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AR046763A1 - Compuestos de haloalqueno, proceso para su produccion y pesticidas que los contienen - Google Patents

Compuestos de haloalqueno, proceso para su produccion y pesticidas que los contienen

Info

Publication number
AR046763A1
AR046763A1 ARP040104640A ARP040104640A AR046763A1 AR 046763 A1 AR046763 A1 AR 046763A1 AR P040104640 A ARP040104640 A AR P040104640A AR P040104640 A ARP040104640 A AR P040104640A AR 046763 A1 AR046763 A1 AR 046763A1
Authority
AR
Argentina
Prior art keywords
alkyl
formula
compound represented
substituted
phenylalkyl
Prior art date
Application number
ARP040104640A
Other languages
English (en)
Original Assignee
Ishihara Sangyo Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ishihara Sangyo Kaisha filed Critical Ishihara Sangyo Kaisha
Publication of AR046763A1 publication Critical patent/AR046763A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C07C381/06—Compounds containing sulfur atoms only bound to two nitrogen atoms
    • C07C381/08—Compounds containing sulfur atoms only bound to two nitrogen atoms having at least one of the nitrogen atoms acylated
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/22—O-Aryl or S-Aryl esters thereof
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/45—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups
    • C07C233/46—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/49—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a carbon atom of an acyclic unsaturated carbon skeleton
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    • C07C233/90—Carboxylic acid amides having nitrogen atoms of carboxamide groups further acylated
    • C07C233/91—Carboxylic acid amides having nitrogen atoms of carboxamide groups further acylated with carbon atoms of the carboxamide groups bound to acyclic carbon atoms
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    • C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
    • C07C243/26—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms
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    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/57—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/62—Compounds containing any of the groups, X being a hetero atom, Y being any atom, e.g. N-acylcarbamates
    • C07C271/64—Y being a hydrogen or a carbon atom, e.g. benzoylcarbamates
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    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/46—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
    • C07C275/48—Y being a hydrogen or a carbon atom
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    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/08—Sulfenic acids; Derivatives thereof
    • C07C313/18—Sulfenamides
    • C07C313/26—Compounds containing any of the groups, X being a hetero atom, Y being any atom
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    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
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  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
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  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Pyridine Compounds (AREA)

Abstract

Un pesticida que contiene al compuesto de haloalqueno como principio activo un insecticida que lo contiene para controlar ácaros y nematodos y un método para controlar una peste. Reivindicación 1: Un compuesto de haloalqueno representado mediante la formula (1) o su sal: en la cual cada uno de X1 y X2 es halógeno; Y es alquilo, haloalquilo o fenilo; n es de 0 a 5; L es -C(=B)Q, -C(=B)B'Q, -C(=B)N(D)Q, -N(D)Q, -N(D)C(=B)Q, -N(D)C(=B)B'Q,-N(D)SO2Q, -N=CHQ, -N=C(Q)2,-SO2Q, -SO2N(D)Q o alquilo sustituido con J (el alquilo puede ser adicionalmente sustituido con otros sustituyentes); J es -C(=B)B'Q, -C(=B)N(D)Q, -SO2Q o -SO2N(D)Q; cada uno de G y D es un átomo de hidrógeno, alquilo, haloalquilo, fenilalquilo, alquenilo, haloalquenilo, fenialquelino, alquinilo, haloalquinilo, fenilalquinilo, -C(=B)Q, -C(=B)B'Q, -C(=B)N(G')Q, -SQ, -SO2Q, -SN(G')Q, -SN(G')C(=B)B'Q o -SO2N(G')Q; G' es alquilo, haloalquilo, fenilalquilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo; cada uno de A, B y B' es un átomo de oxigeno o un átomo de azufre; Q es alquilo el cual puede estar sustituido, alquenilo el cual puede estar sustituido, alquinilo el cual puede estar sustituido, un grupo hidrocarburo cíclico el cual puede estar sustituido, o un grupo heterocíclico de 5 a 12 miembros (el grupo heterocíclico puede estar sustituido) que contiene un heteroátomo opcional seleccionado entre un átomo de oxigeno, un átomo de azufre y un átomo de nitrógeno. Reivindicación 9: Un proceso para producir un compuesto de haloalqueno representado mediante la formula (1) o su sal: en la cual cada uno de X1 y X2 es halógeno; Y es alquilo, haloalquilo o fenilo; n es de 0 a 5; L es -C(B)Q, -C(=B)B'Q, - C(=B)N(D)Q, -N(D)Q, -N(D)C(=B)Q, -N(D)C(=B)B'Q, -N(D)SO2Q, -N=CHQ, -N=C(Q)2, -SO2Q, -SO2N(D)Q o alquilo sustituido con J (el alquilo puede ser adicionalmente sustituido con otros sustituyentes); J es -C(=B)B'Q, -C(=B)N(D)Q, -SO2Q o -SO2N(D)Q; cada uno de G y D es un átomo de hidrógeno, alquilo, haloalquilo, fenilalquilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo, fenilalquinilo, -C(=B)Q, -C(=B)B'Q, -C(=B)N(G')Q, -SQ, -SO2Q, -SN(G')Q, -SN(G')C(=B)B'Q o -SO2N(G')Q; G' es alquilo, haloalquilo, fenilalquilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo; cada uno de A, B y B' es un átomo de oxigeno o un átomo de azufre; Q es alquilo el cual puede estar sustituido, alquenilo el cual puede estar sustituido, alquinilo el cual puede estar sustituido, un grupo hidrocarburo cíclico el cual puede estar sustituido, o un grupo heterocíclico de 5 a 12 miembros (el grupo heterocíclico puede estar sustituido) que contiene un heteroátomo opcional seleccionado entre un átomo de oxigeno, un átomo de azufre y un átomo de nitrógeno, que comprende (i) hacer reaccionar un compuesto representado mediante la formula (2) en la cual X1, X2, Y, n y A son según lo definido previamente, con un compuesto representado mediante la formula (3) o su sal: en la cual L y G son según lo definido previamente; o (ii) hacer reaccionar un compuesto representado mediante la formula (4) en la cual X1, X2, Y, n y A son según lo definido previamente, y T es un átomo de oxígeno o un átomo de azufre, con un compuesto representado mediante la formula (3) o su sal en la cual L y G son según lo definido previamente; o (iii) hacer reaccionar un compuesto representado mediante la formula (5) en la cual X1, X2, Y, n, A y T son según lo definido previamente, y Z es alquilo C1-4, con un compuesto representado mediante la formula (3) o su sal en la cual L y G son según lo definido previamente; o (iv) hacer reaccionar un compuesto representado mediante la formula (6) en la cual X1, X2, Y, n, L y A son según lo definido previamente, con un compuesto representado mediante la formula: G1-X3 en la cual G1 es alquilo, haloalquilo, fenilalquilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, halolquinilo, fenilalquinilo, -C(=B)Q, -C(=B)B'Q, -C(=B)N(G')Q, -SQ, -SO2Q, -SN(G')Q, -SN(G')C(=B)B'Q o -SO2N(G')Q, X3 es halógeno, y B, Q y G' son según lo definido previamente; o (v) hacer reaccionar un compuesto representado mediante la formula (6) en la cual X1, X2, Y, n, L, A son según lo definido previamente, con un compuesto representado mediante la formula: G2-OSO2-U en la cual G2 es alquilo, U es alquilo, haloalquilo, alcoxi, fenilo, fenilo sustituido con halógeno, o fenilo sustituido con alquilo, o (vi) hacer reaccionar un compuesto representado mediante la formula (7) en la cual X1, X2, Y, n, L y G son según lo definido previamente, con un agente tionizante; o (vii) hacer reaccionar un compuesto representado mediante la formula (8) o su sal en la cual X1, X2, Y, n, A, y G son según lo definido previamente, con un compuesto representado mediante la formula CI-E, en la cual E es -C(=B)Q, -C(=B)B'Q, -C(=B)N(D)Q, -SO2Q o -SO2N(D)Q, y D, B, B' y Q son según lo definido previamente, o con un compuesto representado mediante la formula B=C=N-Q (en la cual B y Q son según lo definido previamente).
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