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AR056630A1 - Proceso de polimerizacion en fase semiliquida - Google Patents

Proceso de polimerizacion en fase semiliquida

Info

Publication number
AR056630A1
AR056630A1 ARP050104945A ARP050104945A AR056630A1 AR 056630 A1 AR056630 A1 AR 056630A1 AR P050104945 A ARP050104945 A AR P050104945A AR P050104945 A ARP050104945 A AR P050104945A AR 056630 A1 AR056630 A1 AR 056630A1
Authority
AR
Argentina
Prior art keywords
polymerization process
phase polymerization
diluent
loop reactor
olefin
Prior art date
Application number
ARP050104945A
Other languages
English (en)
Original Assignee
Ineos Mfg Belgium Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=33561438&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AR056630(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ineos Mfg Belgium Nv filed Critical Ineos Mfg Belgium Nv
Publication of AR056630A1 publication Critical patent/AR056630A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • B01J19/2435Loop-type reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/0004Processes in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • B01J2219/00166Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00243Mathematical modelling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • B01J2219/00247Fouling of the reactor or the process equipment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/918Polymerization reactors for addition polymer preparation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Structure Of Emergency Protection For Nuclear Reactors (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Se describe un proceso que comprende polimerizar un monomero de olefina en un reactor de bucle, opcionalmente en combinacion con un comonomero de olefina, en presencia de un catalizador de polimerizacion en un diluyente, para producir una fase semilíquida que comprende un polímero de olefina particulado solido y el diluyente, donde el numero de Froude se mantiene en un valor igual o menor que 20. Reivindicacion 21: Un reactor de bucle de construccion tubular continua caracterizado porque comprende al menos dos secciones horizontales y al menos dos secciones verticales, para poner en práctica un proceso como se indica en cualquiera de la reivindicaciones 1 a 20.
ARP050104945A 2004-11-26 2005-11-25 Proceso de polimerizacion en fase semiliquida AR056630A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0426058.4A GB0426058D0 (en) 2004-11-26 2004-11-26 Chemical process

Publications (1)

Publication Number Publication Date
AR056630A1 true AR056630A1 (es) 2007-10-17

Family

ID=33561438

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP050104945A AR056630A1 (es) 2004-11-26 2005-11-25 Proceso de polimerizacion en fase semiliquida

Country Status (21)

Country Link
US (6) US7632899B2 (es)
EP (3) EP2168676B1 (es)
JP (1) JP5497264B2 (es)
KR (1) KR101233961B1 (es)
CN (2) CN101065183B (es)
AR (1) AR056630A1 (es)
AT (1) ATE456590T1 (es)
AU (1) AU2005308589B2 (es)
BR (1) BRPI0517865A (es)
CA (1) CA2589175C (es)
DE (1) DE602005019199D1 (es)
EA (2) EA015946B1 (es)
ES (3) ES2665720T3 (es)
GB (1) GB0426058D0 (es)
MX (1) MX2007006293A (es)
MY (1) MY155902A (es)
PL (1) PL1827677T3 (es)
SG (1) SG157411A1 (es)
TW (1) TWI374148B (es)
WO (1) WO2006056761A1 (es)
ZA (1) ZA200703920B (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0426058D0 (en) * 2004-11-26 2004-12-29 Solvay Chemical process
GB0426059D0 (en) 2004-11-26 2004-12-29 Solvay Chemical process
ATE509041T1 (de) * 2006-05-22 2011-05-15 Borealis Tech Oy Verfahren zur herstellung von polyolefinen mit extra niedrigem gehalt an verunreinigungen
EP2156886A3 (en) 2006-05-26 2011-12-14 INEOS Manufacturing Belgium NV Slurry phase polymerisation process
EP2033976A1 (en) 2007-09-03 2009-03-11 INEOS Manufacturing Belgium NV Slurry phase polymerisation process
EP2110173A1 (en) 2008-04-16 2009-10-21 INEOS Manufacturing Belgium NV Polymer stream transfer
EA201290438A1 (ru) * 2009-12-18 2013-03-29 Тотал Петрокемикалс Рисерч Фелюй Способ получения суспензионной смеси катализаторов
WO2012084774A1 (en) * 2010-12-22 2012-06-28 Basell Polyolefine Gmbh Process for controlling the relative activity of active centers of catalyst systems comprising at least one late transition metal catalyst component and at least one ziegler catalyst component
RU2607086C2 (ru) * 2011-06-24 2017-01-10 Инеос Юроуп Аг Суспензионный способ полимеризации
WO2013039619A1 (en) 2011-09-16 2013-03-21 Exxonmobil Chemical Patents Inc. Loop reactor configuration for high capacity
US9789463B2 (en) * 2014-06-24 2017-10-17 Chevron Phillips Chemical Company Lp Heat transfer in a polymerization reactor
US10029230B1 (en) * 2017-01-24 2018-07-24 Chevron Phillips Chemical Company Lp Flow in a slurry loop reactor
US11180587B2 (en) * 2019-12-13 2021-11-23 Chevron Phillips Chemical Company Lp Polymerization of propylene
WO2024220786A1 (en) * 2023-04-20 2024-10-24 Braskem S.A. Process for polymerization of ethylene using a cooling system with a slurry-free heat exchanger

Family Cites Families (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3152872A (en) 1964-10-13 figure
US3172737A (en) 1965-03-09 Coolant
US1965980A (en) 1932-09-29 1934-07-10 Ibm Printing mechanism
FR751669A (fr) 1932-09-28 1933-09-07 Tabulating Machine Co Machine pour le triage de cartes perforées à points indicateurs, empilées, applicable aux machines tabulatrices
NL38497C (es) 1932-09-29
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3179087A (en) * 1960-08-30 1965-04-20 Kahn David Inc Writing instrument
US3405109A (en) * 1960-10-03 1968-10-08 Phillips Petroleum Co Polymerization process
US3257362A (en) 1960-11-21 1966-06-21 Phillips Petroleum Co Control of olefin polymerization reactions
US3203766A (en) 1961-07-06 1965-08-31 Phillips Petroleum Co Apparatus for the recovery of solids from pressure vessels
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3293000A (en) * 1962-10-05 1966-12-20 Phillips Petroleum Co Withdrawal of solids from a flowing stream comprising a slurry of same
US3229754A (en) * 1963-03-14 1966-01-18 Phillips Petroleum Co Heating and cooling temperature control system
US3324093A (en) 1963-10-21 1967-06-06 Phillips Petroleum Co Loop reactor
US3279087A (en) 1963-11-08 1966-10-18 Phillips Petroleum Co Solid polymer and liquid diluent separator apparatus and method
US3394093A (en) * 1965-04-01 1968-07-23 Mobil Oil Corp Water-soluble aminoplast resin produced by two stage process and combinations including the same
NL181435B (nl) * 1973-10-17 1900-01-01 Montedison Spa Werkwijze voor polymerisatie onder druk in een buisvormige reactor.
US4121029A (en) 1976-12-06 1978-10-17 Phillips Petroleum Company Polyolefin reactor system
US4424341A (en) * 1981-09-21 1984-01-03 Phillips Petroleum Company Separation of solid polymers and liquid diluent
US4613484A (en) 1984-11-30 1986-09-23 Phillips Petroleum Company Loop reactor settling leg system for separation of solid polymers and liquid diluent
DE3612376A1 (de) 1986-04-12 1987-10-15 Basf Ag Verfahren zum herstellen kleinteiliger homo- und copolymerisate des ethens unter verwendung eines fluessigen alkans als reaktionsmedium
CA2023745A1 (en) 1989-11-27 1991-05-28 Kelly E. Tormaschy Control of polymerization reaction
KR940009020B1 (ko) 1990-07-24 1994-09-29 미쓰이 도오아쓰 가가쿠 가부시키가이샤 α-올레핀의 중합촉매 및 그것을 이용한 폴리 α-올레핀의 제조방법
US5565175A (en) * 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
FI89929C (fi) 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
US5484862A (en) * 1995-03-10 1996-01-16 The Dow Chemical Company Liquid phase powder bed syndiotactic vinylaromatic polymerization
US20040136881A1 (en) 1997-07-15 2004-07-15 Verser Donald W. Separation of polymer particles and vaporized diluent in a cyclone
US6815511B2 (en) 1997-07-15 2004-11-09 Chevron Phillips Chemical Company, Lp Continuous withdrawal from high solids slurry polymerization
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
US7033545B2 (en) 1997-07-15 2006-04-25 Chevon Phillips Chemical Company, Lp Slurry polymerization reactor having large length/diameter ratio
US6329476B1 (en) * 1997-10-14 2001-12-11 Phillips Petroleum Company Olefin polymerization processes and products thereof
CN1166444C (zh) 1998-03-20 2004-09-15 埃克森美孚化学专利公司 浆液聚合中的挥发性物质的连续除去
KR100531628B1 (ko) 1998-03-20 2005-11-29 엑손모빌 케미칼 패턴츠 인코포레이티드 연속적인 슬러리 중합반응의 휘발물질 제거
US7268194B2 (en) 1998-03-20 2007-09-11 Exxonmobil Chemical Patents Inc. Continuous slurry polymerization process and apparatus
US6281300B1 (en) 1998-03-20 2001-08-28 Exxon Chemical Patents, Inc. Continuous slurry polymerization volatile removal
US20020111441A1 (en) 1998-03-20 2002-08-15 Kendrick James Austin Continuous slurry polymerization volatile removal
DE69918432T2 (de) 1998-05-18 2005-08-04 Exxonmobil Chemical Patents Inc., Baytown Kontinuierliche Entfernung von flüchtigen Stoffen in Dispersionspolymerisation
GB9822123D0 (en) * 1998-10-09 1998-12-02 Borealis As Catalyst
CA2379424A1 (en) * 1999-07-15 2001-01-25 Phillips Petroleum Company Slotted slurry take off
US6420497B1 (en) 1999-12-03 2002-07-16 Phillips Petroleum Company Solids concentration in slurry polymerization
KR100349071B1 (ko) 2000-02-02 2002-08-14 삼성종합화학주식회사 생성물 순환 방식을 이용한 신디오탁틱 스티렌계 중합체의제조방법
EP1195388A1 (en) 2000-10-04 2002-04-10 ATOFINA Research Process for producing bimodal polyethylene resins
ES2348659T3 (es) 2001-11-06 2010-12-10 Chevron Phillips Chemical Company Lp Eliminacion continua de suspension de polimerizacion.
KR20040091644A (ko) * 2002-02-19 2004-10-28 엑손모빌 케미칼 패턴츠 인코포레이티드 루프 반응기를 사용하는 연속적인 슬러리 중합 방법
WO2003074167A1 (en) 2002-02-28 2003-09-12 Exxonmobile Chemical Patents Inc. Continuous slurry polymerization process in a loop reactor
US6924340B2 (en) * 2002-04-04 2005-08-02 Equistar Chemicals L.P. Process for removal of intermediate hydrogen from cascaded polyolefin slurry reactors
MXPA05002807A (es) 2002-09-13 2005-12-05 Chevron Philips Chemical Compa Aparato con reactor de bucle y procedimientos de polimerizacion con multiples puntos de alimentacion para olefinas y catalizadores.
WO2004024781A1 (en) * 2002-09-13 2004-03-25 Chevron Phillips Chemical Company Lp Process and apparatus for reducing take-off valve plugging in a polymerization process
MXPA05002954A (es) 2002-09-16 2005-10-19 Chevron Phillips Chemical Co Procedimiento y sistema para remover particulas gruesas desde reciclaje diluyente hasta un reactor de polimerizacion de suspension.
ES2342932T3 (es) 2002-09-16 2010-07-19 Chevron Phillips Chemical Company Lp Dispositivo de alimentacion de una suspension de catalizador para un reactor de polimerizacion.
CA2498766C (en) 2002-09-17 2009-11-24 Chevron Phillips Chemical Company Lp Improved pumping apparatus and process for slurry polymerization in loop reactors
EP1415999B1 (en) 2002-10-30 2007-12-05 Borealis Technology Oy Process and apparatus for producing olefin polymers
BRPI0414467B1 (pt) 2003-09-24 2016-01-19 Basell Polyolefine Gmbh processo para a polimerização de pelo menos um monômero olefínico, e, reator de circuito fechado para a polimerização de monômeros olefínicos
PT1713842E (pt) 2004-02-13 2011-01-17 Total Petrochemicals Res Feluy Processo para a optimização da copolimerização do etileno e de um comonómero de olefina num reactor de polimerização de circulação
US20050272891A1 (en) * 2004-02-13 2005-12-08 Atofina Research S.A. Double loop technology
EP1611948A1 (en) * 2004-07-01 2006-01-04 Total Petrochemicals Research Feluy Polymerization reactors with a by-pass line
GB0426058D0 (en) 2004-11-26 2004-12-29 Solvay Chemical process
GB0426057D0 (en) 2004-11-26 2004-12-29 Solvay Chemical process
GB0426059D0 (en) * 2004-11-26 2004-12-29 Solvay Chemical process
US7547750B2 (en) 2005-10-05 2009-06-16 Chevron Phillips Chemical Company Lp Apparatus and method for removing polymer solids from slurry loop reactor
EP2156886A3 (en) * 2006-05-26 2011-12-14 INEOS Manufacturing Belgium NV Slurry phase polymerisation process

Also Published As

Publication number Publication date
JP5497264B2 (ja) 2014-05-21
CN101065183A (zh) 2007-10-31
US7790119B2 (en) 2010-09-07
TWI374148B (en) 2012-10-11
US7632899B2 (en) 2009-12-15
US20100329934A1 (en) 2010-12-30
EP2168676B1 (en) 2019-01-09
CN101065183B (zh) 2010-09-29
ES2665720T3 (es) 2018-04-26
GB0426058D0 (en) 2004-12-29
ZA200703920B (en) 2008-10-29
AU2005308589A1 (en) 2006-06-01
US20140179880A1 (en) 2014-06-26
MX2007006293A (es) 2007-07-11
TW200626619A (en) 2006-08-01
CN101885796B (zh) 2012-03-21
US20160060369A1 (en) 2016-03-03
CA2589175C (en) 2013-04-23
EP1827677B1 (en) 2010-01-27
EP2277621A3 (en) 2011-03-30
EA015946B1 (ru) 2011-12-30
WO2006056761A1 (en) 2006-06-01
CA2589175A1 (en) 2006-06-01
AU2005308589B2 (en) 2010-11-11
ES2340187T3 (es) 2010-05-31
DE602005019199D1 (de) 2010-03-18
MY155902A (en) 2015-12-15
EP2168676A1 (en) 2010-03-31
JP2008521960A (ja) 2008-06-26
BRPI0517865A (pt) 2008-10-21
EA200700981A1 (ru) 2007-12-28
EP1827677A1 (en) 2007-09-05
EP2277621A2 (en) 2011-01-26
PL1827677T3 (pl) 2010-05-31
EP2277621B1 (en) 2018-01-10
US9567408B2 (en) 2017-02-14
ES2719694T3 (es) 2019-07-12
EA012221B1 (ru) 2009-08-28
EA200900609A1 (ru) 2009-08-28
US20150148501A1 (en) 2015-05-28
US8927665B2 (en) 2015-01-06
SG157411A1 (en) 2009-12-29
US20080132656A1 (en) 2008-06-05
CN101885796A (zh) 2010-11-17
US20090232711A1 (en) 2009-09-17
US8580202B2 (en) 2013-11-12
US9212242B2 (en) 2015-12-15
KR20070084494A (ko) 2007-08-24
ATE456590T1 (de) 2010-02-15
KR101233961B1 (ko) 2013-02-15

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