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AR030905A1 - Un catalizador de hidrodesmetalizacion y el metodo de elaboracion del mismo - Google Patents

Un catalizador de hidrodesmetalizacion y el metodo de elaboracion del mismo

Info

Publication number
AR030905A1
AR030905A1 ARP010104854A ARP010104854A AR030905A1 AR 030905 A1 AR030905 A1 AR 030905A1 AR P010104854 A ARP010104854 A AR P010104854A AR P010104854 A ARP010104854 A AR P010104854A AR 030905 A1 AR030905 A1 AR 030905A1
Authority
AR
Argentina
Prior art keywords
catalyst
hydrodesmetalization
same
pores
particles
Prior art date
Application number
ARP010104854A
Other languages
English (en)
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of AR030905A1 publication Critical patent/AR030905A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Se revela un catalizador para la hidrodesmetalizacion de una corriente de hidrocarburo pesada que comprende partículas de un soporte de alumina que tiene una distribucion bimodal del tamano de poro y cantidades catalíticamente activas de metal del Grupo VIB distribuidas de manera uniforme a través y sobre la superficie de las partículas, donde por lo menos el 20% del volumen total de poros contenidos en dicho catalizador es en poros que tiene un diámetro de poro de por lo menos 1000 A y donde por lo menos el 50% del volumen total de poros contenidos en dicho catalizador es en poros que tienen un diámetro de poro no mayor que 350 A. Se revela también un método para la elaboracion de dicho catalizador y un proceso para separar los metales de una corriente de hidrocarburo pesado utilizando dicho catalizador.
ARP010104854A 2000-10-19 2001-10-17 Un catalizador de hidrodesmetalizacion y el metodo de elaboracion del mismo AR030905A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US69272600A 2000-10-19 2000-10-19

Publications (1)

Publication Number Publication Date
AR030905A1 true AR030905A1 (es) 2003-09-03

Family

ID=24781759

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP010104854A AR030905A1 (es) 2000-10-19 2001-10-17 Un catalizador de hidrodesmetalizacion y el metodo de elaboracion del mismo

Country Status (3)

Country Link
AR (1) AR030905A1 (es)
AU (1) AU2002215374A1 (es)
WO (1) WO2002032570A2 (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6589908B1 (en) * 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
US8025794B2 (en) 2003-12-19 2011-09-27 Shell Oil Company Systems, methods, and catalysts for producing a crude product
CA2659797C (en) 2006-08-03 2015-02-10 Shell Internationale Research Maatschappij B.V. A catalyst and process for the manufacture of ultra-low sulfur distillate product
US7820036B2 (en) 2006-08-03 2010-10-26 Shell Oil Company Highly stable heavy hydrocarbon hydrodesulfurization catalyst and methods of making and use thereof
US7977274B2 (en) 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
MX2007009504A (es) * 2007-08-07 2009-02-06 Mexicano Inst Petrol Catalizador para la primera etapa de hidrodesmetalizacion en un sistema de hidro procesamiento con reactores multiples para el mejoramiento de crudos pesados y extra-pesados.
US8734634B2 (en) 2008-04-10 2014-05-27 Shell Oil Company Method for producing a crude product, method for preparing a diluted hydrocarbon composition, crude products, diluents and uses of such crude products and diluents
US8114806B2 (en) * 2008-04-10 2012-02-14 Shell Oil Company Catalysts having selected pore size distributions, method of making such catalysts, methods of producing a crude product, products obtained from such methods, and uses of products obtained
NZ591675A (en) 2008-09-10 2012-01-12 Haldor Topsoe As Process for manufacturing hydrocarbon fuel from a mixture of a fossil hydrocarbon fuel and biomass utilising a molybdenum catalyst
US10603656B2 (en) 2013-10-17 2020-03-31 Shell Oil Company Ultra-stable heavy hydrocarbon hydroprocessing catalyst and methods of making and use thereof
CN104549329B (zh) * 2013-10-22 2016-08-17 中国石油化工股份有限公司 加氢脱金属催化剂的制备方法
CN110773179A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种氧化铝载体及其制备方法
CN110773187A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种重油加氢脱沥青质催化剂及其制备与应用
CN110773188A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种重油加氢脱沥青质催化剂及其制备与应用
CN110773190A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种重油加氢脱沥青质催化剂及其制备与应用
CN110773183A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种重油加氢脱沥青质催化剂及其制备与应用
CN110773209A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种重油加氢脱沥青质催化剂及其制备与应用
CN112547079A (zh) * 2019-09-25 2021-03-26 中国石油化工股份有限公司 一种重油加氢处理催化剂及其应用
CN116020498B (zh) * 2021-10-27 2024-10-15 中国石油化工股份有限公司 加氢催化剂的制备方法、由该方法制备的催化剂及应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4294685A (en) * 1979-03-13 1981-10-13 Electric Power Research Institute, Inc. Process for coal liquefaction and catalyst
US4526675A (en) * 1983-05-26 1985-07-02 Standard Oil Company (Indiana) Hydrocarbon conversion method
US4846961A (en) * 1986-12-05 1989-07-11 Union Oil Company Of California Hydroprocessing catalyst with a Ni-P-Mo
US4880525A (en) * 1987-09-24 1989-11-14 Shell Oil Company Process for hydrotreating hydrocarbon feeds
MY109378A (en) * 1992-08-18 1997-01-31 Shell Int Research Process for the preparation of a catalyst for a catalyst precursor

Also Published As

Publication number Publication date
WO2002032570A3 (en) 2002-08-29
WO2002032570A2 (en) 2002-04-25
AU2002215374A1 (en) 2002-04-29

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