilo C1-6, cicloalquinil C5-8-alquilo C1-6, cicloalquil C3-6-alquenilo C2-6, cicloalquenil C5-8-alquenilo C2-6, cicloalquinil C5-8-alquenilo C2-6, cicloalquil C3-6-alquinilo C2-6, cicloalquenil C5-8-alquinilo C2-6, cicloalquinil C5-8-alquinilo C2-6, alcadienilo C4-10, alquinilo C2-6, [tri-alquil (C1-6)-silil]-alquinilo C2-6, tri-alquil C1-6-sililo, cicloalquinilo C7-8, arilo, fenil-alquilo C1-6, fenil-alquenilo C2-6, fenil-alquinilo C2-6, fenilsulfonil-alquilo C1-6, heterociclilo, heterociclil-alquilo C1-6, heterociclil-alquenilo C2-6, heterociclil-alquinilo C2-6, fenil-[alcoxi C1-6-carbonil]-alquilo C1-6, Z1P(O)(OR9)2, Z1P(O)(OR9)(R9a), Z2B(OR10)2, Z3COR11, Z4NR12R13, Z5CH=N-O-R14, Z6OR15, Z7SR16, Z7S(O)R16 y Z7SO2R16, en donde las partes alifáticas, cíclicas o aromáticas mencionadas del sustituyente Ra no están sustituidas, pueden estar parcial o completamente halogenadas y/o pueden llevar uno a tres de los siguientes grupos: ciano, hidroxi, alquilo C1-4, halogenalquilo C1-4, cicloalquilo C3-6, alcoxi C1-4, alquil C1-4-tio, di-(alquil C1-4)-amino, alquil C1-4-carbonilo, hidroxicarbonilo, alcoxi C1-4-carbonilo, aminocarbonilo, alquil C1-4-aminocarbonilo, di-(alquil C1-4)aminocarbonilo o alquil C1-4-carboniloxi; Rb, Rc, Rd, Re y Rf representan en cada caso, de modo independiente entre sí, hidrogeno o presentan uno de los significados indicados para Ra; y en donde dos radicales Ra unidos a átomos de anillo adyacentes, de A1, Rb o Rc o dos radicales Rd unidos a átomos de anillo adyacentes de A2, Re o Rf también pueden ser alquileno C3-6, que puede ser parcial o totalmente halogenado y que puede llevar uno a tres de los siguientes grupos: ciano, hidroxi, alquilo C1-4, halogenalquilo C1-4, cicloalquilo C3-6, alcoxi C1-4, alquil C1-4-tio, di-(alquil C1-4)-amino, alquil C1-4-carbonilo, hidroxicarbonilo, alcoxi C1-4-carbonilo, aminocarbonilo, alquil C1-4-aminocarbonilo, di-(alquil C1-4)aminocarbonilo o alquil C1-4-carboniloxi; en donde un grupo CH2 en alquileno C3-6 puede estar reemplazado por un grupo carbonilo, un grupo tiocarbonilo o sulfonilo y en donde uno o dos grupos CH2 no adyacentes en alquileno C3-6 pueden estar reemplazados, en cada caso, por oxígeno, azufre o un grupo NR34, en donde R34 presenta uno de los significados indicados para R12; R1 y R2 están seleccionados, de modo independiente entre sí, de: ciano, alquilo C1-6, cicloalquilo C3-6, alquenilo C3-6, cicloalquenilo C5-8, alquinilo C3-6, cicloalquinilo C7-8, cicloalquil C3-6-alquilo C1-6, cicloalquenil C5-8-alquilo C1-6, cicloalquinil C5-8-alquilo C1-6, cicloalquil C3-6-alquenilo C2-6, cicloalquenil C5-8-alquenilo C2-6, cicloalquinil C3-6-alquenilo C2-6, cicloalquil C3-6-alquinilo C2-6, cicloalquenil C5-8-alquinilo C2-6, cicloalquinil C5-8-alquinilo C2-6, fenilo, fenil-alquilo C1-6, fenil-alquenilo C2-6, fenil-alquinilo C2-6, heterociclilo, heterociclil-alquilo C1-6, heterociclil-alquenilo C2-6, heterociclil-alquinilo C2-6, fenil-[alcoxi C1-6-carbonil]-alquilo C1-6, C(O)R21, NR22R23, OR24, SR24, S(O)R25, SO2R25 y Si(R25a)3; en donde R1 puede significar adicionalmente hidrogeno, y en donde las partes alifáticas, cíclicas o aromáticas mencionadas de los sustituyentes R1 y R2 de modo independiente entre sí no están sustituidas, pueden estar parcial o completamente halogenadas y/o pueden llevar uno a tres de los siguientes grupos: ciano, hidroxi, alquilo C1-4, halogenalquilo C1-4, cicloalquilo C3-6, alcoxi C1-4, alquil C1-4-tio, di-(alquil C1-4)-amino, alquil C1-4-carbonilo, hidroxicarbonilo, alcoxi C1-4-carbonilo, aminocarbonilo, alquil C1-4-aminocarbonilo, di-(alquil C1-4)aminocarbonilo o alquil C1-4-carboniloxi; R3 es halogeno, ciano, nitro o un radical R26, OR27, SR28, S(O)R28, SO2R28, NR29R30 o N(OR31)R32; R4 es hidrogeno, halogeno, ciano, alquilo C1-6, cicloalquilo C3-6, alquenilo C2-6, cicloalquenilo C5-8, alquinilo C2-6, cicloalquinilo C5-8, fenilo, fenil-alquilo C1-6, heterociclilo, heterociclil-alquilo C1-6, fenil-[alcoxi C1-6-carbonil]-alquilo C1-6, o un radical COR21, OR27, SR28, S(O)R28, SO2R26, NR29R30 o N(OR31)R32, en donde las partes alifáticas, cíclicas o aromáticas mencionadas del sustituyente R4 de modo independiente entre si no están sustituidas, pueden estar parcial o completamente halogenadas y/o pueden llevar uno a tres de los siguientes grupos: ciano, hidroxi, alquilo C1-4, halogenalquilo C1-4, cicloalquilo C3-6, alcoxi C1-4, alquil C1-4-tio, di-(alquil C1-4)-amino, alquil C1-4-carbonilo, hidroxicarbonilo, alcoxi C1-4-carbonilo, aminocarbonilo, alquil C1-4-aminocarbonilo, di-(alquil C1-4)aminocarbonilo o alquil C1-4-carboniloxi; R5 es hidrogeno, halogeno, ciano, nitro, hidroxi, alquilo C1-8, alquenilo C2-8, cicloalquilo C3-8, cicloalquenilo C5-8, alquinilo C2-8, alcadienilo C4-8, cicloalquinilo C7-8, cicloalquenil C5-8-alquilo C1-6, cicloalquinil C5-8-alquilo C1-6, cicloalquil C3-6-alquenilo C2-6, cicloalquenil C5-8-alquenilo C2-6, cicloalquinil C5-8-alquenilo C2-6, cicloalquil C3-6-alquinilo C2-6, cicloalquenil C5-8-alquinilo C2-6, cicloalquinil C5-8-alquinilo C2-6, tri-alquil C1-6-sililo, [tri-alquil C1-6-silil]-alquinilo C2-6, fenilo, fenil-alquilo C1-6, fenil-alquenilo C2-6, fenil-alquinilo C2-6, heterociclilo, heterociclil-alquilo C1-6, heterociclilalquenilo C2-6, heterociclil-alquinilo C2-6, fenil-[alcoxi C1-6-carbonil]-alquilo C1-6, C(O)R61, Z8NR62R63, Z11CH=N-O-R64, OR65, Z9SR65a, Z9S(O)R66, Z9S(O)2R66 o Z10P(O)(OR67)2; o R3 junto con R5 es un enlace químico; R6 es halogeno, ciano, nitro, alquenilo C2-8, cicloalquilo C3-8, cicloalquenilo C5-8, alquinilo C2-8, alcadienilo C4-8, cicloalquinilo C7-8, cicloalquenil C5-8-alquilo C1-6, cicloalquinil C5-8-alquilo C1-6, cicloalquil C3-6-alquenilo C2-6, cicloalquenil C5-8-alquenilo C2-6, cicloalquinil C5-8-alquenilo C2-6, cicloalquil C3-6-alquinilo C2-6, cicloalquenil C5-8-alquinilo C2-8, cicloalquinil C5-8-alquinilo C2-6, tri-alquil C1-6-sililo, [tri-alquil C1-6-silil]-alquinilo C2-6, fenilo, fenil-alquilo C1-6, fenil-alquenilo C2-6, fenil-alquinilo C2-6, heterociclilo, heterociclil-alquilo C1-6, heterociclil-alquenilo C2-6, heterociclil-alquinilo C2-6, fenil-[alcoxi C1-6--carbonil]-alquilo C1-6, C(O)R61, Z8NR62R63, Z11CH=N-O-R64, OR65, Z9SR65a, Z9S(O)R66, Z9S(O)2R66 o Z10P(O)(OR67)2; en donde las partes alifáticas, cíclicas o aromáticas mencionadas de los sustituyentes R4, R5 y R6 de modo independiente entre sí pueden estar parcial o completamente halogenadas y/o pueden llevar uno a tres de los siguientes grupos: ciano, hidroxi, alquilo C1-4, halogenalquilo C1-4, cicloalquilo C3-6, alcoxi C1-4, alquil C1-4-tio, di-(alquil C1-4)-amino, alquil C1-4-carbonilo, hidroxicarbonilo, alcoxi C1-4-carbonilo, aminocarbonilo, alquil C1-4-aminocarbonilo, di-(alquil C1-4)aminocarbonilo o alquil C1-4-carboniloxi; R7 es halogeno, ciano, nitro o un radical R26, OR27, SR28, S(O)R28, SO2R28, NR29R30 o N(OR31)R32; R8 presenta uno de los significados indicados para R4; R9, R10 y R67 son de modo independiente entre si, hidrogeno o alquilo C1-6 y R10 en Z2B(OR10)2 pueden formar juntos una cadena de alquileno C2-4; o R9a es alquilo C1-6; R11, R61 son, de modo independiente entre si, hidrogeno, alquilo C1-6, cicloalquilo C3-6, alquenilo C2-6, cicloalquenilo C5-8, alquinilo C2-6, cicloalquinilo C7-8, hidroxi, alcoxi C1-6, alquenil C3-6-oxi, alquinil C3-6-oxi, amino, alquil C1-6-amino, di-(alquil C1-6)amino, alcoxi C1-6-amino, di-(alcoxi C1-6)amino, alquil C1-6-sulfonilamino, alquil C1-6aminosulfonilamino, [di-(aIquil C1-6)amino]sulfonilamino, alquenil C3-6-amino, alquinil C3-6-amino, N-(alquenil C2-6)-N-(alquil C1-6)-amino, N-(alquinil C2-6)-N-(alquil C1-6)-amino, N-(alcoxi C1-6)-N-(alquil C1-6)-amino, N-(alquenil C2-6)-N-(alcoxi C1-6)-amino, N-(alquinil C2-6)-N-(alcoxi C1-6)-amino, fenilo, fenoxi, fenilamino, naftilo o heterociclilo, R12 y R62 son, de modo independiente entre sí, hidrogeno, alquilo C1-6, alcoxi C1-6, cicloalquilo C3-6, cicloalquil C3-6-oxi, alquenilo C3-6, alquenil C3-6-oxi, cicloalquenilo C5-8, alquinilo C3-6, alquinil C3-6-oxi, cicloalquinilo C7-8, alquil C1-6-carbonilo, cicloalquil C3-6-carbonilo, di-(alquil C1-6)aminocarbonilo, alcoxi C1-6-carbonilo, alcoxi C1-6-carbonil-alquilo C1-6, alquil C1-6-sulfonilo, alquil C1-6-aminosulfonilo, di-(alquil C1-6)aminosulfonilo, fenilcarbonilo, fenilaminocarbonilo, fenilsulfonilo, fenilsulfonilaminocarbonilo o heterociclilcarbonilo; R13 y R63 son, de modo independiente entre si, hidrogeno, alquilo C1-6, cicloalquilo C3-6, alquenilo C3-6, cicloalquenilo C5-8, alquinilo C3-6,
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Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8097712B2 (en) 2007-11-07 2012-01-17 Beelogics Inc. Compositions for conferring tolerance to viral disease in social insects, and the use thereof
KR20110080178A (ko) * 2008-10-31 2011-07-12 바스프 에스이 제초 효과를 갖는 피페라진 화합물
US8962584B2 (en) 2009-10-14 2015-02-24 Yissum Research Development Company Of The Hebrew University Of Jerusalem, Ltd. Compositions for controlling Varroa mites in bees
ES2641642T3 (es) 2010-03-08 2017-11-10 Monsanto Technology Llc Moléculas de polinucleótido para regulación génica en plantas
US10760086B2 (en) 2011-09-13 2020-09-01 Monsanto Technology Llc Methods and compositions for weed control
BR112014005795A2 (pt) 2011-09-13 2020-12-08 Monsanto Technology Llc métodos de controle de plantas, de redução da expressão de um gene de hppd de uma planta, de preparação de um nucleotídeo, e de identificação de polinucleotídeos úteis na modulação da expressão do gene de hppd no tratamento externo de uma planta, composições e cassete de expressão microbiana
BR112014005958A2 (pt) 2011-09-13 2020-10-13 Monsanto Technology Llc métodos e composições químicas agrícolas para controle de planta, método de redução de expressão de um gene accase em uma planta, cassete de expressão microbiana, método para fazer um polinucleotídeo, método de identificação de polinucleotídeos úteis na modulação de expressão do gene accase e composição herbicida
CA2848669A1 (en) 2011-09-13 2013-03-21 Monsanto Technology Llc Methods and compositions for weed control targeting epsps
AR087862A1 (es) 2011-09-13 2014-04-23 Monsanto Technology Llc Metodos y composiciones para el control de malezas
WO2013040057A1 (en) 2011-09-13 2013-03-21 Monsanto Technology Llc Methods and compositions for weed control
UY34328A (es) 2011-09-13 2013-04-30 Monsanto Technology Llc ?composiciones y métodos para controlar malezas comprendiendo un polinucleótido y agente de transferencia, y que modulan protoporfirinógeno ix oxidasa?.
US10829828B2 (en) 2011-09-13 2020-11-10 Monsanto Technology Llc Methods and compositions for weed control
US10806146B2 (en) 2011-09-13 2020-10-20 Monsanto Technology Llc Methods and compositions for weed control
CN107739737A (zh) 2011-09-13 2018-02-27 孟山都技术公司 用于杂草控制的方法和组合物
IN2014MN02404A (es) 2012-05-24 2015-08-21 Seeds Ltd Ab
US10683505B2 (en) 2013-01-01 2020-06-16 Monsanto Technology Llc Methods of introducing dsRNA to plant seeds for modulating gene expression
EA032406B1 (ru) 2013-01-01 2019-05-31 Эй.Би. СИДЗ ЛТД. СПОСОБЫ ВВЕДЕНИЯ дсРНК В СЕМЕНА РАСТЕНИЙ ДЛЯ МОДУЛЯЦИИ ЭКСПРЕССИИ ГЕНОВ
WO2014164761A1 (en) 2013-03-13 2014-10-09 Monsanto Technology Llc Methods and compositions for weed control
CA2905104A1 (en) 2013-03-13 2014-10-09 Monsanto Technology Llc Control of lolium species by topical application of herbicidal composition comprising dsrna
US10568328B2 (en) 2013-03-15 2020-02-25 Monsanto Technology Llc Methods and compositions for weed control
US9850496B2 (en) 2013-07-19 2017-12-26 Monsanto Technology Llc Compositions and methods for controlling Leptinotarsa
PL3030663T3 (pl) 2013-07-19 2020-04-30 Monsanto Technology Llc Kompozycje i sposoby kontroli leptinotarsa
UY35817A (es) 2013-11-04 2015-05-29 Us Agriculture ?composiciones y métodos para controlar infestaciones de plagas y parásitos de los artrópodos?.
UA119253C2 (uk) 2013-12-10 2019-05-27 Біолоджикс, Інк. Спосіб боротьби із вірусом у кліща varroa та у бджіл
AR099092A1 (es) 2014-01-15 2016-06-29 Monsanto Technology Llc Métodos y composiciones para el control de malezas utilizando polinucleótidos epsps
EP3420809A1 (en) 2014-04-01 2019-01-02 Monsanto Technology LLC Compositions and methods for controlling insect pests
US10988764B2 (en) 2014-06-23 2021-04-27 Monsanto Technology Llc Compositions and methods for regulating gene expression via RNA interference
US11807857B2 (en) 2014-06-25 2023-11-07 Monsanto Technology Llc Methods and compositions for delivering nucleic acids to plant cells and regulating gene expression
CN114009454A (zh) 2014-07-29 2022-02-08 孟山都技术公司 用于控制昆虫害虫的组合物和方法
US10118890B2 (en) 2014-10-10 2018-11-06 The Research Foundation For The State University Of New York Trifluoromethoxylation of arenes via intramolecular trifluoromethoxy group migration
CN108064288B (zh) 2015-01-22 2021-11-26 孟山都技术公司 用于控制叶甲属的组合物和方法
AU2016270870A1 (en) 2015-06-02 2018-01-04 Monsanto Technology Llc Compositions and methods for delivery of a polynucleotide into a plant
WO2016196782A1 (en) 2015-06-03 2016-12-08 Monsanto Technology Llc Methods and compositions for introducing nucleic acids into plants
WO2017025031A1 (zh) * 2015-08-10 2017-02-16 于跃 一种抗病毒活性双氮氧杂环螺二酮哌嗪生物碱衍生物及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6372604A (ja) * 1986-09-12 1988-04-02 Teijin Ltd 植物に対する抗薬害組成物および抗薬害方法
CN1321130C (zh) * 2004-01-13 2007-06-13 浙江大学 环二肽类化合物的生物制备方法及用途
AR058408A1 (es) * 2006-01-02 2008-01-30 Basf Ag Compuestos de piperazina con accion herbicida
DE502007003395D1 (de) * 2006-01-05 2010-05-20 Basf Se Piperazinverbindungen mit herbizider wirkung

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