AR059885A1 - SELECTIVE INSECTICIDES BASED ON PHTALIC ACID DIAMIDS AND DETOXIFYING AGENTS - Google Patents

Abstract

Claim 1: Agent containing (a) at least one diamide of the phthalic acid of formula (1) in which Hal represents chlorine, bromine or iodine, * designates a carbon atom in the R or S configuration, preferably in the S configuration , and (b) at least one compound that improves phytotolerance in crop plants of the following group of compounds: 4-Dichloroacetyl-1-oxa-4-aza-spiro [4.5] -decane (AD-67, MON-4660) , 1-dichloroacetyl-hexahydro-3,3,8S-trimethylpyrrolo [1,2-a] -pyrimidin-6 (2H) -one (dicylonone, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3- methyl-2H-1,4-benzoxazine (benoxacor), ester, 1-methyl-hexyl of 5-chloro-quinolin-8-oxy-acetic acid (cloquintocet mexyl; see also the related compounds in EP-A-0086750 , EP-A-0094349, EP-A-0191736, EP-A-0492366), 3- (2-Chlorobenzyl) -1- (1-methyl-1-phenylethyl) -urea (cumiluron), alpha- (cyanomethoximine) -phenylacetonitrile (cyometrinyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), 4- (2,4-dichlorophenoxy) -butyri acid co (2,4-DB), 1- (1-methyl-1-phenylethyl) -3- (4-methylphenyl) -urea (daimuron, gave), 3,6-dichloro-2-methoxybenzoic acid (dicamba), S-1-methyl-1-phenylethyl ester of piperidin-1-thiocarboxylic acid (dimepiperate), 2,2-dichloro-N- (2-oxo-2- (2-propenylamino) -ethyl) -N- (2- propenyl) -acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenylacetamide (dichlormid), 4,6-dichloro-2-phenyl-pyrimidine (fenclorim), 1- ethyl acid ether (2,4-Dichloro-phenyl) -5-trichloromethyl-1H-1,2,4-triazol-3-carboxylic acid (pheclorazol ethyl; see also the related compounds in EP-A-0174562 and EP-A-0346620), phenylmethyl ester of 2-chloro-4-trifluoromethyl-thiazole-5-carboxylic acid (flurazole), 4-chloro-N- (1 , 3-dioxolan-2-yl-methoxy) -alpha-trifluoro-acetophenonoxime (fluxophenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyl-oxazolidine (furylazole, MON-13900), 4, Ethyl 5-dihydro-5,5-diphenyl-3-isoxazolcarboxylate (ethyl isoxadifen; see also related compounds in WO 95/07897), 3- (ethoxycarbonyl) -3,6-dichloro-2-methoxybenzoate (lactidichloro), (4-chloro-o-tolyloxy) -acetic acid (MCPA), 2- (4-chloro-o-tolyloxy) -propionic acid (mecoprop), 1- (2,4-dichlorophenyl) -4, Diethyl 5-dihydro-5-methyl-1H-pyrazol-3,5-dicarboxylate (mefenpyr diethyl; see also related compounds in WO 91/07874), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 1-oxa-4-azaspiro [4.5] 2-propenyl decane-4-carbodithioate (MG-838), 1,8-naphthalic acid anhydride, alpha- ( 1,3-dioxylan-2-yl-methoximino) -phenylacetonitrile (oxabentrinyl), 2,2-dichloro-N- (1,3-dioxolan-2-yl-methyl) -N- (2-propenyl) -acetamide ( PPG-1292), 3-dichloroacetyl-2,2-dimethyloxazolidine (R-28725), 3-dichloroacetyl-2,2,5-trimethyloxalidine (R-29148), 4- (4-chloro-o-tolyl) acid - butyric acid, 4- (4-chlorophenoxy) -butyric acid, diphenylmethoxyacetic acid, diphenylmethoxyacetic acid methyl ester, diphenylmethoxyacetic acid ethyl ester, 1- (2-chlorophenyl) -5-phenyl-1H-pyrazole-3- methyl ester carboxylic acid, 1- (2,4-dichlorophenyl) -5-methyl-1 H -pyrazol-3-carboxylic acid ethyl ester, 1- (2,4-dichlorophenyl) -5-isopropyl-1 H -pyrazol- 3-carboxylic acid, 1- (2,4-dichlorophenyl) -5- (1,1-dimethylethyl) -1 H- pyrazol-3-carboxylic acid ethyl ester, 1- (2,4-dichlorophenyl) - 5-phenyl-1H-pyrazol-3-carboxylic acid (see also the related compounds in EP-A-0269806 and EP-A-0333131), 5- (2-acid ethyl ester) , 4-dichlorobenzyl) -2-isoxazolin-3-carboxylic acid, 5-phenyl-2-isoxazolin-3-carboxylic acid ethyl ester, 5- (4-fluorophenyl) -5-phenyl-2-isoxazolin- acid ethyl ester 3-carboxylic acid (see related compounds in WO 91/08202), 1,3-dimethyl-but-1-yl ester of 5-chloroquinolin-8-oxyacetic acid, 4-allyloxybutyl ester of 5-chloroquinolin-8 acid -oxyacetic, 5-chloroquinolin-8-oxyacetic acid 1-allyloxypropyl-2-yl acid ester, 5-chloroquinoline-8-oxyacetic acid methyl ester, 5-chloroquinoline-8-oxyacetic acid ethyl ester, 5-allyl acidic ester -chloroquinolin-8-oxyacetic acid, 2-oxoprop-1-yl ester of 5-chloroquinolin-8-oxyacetic acid, diethyl ester of 5-chloroquinolin-8-oxyalonic acid, diallyl ester of 5-chloroquinolin-8-oximalonic acid, ester 5-chloroquinolin-8-oxyalonic acid diethyl (see also related compounds in EP-A-0582198), 4-carboxy-chroman-4- acid ilacetic (AC-304415, see EP-A-0613618), 4-chlorophenoxyacetic acid, 3,3'-dimethyl-4-methoxybenzophenone, 1-bromo-4-chloromethylsulfonylbenzene, 1- [4- (N- 2-Methoxybenzoylsulfamoyl) -phenyl] -3-methylurea (aka N- (2-methoxybenzoyl) -4 - [(methylaminocarbonyl) -amino] -benzenesulfonamide), 1- [4- (N-2- methoxybenzoylsulfamoyl) -phenyl] - 3,3-dimethylurea, 1- [4- (N-4,5-dimethyl-benzoylsulfamoyl) -phenyl] -3-methylurea, 1- [4- (N-naphthylsulfamoyl) -phenyl] -3,3-dimethylurea, N- (2-methoxy-5-methylbenzoyl) -4- (cyclopropylaminocarbonyl) -benzenesulfonamide, or a remainder of the group of formulas (2) in which r represents 0, 1, 2, 3, 4 or 5, A1D represents a of the divalent heterocyclic groupings of the group of formulas (3); s represents 0, 1, 2, 3, 4 or 5, A2D represents C1-2 alkanediyl, where appropriate substituted with C1-4 alkyl, C1-4 alkoxycarbonyl and / or C1-4 alkenyloxycarbonyl, R8D represents hydroxy, mercapto, amino, C1-6 alkoxy, C1-6 alkylthio, C1-6 alkylamino or di- (C1-4 alkyl) -amino, R9D represents hydroxy, mercapto, amino, C1-7 alkoxy, C1-6 alkenyloxy, C1- alkenyloxy 6-C 1-6 alkoxy, C 1-6 alkylthio, C 1-6 alkylamino or di- (C 1-4 alkyl) -amino, R 10 D represents C 1-4 alkyl, where appropriate substituted respectively with fluorine, chlorine and / or bromine, R11D represents hydrogen, C 1-6 alkyl, C 2-6 alkenyl or C 2-6 alkynyl, C 1-4 alkoxy, C 1-4 dioxolanylalkyl, furyl, C 1-4 furyl alkyl, thienyl, thiazolyl, piperidinyl given the case respectively substituted with fluorine, chlorine and / or bromine, or phenyl, if necessary substituted with fluorine, chlorine and / or bromine or C1-4 alkyl, R12D represents hydrogen or C1-6 alkyl, C2-6 alkenyl or C2-6 alkynyl , C1-4 alkoxy-C1-4 alkyl, dioxyl alkylalkyl C1-4, furyl, furyl C1-4 chyl, thienyl, thiazolyl, piperidinyl if substituted respectively with fluorine, chlorine and / or bromine, or phenyl if necessary substituted with fluorine, chlorine and / or bromine or C1-4 alkyl, R11d and R12D also together represent C3-6 alkanediyl or C2-5 oxaalkanediyl optionally substituted with C1-4 alkyl, phenyl, furyl, a condensed benzene ring or with two substituents which, together with the C atom to which they are attached, form a carbocycle of 5 or 6 members, R13D represents hydrogen, cyano, halogen, or C1-4 alkyl, C3-6 cycloalkyl or phenyl, respectively substituted with fluorine, chlorine and / or bromine, R14D represents hydrogen or C1-6 alkyl, C3 cycloalkyl -6 or tri- (C1-4 alkyl) -silyl substituted as appropriate with hydroxy, cyano, halogen or C1-4 alkoxy, R15D represents hydrogen, cyano, halogen or C1-4 alkyl, C3-6 cycloalkyl or phenyl given the case respectively substituted with fluorine, chlorine and / or bromine, X1D represents nitro, cyano, halogen, alq C1-4 uyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 haloalkoxy, X2D represents hydrogen, cyano, nitro, halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 haloalkoxy, X3D represents hydrogen, cyano, nitro, halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 haloalkoxy, and / or one of the following compounds of the general formulas (4), (5) in the that t represents 0, 1, 2, 3, 4 or 5, v represents 0, 1, 2, 3 or 4, R16D represents hydrogen or C1-4 alkyl, R17D represents hydrogen or C1-4 alkyl, R18D represents hydrogen or alkyl C 1-6, C 1-6 alkoxy, C 1-6 alkylthio, C 1-6 alkyl-amino or di- (C 1-4 alkyl) -amino, respectively substituted with cyano, halogen or C 1-4 alkoxy, or cycloalkyl C3-6, C3-6 cycloalkyloxy, C3-6 cycloalkylthio or C3-6-cycloalkyl, if substituted respectively with cyano, halogen or C1-4 alkyl, R19D represents hydrogen or C1-6 alkyl if necessary substituted with cyano , hydroxy, halogen or C1-4 alkoxy, or C3-6 alkenyl or alkyl C3-6 nyl, if necessary substituted respectively with cyano or halogen, or C3-6 cycloalkyl, if necessary substituted with cyano, halogen or C1-4alkyl, R20D represents hydrogen or C1-6alkyl, if necessary substituted with cyano, hydroxy, halogen or C1-4 alkoxy, or C3-6 alkenyl or C3-6 alkynyl if necessary respectively substituted with cyano or halogen, or C3-6 cycloalkyl, if necessary substituted with cyano, halogen or C1-4 alkyl, or phenyl if case substituted with nitro, cyano, halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 haloalkoxy, or represents together with R10D C2-6 alkanediyl or C2-5 oxaalkanediyl, respectively substituted respectively with alkyl C1-4, X4D represents nitro, cyano, carboxy, carbamoyl, formyl, sulfamoyl, hydroxy, amino, halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 haloalkoxy, and X5D represents nitro, cyano , carboxy, carbamoyl, formyl, sulfamoyl, hydroxy, amino, halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or ha C1-4 loalkoxy.