AR047122A1 - ISOMERIZATION OF SEMICARBAZONA COMPOUNDS - Google Patents
ISOMERIZATION OF SEMICARBAZONA COMPOUNDSInfo
- Publication number
- AR047122A1 AR047122A1 ARP040104192A ARP040104192A AR047122A1 AR 047122 A1 AR047122 A1 AR 047122A1 AR P040104192 A ARP040104192 A AR P040104192A AR P040104192 A ARP040104192 A AR P040104192A AR 047122 A1 AR047122 A1 AR 047122A1
- Authority
- AR
- Argentina
- Prior art keywords
- isomer
- isomerization
- cycloalkyl
- compounds
- alkoxy
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C281/00—Derivatives of carbonic acid containing functional groups covered by groups C07C269/00 - C07C279/00 in which at least one nitrogen atom of these functional groups is further bound to another nitrogen atom not being part of a nitro or nitroso group
- C07C281/06—Compounds containing any of the groups, e.g. semicarbazides
- C07C281/08—Compounds containing any of the groups, e.g. semicarbazides the other nitrogen atom being further doubly-bound to a carbon atom, e.g. semicarbazones
- C07C281/14—Compounds containing any of the groups, e.g. semicarbazides the other nitrogen atom being further doubly-bound to a carbon atom, e.g. semicarbazones the carbon atom being further bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B57/00—Separation of optically-active compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la isomerizacion del isomero Z de compuestos de semicarbazona de la formula general (1) en su isomero E. Reivindicacion 1: Un procedimiento para la isomerizacion del isomero Z I-Z de un compuesto de la formula general (1) es su isomero E I-E, en donde m, p y q son cada uno un entero de 0, 1, 2, 3 o 4; R1, R2, R3 son cada uno independientemente halogeno; OH; CN; NO2; alquilo C1-6, opcionalmente sustituido con alcoxi C1-4, haloalcoxi C1-4 o cicloalquilo C3-6; haloalquilo C1- 6; cicloalquilo C3-6; alcoxi C1-6 opcionalmente sustituido con alcoxi C1-4 o cicloalquilo C3-6; haloalcoxi C1-6; alquilcarbonilo C1-6; cicloalcoxi C3-6; alcoxicarbonilo C1-6 o alcoxicarboniloxi C1-6; caracterizado porque el isomero Z I-Z o una mezcla de los estereoisomeros I-Z e I-E se reacciona en presencia de yodo.Procedure for the isomerization of the Z isomer of semicarbazone compounds of the general formula (1) in its isomer E. Claim 1: A procedure for the isomerization of the Z IZ isomer of a compound of the general formula (1) is its E IE isomer. , where m, p and q are each an integer of 0, 1, 2, 3 or 4; R1, R2, R3 are each independently halogen; OH; CN; NO2; C1-6 alkyl, optionally substituted with C1-4 alkoxy, C1-4 haloalkoxy or C3-6 cycloalkyl; C1-6 haloalkyl; C3-6 cycloalkyl; C1-6 alkoxy optionally substituted with C1-4 alkoxy or C3-6 cycloalkyl; C1-6 haloalkoxy; C1-6 alkylcarbonyl; C3-6 cycloalkoxy; C1-6 alkoxycarbonyl or C1-6 alkoxycarbonyloxy; characterized in that the Z I-Z isomer or a mixture of the I-Z and I-E stereoisomers is reacted in the presence of iodine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51962103P | 2003-11-14 | 2003-11-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR047122A1 true AR047122A1 (en) | 2006-01-11 |
Family
ID=34590435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP040104192A AR047122A1 (en) | 2003-11-14 | 2004-11-12 | ISOMERIZATION OF SEMICARBAZONA COMPOUNDS |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US7371885B2 (en) |
| EP (1) | EP1687263B1 (en) |
| JP (1) | JP4362517B2 (en) |
| KR (1) | KR20060134930A (en) |
| CN (1) | CN100417642C (en) |
| AR (1) | AR047122A1 (en) |
| AT (1) | ATE409689T1 (en) |
| AU (1) | AU2004289444A1 (en) |
| BR (1) | BRPI0416484A (en) |
| CA (1) | CA2545011A1 (en) |
| DE (1) | DE602004016879D1 (en) |
| DK (1) | DK1687263T3 (en) |
| EA (1) | EA200600888A1 (en) |
| ES (1) | ES2311880T3 (en) |
| IL (1) | IL175224A (en) |
| PL (1) | PL1687263T3 (en) |
| SI (1) | SI1687263T1 (en) |
| UA (1) | UA78662C2 (en) |
| WO (1) | WO2005047235A1 (en) |
| ZA (1) | ZA200604804B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2006257340A1 (en) | 2005-06-16 | 2006-12-21 | Basf Aktiengesellschaft | Use of phenylsemicarbazones for seed treatment |
| KR20110038081A (en) * | 2008-06-30 | 2011-04-13 | 바스프 에스이 | Isomerization Method of Semicarbazone Compound |
| US9125411B2 (en) * | 2010-04-15 | 2015-09-08 | Basf Se | UV absorbers for reducing the E/Z isomerization of pesticides |
| DE102010020882A1 (en) * | 2010-05-18 | 2011-11-24 | Alzchem Trostberg Gmbh | Semicarbazone for curing epoxy resins |
| DE102011118501A1 (en) * | 2011-11-15 | 2013-05-16 | Alzchem Ag | Alkyl or dialkyl semicarbazones as hardeners for epoxy resins |
| CN103193684B (en) * | 2013-04-08 | 2016-06-22 | 杭州宇龙化工有限公司 | A kind of preparation method of semicarbazones |
| CN103342666A (en) * | 2013-07-18 | 2013-10-09 | 桂林理工大学 | Synthetic method of 3-ethoxysalicylaldehyde carbohydrazide bis-Schiff base |
| CN104592059B (en) * | 2015-01-07 | 2016-07-06 | 青岛农业大学 | 3-acylhydrazone diphenylurea derivatives and their preparation methods and applications |
| CN105037331B (en) * | 2015-06-17 | 2018-02-09 | 浙江科技学院 | The preparation method of Rosuvastatin intermediate |
| CN106674069B (en) * | 2016-12-06 | 2018-05-11 | 上海博志研新药物技术有限公司 | The preparation method of GFT505 and its intermediate |
| CN108129358B (en) * | 2018-02-05 | 2020-03-24 | 扬州工业职业技术学院 | Clean and efficient metaflumizone synthesis process |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3136794A (en) * | 1962-02-02 | 1964-06-09 | Pfizer & Co C | Stabilization of iodine isomerized vitamin a esters |
| NL131506C (en) * | 1966-01-28 | 1900-01-01 | ||
| ES2089056T3 (en) | 1990-06-16 | 1996-10-01 | Nihon Nohyaku Co Ltd | DERIVATIVES OF HYDRAZINCARBOXAMIDE, A PROCEDURE FOR THE PRODUCTION OF THE SAME, AND USES OF THE SAME. |
| JP5093429B2 (en) * | 2000-10-18 | 2012-12-12 | 日本農薬株式会社 | Animal ectoparasite pest control agent and method of use |
| AR048177A1 (en) * | 2004-03-17 | 2006-04-05 | Basf Ag | PREPARATION OF SEMICARBAZONAS AND AN INTERMEDIARY COMPOUND OF HIDRAZONA. |
-
2004
- 2004-11-12 ES ES04818397T patent/ES2311880T3/en not_active Expired - Lifetime
- 2004-11-12 CN CNB2004800333644A patent/CN100417642C/en not_active Expired - Lifetime
- 2004-11-12 AT AT04818397T patent/ATE409689T1/en not_active IP Right Cessation
- 2004-11-12 EP EP04818397A patent/EP1687263B1/en not_active Expired - Lifetime
- 2004-11-12 KR KR1020067009271A patent/KR20060134930A/en not_active Abandoned
- 2004-11-12 SI SI200430877T patent/SI1687263T1/en unknown
- 2004-11-12 BR BRPI0416484-9A patent/BRPI0416484A/en not_active IP Right Cessation
- 2004-11-12 DE DE602004016879T patent/DE602004016879D1/en not_active Expired - Lifetime
- 2004-11-12 WO PCT/EP2004/012872 patent/WO2005047235A1/en not_active Ceased
- 2004-11-12 EA EA200600888A patent/EA200600888A1/en unknown
- 2004-11-12 JP JP2006538809A patent/JP4362517B2/en not_active Expired - Fee Related
- 2004-11-12 CA CA002545011A patent/CA2545011A1/en not_active Abandoned
- 2004-11-12 DK DK04818397T patent/DK1687263T3/en active
- 2004-11-12 AU AU2004289444A patent/AU2004289444A1/en not_active Abandoned
- 2004-11-12 PL PL04818397T patent/PL1687263T3/en unknown
- 2004-11-12 US US10/578,465 patent/US7371885B2/en not_active Expired - Fee Related
- 2004-11-12 AR ARP040104192A patent/AR047122A1/en unknown
- 2004-12-11 UA UAA200606379A patent/UA78662C2/en unknown
-
2006
- 2006-04-26 IL IL175224A patent/IL175224A/en active IP Right Grant
- 2006-06-12 ZA ZA200604804A patent/ZA200604804B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR20060134930A (en) | 2006-12-28 |
| EP1687263B1 (en) | 2008-10-01 |
| UA78662C2 (en) | 2007-04-10 |
| US7371885B2 (en) | 2008-05-13 |
| IL175224A0 (en) | 2006-09-05 |
| HK1099276A1 (en) | 2007-08-10 |
| AU2004289444A1 (en) | 2005-05-26 |
| SI1687263T1 (en) | 2008-12-31 |
| JP2007511483A (en) | 2007-05-10 |
| ZA200604804B (en) | 2007-11-28 |
| BRPI0416484A (en) | 2007-03-27 |
| PL1687263T3 (en) | 2009-04-30 |
| CN100417642C (en) | 2008-09-10 |
| ATE409689T1 (en) | 2008-10-15 |
| DE602004016879D1 (en) | 2008-11-13 |
| CN1878752A (en) | 2006-12-13 |
| DK1687263T3 (en) | 2009-02-02 |
| IL175224A (en) | 2010-11-30 |
| WO2005047235A1 (en) | 2005-05-26 |
| JP4362517B2 (en) | 2009-11-11 |
| EP1687263A1 (en) | 2006-08-09 |
| EA200600888A1 (en) | 2006-10-27 |
| US20070135520A1 (en) | 2007-06-14 |
| CA2545011A1 (en) | 2005-05-26 |
| ES2311880T3 (en) | 2009-02-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |