AR064514A1 - CATALYTIC SYSTEM OF CHLORID HYDRATION AND PROCEDURE OF MANUFACTURE OF VINYL CHLORIDE FROM ACETYLENE AND CHLORID HYDROGEN IN THE PRESENCE OF THAT CATALYTIC SYSTEM - Google Patents
CATALYTIC SYSTEM OF CHLORID HYDRATION AND PROCEDURE OF MANUFACTURE OF VINYL CHLORIDE FROM ACETYLENE AND CHLORID HYDROGEN IN THE PRESENCE OF THAT CATALYTIC SYSTEMInfo
- Publication number
- AR064514A1 AR064514A1 ARP070105880A ARP070105880A AR064514A1 AR 064514 A1 AR064514 A1 AR 064514A1 AR P070105880 A ARP070105880 A AR P070105880A AR P070105880 A ARP070105880 A AR P070105880A AR 064514 A1 AR064514 A1 AR 064514A1
- Authority
- AR
- Argentina
- Prior art keywords
- chlorid
- catalytic system
- vinyl chloride
- acetylene
- hydration
- Prior art date
Links
- -1 CHLORID HYDROGEN Chemical class 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title abstract 4
- HSFWRNGVRCDJHI-UHFFFAOYSA-N Acetylene Chemical compound C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 title abstract 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title 1
- 230000036571 hydration Effects 0.000 title 1
- 238000006703 hydration reaction Methods 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 title 1
- 239000001257 hydrogen Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 150000003058 platinum compounds Chemical class 0.000 abstract 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 abstract 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 238000007038 hydrochlorination reaction Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000001119 stannous chloride Substances 0.000 abstract 1
- 235000011150 stannous chloride Nutrition 0.000 abstract 1
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
- B01J31/30—Halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Sistema catalítico de clorhidratacion que comprende al menos un clorhidrato de amina y al menos un compuesto de un metal del grupo VIII elegido entre el grupo constituido por las mezclas de un compuesto de platino (IV) con el cloruro de estano (II), las mezclas de un compuesto de platino (II) con el oxido de trifenilfosfina y las mezclas de un compuesto de paladio (II) con la trifenilfosfina. Ese sistema catalítico es conveniente para la preparacion del cloruro de vinilo por reaccion del acetileno con el ácido clorhídrico.Catalytic hydrochlorination system comprising at least one amine hydrochloride and at least one compound of a group VIII metal selected from the group consisting of mixtures of a platinum compound (IV) with stannous chloride (II), mixtures of a platinum (II) compound with triphenylphosphine oxide and mixtures of a palladium (II) compound with triphenylphosphine. This catalytic system is convenient for the preparation of vinyl chloride by reacting acetylene with hydrochloric acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0611356A FR2910350B1 (en) | 2006-12-22 | 2006-12-22 | CATALYTIC HYDROCHLORIZATION SYSTEM AND PROCESS FOR PRODUCING VINYL CHLORIDE FROM ACETYLENE AND HYDROGEN CHLORIDE IN THE PRESENCE OF THIS CATALYTIC SYSTEM |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR064514A1 true AR064514A1 (en) | 2009-04-08 |
Family
ID=38255551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP070105880A AR064514A1 (en) | 2006-12-22 | 2007-12-21 | CATALYTIC SYSTEM OF CHLORID HYDRATION AND PROCEDURE OF MANUFACTURE OF VINYL CHLORIDE FROM ACETYLENE AND CHLORID HYDROGEN IN THE PRESENCE OF THAT CATALYTIC SYSTEM |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20100063333A1 (en) |
| EP (1) | EP2101916A1 (en) |
| CN (1) | CN101605604A (en) |
| AR (1) | AR064514A1 (en) |
| AU (1) | AU2007338081A1 (en) |
| BR (1) | BRPI0720929A2 (en) |
| CO (1) | CO6210696A2 (en) |
| FR (1) | FR2910350B1 (en) |
| MX (1) | MX2009006776A (en) |
| RU (1) | RU2009128222A (en) |
| TW (1) | TW200835553A (en) |
| WO (1) | WO2008077868A1 (en) |
| ZA (1) | ZA200904659B (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102267868B (en) * | 2010-06-01 | 2013-06-19 | 滨化集团股份有限公司 | Industrial production apparatus for trichloroethylene |
| TW201236758A (en) | 2010-12-22 | 2012-09-16 | Solvay | Catalytic system and its use for the manufacture of vinyl chloride by hydrochlorination of acetylene |
| EA024478B1 (en) | 2010-12-22 | 2016-09-30 | Солвей Са | Catalytic system and its use for the manufacture of vinyl chloride by hydrochlorination of acetylene |
| TW201228725A (en) | 2010-12-22 | 2012-07-16 | Solvay | Catalytic system and its use for the manufacture of vinyl chloride by hydrochlorination of acetylene |
| CN107417487A (en) | 2011-02-24 | 2017-12-01 | 索维公司 | Method for hydrohalogenation alkynes and for manufacturing chlorination alkene by the hydrochlorination of alkynes |
| CN102266784B (en) * | 2011-06-07 | 2013-02-27 | 李伟 | Preparation method for and application of novel load type composite metal catalyst |
| CN102380407B (en) * | 2011-08-25 | 2013-11-20 | 成都惠恩精细化工有限责任公司 | Low-mercury catalyst for acetylene hydrochlorination |
| EP2617698A1 (en) * | 2012-06-27 | 2013-07-24 | Solvay Sa | Process for the hydrohalogenation of an unsaturated hydrocarbon and for the manufacture of vinyl chloride by hydrochlorination of acetylene |
| CN103623839B (en) * | 2012-08-24 | 2015-12-09 | 天津市天地创智科技发展有限公司 | The Ru-Ni-Cu catalyst of acetylene hydrochlorination synthesizing chloroethylene |
| CN103623836B (en) * | 2012-08-24 | 2015-12-02 | 天津大学 | The Ru-Pt-Ni catalyst of acetylene hydrochlorination synthesizing chloroethylene |
| CN108503504A (en) * | 2017-08-02 | 2018-09-07 | 毛艳慧 | A kind of Vinyl Chloride Production System and method of combination carbide and high-temperature chlorination |
| CN108993595B (en) * | 2018-06-27 | 2021-04-23 | 厦门中科易工化学科技有限公司 | Copper-based catalyst for synthesizing vinyl chloride by hydrochlorinating acetylene and preparation method and application thereof |
| CN115608359B (en) * | 2021-07-16 | 2024-04-05 | 中国科学院大连化学物理研究所 | A copper catalyst and its preparation method and application |
| CN115382579B (en) * | 2022-09-01 | 2023-07-07 | 贵州重力科技环保股份有限公司 | Acetylene copper chloride catalyst and preparation method and application thereof |
| CN117299213B (en) * | 2023-09-06 | 2025-09-26 | 贵研工业催化剂(云南)有限公司 | A platinum complex catalyst, its preparation method and application, and a method for preparing vinyl chloride by acetylene hydrochlorination |
| CN117599823A (en) * | 2023-10-20 | 2024-02-27 | 内蒙古圣龙大地科技有限公司 | A mercury-free catalyst and its preparation method and application |
| CN117772289B (en) * | 2023-12-28 | 2026-01-23 | 贵州重力科技环保股份有限公司 | Acetylene copper chloride complex catalyst, preparation method and application |
| EP4596102A1 (en) | 2024-02-01 | 2025-08-06 | Johnson Matthey Public Limited Company | Platinum containing catalyst, method of preparation, and use |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3824634A1 (en) * | 1988-04-30 | 1989-11-09 | Huels Chemische Werke Ag | METHOD FOR PRODUCING VINYL CHLORIDE BY REACTIVATING ACETYLENE WITH HYDROCHLORINE |
| BE1004983A3 (en) * | 1991-06-20 | 1993-03-09 | Solvay | CATALYST SYSTEM AND METHOD hydrochlorination CHLORIDE PRODUCTION START IN VINYL CHLORIDE ACETYLENE AND HYDROGEN IN THE PRESENCE OF THIS SYSTEM CATALYST. |
| BE1004984A3 (en) * | 1991-06-20 | 1993-03-09 | Solvay | CATALYST SYSTEM AND METHOD hydrochlorination CHLORIDE PRODUCTION START IN VINYL CHLORIDE ACETYLENE AND HYDROGEN IN THE PRESENCE OF THIS SYSTEM CATALYST. |
| FR2768725B1 (en) * | 1997-09-24 | 1999-11-12 | Solvay | PROCESS FOR THE PREPARATION OF 2-CHLOROPROP-1-ENE |
| FR2822459B1 (en) * | 2001-03-22 | 2004-07-09 | Solvay | PROCESS FOR THE PREPARATION OF A HALOGENATED OLEFIN |
-
2006
- 2006-12-22 FR FR0611356A patent/FR2910350B1/en not_active Expired - Fee Related
-
2007
- 2007-12-11 TW TW096147256A patent/TW200835553A/en unknown
- 2007-12-20 CN CNA2007800511293A patent/CN101605604A/en active Pending
- 2007-12-20 MX MX2009006776A patent/MX2009006776A/en not_active Application Discontinuation
- 2007-12-20 BR BRPI0720929-0A patent/BRPI0720929A2/en not_active IP Right Cessation
- 2007-12-20 US US12/520,497 patent/US20100063333A1/en not_active Abandoned
- 2007-12-20 AU AU2007338081A patent/AU2007338081A1/en not_active Abandoned
- 2007-12-20 RU RU2009128222/04A patent/RU2009128222A/en not_active Application Discontinuation
- 2007-12-20 EP EP07857901A patent/EP2101916A1/en not_active Withdrawn
- 2007-12-20 WO PCT/EP2007/064280 patent/WO2008077868A1/en not_active Ceased
- 2007-12-21 AR ARP070105880A patent/AR064514A1/en unknown
-
2009
- 2009-06-24 CO CO09065394A patent/CO6210696A2/en not_active Application Discontinuation
- 2009-07-02 ZA ZA200904659A patent/ZA200904659B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| TW200835553A (en) | 2008-09-01 |
| FR2910350A1 (en) | 2008-06-27 |
| ZA200904659B (en) | 2010-09-29 |
| BRPI0720929A2 (en) | 2014-04-01 |
| MX2009006776A (en) | 2009-07-06 |
| RU2009128222A (en) | 2011-01-27 |
| FR2910350B1 (en) | 2009-01-30 |
| EP2101916A1 (en) | 2009-09-23 |
| CO6210696A2 (en) | 2010-10-20 |
| CN101605604A (en) | 2009-12-16 |
| WO2008077868A1 (en) | 2008-07-03 |
| AU2007338081A1 (en) | 2008-07-03 |
| US20100063333A1 (en) | 2010-03-11 |
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